skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Anomalous Solute Diffusivity in Ionic Liquids: Label-Free Visualization and Physical Origins

Authors:
; ; ; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1501709
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Published Article
Journal Name:
Physical Review X
Additional Journal Information:
Journal Name: Physical Review X Journal Volume: 9 Journal Issue: 1; Journal ID: ISSN 2160-3308
Publisher:
American Physical Society
Country of Publication:
United States
Language:
English

Citation Formats

Bayles, Alexandra V., Valentine, Connor S., Überrück, Till, Danielsen, Scott P. O., Han, Songi, Helgeson, Matthew E., and Squires, Todd M. Anomalous Solute Diffusivity in Ionic Liquids: Label-Free Visualization and Physical Origins. United States: N. p., 2019. Web. doi:10.1103/PhysRevX.9.011048.
Bayles, Alexandra V., Valentine, Connor S., Überrück, Till, Danielsen, Scott P. O., Han, Songi, Helgeson, Matthew E., & Squires, Todd M. Anomalous Solute Diffusivity in Ionic Liquids: Label-Free Visualization and Physical Origins. United States. doi:10.1103/PhysRevX.9.011048.
Bayles, Alexandra V., Valentine, Connor S., Überrück, Till, Danielsen, Scott P. O., Han, Songi, Helgeson, Matthew E., and Squires, Todd M. Mon . "Anomalous Solute Diffusivity in Ionic Liquids: Label-Free Visualization and Physical Origins". United States. doi:10.1103/PhysRevX.9.011048.
@article{osti_1501709,
title = {Anomalous Solute Diffusivity in Ionic Liquids: Label-Free Visualization and Physical Origins},
author = {Bayles, Alexandra V. and Valentine, Connor S. and Überrück, Till and Danielsen, Scott P. O. and Han, Songi and Helgeson, Matthew E. and Squires, Todd M.},
abstractNote = {},
doi = {10.1103/PhysRevX.9.011048},
journal = {Physical Review X},
number = 1,
volume = 9,
place = {United States},
year = {2019},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1103/PhysRevX.9.011048

Citation Metrics:
Cited by: 1 work
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2
journal, May 2011

  • Hallett, Jason P.; Welton, Tom
  • Chemical Reviews, Vol. 111, Issue 5
  • DOI: 10.1021/cr1003248

Recent Applications of Ionic Liquids in Separation Technology
journal, April 2010


Theoretical and spectroscopic studies of 1-butyl-3-methylimidazolium iodide room temperature ionic liquid: Its differences with chloride and bromide derivatives
journal, June 2010


Ionic liquids. Green solvents for the future
journal, January 2000


A review of extractive desulfurization of fuel oils using ionic liquids
journal, January 2014

  • Abro, Rashid; Abdeltawab, Ahmed A.; Al-Deyab, Salem S.
  • RSC Adv., Vol. 4, Issue 67
  • DOI: 10.1039/C4RA03478C

Performance of Quantum Chemically Derived Charges and Persistence of Ion Cages in Ionic Liquids. A Molecular Dynamics Simulations Study of 1- n -Butyl-3-methylimidazolium Bromide
journal, February 2011

  • Kohagen, Miriam; Brehm, Martin; Thar, Jens
  • The Journal of Physical Chemistry B, Vol. 115, Issue 4
  • DOI: 10.1021/jp109612k

Small angle neutron scattering from 1-alkyl-3-methylimidazolium hexafluorophosphate ionic liquids ([Cnmim][PF6], n=4, 6, and 8)
journal, August 2010

  • Hardacre, Christopher; Holbrey, John D.; Mullan, Claire L.
  • The Journal of Chemical Physics, Vol. 133, Issue 7
  • DOI: 10.1063/1.3473825

Effect of Water on the Molecular Structure and Arrangement of Nitrile-Functionalized Ionic Liquids
journal, February 2006

  • Saha, Satyen
  • The Journal of Physical Chemistry B, Vol. 110, Issue 6
  • DOI: 10.1021/jp053817t

Ionic liquids in separations of azeotropic systems – A review
journal, March 2012

