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Title: Bulk crystal growth and characterization of the bismuth ferrite-based material Bi3FeO4(MoO4)2

Abstract

The large, high-quality Bi 3 FeO 4 (MoO 4 ) 2 single crystals of size up to 28 × 20 × 12 mm 3 were grown successfully by the TSSG method. The thermal, optical, magnetization, and polarized Raman properties are investigated in detail.

Authors:
 [1];  [1];  [1]; ORCiD logo [2];  [1];  [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Shandong Univ., Jinan (China)
  2. Shandong Univ., Jinan (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1502530
Alternate Identifier(s):
OSTI ID: 1499826
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
CrystEngComm
Additional Journal Information:
Journal Volume: 21; Journal Issue: 15; Journal ID: ISSN 1466-8033
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Li, Conggang, Gao, Zeliang, Tian, Xiangxin, Zhang, Junjie, Ju, Dianxing, Wu, Qian, Lu, Weiqun, Sun, Youxuan, Cui, Deliang, and Tao, Xutang. Bulk crystal growth and characterization of the bismuth ferrite-based material Bi3FeO4(MoO4)2. United States: N. p., 2019. Web. doi:10.1039/C8CE02137F.
Li, Conggang, Gao, Zeliang, Tian, Xiangxin, Zhang, Junjie, Ju, Dianxing, Wu, Qian, Lu, Weiqun, Sun, Youxuan, Cui, Deliang, & Tao, Xutang. Bulk crystal growth and characterization of the bismuth ferrite-based material Bi3FeO4(MoO4)2. United States. doi:10.1039/C8CE02137F.
Li, Conggang, Gao, Zeliang, Tian, Xiangxin, Zhang, Junjie, Ju, Dianxing, Wu, Qian, Lu, Weiqun, Sun, Youxuan, Cui, Deliang, and Tao, Xutang. Tue . "Bulk crystal growth and characterization of the bismuth ferrite-based material Bi3FeO4(MoO4)2". United States. doi:10.1039/C8CE02137F. https://www.osti.gov/servlets/purl/1502530.
@article{osti_1502530,
title = {Bulk crystal growth and characterization of the bismuth ferrite-based material Bi3FeO4(MoO4)2},
author = {Li, Conggang and Gao, Zeliang and Tian, Xiangxin and Zhang, Junjie and Ju, Dianxing and Wu, Qian and Lu, Weiqun and Sun, Youxuan and Cui, Deliang and Tao, Xutang},
abstractNote = {The large, high-quality Bi 3 FeO 4 (MoO 4 ) 2 single crystals of size up to 28 × 20 × 12 mm 3 were grown successfully by the TSSG method. The thermal, optical, magnetization, and polarized Raman properties are investigated in detail.},
doi = {10.1039/C8CE02137F},
journal = {CrystEngComm},
number = 15,
volume = 21,
place = {United States},
year = {2019},
month = {3}
}

Journal Article:
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Works referenced in this record:

Polymorphic Smooth Interfaces Formation Based on the Biphasic BaTeMo 2 O 9 Using Top Multi-Seeded Growth
journal, July 2018


Generalized Gradient Approximation Made Simple
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Intrinsic Ferroelasticity and/or Multiferroicity in Two-Dimensional Phosphorene and Phosphorene Analogues
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Spontaneous Raman spectroscopy of tungstate and molybdate crystals for Raman lasers
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Synthesis, crystal growth, and characterization of the orthorhombic BaTeW2O9: a new polymorph of BaTeW2O9
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Controlled Growth of Layered Acentric CdTeMoO 6 Single Crystals with Linear and Nonlinear Optical Properties
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A Comprehensive Scenario of the Crystal Growth of γ-Bi 2 MoO 6 Catalyst during Hydrothermal Synthesis
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Biaxial crystal β-BaTeMo_2O_9: theoretical analysis and the feasibility as high-efficiency acousto-optic Q-switch
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Electrical properties of bismuth ferrites: Bi2Fe4O9 and Bi25FeO39
journal, February 2019


