Quantum cascade laser-based analyzer for hydrogen sulfide detection at sub-parts-per-million levels
Abstract
Due to its high toxicity, monitoring of hydrogen sulfide (H2S) concentration is essential in many industrial sites (such as natural gas extraction sites, petroleum refineries, geothermal power plants, or waste water treatment facilities), which require sub-parts-per-million sensitivities. We report on a quantum cascade laserbased spectroscopic system for detection of H2S in the midinfrared at ~7.2 μm. We present a sensor design utilizing Herriott multipass cell and a wavelength modulation spectroscopy to achieve a detection limit of 140 parts per billion for 1-s integration time.
- Authors:
-
- Wroclaw Research Centre EIT+, Wroclaw (Poland). Laser Sensing Lab.; Wroclaw Univ. of Science and Technology, Wroclaw (Poland). Dept. of Optics and Photonics, Faculty of Fundamental Problems of Technology
- Wroclaw Univ. of Science and Technology, Wroclaw (Poland). Laser and Fiber Electronics Group
- Wroclaw Research Centre EIT+, Wroclaw (Poland). Laser Sensing Lab.
- Princeton Univ., NJ (United States). Electrical Engineering Dept.
- Publication Date:
- Research Org.:
- International Business Machines Corporation, Yorktown Heights, NY (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E); Polish Ministry of Science and Higher Education; National Centre for Research and Development (NCBiR)
- OSTI Identifier:
- 1502477
- Grant/Contract Number:
- AR0000540
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Optical Engineering
- Additional Journal Information:
- Journal Volume: 57; Journal Issue: 01; Journal ID: ISSN 0091-3286
- Publisher:
- SPIE
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 47 OTHER INSTRUMENTATION; molecular spectroscopy; laser spectroscopy; wavelength modulation spectroscopy; quantum cascade laser; hydrogen sulfide
Citation Formats
Nikodem, Michal, Krzempek, Karol, Stachowiak, Dorota, and Wysocki, Gerard. Quantum cascade laser-based analyzer for hydrogen sulfide detection at sub-parts-per-million levels. United States: N. p., 2017.
Web. doi:10.1117/1.oe.57.1.011019.
Nikodem, Michal, Krzempek, Karol, Stachowiak, Dorota, & Wysocki, Gerard. Quantum cascade laser-based analyzer for hydrogen sulfide detection at sub-parts-per-million levels. United States. https://doi.org/10.1117/1.oe.57.1.011019
Nikodem, Michal, Krzempek, Karol, Stachowiak, Dorota, and Wysocki, Gerard. Wed .
"Quantum cascade laser-based analyzer for hydrogen sulfide detection at sub-parts-per-million levels". United States. https://doi.org/10.1117/1.oe.57.1.011019. https://www.osti.gov/servlets/purl/1502477.
@article{osti_1502477,
title = {Quantum cascade laser-based analyzer for hydrogen sulfide detection at sub-parts-per-million levels},
author = {Nikodem, Michal and Krzempek, Karol and Stachowiak, Dorota and Wysocki, Gerard},
abstractNote = {Due to its high toxicity, monitoring of hydrogen sulfide (H2S) concentration is essential in many industrial sites (such as natural gas extraction sites, petroleum refineries, geothermal power plants, or waste water treatment facilities), which require sub-parts-per-million sensitivities. We report on a quantum cascade laserbased spectroscopic system for detection of H2S in the midinfrared at ~7.2 μm. We present a sensor design utilizing Herriott multipass cell and a wavelength modulation spectroscopy to achieve a detection limit of 140 parts per billion for 1-s integration time.},
doi = {10.1117/1.oe.57.1.011019},
journal = {Optical Engineering},
number = 01,
volume = 57,
place = {United States},
year = {Wed Oct 11 00:00:00 EDT 2017},
month = {Wed Oct 11 00:00:00 EDT 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Cited by: 7 works
Citation information provided by
Web of Science
Web of Science
Figures / Tables:
Fig. 1 : (a) Infrared absorption spectrum of H2S based on HITRAN database. Near-infrared band (typically used for optical-based H2S detection) and spectral region explored in this work (at ∼7.2 μm) are indicated. (b) Line intensities for three molecules: hydrogen sulfide, methane, and water vapor. The chosen transition at ∼1389.3more »
All figures and tables
(5 total)
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
High Resolution Vibrational–Rotational Spectrum of H2S in the Region of the ν2Fundamental Band
journal, April 1996
- Ulenikov, O. N.; Malikova, A. B.; Koivusaari, M.
