Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries

Luque, Guillermina L.; Li, Yan; Zeng, Xiaoqiao; Luo, Xiangyi; Leiva, Ezequiel P.  M.; Chen, Zonghai; Amine, Khalil

doi:10.1007/s10008-018-4145-2

Title: Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries

Journal Article · 14 November 2018 · Journal of Solid State Electrochemistry

DOI: https://doi.org/10.1007/s10008-018-4145-2 · OSTI ID:1501868

^[1]; Li, Yan ^[2]; Zeng, Xiaoqiao ^[2]; Luo, Xiangyi ^[2]; Leiva, Ezequiel P. M. ^[3]; Chen, Zonghai ^[2]; Amine, Khalil ^[2]

Argonne National Lab. (ANL), Lemont, IL (United States); Universidad Nacional de Córdoba, Córdoba (Argentina)
Argonne National Lab. (ANL), Lemont, IL (United States)
Universidad Nacional de Córdoba, Córdoba (Argentina)

The electrochemical performance of SiO-SnCoC composite anode for high-energy lithium-ion batteries was evaluated with particular emphasis on the impact of Alginate as a polymeric binder, as well as fluoroethylene carbonate (FEC) as electrolyte additive. It was found that the presence of FEC and the use of alginate pH3 as binder help to improve the electrochemical stability of the composite anode, showing the best electrochemical performance with a high specific capacity, great capacity retention, and excellent coulombic efficiency. Specifically, the high precision self-discharge current study revealed that the alginate binder slowed down the parasitic reactions between the lithiated anode and the non-aqueous electrolyte.

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Research Organization:: Argonne National Lab. (ANL), Lemont, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1501868

Journal Information:: Journal of Solid State Electrochemistry, Journal Name: Journal of Solid State Electrochemistry Journal Issue: 2 Vol. 23; ISSN 1432-8488

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Alginate
Anode
Fluoroethylene carbonate
Lithium-ion batteries
Parasitic reaction
Self-discharge

Title: Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries

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