  • Pereiro, A. B.; Araújo, J. M. M.; Esperança, J. M. S. S.
  • The Journal of Chemical Thermodynamics, Vol. 46
  • DOI: 10.1016/j.jct.2011.05.026

Review on the Use of Ionic Liquids (ILs) as Alternative Fluids for CO 2 Capture and Natural Gas Sweetening
journal, November 2010

  • Karadas, Ferdi; Atilhan, Mert; Aparicio, Santiago
  • Energy & Fuels, Vol. 24, Issue 11
  • DOI: 10.1021/ef1011337

Ionic-Liquid-Based CO 2 Capture Systems: Structure, Interaction and Process
journal, May 2017


Desulfurisation of oils using ionic liquids: selection of cationic and anionic components to enhance extraction efficiency
journal, January 2008

  • Holbrey, John D.; López-Martin, Ignacio; Rothenberg, Gadi
  • Green Chem., Vol. 10, Issue 1
  • DOI: 10.1039/B710651C

Side chain fluorination and anion effect on the structure of 1-butyl-3-methylimidazolium ionic liquids
journal, August 2013

  • Weber, Henry; Hollóczki, Oldamur; Pensado, Alfonso S.
  • The Journal of Chemical Physics, Vol. 139, Issue 8
  • DOI: 10.1063/1.4818540

A SAXS/WAXS/GISAXS Beamline with Multilayer Monochromator
journal, October 2010


Nanoscale heterogeneity in alkyl-methylimidazolium bromide ionic liquids
journal, March 2011

  • Aoun, Bachir; Goldbach, Andreas; González, Miguel A.
  • The Journal of Chemical Physics, Vol. 134, Issue 10
  • DOI: 10.1063/1.3563540

‘Green’ leaching: recyclable and selective leaching of gold-bearing ore in an ionic liquid
journal, January 2004

  • Whitehead, Jacqueline A.; Lawrance, Geoffrey A.; McCluskey, Adam
  • Green Chem., Vol. 6, Issue 7
  • DOI: 10.1039/B406148A

How Is Diffusion of Neutral and Charged Tracers Related to the Structure and Dynamics of a Room-Temperature Ionic Liquid? Large Deviations from Stokes–Einstein Behavior Explained
journal, April 2015

  • Araque, Juan C.; Yadav, Sharad K.; Shadeck, Michael
  • The Journal of Physical Chemistry B, Vol. 119, Issue 23
  • DOI: 10.1021/acs.jpcb.5b01093

Influence of chloride, water, and organic solvents on the physical properties of ionic liquids
journal, January 2000

  • Seddon, Kenneth R.; Stark, Annegret; Torres, María-José
  • Pure and Applied Chemistry, Vol. 72, Issue 12
  • DOI: 10.1351/pac200072122275

Processing of metals and metal oxides using ionic liquids
journal, January 2011

  • Abbott, Andrew P.; Frisch, Gero; Hartley, Jennifer
  • Green Chemistry, Vol. 13, Issue 3
  • DOI: 10.1039/C0GC00716A

Structure of ionic liquids of 1-alkyl-3-methylimidazolium cations: A systematic computer simulation study
journal, January 2004

  • Urahata, Sérgio M.; Ribeiro, Mauro C. C.
  • The Journal of Chemical Physics, Vol. 120, Issue 4
  • DOI: 10.1063/1.1635356

Small-Angle X-ray Scattering Studies of Liquid Crystalline 1-Alkyl-3-methylimidazolium Salts
journal, February 2002

  • Bradley, A. E.; Hardacre, C.; Holbrey, J. D.
  • Chemistry of Materials, Vol. 14, Issue 2
  • DOI: 10.1021/cm010542v

Measuring concentration fields in microfluidic channels in situ with a Fabry–Perot interferometer
journal, January 2015

  • Vogus, Douglas R.; Mansard, Vincent; Rapp, Michael V.
  • Lab on a Chip, Vol. 15, Issue 7
  • DOI: 10.1039/C5LC00095E

