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Title: Mn IV -Oxo complex of a bis(benzimidazolyl)-containing N5 ligand reveals different reactivity trends for Mn IV -oxo than Fe IV -oxo species

Investigations of a Mn IV -oxo adduct supported by an N5 ligand with mixed pyridyl and benzimidazolyl ligation uncovers distinct reactivity trends for Mn IV -oxo and Fe IV -oxo adducts at parity of coordination sphere.
Authors:
 [1] ;  [1] ;  [2] ;  [1] ;  [2] ;  [1] ; ORCiD logo [2] ; ORCiD logo [1]
  1. The University of Kansas, Department of Chemistry and Center for Environmentally Beneficial Catalysis, Lawrence, USA
  2. Lund University, Chemical Physics, Department of Chemistry, SE-221 00 Lund, Sweden
Publication Date:
Grant/Contract Number:
SC0016359; AC02-76SF00515; SC0012704
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 48 Journal Issue: 15; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1503397

Denler, Melissa C., Massie, Allyssa A., Singh, Reena, Stewart-Jones, Eleanor, Sinha, Arup, Day, Victor W., Nordlander, Ebbe, and Jackson, Timothy A.. Mn IV -Oxo complex of a bis(benzimidazolyl)-containing N5 ligand reveals different reactivity trends for Mn IV -oxo than Fe IV -oxo species. United Kingdom: N. p., Web. doi:10.1039/C9DT00308H.
Denler, Melissa C., Massie, Allyssa A., Singh, Reena, Stewart-Jones, Eleanor, Sinha, Arup, Day, Victor W., Nordlander, Ebbe, & Jackson, Timothy A.. Mn IV -Oxo complex of a bis(benzimidazolyl)-containing N5 ligand reveals different reactivity trends for Mn IV -oxo than Fe IV -oxo species. United Kingdom. doi:10.1039/C9DT00308H.
Denler, Melissa C., Massie, Allyssa A., Singh, Reena, Stewart-Jones, Eleanor, Sinha, Arup, Day, Victor W., Nordlander, Ebbe, and Jackson, Timothy A.. 2019. "Mn IV -Oxo complex of a bis(benzimidazolyl)-containing N5 ligand reveals different reactivity trends for Mn IV -oxo than Fe IV -oxo species". United Kingdom. doi:10.1039/C9DT00308H.
@article{osti_1503397,
title = {Mn IV -Oxo complex of a bis(benzimidazolyl)-containing N5 ligand reveals different reactivity trends for Mn IV -oxo than Fe IV -oxo species},
author = {Denler, Melissa C. and Massie, Allyssa A. and Singh, Reena and Stewart-Jones, Eleanor and Sinha, Arup and Day, Victor W. and Nordlander, Ebbe and Jackson, Timothy A.},
abstractNote = {Investigations of a Mn IV -oxo adduct supported by an N5 ligand with mixed pyridyl and benzimidazolyl ligation uncovers distinct reactivity trends for Mn IV -oxo and Fe IV -oxo adducts at parity of coordination sphere.},
doi = {10.1039/C9DT00308H},
journal = {Dalton Transactions},
number = 15,
volume = 48,
place = {United Kingdom},
year = {2019},
month = {4}
}

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