Physics and Applications of Bismuth Ferrite
journal, June 2009


Surface, optical characteristics and photocatalytic ability of Scheelite-type monoclinic Bi3FeMo2O12 nanoparticles
journal, November 2016


Crystal Growth and Optical Properties of Beryllium-Free Nonlinear Optical Crystal K 3 Ba 3 Li 2 Al 4 B 6 O 20 F
journal, January 2018


Room-temperature coexistence of large electric polarization and magnetic order in Bi Fe O 3 single crystals
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Bond-valence parameters for solids
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  • Acta Crystallographica Section B Structural Science, Vol. 47, Issue 2
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Understanding ferroelectricity in layered perovskites: new ideas and insights from theory and experiments
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Protein-assisted synthesis of single-crystal nanowires of bismuth compounds
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Bi3(FeO4)(MoO4)2 and Bi3(GaO4)(MoO4)2 - new compounds with scheelite related structures
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First-principles study of multiferroic RbFe ( MoO 4 ) 2
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Anomalous Photovoltaic Effect in Centrosymmetric Ferroelastic BiVO 4
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The origin of coloration of CaGdAlO 4 crystals and its effect on their physical properties
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Electric–elastic properties of a novel high-quality CdTeMoO 6 piezoelectric crystal
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  • DOI: 10.1039/C8CE01196F

High efficient external resonator Raman laser based on the monoclinic single crystal BaTeMo 2 O 9
journal, June 2012

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Top-Seeded Solution Growth, Structure, Morphology, and Functional Properties of a New Polar Crystal — Cs 2 TeW 3 O 12
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Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation
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  • DOI: 10.1021/cm2015143

Multiferroic bismuth ferrite-based materials for multifunctional applications: Ceramic bulks, thin films and nanostructures
journal, December 2016


Multiferroicity in the generic easy-plane triangular lattice antiferromagnet RbFe(MoO 4 ) 2
journal, August 2013


Restoring the Density-Gradient Expansion for Exchange in Solids and Surfaces
journal, April 2008


Recent Progress in Multiferroic Magnetoelectric Composites: from Bulk to Thin Films
journal, February 2011


Efficient Raman scattering response and large piezoelectricity in noncentrosymmetric MnHg(SCN) 4 crystals
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  • Liu, Xitao; Long, Peiqing; Wang, Xinqiang
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  • DOI: 10.1039/C7TC00622E

Top-seeded solution growth and characterization of a Bi 2 Mo 2.66 W 0.34 O 12 single crystal
journal, January 2015

  • Tian, Xiangxin; Wu, Qian; Zhao, Peng
  • CrystEngComm, Vol. 17, Issue 24
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Investigations into anisotropic properties of the nonlinear optical material CdTeMoO6 with quasi-two-dimensional structure
journal, March 2019


Materials Discovery by Flux Crystal Growth: Quaternary and Higher Order Oxides
journal, January 2012

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Magnetostructural correlations in BiFeO 3 -based multiferroics
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    Works referencing / citing this record:

    Surface, optical characteristics and photocatalytic ability of Scheelite-type monoclinic Bi3FeMo2O12 nanoparticles
    journal, November 2016


    Epitaxial BiFeO3 Multiferroic Thin Film Heterostructures
    journal, March 2003


    The origin of coloration of CaGdAlO 4 crystals and its effect on their physical properties
    journal, January 2017

    • Hu, Qiangqiang; Jia, Zhitai; Tang, Cheng
    • CrystEngComm, Vol. 19, Issue 3
    • DOI: 10.1039/c6ce02411d

    Physics and Applications of Bismuth Ferrite
    journal, June 2009


    The compounds and the phase diagram of MoO3-Rich Bi2O3MoO3 system
    journal, April 1975


