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Title: The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy

In molecular solids derived from Prussian blue, intermetallic charge transfer is fostered through a cyano bridge two metal ions. In this paper, isostructural trivalent lanthanide and tetravalent actinide Prussian blue analogs' valence orbitals are probed by soft X-ray absorption measurements.
Authors:
ORCiD logo [1] ; ORCiD logo [1] ; ORCiD logo [1] ; ORCiD logo [2] ;  [2] ;  [3] ; ORCiD logo [4]
  1. CEA, Bagnols-sur-Ceze (France)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  3. Synchrotron SOLEILL'Orme des Merisiers, Gif-sur-Yvette Cedex (France)
  4. CEA, Bagnols-sur-Ceze (France); Univ. Cote d'Azur, Nice (France)
Publication Date:
Grant/Contract Number:
AC02-05CH11231
Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 54; Journal Issue: 86; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Research Org:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1503653

Dumas, Thomas, Guillaumont, Dominique, Moisy, Philippe, Shuh, David K., Tyliszczak, Tolek, Solari, Pier Lorenzo, and Den Auwer, Christophe. The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy. United States: N. p., Web. doi:10.1039/c8cc05176c.
Dumas, Thomas, Guillaumont, Dominique, Moisy, Philippe, Shuh, David K., Tyliszczak, Tolek, Solari, Pier Lorenzo, & Den Auwer, Christophe. The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy. United States. doi:10.1039/c8cc05176c.
Dumas, Thomas, Guillaumont, Dominique, Moisy, Philippe, Shuh, David K., Tyliszczak, Tolek, Solari, Pier Lorenzo, and Den Auwer, Christophe. 2018. "The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy". United States. doi:10.1039/c8cc05176c.
@article{osti_1503653,
title = {The electronic structure of f-element Prussian blue analogs determined by soft X-ray absorption spectroscopy},
author = {Dumas, Thomas and Guillaumont, Dominique and Moisy, Philippe and Shuh, David K. and Tyliszczak, Tolek and Solari, Pier Lorenzo and Den Auwer, Christophe},
abstractNote = {In molecular solids derived from Prussian blue, intermetallic charge transfer is fostered through a cyano bridge two metal ions. In this paper, isostructural trivalent lanthanide and tetravalent actinide Prussian blue analogs' valence orbitals are probed by soft X-ray absorption measurements.},
doi = {10.1039/c8cc05176c},
journal = {ChemComm},
number = 86,
volume = 54,
place = {United States},
year = {2018},
month = {9}
}

Works referenced in this record:

The Color and Electronic Configurations of Prussian Blue
journal, May 1962