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Title: Full Dissolution of the Whole Lithium Sulfide Family (Li 2 S 8 to Li 2 S) in a Safe Eutectic Solvent for Rechargeable Lithium-Sulfur Batteries

Authors:
ORCiD logo [1];  [1];  [2];  [3];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [2]; ORCiD logo [1]
  1. Program of Materials Science and Engineering, Department of Applied Physics and Applied Mathematics, Columbia University, 500 W 120th St New York NY 10027 USA
  2. Department of Mechanical Engineering, The State University of New York, Binghamton, 85 Murray Hill Rd. Suite 1300, Rm#1320 Binghamton NY 13902 USA
  3. Langmuir Center of Colloids and Interfaces, Columbia University, 500 W 120th St New York NY 10027 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1503350
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie (International Edition)
Additional Journal Information:
Journal Name: Angewandte Chemie (International Edition); Journal ID: ISSN 1433-7851
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Cheng, Qian, Xu, Weiheng, Qin, Shiyi, Das, Subhabrata, Jin, Tianwei, Li, Aijun, Li, Alex Ceng, Qie, Boyu, Yao, Pengcheng, Zhai, Haowei, Shi, Changmin, Yong, Xin, and Yang, Yuan. Full Dissolution of the Whole Lithium Sulfide Family (Li 2 S 8 to Li 2 S) in a Safe Eutectic Solvent for Rechargeable Lithium-Sulfur Batteries. Germany: N. p., 2019. Web. doi:10.1002/anie.201812611.
Cheng, Qian, Xu, Weiheng, Qin, Shiyi, Das, Subhabrata, Jin, Tianwei, Li, Aijun, Li, Alex Ceng, Qie, Boyu, Yao, Pengcheng, Zhai, Haowei, Shi, Changmin, Yong, Xin, & Yang, Yuan. Full Dissolution of the Whole Lithium Sulfide Family (Li 2 S 8 to Li 2 S) in a Safe Eutectic Solvent for Rechargeable Lithium-Sulfur Batteries. Germany. doi:10.1002/anie.201812611.
Cheng, Qian, Xu, Weiheng, Qin, Shiyi, Das, Subhabrata, Jin, Tianwei, Li, Aijun, Li, Alex Ceng, Qie, Boyu, Yao, Pengcheng, Zhai, Haowei, Shi, Changmin, Yong, Xin, and Yang, Yuan. Tue . "Full Dissolution of the Whole Lithium Sulfide Family (Li 2 S 8 to Li 2 S) in a Safe Eutectic Solvent for Rechargeable Lithium-Sulfur Batteries". Germany. doi:10.1002/anie.201812611.
@article{osti_1503350,
title = {Full Dissolution of the Whole Lithium Sulfide Family (Li 2 S 8 to Li 2 S) in a Safe Eutectic Solvent for Rechargeable Lithium-Sulfur Batteries},
author = {Cheng, Qian and Xu, Weiheng and Qin, Shiyi and Das, Subhabrata and Jin, Tianwei and Li, Aijun and Li, Alex Ceng and Qie, Boyu and Yao, Pengcheng and Zhai, Haowei and Shi, Changmin and Yong, Xin and Yang, Yuan},
abstractNote = {},
doi = {10.1002/anie.201812611},
journal = {Angewandte Chemie (International Edition)},
number = ,
volume = ,
place = {Germany},
year = {2019},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/anie.201812611

Citation Metrics:
Cited by: 10 works
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Works referenced in this record:

Ultrafine TiO 2 Decorated Carbon Nanofibers as Multifunctional Interlayer for High-Performance Lithium–Sulfur Battery
journal, August 2016

  • Liang, Gemeng; Wu, Junxiong; Qin, Xianying
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 35
  • DOI: 10.1021/acsami.6b07487

Graphene-Based Three-Dimensional Hierarchical Sandwich-type Architecture for High-Performance Li/S Batteries
journal, September 2013

  • Chen, Renjie; Zhao, Teng; Lu, Jun
  • Nano Letters, Vol. 13, Issue 10
  • DOI: 10.1021/nl4016683

Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries
journal, May 2011

  • Jayaprakash, N.; Shen, J.; Moganty, Surya S.
  • Angewandte Chemie, Vol. 123, Issue 26, p. 6026-6030
  • DOI: 10.1002/ange.201100637