    Thermodynamic Properties, Mössbauer Study, and First-Principles Calculations of TlFe(MoO 4 ) 2
    journal, July 2018

    • Sobolev, A. V.; Kozlyakova, E. S.; Glazkova, I. S.
    • The Journal of Physical Chemistry C, Vol. 122, Issue 34
    • DOI: 10.1021/acs.jpcc.8b05122

    Anomalous Photovoltaic Effect in Centrosymmetric Ferroelastic BiVO 4
    journal, September 2018


    Biaxial crystal β-BaTeMo_2O_9: theoretical analysis and the feasibility as high-efficiency acousto-optic Q-switch
    journal, January 2017

    • Wu, Qian; Gao, Zeliang; Tian, Xiangxin
    • Optics Express, Vol. 25, Issue 21
    • DOI: 10.1364/oe.25.024893

    Materials Discovery by Flux Crystal Growth: Quaternary and Higher Order Oxides
    journal, January 2012

    • Bugaris, Daniel E.; zur Loye, Hans-Conrad
    • Angewandte Chemie International Edition, Vol. 51, Issue 16
    • DOI: 10.1002/anie.201102676

    Synthesis, crystal growth, and characterization of the orthorhombic BaTeW2O9: a new polymorph of BaTeW2O9
    journal, January 2013

    • Zhang, Zhonghan; Tao, Xutang; Zhang, Junjie
    • CrystEngComm, Vol. 15, Issue 47
    • DOI: 10.1039/c3ce41272e

    Polymorphic Smooth Interfaces Formation Based on the Biphasic BaTeMo 2 O 9 Using Top Multi-Seeded Growth
    journal, July 2018


    Magnetostructural correlations in BiFeO 3 -based multiferroics
    journal, January 2017

    • Khomchenko, V. A.; Karpinsky, D. V.; Paixão, J. A.
    • Journal of Materials Chemistry C, Vol. 5, Issue 14
    • DOI: 10.1039/c7tc00833c

    Efficient Raman scattering response and large piezoelectricity in noncentrosymmetric MnHg(SCN) 4 crystals
    journal, January 2017

    • Liu, Xitao; Long, Peiqing; Wang, Xinqiang
    • Journal of Materials Chemistry C, Vol. 5, Issue 13
    • DOI: 10.1039/c7tc00622e

    A Comprehensive Scenario of the Crystal Growth of γ-Bi 2 MoO 6 Catalyst during Hydrothermal Synthesis
    journal, November 2012

    • Kongmark, Chanapa; Coulter, Rachel; Cristol, Sylvain
    • Crystal Growth & Design, Vol. 12, Issue 12
    • DOI: 10.1021/cg301070e

    Bond-valence parameters for solids
    journal, April 1991

    • Brese, N. E.; O'Keeffe, M.
    • Acta Crystallographica Section B Structural Science, Vol. 47, Issue 2
    • DOI: 10.1107/s0108768190011041

    Top-seeded solution growth and characterization of a Bi 2 Mo 2.66 W 0.34 O 12 single crystal
    journal, January 2015

    • Tian, Xiangxin; Wu, Qian; Zhao, Peng
    • CrystEngComm, Vol. 17, Issue 24
    • DOI: 10.1039/c5ce00639b

    Controlled Growth of Layered Acentric CdTeMoO 6 Single Crystals with Linear and Nonlinear Optical Properties
    journal, May 2018

    • Li, Conggang; Tian, Xiangxin; Gao, Zeliang
    • Crystal Growth & Design, Vol. 18, Issue 6
    • DOI: 10.1021/acs.cgd.8b00085

    Generalized Gradient Approximation Made Simple
    journal, October 1996

    • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
    • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
    • DOI: 10.1103/physrevlett.77.3865

    Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation
    journal, August 2011

    • Zhang, Junjie; Zhang, Zhonghan; Zhang, Weiguo
    • Chemistry of Materials, Vol. 23, Issue 16
    • DOI: 10.1021/cm2015143

