Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries

Luque, Guillermina L.; Li, Yan; Zeng, Xiaoqiao; Luo, Xiangyi; Leiva, Ezequiel P.  M.; Chen, Zonghai; Amine, Khalil

doi:10.1007/s10008-018-4145-2

Title: Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries

Journal Article · 15 November 2018 · Journal of Solid State Electrochemistry

DOI: https://doi.org/10.1007/s10008-018-4145-2 · OSTI ID:1501868

^[1]; Li, Yan ^[2]; Zeng, Xiaoqiao ^[2]; Luo, Xiangyi ^[2]; Leiva, Ezequiel P. M. ^[3]; Chen, Zonghai ^[2]; Amine, Khalil ^[2]

Argonne National Lab. (ANL), Lemont, IL (United States); Universidad Nacional de Córdoba, Córdoba (Argentina)
Argonne National Lab. (ANL), Lemont, IL (United States)
Universidad Nacional de Córdoba, Córdoba (Argentina)

The electrochemical performance of SiO-SnCoC composite anode for high-energy lithium-ion batteries was evaluated with particular emphasis on the impact of Alginate as a polymeric binder, as well as fluoroethylene carbonate (FEC) as electrolyte additive. It was found that the presence of FEC and the use of alginate pH3 as binder help to improve the electrochemical stability of the composite anode, showing the best electrochemical performance with a high specific capacity, great capacity retention, and excellent coulombic efficiency. Specifically, the high precision self-discharge current study revealed that the alginate binder slowed down the parasitic reactions between the lithiated anode and the non-aqueous electrolyte.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1501868

Journal Information:: Journal of Solid State Electrochemistry, Vol. 23, Issue 2; ISSN 1432-8488

Country of Publication:: United States

Language:: English

References (34)

