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Title: Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries

Abstract

The electrochemical performance of SiO-SnCoC composite anode for high-energy lithium-ion batteries was evaluated with particular emphasis on the impact of Alginate as a polymeric binder, as well as fluoroethylene carbonate (FEC) as electrolyte additive. It was found that the presence of FEC and the use of alginate pH3 as binder help to improve the electrochemical stability of the composite anode, showing the best electrochemical performance with a high specific capacity, great capacity retention, and excellent coulombic efficiency. Specifically, the high precision self-discharge current study revealed that the alginate binder slowed down the parasitic reactions between the lithiated anode and the non-aqueous electrolyte.

Authors:
ORCiD logo [1];  [2];  [2];  [2];  [3];  [2];  [2]
  1. Argonne National Lab. (ANL), Lemont, IL (United States); Universidad Nacional de Córdoba, Córdoba (Argentina)
  2. Argonne National Lab. (ANL), Lemont, IL (United States)
  3. Universidad Nacional de Córdoba, Córdoba (Argentina)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
OSTI Identifier:
1501868
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Solid State Electrochemistry
Additional Journal Information:
Journal Volume: 23; Journal Issue: 2; Journal ID: ISSN 1432-8488
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE; Alginate; Anode; Fluoroethylene carbonate; Lithium-ion batteries; Parasitic reaction; Self-discharge

Citation Formats

Luque, Guillermina L., Li, Yan, Zeng, Xiaoqiao, Luo, Xiangyi, Leiva, Ezequiel P. M., Chen, Zonghai, and Amine, Khalil. Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries. United States: N. p., 2018. Web. doi:10.1007/s10008-018-4145-2.
Luque, Guillermina L., Li, Yan, Zeng, Xiaoqiao, Luo, Xiangyi, Leiva, Ezequiel P. M., Chen, Zonghai, & Amine, Khalil. Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries. United States. https://doi.org/10.1007/s10008-018-4145-2
Luque, Guillermina L., Li, Yan, Zeng, Xiaoqiao, Luo, Xiangyi, Leiva, Ezequiel P. M., Chen, Zonghai, and Amine, Khalil. Thu . "Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries". United States. https://doi.org/10.1007/s10008-018-4145-2. https://www.osti.gov/servlets/purl/1501868.
@article{osti_1501868,
title = {Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries},
author = {Luque, Guillermina L. and Li, Yan and Zeng, Xiaoqiao and Luo, Xiangyi and Leiva, Ezequiel P. M. and Chen, Zonghai and Amine, Khalil},
abstractNote = {The electrochemical performance of SiO-SnCoC composite anode for high-energy lithium-ion batteries was evaluated with particular emphasis on the impact of Alginate as a polymeric binder, as well as fluoroethylene carbonate (FEC) as electrolyte additive. It was found that the presence of FEC and the use of alginate pH3 as binder help to improve the electrochemical stability of the composite anode, showing the best electrochemical performance with a high specific capacity, great capacity retention, and excellent coulombic efficiency. Specifically, the high precision self-discharge current study revealed that the alginate binder slowed down the parasitic reactions between the lithiated anode and the non-aqueous electrolyte.},
doi = {10.1007/s10008-018-4145-2},
journal = {Journal of Solid State Electrochemistry},
number = 2,
volume = 23,
place = {United States},
year = {2018},
month = {11}
}

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Works referenced in this record:

Acrylic Acid-Based Copolymers as Functional Binder for Silicon/Graphite Composite Electrode in Lithium-Ion Batteries
journal, January 2015

  • Aoki, Shoko; Han, Zhen-Ji; Yamagiwa, Kiyofumi
  • Journal of The Electrochemical Society, Vol. 162, Issue 12
  • DOI: 10.1149/2.0171512jes

Alginate: Properties and biomedical applications
journal, January 2012


A review on electrolyte additives for lithium-ion batteries
journal, November 2006


Formation of Polysaccharide Gel Layers in the Presence of Ca 2+ and K + Ions:  Measurements and Mechanisms
journal, January 2007

  • de Kerchove, Alexis J.; Elimelech, Menachem
  • Biomacromolecules, Vol. 8, Issue 1
  • DOI: 10.1021/bm060670i

Carboxymethyl chitosan: A new water soluble binder for Si anode of Li-ion batteries
journal, February 2014


Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries
journal, January 2011

  • Ji, Liwen; Lin, Zhan; Alcoutlabi, Mataz
  • Energy & Environmental Science, Vol. 4, Issue 8, p. 2682-2699
  • DOI: 10.1039/c0ee00699h

New Anode Material Based on SiO–Sn x Co y C z for Lithium Batteries
journal, December 2012

  • Liu, Bo; Abouimrane, Ali; Ren, Yang
  • Chemistry of Materials, Vol. 24, Issue 24
  • DOI: 10.1021/cm3017853

Dual-functional gum arabic binder for silicon anodes in lithium ion batteries
journal, March 2015


