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Title: Electrochemical oxidation of trivalent americium using a dipyrazinylpyridine modified ITO electrode

Abstract

We present here the electrochemical oxidation of Am( iii ) to Am V O 2 + and Am VI O 2 2+ in pH 1 nitric acid using a mesoporous tin-doped indium oxide electrode modified with a covalently attached dipyrazinylpyridine ligand.

Authors:
 [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Chemistry and Biochemistry, Florida International University, Miami, USA
  2. Idaho National Laboratory, Idaho Falls, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1501721
Grant/Contract Number:  
NE0008539
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Chemical Communications
Additional Journal Information:
Journal Name: Chemical Communications Journal Volume: 55 Journal Issue: 28; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Lopez, Michael J., Sheridan, Matthew V., McLachlan, Jeffrey R., Grimes, Travis S., and Dares, Christopher J. Electrochemical oxidation of trivalent americium using a dipyrazinylpyridine modified ITO electrode. United Kingdom: N. p., 2019. Web. doi:10.1039/C9CC00837C.
Lopez, Michael J., Sheridan, Matthew V., McLachlan, Jeffrey R., Grimes, Travis S., & Dares, Christopher J. Electrochemical oxidation of trivalent americium using a dipyrazinylpyridine modified ITO electrode. United Kingdom. doi:10.1039/C9CC00837C.
Lopez, Michael J., Sheridan, Matthew V., McLachlan, Jeffrey R., Grimes, Travis S., and Dares, Christopher J. Tue . "Electrochemical oxidation of trivalent americium using a dipyrazinylpyridine modified ITO electrode". United Kingdom. doi:10.1039/C9CC00837C.
@article{osti_1501721,
title = {Electrochemical oxidation of trivalent americium using a dipyrazinylpyridine modified ITO electrode},
author = {Lopez, Michael J. and Sheridan, Matthew V. and McLachlan, Jeffrey R. and Grimes, Travis S. and Dares, Christopher J.},
abstractNote = {We present here the electrochemical oxidation of Am( iii ) to Am V O 2 + and Am VI O 2 2+ in pH 1 nitric acid using a mesoporous tin-doped indium oxide electrode modified with a covalently attached dipyrazinylpyridine ligand.},
doi = {10.1039/C9CC00837C},
journal = {Chemical Communications},
number = 28,
volume = 55,
place = {United Kingdom},
year = {2019},
month = {4}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on March 12, 2020
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