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Title: Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries

The electrochemical performance of SiO-SnCoC composite anode for high-energy lithium-ion batteries was evaluated with particular emphasis on the impact of Alginate as a polymeric binder, as well as fluoroethylene carbonate (FEC) as electrolyte additive. It was found that the presence of FEC and the use of alginate pH3 as binder help to improve the electrochemical stability of the composite anode, showing the best electrochemical performance with a high specific capacity, great capacity retention, and excellent coulombic efficiency. Specifically, the high precision self-discharge current study revealed that the alginate binder slowed down the parasitic reactions between the lithiated anode and the non-aqueous electrolyte.
Authors:
ORCiD logo [1] ;  [2] ;  [2] ;  [2] ;  [3] ;  [2] ;  [2]
  1. Argonne National Lab. (ANL), Lemont, IL (United States); Universidad Nacional de Córdoba, Córdoba (Argentina)
  2. Argonne National Lab. (ANL), Lemont, IL (United States)
  3. Universidad Nacional de Córdoba, Córdoba (Argentina)
Publication Date:
Grant/Contract Number:
AC02-06CH11357
Type:
Accepted Manuscript
Journal Name:
Journal of Solid State Electrochemistry
Additional Journal Information:
Journal Volume: 23; Journal Issue: 2; Journal ID: ISSN 1432-8488
Research Org:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE; Alginate; Anode; Fluoroethylene carbonate; Lithium-ion batteries; Parasitic reaction; Self-discharge
OSTI Identifier:
1501868

Luque, Guillermina L., Li, Yan, Zeng, Xiaoqiao, Luo, Xiangyi, Leiva, Ezequiel P. M., Chen, Zonghai, and Amine, Khalil. Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries. United States: N. p., Web. doi:10.1007/s10008-018-4145-2.
Luque, Guillermina L., Li, Yan, Zeng, Xiaoqiao, Luo, Xiangyi, Leiva, Ezequiel P. M., Chen, Zonghai, & Amine, Khalil. Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries. United States. doi:10.1007/s10008-018-4145-2.
Luque, Guillermina L., Li, Yan, Zeng, Xiaoqiao, Luo, Xiangyi, Leiva, Ezequiel P. M., Chen, Zonghai, and Amine, Khalil. 2018. "Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries". United States. doi:10.1007/s10008-018-4145-2.
@article{osti_1501868,
title = {Impact of alginate and fluoroethylene carbonate on the electrochemical performance of SiO–SnCoC anode for lithium-ion batteries},
author = {Luque, Guillermina L. and Li, Yan and Zeng, Xiaoqiao and Luo, Xiangyi and Leiva, Ezequiel P. M. and Chen, Zonghai and Amine, Khalil},
abstractNote = {The electrochemical performance of SiO-SnCoC composite anode for high-energy lithium-ion batteries was evaluated with particular emphasis on the impact of Alginate as a polymeric binder, as well as fluoroethylene carbonate (FEC) as electrolyte additive. It was found that the presence of FEC and the use of alginate pH3 as binder help to improve the electrochemical stability of the composite anode, showing the best electrochemical performance with a high specific capacity, great capacity retention, and excellent coulombic efficiency. Specifically, the high precision self-discharge current study revealed that the alginate binder slowed down the parasitic reactions between the lithiated anode and the non-aqueous electrolyte.},
doi = {10.1007/s10008-018-4145-2},
journal = {Journal of Solid State Electrochemistry},
number = 2,
volume = 23,
place = {United States},
year = {2018},
month = {11}
}

Works referenced in this record:

A review on electrolyte additives for lithium-ion batteries
journal, November 2006

Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries
journal, January 2011
  • Ji, Liwen; Lin, Zhan; Alcoutlabi, Mataz
  • Energy & Environmental Science, Vol. 4, Issue 8, p. 2682-2699
  • DOI: 10.1039/c0ee00699h