skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations

Abstract

Small A-site cations (Mn2+) induce complex magnetic structures in this transition-metal-only double perovskite.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3];  [3]; ORCiD logo [4]; ORCiD logo [5];  [6];  [2];  [1]; ORCiD logo [1];  [7];  [5]; ORCiD logo [8]; ORCiD logo [8];  [9];  [9];  [10];  [5];  [11]; ORCiD logo [1]
  1. Rutgers Univ., Piscataway, NJ (United States). Dept. of Chemistry and Chemical Biology
  2. Univ. of Kent, Canterbury (United Kingdom). School of Physical Sciences
  3. Science and Technology Facilities Council (STFC), Chilton (United Kingdom). Rutherford Appleton Lab. (RAL). ISIS Facility
  4. George Mason Univ., Fairfax, VA (United States). Dept. of Chemistry and Biochemistry
  5. Univ. of Chinese Academy of Sciences, Beijing (China). Inst. of Physics
  6. Rutgers Univ., Piscataway, NJ (United States). Dept. of Physics and Astronomy
  7. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
  8. Sun Yat-Sen Univ., Guangzhou (China). MOE Key Lab. of Bioinorganic and Synthetic Chemistry. School of Chemistry
  9. Brookhaven National Lab. (BNL), Upton, NY (United States). NSLS-II
  10. National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States). Materials Measurement Science Division. Material Measurement Lab.
  11. Columbia Univ., Palisades, NY (United States). Lamont Doherty Earth Observatory
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States); Rutgers Univ., Piscataway, NJ (United States); Univ. of Kent, Canterbury (United Kingdom); Univ. of Chinese Academy of Sciences, Beijing (China); Sun Yat-Sen Univ., Guangzhou (China); Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Leverhulme Trust (United Kingdom); National Natural Science Foundation of China (NSFC); National Science Foundation (NSF), Directorate for Mathematical and Physical Sciences Division of Materials Research (MPS-DMR); Leverhulme Trust; Royal Society United Kingdom
OSTI Identifier:
1502801
Alternate Identifier(s):
OSTI ID: 1497244; OSTI ID: 1524406
Report Number(s):
BNL-211429-2019-JAAM
Journal ID: ISSN 1359-7345
Grant/Contract Number:  
SC0012704; DMR-1507252; RPG-2017-362; NSFC-11804404; AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 55; Journal Issue: 23; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Frank, Corey E., McCabe, Emma E., Orlandi, Fabio, Manuel, Pascal, Tan, Xiaoyan, Deng, Zheng, Croft, Mark, Cascos, Vanessa, Emge, Thomas, Feng, Hai L., Lapidus, Saul, Jin, Changqing, Wu, MeiXia, Li, Man Rong, Ehrlich, Steven, Khalid, Syed, Quackenbush, Nicholas, Yu, Shuang, Walker, David, and Greenblatt, Martha. Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations. United States: N. p., 2019. Web. https://doi.org/10.1039/C9CC00038K.
Frank, Corey E., McCabe, Emma E., Orlandi, Fabio, Manuel, Pascal, Tan, Xiaoyan, Deng, Zheng, Croft, Mark, Cascos, Vanessa, Emge, Thomas, Feng, Hai L., Lapidus, Saul, Jin, Changqing, Wu, MeiXia, Li, Man Rong, Ehrlich, Steven, Khalid, Syed, Quackenbush, Nicholas, Yu, Shuang, Walker, David, & Greenblatt, Martha. Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations. United States. https://doi.org/10.1039/C9CC00038K
Frank, Corey E., McCabe, Emma E., Orlandi, Fabio, Manuel, Pascal, Tan, Xiaoyan, Deng, Zheng, Croft, Mark, Cascos, Vanessa, Emge, Thomas, Feng, Hai L., Lapidus, Saul, Jin, Changqing, Wu, MeiXia, Li, Man Rong, Ehrlich, Steven, Khalid, Syed, Quackenbush, Nicholas, Yu, Shuang, Walker, David, and Greenblatt, Martha. Tue . "Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations". United States. https://doi.org/10.1039/C9CC00038K. https://www.osti.gov/servlets/purl/1502801.
@article{osti_1502801,
title = {Mn2CoReO6: a robust multisublattice antiferromagnetic perovskite with small A-site cations},
author = {Frank, Corey E. and McCabe, Emma E. and Orlandi, Fabio and Manuel, Pascal and Tan, Xiaoyan and Deng, Zheng and Croft, Mark and Cascos, Vanessa and Emge, Thomas and Feng, Hai L. and Lapidus, Saul and Jin, Changqing and Wu, MeiXia and Li, Man Rong and Ehrlich, Steven and Khalid, Syed and Quackenbush, Nicholas and Yu, Shuang and Walker, David and Greenblatt, Martha},
abstractNote = {Small A-site cations (Mn2+) induce complex magnetic structures in this transition-metal-only double perovskite.},
doi = {10.1039/C9CC00038K},
journal = {ChemComm},
number = 23,
volume = 55,
place = {United States},
year = {2019},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Prediction of the crystal structures of perovskites using the software program SPuDS
journal, November 2001