The binder effect on an oxide-based anode in lithium and sodium-ion battery applications: the fastest way to ultrahigh performance
journal, January 2014

  • Ming, Jun; Ming, Hai; Kwak, Won-Jin
  • Chem. Commun., Vol. 50, Issue 87
  • DOI: 10.1039/C4CC02657H

A high-performance alginate hydrogel binder for the Si/C anode of a Li-ion battery
journal, January 2014

  • Liu, Jie; Zhang, Qian; Wu, Zhan-Yu
  • Chemical Communications, Vol. 50, Issue 48
  • DOI: 10.1039/c4cc00081a

Chitosan, a new and environmental benign electrode binder for use with graphite anode in lithium-ion batteries
journal, August 2013


Potential of lithium-ion batteries in renewable energy
journal, April 2015


Silicon Composite Electrode with High Capacity and Long Cycle Life
journal, January 2009

  • Mazouzi, D.; Lestriez, B.; Roué, L.
  • Electrochemical and Solid-State Letters, Vol. 12, Issue 11
  • DOI: 10.1149/1.3212894

What Makes Fluoroethylene Carbonate Different?
journal, June 2015

  • Shkrob, Ilya A.; Wishart, James F.; Abraham, Daniel P.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 27
  • DOI: 10.1021/acs.jpcc.5b03591

Mechanically alloyed composite anode materials based on SiO–SnxFeyCz for Li-ion batteries
journal, January 2013

  • Liu, Bo; Abouimrane, Ali; Brown, Dennis E.
  • Journal of Materials Chemistry A, Vol. 1, Issue 13
  • DOI: 10.1039/c3ta00101f

Toward Efficient Binders for Li-Ion Battery Si-Based Anodes: Polyacrylic Acid
journal, October 2010

  • Magasinski, Alexandre; Zdyrko, Bogdan; Kovalenko, Igor
  • ACS Applied Materials & Interfaces, Vol. 2, Issue 11
  • DOI: 10.1021/am100871y

Review on recent progress of nanostructured anode materials for Li-ion batteries
journal, July 2014


Lithium ion rechargeable batteries: State of the art and future needs of microscopic theoretical models and simulations
journal, February 2015


Key Parameters Governing the Reversibility of Si/Carbon/CMC Electrodes for Li-Ion Batteries
journal, February 2010

  • Bridel, J. -S.; Azaïs, T.; Morcrette, M.
  • Chemistry of Materials, Vol. 22, Issue 3
  • DOI: 10.1021/cm902688w

Amorphous silicon as a possible anode material for Li-ion batteries
journal, September 1999


Phase Changes in Electrochemically Lithiated Silicon at Elevated Temperature
journal, January 2006

  • Wang, Yadong; Dahn, Jeff
  • Journal of The Electrochemical Society, Vol. 153, Issue 12
  • DOI: 10.1149/1.2359690

Stable SiOC/Sn Nanocomposite Anodes for Lithium-Ion Batteries with Outstanding Cycling Stability
journal, March 2014

  • Kaspar, Jan; Terzioglu, Caglar; Ionescu, Emanuel
  • Advanced Functional Materials, Vol. 24, Issue 26
  • DOI: 10.1002/adfm.201303828

A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries
journal, September 2011


Kinetic Study of Parasitic Reactions in Lithium-Ion Batteries: A Case Study on LiNi 0.6 Mn 0.2 Co 0.2 O 2
journal, January 2016

  • Zeng, Xiaoqiao; Xu, Gui-Liang; Li, Yan
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 5
  • DOI: 10.1021/acsami.5b11800

Alloy Negative Electrodes for Li-Ion Batteries
journal, October 2014

  • Obrovac, M. N.; Chevrier, V. L.
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr500207g

Effect of the Electrolyte Composition on SEI Reactions at Si Anodes of Li-Ion Batteries
journal, March 2015

  • Martinez de la Hoz, Julibeth M.; Soto, Fernando A.; Balbuena, Perla B.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 13
  • DOI: 10.1021/acs.jpcc.5b01228

Li-ion battery materials: present and future
journal, June 2015


Investigations on high energy lithium-ion batteries with aqueous binder
journal, December 2013


Study on Polymer Binders for High-Capacity SiO Negative Electrode of Li-Ion Batteries
journal, June 2011

  • Komaba, Shinichi; Shimomura, Keiji; Yabuuchi, Naoaki
  • The Journal of Physical Chemistry C, Vol. 115, Issue 27
  • DOI: 10.1021/jp201691g

Critical roles of binders and formulation at multiscales of silicon-based composite electrodes
journal, April 2015


A comparative study of Si-containing electrolyte additives for lithium ion battery: Which one is better and why is it better
journal, February 2017


Improvement of cyclability of Si as anode for Li-ion batteries
journal, July 2009


The Effect of Fluoroethylene Carbonate as an Additive on the Solid Electrolyte Interphase on Silicon Lithium-Ion Electrodes
journal, August 2015