- Journal of Molecular Spectroscopy, Vol. 176, Issue 2
Chirped Laser Dispersion Spectroscopy for Remote Open-Path Trace-Gas Sensing
journal, November 2012
- Nikodem, Michal; Wysocki, Gerard
- Sensors, Vol. 12, Issue 12
Implementation of a quantum cascade laser-based gas sensor prototype for sub-ppmv H2S measurements in a petrochemical process gas stream
journal, September 2016
- Moser, Harald; Pölz, Walter; Waclawek, Johannes Paul
- Analytical and Bioanalytical Chemistry, Vol. 409, Issue 3
The infrared spectrum of H 2 S from 1 to 5 μm
journal, November 1994
- Bykov, Alexander D.; Naumenko, Olga V.; Smirnov, Maxim A.
- Canadian Journal of Physics, Vol. 72, Issue 11-12
A compact QCL based methane and nitrous oxide sensor for environmental and medical applications
journal, January 2014
- Jahjah, Mohammad; Ren, Wei; Stefański, Przemysław
- The Analyst, Vol. 139, Issue 9
H2S trace concentration measurements using off-axis integrated cavity output spectroscopy in the near-infrared
journal, December 2007
- Chen, W.; Kosterev, A. A.; Tittel, F. K.
- Applied Physics B, Vol. 90, Issue 2
A quantum cascade laser-based water vapor isotope analyzer for environmental monitoring
journal, September 2014
- Wang, W. E.; Michel, A. P. M.; Wang, L.
- Review of Scientific Instruments, Vol. 85, Issue 9
The HITRAN2012 molecular spectroscopic database
journal, November 2013
- Rothman, L. S.; Gordon, I. E.; Babikov, Y.
- Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 130, p. 4-50
H2S and CO2 gas sensing using DFB laser diodes emitting at 1.57 μm
journal, October 1995
- Weldon, V.; O'Gorman, J.; Phelan, P.
- Sensors and Actuators B: Chemical, Vol. 29, Issue 1-3
In situ and wide range quantification of hydrogen sulfide in industrial gases by means of photoacoustic spectroscopy
journal, April 2013
- Szabó, A.; Mohácsi, Á; Gulyás, G.
- Measurement Science and Technology, Vol. 24, Issue 6
Accuracy and precision of laser spectrometers for trace gas sensing in the presence of optical fringes and atmospheric turbulence
journal, August 2010
- Werle, P.
- Applied Physics B, Vol. 102, Issue 2
Photoacoustic Techniques for Trace Gas Sensing Based on Semiconductor Laser Sources
journal, December 2009
- Elia, Angela; Lugarà, Pietro Mario; Di Franco, Cinzia
- Sensors, Vol. 9, Issue 12
Fiber-Amplifier-Enhanced QEPAS Sensor for Simultaneous Trace Gas Detection of NH3 and H2S
journal, October 2015
- Wu, Hongpeng; Dong, Lei; Liu, Xiaoli
- Sensors, Vol. 15, Issue 10
Off-beam quartz-enhanced photoacoustic spectroscopy-based sensor for hydrogen sulfide trace gas detection using a mode-hop-free external cavity quantum cascade laser
journal, April 2017
- Helman, Marek; Moser, Harald; Dudkowiak, Alina
- Applied Physics B, Vol. 123, Issue 5
Chirped laser dispersion spectroscopy for laser-based hydrogen sulfide detection in open-path conditions
journal, January 2016
- Nikodem, Michał
- Optics Express, Vol. 24, Issue 10
Shot-noise Limited Faraday Rotation Spectroscopy for Detection of Nitric Oxide Isotopes in Breath, Urine and Blood
journal, March 2015
- Wang, Yin; Nikodem, Michal; Zhang, Eric
- Scientific Reports, Vol. 5, Issue 1
Widely-tunable mid-infrared fiber-coupled quartz-enhanced photoacoustic sensor for environmental monitoring
journal, January 2014
- Siciliani de Cumis, M.; Viciani, S.; Borri, S.
- Optics Express, Vol. 22, Issue 23
A quartz-enhanced photoacoustic sensor for H2S trace-gas detection at 2.6 μm
journal, December 2014
- Viciani, S.; Siciliani de Cumis, M.; Borri, S.
- Applied Physics B, Vol. 119, Issue 1
Application of a ring cavity surface emitting quantum cascade laser (RCSE-QCL) on the measurement of H_2S in a CH_4 matrix for process analytics
journal, January 2016
- Moser, Harald; Genner, Andreas; Ofner, Johannes
- Optics Express, Vol. 24, Issue 6
Works referencing / citing this record:
Simultaneous monitoring of 32 S, 33 S and 34 S isotopes of H 2 S using cavity ring-down spectroscopy with a mid-infrared external-cavity quantum cascade laser
journal, January 2019
- Pal, Mithun; Maithani, Sanchi; Maity, Abhijit
- Journal of Analytical Atomic Spectrometry, Vol. 34, Issue 5
Figures / Tables found in this record:
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.