  • Lufaso, Michael W.; Woodward, Patrick M.
  • Acta Crystallographica Section B Structural Science, Vol. 57, Issue 6
  • DOI: 10.1107/S0108768101015282

Competing antiferromagnetic orders in the double perovskite Mn 2 MnReO 6 (Mn 3 ReO 6 )
journal, January 2016

  • Arévalo-López, A. M.; Stegemann, F.; Attfield, J. P.
  • Chemical Communications, Vol. 52, Issue 32
  • DOI: 10.1039/C6CC01290F

Mn 2 MnReO 6 : Synthesis and Magnetic Structure Determination of a New Transition-Metal-Only Double Perovskite Canted Antiferromagnet
journal, April 2016


The End of Moore's Law: A New Beginning for Information Technology
journal, March 2017

  • Theis, Thomas N.; Wong, H. -S. Philip
  • Computing in Science & Engineering, Vol. 19, Issue 2
  • DOI: 10.1109/MCSE.2017.29

Room-temperature magnetoresistance in an oxide material with an ordered double-perovskite structure
journal, October 1998

  • Kobayashi, K. -I.; Kimura, T.; Sawada, H.
  • Nature, Vol. 395, Issue 6703
  • DOI: 10.1038/27167

Weak spin interactions in Mott insulating La 2 O 2 Fe 2 OSe 2
journal, March 2014


Science and research policy at the end of Moore’s law
journal, January 2018

  • Khan, Hassan N.; Hounshell, David A.; Fuchs, Erica R. H.
  • Nature Electronics, Vol. 1, Issue 1
  • DOI: 10.1038/s41928-017-0005-9

Room temperature magnetoresistance in Ba2FeMoO6
journal, May 2001


Crystal structure of Ln1/3NbO3 (Ln=Nd, Pr) and phase transition in Nd1/3NbO3
journal, June 2007

  • Zhang, Zhaoming; Howard, Christopher J.; Kennedy, Brendan J.
  • Journal of Solid State Chemistry, Vol. 180, Issue 6
  • DOI: 10.1016/j.jssc.2007.03.029

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976


Synthesis, Crystal Structure, and Physical Properties of Sr 2 FeOsO 6
journal, May 2013

  • Paul, Avijit Kumar; Jansen, Martin; Yan, Binghai
  • Inorganic Chemistry, Vol. 52, Issue 11
  • DOI: 10.1021/ic400740f

Magnetism of the double perovskite Sr2FeMoO6
journal, March 2003

  • Lofland, S. E.; Scabarozi, T.; Moritomo, Y.
  • Journal of Magnetism and Magnetic Materials, Vol. 260, Issue 1-2
  • DOI: 10.1016/S0304-8853(02)01318-5

An overview of double perovskites A2B′B″O6 with small ions at A site: Synthesis, structure and magnetic properties
journal, April 2018


Investigations of the magnetic properties and structures of the pillared perovskites, La5Re3MO16 (M=Co, Ni)
journal, July 2006

  • Cuthbert, Heather L.; Greedan, John E.; Cranswick, Lachlan
  • Journal of Solid State Chemistry, Vol. 179, Issue 7
  • DOI: 10.1016/j.jssc.2006.03.043

Large Magnetization and Frustration Switching of Magnetoresistance in the Double-Perovskite Ferrimagnet Mn 2 FeReO 6
journal, August 2015

