Synthesis and Reactivity of Paramagnetic Nickel Polypyridyl Complexes Relevant to C(sp 2 )–C(sp 3 )Coupling Reactions

Mohadjer Beromi, Megan; Brudvig, Gary W.; Hazari, Nilay; Lant, Hannah M. C.; Mercado, Brandon Q.

doi:10.1002/ange.201901866

Title: Synthesis and Reactivity of Paramagnetic Nickel Polypyridyl Complexes Relevant to C(sp ² )–C(sp ³ )Coupling Reactions

Journal Article · 26 March 2019 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.201901866 · OSTI ID:1503721

Mohadjer Beromi, Megan ^[1]; Brudvig, Gary W. ^[1];

^[1]; Lant, Hannah M. C. ^[1]; Mercado, Brandon Q. ^[1]

The Department of Chemistry Yale University P.O. Box 208107 New Haven CT 06520 USA

Abstract A number of new transition metal catalyzed methods for the formation of C(sp ² )–C(sp ³ ) bonds have recently been described. These reactions often utilize bidentate polypyridyl‐ligated Ni catalysts, and paramagnetic Ni ^I halide or aryl species are proposed in the catalytic cycles. However, there is little knowledge about complexes of this type. Here, we report the synthesis of paramagnetic bidentate polypyridyl‐ligated Ni halide and aryl complexes through elementary reactions proposed in catalytic cycles for C(sp ² )–C(sp ³ ) bond formation. We investigate the ability of these complexes to undergo organometallic reactions that are relevant to C(sp ² )–C(sp ³ ) coupling through stoichiometric studies and also explore their catalytic activity.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-05ER15646

OSTI ID:: 1503721

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 18 Vol. 131; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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