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Title: Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations

Abstract

Mn2CoReO6, the fourth known magnetic transition-metal-only double perovskite oxide (space group P21/n) was synthesized here at high pressure and temperature (8 GPa, 1350 °C). Large structural distortions are induced by the small A-site Mn2+ cations. Mn2CoReO6 exhibits complex magnetic properties with a robust antiferromagnetic order (TN = 94 K) involving all cation sublattices.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3];  [3]; ORCiD logo [4]; ORCiD logo [5];  [6];  [2];  [1]; ORCiD logo [1];  [7];  [5]; ORCiD logo [8]; ORCiD logo [8];  [9];  [9];  [10];  [5];  [11]; ORCiD logo [1]
  1. Rutgers Univ., Piscataway, NJ (United States). Dept. of Chemistry and Chemical Biology
  2. Univ. of Kent, Canterbury (United Kingdom). School of Physical Sciences
  3. Science and Technology Facilities Council (STFC), Chilton (United Kingdom). Rutherford Appleton Lab. (RAL). ISIS Facility
  4. George Mason Univ., Fairfax, VA (United States). Dept. of Chemistry and Biochemistry
  5. Univ. of Chinese Academy of Sciences, Beijing (China). Inst. of Physics
  6. Rutgers Univ., Piscataway, NJ (United States). Dept. of Physics and Astronomy
  7. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
  8. Sun Yat-Sen Univ., Guangzhou (China). MOE Key Lab. of Bioinorganic and Synthetic Chemistry. School of Chemistry
  9. Brookhaven National Lab. (BNL), Upton, NY (United States). NSLS-II
  10. National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Materials Measurement Science Division. Material Measurement Lab.
  11. Columbia Univ., Palisades, NY (United States). Lamont Doherty Earth Observatory
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States); Rutgers Univ., Piscataway, NJ (United States); Univ. of Kent, Canterbury (United Kingdom); Univ. of Chinese Academy of Sciences, Beijing (China); Sun Yat-Sen Univ., Guangzhou (China); Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Leverhulme Trust (United Kingdom); National Natural Science Foundation of China (NNSFC); National Science Foundation (NSF), Directorate for Mathematical and Physical Sciences Division of Materials Research (MPS-DMR); Leverhulme Trust; Royal Society United Kingdom
OSTI Identifier:
1502801
Alternate Identifier(s):
OSTI ID: 1497244; OSTI ID: 1524406
Report Number(s):
BNL-211429-2019-JAAM
Journal ID: ISSN 1359-7345
Grant/Contract Number:  
SC0012704; DMR-1507252; RPG-2017-362; NSFC-11804404; AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 55; Journal Issue: 23; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Frank, Corey E., McCabe, Emma E., Orlandi, Fabio, Manuel, Pascal, Tan, Xiaoyan, Deng, Zheng, Croft, Mark, Cascos, Vanessa, Emge, Thomas, Feng, Hai L., Lapidus, Saul, Jin, Changqing, Wu, MeiXia, Li, Man Rong, Ehrlich, Steven, Khalid, Syed, Quackenbush, Nicholas, Yu, Shuang, Walker, David, and Greenblatt, Martha. Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations. United States: N. p., 2019. Web. doi:10.1039/C9CC00038K.
Frank, Corey E., McCabe, Emma E., Orlandi, Fabio, Manuel, Pascal, Tan, Xiaoyan, Deng, Zheng, Croft, Mark, Cascos, Vanessa, Emge, Thomas, Feng, Hai L., Lapidus, Saul, Jin, Changqing, Wu, MeiXia, Li, Man Rong, Ehrlich, Steven, Khalid, Syed, Quackenbush, Nicholas, Yu, Shuang, Walker, David, & Greenblatt, Martha. Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations. United States. doi:10.1039/C9CC00038K.
Frank, Corey E., McCabe, Emma E., Orlandi, Fabio, Manuel, Pascal, Tan, Xiaoyan, Deng, Zheng, Croft, Mark, Cascos, Vanessa, Emge, Thomas, Feng, Hai L., Lapidus, Saul, Jin, Changqing, Wu, MeiXia, Li, Man Rong, Ehrlich, Steven, Khalid, Syed, Quackenbush, Nicholas, Yu, Shuang, Walker, David, and Greenblatt, Martha. Tue . "Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations". United States. doi:10.1039/C9CC00038K. https://www.osti.gov/servlets/purl/1502801.
@article{osti_1502801,
title = {Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations},
author = {Frank, Corey E. and McCabe, Emma E. and Orlandi, Fabio and Manuel, Pascal and Tan, Xiaoyan and Deng, Zheng and Croft, Mark and Cascos, Vanessa and Emge, Thomas and Feng, Hai L. and Lapidus, Saul and Jin, Changqing and Wu, MeiXia and Li, Man Rong and Ehrlich, Steven and Khalid, Syed and Quackenbush, Nicholas and Yu, Shuang and Walker, David and Greenblatt, Martha},
abstractNote = {Mn2CoReO6, the fourth known magnetic transition-metal-only double perovskite oxide (space group P21/n) was synthesized here at high pressure and temperature (8 GPa, 1350 °C). Large structural distortions are induced by the small A-site Mn2+ cations. Mn2CoReO6 exhibits complex magnetic properties with a robust antiferromagnetic order (TN = 94 K) involving all cation sublattices.},
doi = {10.1039/C9CC00038K},
journal = {ChemComm},
number = 23,
volume = 55,
place = {United States},
year = {2019},
month = {2}
}

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    Large Magnetization and Frustration Switching of Magnetoresistance in the Double-Perovskite Ferrimagnet Mn 2 FeReO 6
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    • Arévalo-López, Angel M.; McNally, Graham M.; Attfield, J. Paul
    • Angewandte Chemie International Edition, Vol. 54, Issue 41
    • DOI: 10.1002/anie.201506540

    Crystal and Magnetic Structure of Sr2MReO6 (M = Ni, Co, Zn) Double Perovskites: A Neutron Diffraction Study
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    An overview of double perovskites A2B′B″O6 with small ions at A site: Synthesis, structure and magnetic properties
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    Investigations of the magnetic properties and structures of the pillared perovskites, La5Re3MO16 (M=Co, Ni)
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    • Cuthbert, Heather L.; Greedan, John E.; Cranswick, Lachlan
    • Journal of Solid State Chemistry, Vol. 179, Issue 7
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    Crystal structure of Ln1/3NbO3 (Ln=Nd, Pr) and phase transition in Nd1/3NbO3
    journal, June 2007

    • Zhang, Zhaoming; Howard, Christopher J.; Kennedy, Brendan J.
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    Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
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