An Aqueous Dual‐Ion Battery Cathode of Mn 3 O 4 via Reversible Insertion of Nitrate
Abstract
Abstract We report reversible electrochemical insertion of NO 3 − into manganese(II, III) oxide (Mn 3 O 4 ) as a cathode for aqueous dual‐ion batteries. Characterization by TGA, FTIR, EDX, XANES, EXAFS, and EQCM collectively provides unequivocal evidence that reversible oxidative NO 3 − insertion takes place inside Mn 3 O 4 . Ex situ HRTEM and corresponding EDX mapping results suggest that NO 3 − insertion de‐crystallizes the structure of Mn 3 O 4 . Kinetic studies reveal fast migration of NO 3 − in the Mn 3 O 4 structure. This finding may open a new direction for novel low‐cost aqueous dual‐ion batteries.
- Authors:
-
[1]
- Department of Chemistry Oregon State University Corvallis OR 97331-4003 USA
- Department of Chemistry Oregon State University Corvallis OR 97331-4003 USA, Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education) College of Physics Jilin University Changchun 130012 P. R. China
- Chemical Sciences and Engineering Division and X-ray Science Division Advanced Photon Sources Argonne National Laboratory Lemont IL 60439 USA
- CAMCOR University of Oregon Eugene OR 97403 USA
- Hewlett–Packard Co. 1000 NE Circle Blvd. Corvallis OR 97330 USA
- Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education) College of Physics Jilin University Changchun 130012 P. R. China
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1501947
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 131 Journal Issue: 16; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Jiang, Heng, Wei, Zhixuan, Ma, Lu, Yuan, Yifei, Hong, Jessica J., Wu, Xianyong, Leonard, Daniel P., Holoubek, John, Razink, Joshua James, Stickle, William F., Du, Fei, Wu, Tianpin, Lu, Jun, and Ji, Xiulei. An Aqueous Dual‐Ion Battery Cathode of Mn 3 O 4 via Reversible Insertion of Nitrate. Germany: N. p., 2019.
Web. doi:10.1002/ange.201814646.
Jiang, Heng, Wei, Zhixuan, Ma, Lu, Yuan, Yifei, Hong, Jessica J., Wu, Xianyong, Leonard, Daniel P., Holoubek, John, Razink, Joshua James, Stickle, William F., Du, Fei, Wu, Tianpin, Lu, Jun, & Ji, Xiulei. An Aqueous Dual‐Ion Battery Cathode of Mn 3 O 4 via Reversible Insertion of Nitrate. Germany. https://doi.org/10.1002/ange.201814646
Jiang, Heng, Wei, Zhixuan, Ma, Lu, Yuan, Yifei, Hong, Jessica J., Wu, Xianyong, Leonard, Daniel P., Holoubek, John, Razink, Joshua James, Stickle, William F., Du, Fei, Wu, Tianpin, Lu, Jun, and Ji, Xiulei. Tue .
"An Aqueous Dual‐Ion Battery Cathode of Mn 3 O 4 via Reversible Insertion of Nitrate". Germany. https://doi.org/10.1002/ange.201814646.
@article{osti_1501947,
title = {An Aqueous Dual‐Ion Battery Cathode of Mn 3 O 4 via Reversible Insertion of Nitrate},
author = {Jiang, Heng and Wei, Zhixuan and Ma, Lu and Yuan, Yifei and Hong, Jessica J. and Wu, Xianyong and Leonard, Daniel P. and Holoubek, John and Razink, Joshua James and Stickle, William F. and Du, Fei and Wu, Tianpin and Lu, Jun and Ji, Xiulei},
abstractNote = {Abstract We report reversible electrochemical insertion of NO 3 − into manganese(II, III) oxide (Mn 3 O 4 ) as a cathode for aqueous dual‐ion batteries. Characterization by TGA, FTIR, EDX, XANES, EXAFS, and EQCM collectively provides unequivocal evidence that reversible oxidative NO 3 − insertion takes place inside Mn 3 O 4 . Ex situ HRTEM and corresponding EDX mapping results suggest that NO 3 − insertion de‐crystallizes the structure of Mn 3 O 4 . Kinetic studies reveal fast migration of NO 3 − in the Mn 3 O 4 structure. This finding may open a new direction for novel low‐cost aqueous dual‐ion batteries.},
doi = {10.1002/ange.201814646},
journal = {Angewandte Chemie},
number = 16,
volume = 131,
place = {Germany},
year = {Tue Mar 19 00:00:00 EDT 2019},
month = {Tue Mar 19 00:00:00 EDT 2019}
}
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