A link between structure, diffusion and rotations of hydrogen bonding tracers in ionic liquids
journal, May 2016

  • Araque, Juan C.; Daly, Ryan P.; Margulis, Claudio J.
  • The Journal of Chemical Physics, Vol. 144, Issue 20
  • DOI: 10.1063/1.4951012

Structural Determination of Ionic Liquids with Theoretical Methods: C 8 mimBr and C 8 mimCl. Strength and Weakness of Current Force Fields
journal, March 2010

  • Bodo, E.; Gontrani, L.; Triolo, A.
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 7
  • DOI: 10.1021/jz100146r

What is the Origin of the Prepeak in the X-ray Scattering of Imidazolium-Based Room-Temperature Ionic Liquids?
journal, December 2010

  • Annapureddy, Harsha V. R.; Kashyap, Hemant K.; De Biase, Pablo M.
  • The Journal of Physical Chemistry B, Vol. 114, Issue 50
  • DOI: 10.1021/jp108545z

Ionic Liquid versus Li + Aqueous Solutions: Water Dynamics near Bistriflimide Anions
journal, August 2016

  • Giammanco, Chiara H.; Kramer, Patrick L.; Fayer, Michael D.
  • The Journal of Physical Chemistry B, Vol. 120, Issue 37
  • DOI: 10.1021/acs.jpcb.6b07145

Structural Properties of 1-Alkyl-3-methylimidazolium Bis{(trifluoromethyl)sulfonyl}amide Ionic Liquids: X-ray Diffraction Data and Molecular Dynamics Simulations
journal, December 2010

  • Bodo, Enrico; Gontrani, Lorenzo; Caminiti, Ruggero
  • The Journal of Physical Chemistry B, Vol. 114, Issue 49
  • DOI: 10.1021/jp1093299

Structures of ionic liquid–water mixtures investigated by IR and NMR spectroscopy
journal, January 2014

  • Cha, Seoncheol; Ao, Mingqi; Sung, Woongmo
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 20
  • DOI: 10.1039/C4CP00589A

Easy prediction of the refractive index for binary mixtures of ionic liquids with water or ethanol
journal, April 2012


Dynamics of water, methanol, and ethanol in a room temperature ionic liquid
journal, June 2015

  • Kramer, Patrick L.; Giammanco, Chiara H.; Fayer, Michael D.
  • The Journal of Chemical Physics, Vol. 142, Issue 21
  • DOI: 10.1063/1.4914156

Carbon capture with ionic liquids: overview and progress
journal, January 2012

  • Zhang, Xiangping; Zhang, Xiaochun; Dong, Haifeng
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee21152a

Ionic liquid clusters: structure, formation mechanism, and effect on the behavior of ionic liquids
journal, January 2014

  • Chen, Shimou; Zhang, Suojiang; Liu, Xiaomin
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 13
  • DOI: 10.1039/C3CP53116C

An ionic liquid process for mercury removal from natural gas
journal, January 2015

  • Abai, Mahpuzah; Atkins, Martin P.; Hassan, Amiruddin
  • Dalton Transactions, Vol. 44, Issue 18
  • DOI: 10.1039/C4DT03273J

Interactions between water and 1-butyl-1-methylpyrrolidinium ionic liquids
journal, August 2015

  • Fadeeva, Tatiana A.; Husson, Pascale; DeVine, Jessalyn A.
  • The Journal of Chemical Physics, Vol. 143, Issue 6
  • DOI: 10.1063/1.4928065

Effect of Water on the Local Structure and Phase Behavior of Imidazolium-Based Protic Ionic Liquids
journal, January 2015

  • Yaghini, Negin; Pitawala, Jagath; Matic, Aleksandar
  • The Journal of Physical Chemistry B, Vol. 119, Issue 4
  • DOI: 10.1021/jp510691e

The Kramers problem: Fifty years of development
journal, December 1991


Carbon Dioxide Capture Using Ionic Liquid 1-Butyl-3-methylimidazolium Acetate
journal, October 2010

