Title: Combining X-ray Kβ1,3, valence-to-core, and X-ray Raman spectroscopy for studying Earth materials at high pressure and temperature: the case of siderite

Journal Article · · Journal of Analytical Atomic Spectrometry
DOI: https://doi.org/10.1039/c8ja00247a · OSTI ID:1503081
 [1];  [2]; ORCiD logo [1];  [3]; ORCiD logo [4];  [5]; ORCiD logo [5]; ORCiD logo [1]; ORCiD logo [1];  [6];  [7];  [8];  [9]; ORCiD logo [10];  [1];  [2]
  1. Technische Univ. Dortmund, Dortmund (Germany)
  2. Univ. Potsdam, Potsdam (Germany)
  3. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)
  4. Hungarian Academy Sciences, Budapest (Hungary)
  5. European Synchrotron Radiation Facility, Grenoble Cedex (France)
  6. Univ. Munster, Munster (Germany)
  7. Univ. of Bayreuth, Bayreuth (Germany)
  8. Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); SLAC National Accelerator Lab., Menlo Park, CA (United States)
  9. European XFEL, Hamburg (Germany)
  10. European XFEL, Hamburg (Germany); Adam Mickiewicz Univ., Poznan (Poland)

The high spin to low spin transition of siderite is studied by simultaneous X-ray emission and X-ray Raman scattering spectroscopy.

Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
1503081
Journal Information:
Journal of Analytical Atomic Spectrometry, Journal Name: Journal of Analytical Atomic Spectrometry Journal Issue: 2 Vol. 34; ISSN JASPE2; ISSN 0267-9477
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English

References (68)