Acrylic Acid-Based Copolymers as Functional Binder for Silicon/Graphite Composite Electrode in Lithium-Ion Batteries Aoki, Shoko; Han, Zhen-Ji; Yamagiwa, Kiyofumi Journal of The Electrochemical Society, Vol. 162, Issue 12 https://doi.org/10.1149/2.0171512jes	journal	January 2015
Alginate: Properties and biomedical applications Lee, Kuen Yong; Mooney, David J. Progress in Polymer Science, Vol. 37, Issue 1 https://doi.org/10.1016/j.progpolymsci.2011.06.003	journal	January 2012
A review on electrolyte additives for lithium-ion batteries Zhang, Sheng Shui Journal of Power Sources, Vol. 162, Issue 2, p. 1379-1394 https://doi.org/10.1016/j.jpowsour.2006.07.074	journal	November 2006
Formation of Polysaccharide Gel Layers in the Presence of Ca ²⁺ and K ⁺ Ions: Measurements and Mechanisms de Kerchove, Alexis J.; Elimelech, Menachem Biomacromolecules, Vol. 8, Issue 1 https://doi.org/10.1021/bm060670i	journal	January 2007
Carboxymethyl chitosan: A new water soluble binder for Si anode of Li-ion batteries Yue, Lu; Zhang, Lingzhi; Zhong, Haoxiang Journal of Power Sources, Vol. 247 https://doi.org/10.1016/j.jpowsour.2013.08.073	journal	February 2014
Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries Ji, Liwen; Lin, Zhan; Alcoutlabi, Mataz Energy & Environmental Science, Vol. 4, Issue 8, p. 2682-2699 https://doi.org/10.1039/c0ee00699h	journal	January 2011
New Anode Material Based on SiO–Sn _x Co _y C _z for Lithium Batteries Liu, Bo; Abouimrane, Ali; Ren, Yang Chemistry of Materials, Vol. 24, Issue 24 https://doi.org/10.1021/cm3017853	journal	December 2012
Dual-functional gum arabic binder for silicon anodes in lithium ion batteries Ling, Min; Xu, Yanan; Zhao, Hui Nano Energy, Vol. 12 https://doi.org/10.1016/j.nanoen.2014.12.011	journal	March 2015
The binder effect on an oxide-based anode in lithium and sodium-ion battery applications: the fastest way to ultrahigh performance Ming, Jun; Ming, Hai; Kwak, Won-Jin Chem. Commun., Vol. 50, Issue 87 https://doi.org/10.1039/C4CC02657H	journal	January 2014
A high-performance alginate hydrogel binder for the Si/C anode of a Li-ion battery Liu, Jie; Zhang, Qian; Wu, Zhan-Yu Chemical Communications, Vol. 50, Issue 48 https://doi.org/10.1039/c4cc00081a	journal	January 2014
Chitosan, a new and environmental benign electrode binder for use with graphite anode in lithium-ion batteries Chai, Lili; Qu, Qunting; Zhang, Longfei Electrochimica Acta, Vol. 105 https://doi.org/10.1016/j.electacta.2013.05.009	journal	August 2013
Potential of lithium-ion batteries in renewable energy Diouf, Boucar; Pode, Ramchandra Renewable Energy, Vol. 76 https://doi.org/10.1016/j.renene.2014.11.058	journal	April 2015
Silicon Composite Electrode with High Capacity and Long Cycle Life Mazouzi, D.; Lestriez, B.; Roué, L. Electrochemical and Solid-State Letters, Vol. 12, Issue 11 https://doi.org/10.1149/1.3212894	journal	January 2009
What Makes Fluoroethylene Carbonate Different? Shkrob, Ilya A.; Wishart, James F.; Abraham, Daniel P. The Journal of Physical Chemistry C, Vol. 119, Issue 27 https://doi.org/10.1021/acs.jpcc.5b03591	journal	June 2015
Mechanically alloyed composite anode materials based on SiO–SnxFeyCz for Li-ion batteries Liu, Bo; Abouimrane, Ali; Brown, Dennis E. Journal of Materials Chemistry A, Vol. 1, Issue 13 https://doi.org/10.1039/c3ta00101f	journal	January 2013
Toward Efficient Binders for Li-Ion Battery Si-Based Anodes: Polyacrylic Acid Magasinski, Alexandre; Zdyrko, Bogdan; Kovalenko, Igor ACS Applied Materials & Interfaces, Vol. 2, Issue 11 https://doi.org/10.1021/am100871y	journal	October 2010
Review on recent progress of nanostructured anode materials for Li-ion batteries Goriparti, Subrahmanyam; Miele, Ermanno; De Angelis, Francesco Journal of Power Sources, Vol. 257 https://doi.org/10.1016/j.jpowsour.2013.11.103	journal	July 2014
Lithium ion rechargeable batteries: State of the art and future needs of microscopic theoretical models and simulations Miranda, D.; Costa, C. M.; Lanceros-Mendez, S. Journal of Electroanalytical Chemistry, Vol. 739 https://doi.org/10.1016/j.jelechem.2014.12.010	journal	February 2015
Key Parameters Governing the Reversibility of Si/Carbon/CMC Electrodes for Li-Ion Batteries ^† Bridel, J. -S.; Azaïs, T.; Morcrette, M. Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm902688w	journal	February 2010
Amorphous silicon as a possible anode material for Li-ion batteries Bourderau, S.; Brousse, T.; Schleich, D. M. Journal of Power Sources, Vol. 81-82 https://doi.org/10.1016/S0378-7753(99)00194-9	journal	September 1999
Phase Changes in Electrochemically Lithiated Silicon at Elevated Temperature Wang, Yadong; Dahn, Jeff Journal of The Electrochemical Society, Vol. 153, Issue 12 https://doi.org/10.1149/1.2359690	journal	January 2006
Stable SiOC/Sn Nanocomposite Anodes for Lithium-Ion Batteries with Outstanding Cycling Stability Kaspar, Jan; Terzioglu, Caglar; Ionescu, Emanuel Advanced Functional Materials, Vol. 24, Issue 26 https://doi.org/10.1002/adfm.201303828	journal	March 2014
A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries Kovalenko, I.; Zdyrko, B.; Magasinski, A. Science, Vol. 334, Issue 6052 https://doi.org/10.1126/science.1209150	journal	September 2011
Kinetic Study of Parasitic Reactions in Lithium-Ion Batteries: A Case Study on LiNi _0.6 Mn _0.2 Co _0.2 O ₂ Zeng, Xiaoqiao; Xu, Gui-Liang; Li, Yan ACS Applied Materials & Interfaces, Vol. 8, Issue 5 https://doi.org/10.1021/acsami.5b11800	journal	January 2016
Alloy Negative Electrodes for Li-Ion Batteries Obrovac, M. N.; Chevrier, V. L. Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500207g	journal	October 2014
Effect of the Electrolyte Composition on SEI Reactions at Si Anodes of Li-Ion Batteries Martinez de la Hoz, Julibeth M.; Soto, Fernando A.; Balbuena, Perla B. The Journal of Physical Chemistry C, Vol. 119, Issue 13 https://doi.org/10.1021/acs.jpcc.5b01228	journal	March 2015
Li-ion battery materials: present and future Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae Materials Today, Vol. 18, Issue 5 https://doi.org/10.1016/j.mattod.2014.10.040	journal	June 2015
A coordinatively cross-linked polymeric network as a functional binder for high-performance silicon submicro-particle anodes in lithium-ion batteries Zhang, Li; Zhang, Liya; Chai, Lili J. Mater. Chem. A, Vol. 2, Issue 44 https://doi.org/10.1039/C4TA04320K	journal	January 2014
Investigations on high energy lithium-ion batteries with aqueous binder Wu, Qingliu; Ha, Seonbaek; Prakash, Jai Electrochimica Acta, Vol. 114 https://doi.org/10.1016/j.electacta.2013.09.068	journal	December 2013
Study on Polymer Binders for High-Capacity SiO Negative Electrode of Li-Ion Batteries Komaba, Shinichi; Shimomura, Keiji; Yabuuchi, Naoaki The Journal of Physical Chemistry C, Vol. 115, Issue 27 https://doi.org/10.1021/jp201691g	journal	June 2011
Critical roles of binders and formulation at multiscales of silicon-based composite electrodes Mazouzi, D.; Karkar, Z.; Reale Hernandez, C. Journal of Power Sources, Vol. 280 https://doi.org/10.1016/j.jpowsour.2015.01.140	journal	April 2015
A comparative study of Si-containing electrolyte additives for lithium ion battery: Which one is better and why is it better Wang, Kang; Xing, Lidan; Zhu, Yunmin Journal of Power Sources, Vol. 342 https://doi.org/10.1016/j.jpowsour.2016.12.112	journal	February 2017
Improvement of cyclability of Si as anode for Li-ion batteries Ding, Ning; Xu, Jing; Yao, Yaxuan Journal of Power Sources, Vol. 192, Issue 2 https://doi.org/10.1016/j.jpowsour.2009.03.017	journal	July 2009
The Effect of Fluoroethylene Carbonate as an Additive on the Solid Electrolyte Interphase on Silicon Lithium-Ion Electrodes Schroder, Kjell; Alvarado, Judith; Yersak, Thomas A. Chemistry of Materials, Vol. 27, Issue 16 https://doi.org/10.1021/acs.chemmater.5b01627	journal	August 2015

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
25 ENERGY STORAGE
Alginate
Anode
Fluoroethylene carbonate
Lithium-ion batteries
Parasitic reaction
Self-discharge

Title: Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries

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