    Top-Seeded Solution Growth, Structure, Morphology, and Functional Properties of a New Polar Crystal — Cs 2 TeW 3 O 12
    journal, August 2015

    • Zhao, Peng; Cong, Hengjiang; Tian, Xiangxin
    • Crystal Growth & Design, Vol. 15, Issue 9
    • DOI: 10.1021/acs.cgd.5b00753

    A short history of SHELX
    journal, December 2007

    • Sheldrick, George M.
    • Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
    • DOI: 10.1107/s0108767307043930

    Multiferroic bismuth ferrite-based materials for multifunctional applications: Ceramic bulks, thin films and nanostructures
    journal, December 2016


    Electrical properties of bismuth ferrites: Bi2Fe4O9 and Bi25FeO39
    journal, February 2019


    CSD 1879545: Experimental Crystal Structure Determination
    dataset, January 2019

    • Li, Conggang; Gao, Zeliang; Tian, Xiangxin
    • FIZ Karlsruhe – Leibniz Institute for Information Infrastructure
    • DOI: 10.25505/fiz.icsd.cc212thg

    Investigations into anisotropic properties of the nonlinear optical material CdTeMoO6 with quasi-two-dimensional structure
    journal, March 2019


    Room-temperature coexistence of large electric polarization and magnetic order in Bi Fe O 3 single crystals
    journal, July 2007


    Recent Progress in Multiferroic Magnetoelectric Composites: from Bulk to Thin Films
    journal, February 2011


    Bi3(FeO4)(MoO4)2 and Bi3(GaO4)(MoO4)2 - new compounds with scheelite related structures
    journal, July 1974


    A comprehensive study of disordered and ordered scheelite-related Bi3(FeO4)(MoO4)2
    journal, April 1976

    • Jeitschko, W.; Sleight, A. W.; McClellan, W. R.
    • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 32, Issue 4
    • DOI: 10.1107/s056774087600486x

    Crystal Growth and Optical Properties of Beryllium-Free Nonlinear Optical Crystal K 3 Ba 3 Li 2 Al 4 B 6 O 20 F
    journal, January 2018


    Protein-assisted synthesis of single-crystal nanowires of bismuth compounds
    journal, January 2005

    • Gao, Feng; Lu, Qingyi; Komarneni, Sridhar
    • Chemical Communications, Issue 4
    • DOI: 10.1039/b413584a

    High efficient external resonator Raman laser based on the monoclinic single crystal BaTeMo 2 O 9
    journal, June 2012

    • Gao, Zeliang; Liu, Shande; Zhang, Shaojun
    • Applied Physics Letters, Vol. 100, Issue 26
    • DOI: 10.1063/1.4730635

    Understanding ferroelectricity in layered perovskites: new ideas and insights from theory and experiments
    journal, January 2015

    • Benedek, Nicole A.; Rondinelli, James M.; Djani, Hania
    • Dalton Transactions, Vol. 44, Issue 23
    • DOI: 10.1039/c5dt00010f

    First-principles study of multiferroic RbFe ( MoO 4 ) 2
    journal, July 2014


    Multiferroicity in the generic easy-plane triangular lattice antiferromagnet RbFe(MoO 4 ) 2
    journal, August 2013


    Spontaneous Raman spectroscopy of tungstate and molybdate crystals for Raman lasers
    journal, December 2000


    Intrinsic Ferroelasticity and/or Multiferroicity in Two-Dimensional Phosphorene and Phosphorene Analogues
    journal, April 2016


    Restoring the Density-Gradient Expansion for Exchange in Solids and Surfaces
    journal, April 2008


    Electric–elastic properties of a novel high-quality CdTeMoO 6 piezoelectric crystal
    journal, January 2018

    • Li, Conggang; Gao, Zeliang; Tian, Xiangxin
    • CrystEngComm, Vol. 20, Issue 37
    • DOI: 10.1039/c8ce01196f