Valence to Core X-ray Emission Spectroscopy journal May 2014
Valence-to-Core X-Ray Emission Spectroscopy of Iron-Carbonyl Complexes: Implications for the Examination of Catalytic Intermediates journal October 2013
Effects of the Electronic spin Transitions of iron in Lower Mantle Minerals: Implications for deep Mantle Geophysics and Geochemistry: spin Transition in Lower Mantle journal April 2013
Chemical mass transfer in magmatic processes IV. A revised and internally consistent thermodynamic model for the interpolation and extrapolation of liquid-solid equilibria in magmatic systems at elevated temperatures and pressures journal March 1995
Iron speciation in minerals and glasses probed by $$\hbox{M}_{2/3}$$ M 2 / 3 -edge X-ray Raman scattering spectroscopy journal May 2014
Chemical mass transfer in magmatic processes IV. A revised and internally consistent thermodynamic model for the interpolation and extrapolation of liquid-solid equilibria in magmatic systems at elevated temperatures and pressures journal March 1995
Chemical dependence of interatomic X-ray transition energies and intensities – a study of Mn Kβ″ and Kβ2,5 spectra journal March 1999
High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes—electronic and structural information journal January 2005
Carbonates from the lower part of transition zone or even the lower mantle journal August 2007
The deep carbon cycle and melting in Earth's interior journal September 2010
Lithium borate crystals and glasses: How similar are they? A non-resonant inelastic X-ray scattering study around the B and O K -edges journal September 2017
Cation Hydration in Supercritical NaOH and HCl Aqueous Solutions journal December 2017
High-resolution manganese x-ray fluorescence spectroscopy. Oxidation-state and spin-state sensitivity journal April 1994
Probing the 3d Spin Momentum with X-ray Emission Spectroscopy:  The Case of Molecular-Spin Transitions journal June 2006
The high-pressure electronic structure of magnesiowustite (Mg, Fe)O: Applications to the physics and chemistry of the lower mantle journal August 1991
Simulating the core-mantle boundary: An experimental study of high-pressure reactions between silicates and liquid iron journal July 1989
Calibration of the ruby pressure gauge to 800 kbar under quasi-hydrostatic conditions journal January 1986
Spin transition of iron in magnesiowüstite in the Earth's lower mantle journal July 2005
Mineralogy at the extremes journal January 2008
Stability of iron-bearing carbonates in the deep Earth’s interior journal July 2017
Intermediate-spin ferrous iron in lowermost mantle post-perovskite and perovskite journal September 2008
Direct tomography with chemical-bond contrast journal May 2011
Pressure driven spin transition in siderite and magnesiosiderite single crystals journal November 2017
Diamond formation in the deep lower mantle: a high-pressure reaction of MgCO3 and SiO2 journal January 2017
HERFD-XAS and valence-to-core-XES: new tools to push the limits in research with hard X-rays? journal January 2014
Bulk sensitive determination of the Fe 3+ /Fe Tot -ratio in minerals by Fe L 2/3 -edge X-ray Raman scattering journal January 2016
Local Structures around Si, Al and Na in Hydrated Silicate Glasses
  • Farges, François; de Wispelaere, Sidoine; Rossano, Stéphanie
  • X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference, AIP Conference Proceedings https://doi.org/10.1063/1.2644478
conference January 2007
Nearest-neighbor oxygen distances in liquid water and ice observed by x-ray Raman based extended x-ray absorption fine structure journal November 2007
A diamond anvil cell for x-ray fluorescence measurements of trace elements in fluids at high pressure and high temperature journal March 2009
Phase separation and Si nanocrystal formation in bulk SiO studied by x-ray scattering journal February 2010
A high resolution and large solid angle x-ray Raman spectroscopy end-station at the Stanford Synchrotron Radiation Lightsource journal April 2012
A multi-crystal wavelength dispersive x-ray spectrometer journal July 2012
A von Hamos x-ray spectrometer based on a segmented-type diffraction crystal for single-shot x-ray emission spectroscopy and time-resolved resonant inelastic x-ray scattering studies journal October 2012
Pressure induced spin transition revealed by iron M 2,3 -edge spectroscopy journal June 2014
X-ray Raman scattering study of MgSiO3 glass at high pressure: Implication for triclustered MgSiO3 melt in Earth's mantle journal June 2008
Microscopic structure of water at elevated pressures and temperatures journal March 2013
Iron spin state in silicate perovskite at conditions of the Earth's deep interior journal August 2013
Spectroscopy of low and intermediate Z elements at extreme conditions: in situ studies of Earth materials at pressure and temperature via X-ray Raman scattering journal July 2016
EXAFS studies under high pressure by X-ray Raman scattering journal July 2016
LAMBDA — Large Area Medipix3-Based Detector Array journal November 2012
Spin-polarized photoelectron diffraction journal April 1985
Spin crossover in ( Mg , Fe ) O : A Mössbauer effect study with an alternative interpretation of x-ray emission spectroscopy data journal March 2006
Structure of siderite FeCO 3 to 56 GPa and hysteresis of its spin-pairing transition journal August 2010
Disentangling structural information from core-level excitation spectra journal July 2017
Direct Evidence from Gas-Phase Atomic Spectra for an Unscreened Intra-Atomic Origin of Outer-Core Multiplet Splittings in Solid Manganese Compounds journal November 1988
Pressure-Induced High-Spin to Low-Spin Transition in FeS Evidenced by X-Ray Emission Spectroscopy journal April 1999
Magnetism in FeO at Megabar Pressures from X-Ray Emission Spectroscopy journal November 1999
An extraction algorithm for core-level excitations in non-resonant inelastic X-ray scattering spectra journal February 2008
Multiple-element spectrometer for non-resonant inelastic X-ray spectroscopy of electronic excitations journal June 2009
Planning, performing and analyzing X-ray Raman scattering experiments journal February 2015
Direct tomography imaging for inelastic X-ray scattering experiments at high pressure journal January 2017
Miniature diamond anvils for X-ray Raman scattering spectroscopy experiments at high pressure journal January 2017
A large-solid-angle X-ray Raman scattering spectrometer at ID20 of the European Synchrotron Radiation Facility journal February 2017
X-ray Raman spectroscopy of lithium-ion battery electrolyte solutions in a flow cell journal February 2018
Electronic Transitions in Perovskite: Possible Nonconvecting Layers in the Lower Mantle journal July 2004
Spin Transition Zone in Earth's Lower Mantle journal September 2007
Effect of temperature on the pressure-induced spin transition in siderite and iron-bearing magnesite: a Raman spectroscopy study [Effect of temperature on the pressure-induced spin transition in siderite and iron-bearing magnesite: a Raman spectroscopy study] journal December 2017
Spin Transitions in Mantle Minerals journal May 2014
Silicate Perovskite journal May 1992
High-pressure spectroscopic study of siderite (FeCO 3 ) with a focus on spin crossover journal November 2015
Compression of single-crystal magnesium oxide to 118 GPa and a ruby pressure gauge for helium pressure media journal November 2008
Spin and valence states of iron in Al-bearing silicate glass at high pressures studied by synchrotron Mossbauer and X-ray emission spectroscopy journal February 2014
Thermal equation of state and spin transition of magnesiosiderite at high pressure and temperature journal January 2014
Probing of Pressure-Induced Bonding Transitions in Crystalline and Amorphous Earth Materials: Insights from X-ray Raman Scattering at High Pressure journal January 2014
Pressure driven spin transition in siderite and magnesiosiderite single crystals text January 2017
Stability of iron-bearing carbonates in the deep Earth’s interior text January 2017
Disentangling Structural Information From Core-level Excitation Spectra text January 2017
Pressure induced high-spin to low-spin transition in FeS evidenced by x-ray emission spectroscopy text January 1998

Cited By (3)

Persistent Octahedral Coordination in Amorphous GeO 2 Up to 100 GPa by K β ′ ′ X-Ray Emission Spectroscopy journal February 2019
A von Hamos-type hard X-ray spectrometer at the PETRA III beamline P64 journal January 2020
A von Hamos-type hard X-ray spectrometer at the PETRA III beamline P64 text January 2020