Ammonium Additives to Dissolve Lithium Sulfide through Hydrogen Binding for High-Energy Lithium–Sulfur Batteries
journal, July 2016

  • Pan, Huilin; Han, Kee Sung; Vijayakumar, M.
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 5
  • DOI: 10.1021/acsami.6b04158

Graphene-Wrapped Sulfur Particles as a Rechargeable Lithium–Sulfur Battery Cathode Material with High Capacity and Cycling Stability
journal, July 2011

  • Wang, Hailiang; Yang, Yuan; Liang, Yongye
  • Nano Letters, Vol. 11, Issue 7, p. 2644-2647
  • DOI: 10.1021/nl200658a

Ferrocene-Promoted Long-Cycle Lithium-Sulfur Batteries
journal, October 2016


Surface-enhanced redox chemistry of polysulphides on a metallic and polar host for lithium-sulphur batteries
journal, August 2014

  • Pang, Quan; Kundu, Dipan; Cuisinier, Marine
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5759

Strong Lithium Polysulfide Chemisorption on Electroactive Sites of Nitrogen-Doped Carbon Composites For High-Performance Lithium-Sulfur Battery Cathodes
journal, February 2015

  • Song, Jiangxuan; Gordin, Mikhail L.; Xu, Terrence
  • Angewandte Chemie, Vol. 127, Issue 14
  • DOI: 10.1002/ange.201411109

Sulphur–TiO2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries
journal, January 2013

  • Wei Seh, Zhi; Li, Weiyang; Cha, Judy J.
  • Nature Communications, Vol. 4, Article No. 1331
  • DOI: 10.1038/ncomms2327

Understanding the Nature of Absorption/Adsorption in Nanoporous Polysulfide Sorbents for the Li–S Battery
journal, September 2012

  • Evers, Scott; Yim, Taeeun; Nazar, Linda F.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 37
  • DOI: 10.1021/jp304380j

High “C” rate Li-S cathodes: sulfur imbibed bimodal porous carbons
journal, January 2011

  • He, Guang; Ji, Xiulei; Nazar, Linda
  • Energy & Environmental Science, Vol. 4, Issue 8
  • DOI: 10.1039/c1ee01219c

In situ Raman spectroscopy distinguishes between reversible and irreversible thiol modifications in l -cysteine
journal, January 2017

  • Bazylewski, Paul; Divigalpitiya, Ranjith; Fanchini, Giovanni
  • RSC Advances, Vol. 7, Issue 5
  • DOI: 10.1039/C6RA25879D

Encapsulating Various Sulfur Allotropes within Graphene Nanocages for Long-Lasting Lithium Storage
journal, March 2018

  • Yuan, Yifei; Tan, Guoqiang; Wen, Jianguo
  • Advanced Functional Materials, Vol. 28, Issue 38
  • DOI: 10.1002/adfm.201706443

Healing High-Loading Sulfur Electrodes with Unprecedented Long Cycling Life: Spatial Heterogeneity Control
journal, March 2017

  • Peng, Hong-Jie; Huang, Jia-Qi; Liu, Xin-Yan
  • Journal of the American Chemical Society, Vol. 139, Issue 25
  • DOI: 10.1021/jacs.6b12358

Addressing Passivation in Lithium-Sulfur Battery Under Lean Electrolyte Condition
journal, February 2018

  • Pan, Huilin; Han, Kee Sung; Engelhard, Mark H.
  • Advanced Functional Materials, Vol. 28, Issue 38
  • DOI: 10.1002/adfm.201707234

A Polyaniline-Coated Sulfur/Carbon Composite with an Enhanced High-Rate Capability as a Cathode Material for Lithium/Sulfur Batteries
journal, May 2012

  • Li, Guo-Chun; Li, Guo-Ran; Ye, Shi-Hai
  • Advanced Energy Materials, Vol. 2, Issue 10
  • DOI: 10.1002/aenm.201200017

Molecular Materials for Nonaqueous Flow Batteries with a High Coulombic Efficiency and Stable Cycling
journal, November 2017


Characterization of caprolactam based eutectic ionic liquids and their application in SO2 absorption
journal, April 2013


Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries
journal, May 2011

  • Jayaprakash, N.; Shen, J.; Moganty, Surya S.
  • Angewandte Chemie International Edition, Vol. 50, Issue 26, p. 5904-5908
  • DOI: 10.1002/anie.201100637

Deep eutectic solvents for green and efficient iron-mediated ligand-free atom transfer radical polymerization
journal, January 2017

  • Wang, Jirong; Han, Jianyu; Khan, Mohd Yusuf
  • Polymer Chemistry, Vol. 8, Issue 10
  • DOI: 10.1039/C6PY02066F

Understanding the Dielectric Properties of Liquid Amides from a Polarizable Force Field
journal, March 2008

  • Harder, Edward; Anisimov, Victor M.; Whitfield, Troy
  • The Journal of Physical Chemistry B, Vol. 112, Issue 11
  • DOI: 10.1021/jp709729d

Smaller Sulfur Molecules Promise Better Lithium–Sulfur Batteries
journal, October 2012

  • Xin, Sen; Gu, Lin; Zhao, Na-Hong
  • Journal of the American Chemical Society, Vol. 134, Issue 45
  • DOI: 10.1021/ja308170k

Ferrocene-Promoted Long-Cycle Lithium-Sulfur Batteries
journal, October 2016

  • Mi, Yingying; Liu, Wen; Yang, Ke R.
  • Angewandte Chemie International Edition, Vol. 55, Issue 47
  • DOI: 10.1002/anie.201609147

A Polyethylene Glycol-Supported Microporous Carbon Coating as a Polysulfide Trap for Utilizing Pure Sulfur Cathodes in Lithium-Sulfur Batteries
journal, September 2014


Li–O2 and Li–S batteries with high energy storage
journal, January 2012

  • Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
  • Nature Materials, Vol. 11, Issue 1, p. 19-29
  • DOI: 10.1038/nmat3191

Slurryless Li 2 S/Reduced Graphene Oxide Cathode Paper for High-Performance Lithium Sulfur Battery
journal, February 2015


Non-encapsulation approach for high-performance Li–S batteries through controlled nucleation and growth
journal, September 2017


Design of Battery Electrodes with Dual-Scale Porosity to Minimize Tortuosity and Maximize Performance
journal, December 2012

  • Bae, Chang-Jun; Erdonmez, Can K.; Halloran, John W.
  • Advanced Materials, Vol. 25, Issue 9
  • DOI: 10.1002/adma.201204055

Gas solubilities in deep eutectic solvents
journal, October 2017


Ambient-Air Stable Lithiated Anode for Rechargeable Li-Ion Batteries with High Energy Density
journal, October 2016


Confined Sulfur in Microporous Carbon Renders Superior Cycling Stability in Li/S Batteries
journal, June 2015

  • Xu, Yunhua; Wen, Yang; Zhu, Yujie
  • Advanced Functional Materials, Vol. 25, Issue 27
  • DOI: 10.1002/adfm.201500983

Flammability of Li-Ion Battery Electrolytes: Flash Point and Self-Extinguishing Time Measurements
journal, January 2015

  • Hess, Steffen; Wohlfahrt-Mehrens, Margret; Wachtler, Mario
  • Journal of The Electrochemical Society, Vol. 162, Issue 2
  • DOI: 10.1149/2.0121502jes

A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
journal, May 2009

  • Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F.
  • Nature Materials, Vol. 8, Issue 6, p. 500-506
  • DOI: 10.1038/nmat2460

Strong Lithium Polysulfide Chemisorption on Electroactive Sites of Nitrogen-Doped Carbon Composites For High-Performance Lithium-Sulfur Battery Cathodes
journal, February 2015

  • Song, Jiangxuan; Gordin, Mikhail L.; Xu, Terrence
  • Angewandte Chemie International Edition, Vol. 54, Issue 14
  • DOI: 10.1002/anie.201411109

Surface modification of polyaniline nanorods with thiol-terminated poly(ethylene oxide)
journal, February 2018

  • DiTullio, Brandon T.; Wright, Cassandra J.; Hayes, Patricia
  • Colloid and Polymer Science, Vol. 296, Issue 4
  • DOI: 10.1007/s00396-018-4278-y