The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

Dumas, Thomas; Guillaumont, Dominique; Moisy, Philippe; Shuh, David K.; Tyliszczak, Tolek; Solari, Pier Lorenzo; Den Auwer, Christophe

doi:10.1039/c8cc05176c

Title: The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

Journal Article · 25 September 2018 · ChemComm

DOI: https://doi.org/10.1039/c8cc05176c · OSTI ID:1503653

^[1];

^[2]; Tyliszczak, Tolek ^[2]; Solari, Pier Lorenzo ^[3];

^[4]

CEA, Bagnols-sur-Ceze (France)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Synchrotron SOLEILL'Orme des Merisiers, Gif-sur-Yvette Cedex (France)
CEA, Bagnols-sur-Ceze (France); Univ. Cote d'Azur, Nice (France)

In molecular solids derived from Prussian blue, intermetallic charge transfer is fostered through a cyano bridge two metal ions. In this paper, isostructural trivalent lanthanide and tetravalent actinide Prussian blue analogs' valence orbitals are probed by soft X-ray absorption measurements.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1503653

Journal Information:: ChemComm, Vol. 54, Issue 86; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 3 works

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