Secondary organic aerosol (SOA) yields from NO3 radical + isoprene based on nighttime aircraft power plant plume transects

Fry, Juliane L.; Brown, Steven S.; Middlebrook, Ann M.; Edwards, Peter M.; Campuzano-Jost, Pedro; Day, Douglas A.; Jimenez, José L.; Allen, Hannah M.; Ryerson, Thomas B.; Pollack, Ilana; Graus, Martin; Warneke, Carsten; de Gouw, Joost A.; Brock, Charles A.; Gilman, Jessica; Lerner, Brian M.; Dubé, William P.; Liao, Jin; Welti, André

doi:10.5194/acp-18-11663-2018

Title: Secondary organic aerosol (SOA) yields from NO₃ radical + isoprene based on nighttime aircraft power plant plume transects

Journal Article · 15 August 2018 · Atmospheric Chemistry and Physics (Online)

DOI: https://doi.org/10.5194/acp-18-11663-2018 · OSTI ID:1502876

Fry, Juliane L. ^[1]; Brown, Steven S. ^[2];

^[3];

^[4];

^[5];

^[5]; Allen, Hannah M. ^[6]; Ryerson, Thomas B. ^[3]; Pollack, Ilana ^[7]; Graus, Martin ^[8]; Warneke, Carsten ^[2];

^[5]; Brock, Charles A. ^[3]; Gilman, Jessica ^[2]; Lerner, Brian M. ^[9]; Dubé, William P. ^[2]; Liao, Jin ^[10];

^[11]

Reed College, Portland, OR (United States); Chemistry Department, Reed College, Portland, OR, USA
National Oceanic and Atmospheric Administration, Boulder, CO (United States); Univ. of Colorado, Boulder, CO (United States)
National Oceanic and Atmospheric Administration, Boulder, CO (United States)
National Oceanic and Atmospheric Administration, Boulder, CO (United States); Univ. of Colorado, Boulder, CO (United States); Univ. of York, York (United Kingdom)
Univ. of Colorado, Boulder, CO (United States)
California Inst. of Technology (CalTech), Pasadena, CA (United States)
National Oceanic and Atmospheric Administration, Boulder, CO (United States); Colorado State Univ., Fort Collins, CO (United States); Univ. of Colorado, Boulder, CO (United States)
Univ. of Colorado, Boulder, CO (United States); Univ. of Innsbruck, Innsbruck (Austria)
National Oceanic and Atmospheric Administration, Boulder, CO (United States); Univ. of Colorado, Boulder, CO (United States); Aerodyne Research, Inc., Billerica, MA (United States)
National Oceanic and Atmospheric Administration, Boulder, CO (United States); Univ. of Colorado, Boulder, CO (United States); Univ. Space Research Assoc., Columbia, MD (United States); NASA Goddard Space Flight Center (GSFC), Greenbelt, MD (United States)
National Oceanic and Atmospheric Administration, Boulder, CO (United States); Univ. of Colorado, Boulder, CO (United States); Leibniz Institute for Tropospheric Research, Leipzig (Germany)

Nighttime reaction of nitrate radicals (NO₃) with biogenic volatile organic compounds (BVOC) has been proposed as a potentially important but also highly uncertain source of secondary organic aerosol (SOA). The southeastern United States has both high BVOC and nitrogen oxide (NO_x) emissions, resulting in a large model-predicted NO₃-BVOC source of SOA. Coal-fired power plants in this region constitute substantial NO_x emissions point sources into a nighttime atmosphere characterized by high regionally widespread concentrations of isoprene. In this paper, we exploit nighttime aircraft observations of these power plant plumes, in which NO₃ radicals rapidly remove isoprene, to obtain field-based estimates of the secondary organic aerosol yield from NO₃ + isoprene. Observed in-plume increases in nitrate aerosol are consistent with organic nitrate aerosol production from NO₃ + isoprene, and these are used to determine molar SOA yields, for which the average over nine plumes is 9 % (±5 %). Corresponding mass yields depend on the assumed molecular formula for isoprene-NO₃-SOA, but the average over nine plumes is 27 %(±14 %), on average larger than those previously measured in chamber studies (12 %–14 % mass yield as ΔOA / ΔVOC after oxidation of both double bonds). Yields are larger for longer plume ages.This suggests that ambient aging processes lead more effectively to condensable material than typical chamber conditions allow. We discuss potential mechanistic explanations for this difference, including longer ambient peroxy radical lifetimes and heterogeneous reactions of NO₃-isoprene gas phase products. As a result more in-depth studies are needed to better understand the aerosol yield and oxidation mechanism of NO₃ radical + isoprene, a coupled anthropogenic–biogenic source of SOA that may be regionally significant.