  • Shiflett, Mark B.; Drew, David W.; Cantini, Robert A.
  • Energy & Fuels, Vol. 24, Issue 10
  • DOI: 10.1021/ef100868a

Structure and Nanostructure in Ionic Liquids
journal, June 2015

  • Hayes, Robert; Warr, Gregory G.; Atkin, Rob
  • Chemical Reviews, Vol. 115, Issue 13
  • DOI: 10.1021/cr500411q

Application and Perspective of Ionic Liquids on Rare Earths Green Separation
journal, January 2012


Structure of a Prototypic Ionic Liquid: Ethyl-methylimidazolium Bromide
journal, October 2010

  • Aoun, Bachir; Goldbach, Andreas; Kohara, Shinji
  • The Journal of Physical Chemistry B, Vol. 114, Issue 39
  • DOI: 10.1021/jp1070715

Carbon dioxide uptake from natural gas by binary ionic liquid–water mixtures
journal, January 2015

  • Anderson, Kris; Atkins, Martin P.; Estager, Julien
  • Green Chemistry, Vol. 17, Issue 8
  • DOI: 10.1039/C5GC00720H

Importance of dispersion forces for prediction of thermodynamic and transport properties of some common ionic liquids
journal, January 2014

  • Izgorodina, Ekaterina I.; Golze, Dorothea; Maganti, Radha
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 16
  • DOI: 10.1039/C3CP53035C

Nika : software for two-dimensional data reduction
journal, March 2012


Use of ionic liquids as ‘green’ solvents for extractions
journal, January 2005

  • Zhao, Hua; Xia, Shuqian; Ma, Peisheng
  • Journal of Chemical Technology & Biotechnology, Vol. 80, Issue 10
  • DOI: 10.1002/jctb.1333

What Are Functional Ionic Liquids for the Absorption of Acidic Gases?
journal, February 2013

  • Ren, Shuhang; Hou, Yucui; Tian, Shidong
  • The Journal of Physical Chemistry B, Vol. 117, Issue 8
  • DOI: 10.1021/jp311707e

Continuous gas-phase desulfurisation using supported ionic liquid phase (SILP) materials
journal, January 2010

  • Kohler, Florian; Roth, Daniel; Kuhlmann, Esther
  • Green Chemistry, Vol. 12, Issue 6
  • DOI: 10.1039/C004883F

Inexpensive ionic liquids: [HSO 4 ] -based solvent production at bulk scale
journal, January 2014

  • Chen, Long; Sharifzadeh, Mahdi; Mac Dowell, Niall
  • Green Chem., Vol. 16, Issue 6
  • DOI: 10.1039/C4GC00016A

Structure of an ionic liquid, 1-n-butyl-3-methylimidazolium iodide, studied by wide-angle X-ray scattering and Raman spectroscopy
journal, July 2004


Interfacial structure and structural forces in mixtures of ionic liquid with a polar solvent
journal, January 2018

  • Coles, Samuel W.; Smith, Alexander M.; Fedorov, Maxim V.
  • Faraday Discussions, Vol. 206
  • DOI: 10.1039/C7FD00168A

A review of CO2 capture by absorption in ionic liquid-based solvents
journal, January 2015

  • Babamohammadi, Shervan; Shamiri, Ahmad; Aroua, Mohamed Kheireddine
  • Reviews in Chemical Engineering, Vol. 31, Issue 4
  • DOI: 10.1515/revce-2014-0032

Solute Diffusion in Ionic Liquids, NMR Measurements and Comparisons to Conventional Solvents
journal, September 2013

  • Kaintz, Anne; Baker, Gary; Benesi, Alan
  • The Journal of Physical Chemistry B, Vol. 117, Issue 39
  • DOI: 10.1021/jp405393d

Measuring Interfacial Polymerization Kinetics Using Microfluidic Interferometry
journal, February 2018

  • Nowbahar, Arash; Mansard, Vincent; Mecca, Jodi M.
  • Journal of the American Chemical Society, Vol. 140, Issue 9
  • DOI: 10.1021/jacs.7b12121

