Title: Chemical stability and superconductivity in Ag-sheathed CaKFe4As4 superconducting tapes

Journal Article · · Superconductor Science and Technology

Ag-sheathed CaKFe4As4 superconducting tapes have been fabricated via the ex situ powder-in-tube method. X-ray diffraction analyses suggest that the CaKFe4As4 phase reacts strongly with the silver sheath at temperature above 500 °C. We therefore anneal the tape at 500 °C and obtain a transport critical current density J c(4.2 K, 0 T) ~ 2.7 × 104 A cm–2. The pinning potential derived from magnetoresistance measurements is one order of magnitude lower than that of the (Ba/Sr)1–xKxFe2As2 tapes. Combining with the scanning electron microscopy and magneto-optical imaging results, we suggest that bad connectivity between superconducting grains caused by the low sintering temperature is the main factor responsible for the low J c. Furthermore, this system is still a promising candidate for superconducting wires and tapes if we find a compatible sheath material and further optimize the post-annealing process to achieve better grain connectivity.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
Chinese Academy of Sciences (CAS); National Natural Science Foundation of China; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1503251
Journal Information:
Superconductor Science and Technology, Journal Name: Superconductor Science and Technology Journal Issue: 1 Vol. 32; ISSN 0953-2048
Publisher:
IOP PublishingCopyright Statement
Country of Publication:
United States
Language:
English

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