Gas-Diffusion Electrodes for Carbon Dioxide Reduction: A New Paradigm

Higgins, Drew; Hahn, Christopher; Xiang, Chengxiang; Jaramillo, Thomas F.; Weber, Adam Z.

doi:10.1021/acsenergylett.8b02035

Title: Gas-Diffusion Electrodes for Carbon Dioxide Reduction: A New Paradigm

Journal Article · 14 December 2018 · ACS Energy Letters

DOI: https://doi.org/10.1021/acsenergylett.8b02035 · OSTI ID:1503644

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Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
California Inst. of Technology (CalTech), Pasadena, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Here significant advances have been made in recent years discovering new electrocatalysts and developing a fundamental understanding of electrochemical CO₂ reduction processes. This field has progressed to the point that efforts can now focus on translating this knowledge toward the development of practical CO₂ electrolyzers, which have the potential to replace conventional petrochemical processes as a sustainable route to produce fuels and chemicals. In this Perspective, we take a critical look at the progress in incorporating electrochemical CO₂ reduction catalysts into practical device architectures that operate using vapor-phase CO₂ reactants, thereby overcoming intrinsic limitations of aqueous-based systems. Performance comparison is made between state-of-the-art CO₂ electrolyzers and commercial H₂O electrolyzers—a well-established technology that provides realistic performance targets. Beyond just higher rates, vapor-fed reactors represent new paradigms for unprecedented control of local reaction conditions, and we provide a perspective on the challenges and opportunities for generating fundamental knowledge and achieving technological progress toward the development of practical CO₂ electrolyzers.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-76SF00515; NRF-2017R1A6A3A03006971

OSTI ID:: 1503644

Journal Information:: ACS Energy Letters, Vol. 4, Issue 1; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 351 works

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