  • Arévalo-López, Angel M.; McNally, Graham M.; Attfield, J. Paul
  • Angewandte Chemie International Edition, Vol. 54, Issue 41
  • DOI: 10.1002/anie.201506540

Study of the valence state and electronic structure in Sr2FeMO6 (M = W, Mo, Re and Sb) double perovskites
journal, January 2010

  • Retuerto, M.; Jiménez-Villacorta, F.; Martínez-Lope, M. J.
  • Physical Chemistry Chemical Physics, Vol. 12, Issue 41
  • DOI: 10.1039/c004370b

Crystal and Magnetic Structure of Sr2MReO6 (M = Ni, Co, Zn) Double Perovskites: A Neutron Diffraction Study
journal, February 2008

  • Retuerto, María; Martínez-Lope, María Jesús; García-Hernández, Mar
  • European Journal of Inorganic Chemistry, Vol. 2008, Issue 4
  • DOI: 10.1002/ejic.200700753

Half-Metallicity in Pb 2 CoReO 6 Double Perovskite and High Magnetic Ordering Temperature in Pb 2 CrReO 6 Perovskite
journal, June 2015


Structural and spectroscopic properties of the polar antiferromagnet N i 2 MnTe O 6
journal, April 2018


Mn 2 (Fe 0.8 Mo 0.2 )MoO 6 : A Double Perovskite with Multiple Transition Metal Sublattice Magnetic Effects
journal, June 2018


Electronic Structure of Sr 2 FeMoO 6
journal, September 2000


Sr 4 M 3 ReO 12 (M = Co, Fe): New Ferromagnetic Perovskite Oxides
journal, July 2008

  • Nag, Abanti; Manjanna, J.; Tiwari, R. M.
  • Chemistry of Materials, Vol. 20, Issue 13
  • DOI: 10.1021/cm800749s

Intergrain tunneling magnetoresistance in polycrystals of the ordered double perovskite Sr 2 FeReO 6
journal, May 1999


ISODISPLACE : a web-based tool for exploring structural distortions
journal, July 2006

  • Campbell, Branton J.; Stokes, Harold T.; Tanner, David E.
  • Journal of Applied Crystallography, Vol. 39, Issue 4
  • DOI: 10.1107/S0021889806014075

CoReO4, a new rutile-type derivative with ordering of two cations
journal, July 1992


A2B′B″O6 perovskites: A review
journal, May 2015


Giant Magnetoresistance in the Half-Metallic Double-Perovskite Ferrimagnet Mn 2 FeReO 6
journal, July 2015

  • Li, Man-Rong; Retuerto, Maria; Deng, Zheng
  • Angewandte Chemie International Edition, Vol. 54, Issue 41
  • DOI: 10.1002/anie.201506456

Large Magnetization and Frustration Switching of Magnetoresistance in the Double-Perovskite Ferrimagnet Mn 2 FeReO 6
journal, August 2015

  • Arévalo-López, Angel M.; McNally, Graham M.; Attfield, J. Paul
  • Angewandte Chemie, Vol. 127, Issue 41
  • DOI: 10.1002/ange.201506540

Giant Magnetoresistance in the Half-Metallic Double-Perovskite Ferrimagnet Mn 2 FeReO 6
journal, July 2015

  • Li, Man-Rong; Retuerto, Maria; Deng, Zheng
  • Angewandte Chemie, Vol. 127, Issue 41
  • DOI: 10.1002/ange.201506456

    Works referencing / citing this record:

    Magnetic frustration in the high-pressure Mn 2 MnTeO 6 (Mn 3 TeO 6 -II) double perovskite
    journal, January 2019

    • Arévalo-López, Ángel M.; Solana-Madruga, Elena; Aguilar-Maldonado, Cintli
    • Chemical Communications, Vol. 55, Issue 96
    • DOI: 10.1039/c9cc07733b

    Magnetic transitions in exotic perovskites stabilized by chemical and physical pressure
    journal, January 2020

    • Ma, Yalin; Molokeev, Maxim S.; Zhu, Chuanhui
    • Journal of Materials Chemistry C, Vol. 8, Issue 15
    • DOI: 10.1039/c9tc06976c