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Research Organization:: Univ. of Colorado, Denver, CO (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23)

Grant/Contract Number:: SC0016559

OSTI ID:: 1502876

Journal Information:: Atmospheric Chemistry and Physics (Online), Journal Name: Atmospheric Chemistry and Physics (Online) Journal Issue: 16 Vol. 18; ISSN 1680-7324

Publisher:: European Geosciences UnionCopyright Statement

Country of Publication:: United States

Language:: English

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Secondary organic aerosol formation from in situ OH, O ₃ , and NO ₃ oxidation of ambient forest air in an oxidation flow reactor Palm, Brett B.; Campuzano-Jost, Pedro; Day, Douglas A. Atmospheric Chemistry and Physics, Vol. 17, Issue 8 https://doi.org/10.5194/acp-17-5331-2017	journal	January 2017
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Determination of the Aerosol Yield of Isoprene in the Presence of an Organic Seed with Carbon Isotope Analysis Dommen, Josef; Hellén, Heidi; Saurer, Matthias Environmental Science & Technology, Vol. 43, Issue 17 https://doi.org/10.1021/es9006959	journal	September 2009
Performance characteristics of the ultra high sensitivity aerosol spectrometer for particles between 55 and 800nm: Laboratory and field studies Cai, Yong; Montague, Derek C.; Mooiweer-Bryan, Wiesje Journal of Aerosol Science, Vol. 39, Issue 9 https://doi.org/10.1016/j.jaerosci.2008.04.007	journal	September 2008
Aerosol mass spectrometer constraint on the global secondary organic aerosol budget Spracklen, D. V.; Jimenez, J. L.; Carslaw, K. S. Atmospheric Chemistry and Physics, Vol. 11, Issue 23 https://doi.org/10.5194/acp-11-12109-2011	journal	January 2011
Observational Insights into Aerosol Formation from Isoprene Worton, David R.; Surratt, Jason D.; LaFranchi, Brian W. Environmental Science & Technology, Vol. 47, Issue 20 https://doi.org/10.1021/es4011064	journal	September 2013

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Characterization of nighttime formation of particulate organic nitrates based on high-resolution aerosol mass spectrometry in an urban atmosphere in China Yu, Kuangyou; Zhu, Qiao; Du, Ke Atmospheric Chemistry and Physics, Vol. 19, Issue 7 https://doi.org/10.5194/acp-19-5235-2019	journal	January 2019
Chemical composition and hydrolysis of organic nitrate aerosol formed from hydroxyl and nitrate radical oxidation of α-pinene and β-pinene Takeuchi, Masayuki; Ng, Nga L. Atmospheric Chemistry and Physics, Vol. 19, Issue 19 https://doi.org/10.5194/acp-19-12749-2019	journal	January 2019
Aircraft-based observations of isoprene-epoxydiol-derived secondary organic aerosol (IEPOX-SOA) in the tropical upper troposphere over the Amazon region Schulz, Christiane; Schneider, Johannes; Amorim Holanda, Bruna Atmospheric Chemistry and Physics, Vol. 18, Issue 20 https://doi.org/10.5194/acp-18-14979-2018	journal	January 2018

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