Ionic liquids: solvent properties and organic reactivity
journal, January 2005

  • Chiappe, Cinzia; Pieraccini, Daniela
  • Journal of Physical Organic Chemistry, Vol. 18, Issue 4
  • DOI: 10.1002/poc.863

Nanoscale Segregation in Room Temperature Ionic Liquids
journal, May 2007

  • Triolo, Alessandro; Russina, Olga; Bleif, Hans-Jurgen
  • The Journal of Physical Chemistry B, Vol. 111, Issue 18
  • DOI: 10.1021/jp067705t

Comparison of Ionic Liquids to Conventional Organic Solvents for Extraction of Aromatics from Aliphatics
journal, April 2016

  • Canales, Roberto I.; Brennecke, Joan F.
  • Journal of Chemical & Engineering Data, Vol. 61, Issue 5
  • DOI: 10.1021/acs.jced.6b00077

DESIGNER SOLVENTS: Ionic liquids may boost clean technology development
journal, March 1998


A review of ionic liquids: Applications towards catalytic organic transformations
journal, February 2017


Are ionic liquids a proper solution to current environmental challenges?
journal, January 2014

  • Cevasco, Giorgio; Chiappe, Cinzia
  • Green Chemistry, Vol. 16, Issue 5
  • DOI: 10.1039/C3GC42096E

Water Dynamics in 1-Alkyl-3-methylimidazolium Tetrafluoroborate Ionic Liquids
journal, October 2016

  • Giammanco, Chiara H.; Kramer, Patrick L.; Wong, Daryl B.
  • The Journal of Physical Chemistry B, Vol. 120, Issue 44
  • DOI: 10.1021/acs.jpcb.6b08410

Ionic liquids as electrolytes
journal, August 2006


Influence of Water on Diffusion in Imidazolium-Based Ionic Liquids: A Pulsed Field Gradient NMR study
journal, May 2009

  • Menjoge, Amrish; Dixon, JaNeille; Brennecke, Joan F.
  • The Journal of Physical Chemistry B, Vol. 113, Issue 18
  • DOI: 10.1021/jp900902n

Natural Gas Dehydration with Ionic Liquids
journal, January 2017


CO2 Capture by a Task-Specific Ionic Liquid
journal, February 2002

  • Bates, Eleanor D.; Mayton, Rebecca D.; Ntai, Ioanna
  • Journal of the American Chemical Society, Vol. 124, Issue 6, p. 926-927
  • DOI: 10.1021/ja017593d

Brønsted acidic ionic liquids: Green catalysts for essential organic reactions
journal, June 2016


CHEMISTRY: Ionic Liquids--Solvents of the Future?
journal, October 2003


Structural Characterization of the 1-Butyl-3-methylimidazolium Chloride Ion Pair Using ab Initio Methods
journal, February 2006

  • Hunt, Patricia A.; Gould, Ian R.
  • The Journal of Physical Chemistry A, Vol. 110, Issue 6
  • DOI: 10.1021/jp0547865

Hierarchical structure and dynamics of an ionic liquid 1-octyl-3-methylimidazolium chloride
journal, August 2011

  • Yamamuro, Osamu; Yamada, Takeshi; Kofu, Maiko
  • The Journal of Chemical Physics, Vol. 135, Issue 5
  • DOI: 10.1063/1.3622598

Hydrogen Bonding in 1-Butyl- and 1-Ethyl-3-methylimidazolium Chloride Ionic Liquids
journal, April 2012

  • Skarmoutsos, Ioannis; Dellis, Dimitris; Matthews, Richard P.
  • The Journal of Physical Chemistry B, Vol. 116, Issue 16
  • DOI: 10.1021/jp209485y

Anomalous Diffusion of Water in [BMIM][TFSI] Room-Temperature Ionic Liquid
journal, October 2007

  • Rollet, Anne-Laure; Porion, Patrice; Vaultier, Michel
  • The Journal of Physical Chemistry B, Vol. 111, Issue 41
  • DOI: 10.1021/jp075378z

Hydrophobic task-specific ionic liquids: Synthesis, properties and application for the capture of SO2
journal, August 2014