Direct observation of pitting corrosion evolutions on carbon steel surfaces at the nano-to-micro- scales
Abstract
The Cl¯-induced corrosion of metals and alloys is of relevance to a wide range of engineered materials, structures, and systems. Because of the challenges in studying pitting corrosion in a quantitative and statistically significant manner, its kinetics remain poorly understood. Herein, by direct, nano- to micro-scale observations using vertical scanning interferometry (VSI), we examine the temporal evolution of pitting corrosion on AISI 1045 carbon steel over large surface areas in Cl¯-free, and Cl¯-enriched solutions. Special focus is paid to examine the nucleation and growth of pits, and the associated formation of roughened regions on steel surfaces. By statistical analysis of hundreds of individual pits, three stages of pitting corrosion, namely, induction, propagation, and saturation, are quantitatively distinguished. By quantifying the kinetics of these processes, we contextualize our current understanding of electrochemical corrosion within a framework that considers spatial dynamics and morphology evolutions. In the presence of Cl¯ ions, corrosion is highly accelerated due to multiple autocatalytic factors including destabilization of protective surface oxide films and preservation of aggressive microenvironments within the pits, both of which promote continued pit nucleation and growth. Furthermore these findings offer new insights into predicting and modeling steel corrosion processes in mid-pH aqueous environments
- Publication Date:
- Research Org.:
- Univ. of California, Los Angeles, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1500090
- Grant/Contract Number:
- NE0008398
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Guo, Peng, La Plante, Erika Callagon, Wang, Bu, Chen, Xin, Balonis, Magdalena, Bauchy, Mathieu, and Sant, Gaurav. Direct observation of pitting corrosion evolutions on carbon steel surfaces at the nano-to-micro- scales. United States: N. p., 2018.
Web. doi:10.1038/s41598-018-26340-5.
Guo, Peng, La Plante, Erika Callagon, Wang, Bu, Chen, Xin, Balonis, Magdalena, Bauchy, Mathieu, & Sant, Gaurav. Direct observation of pitting corrosion evolutions on carbon steel surfaces at the nano-to-micro- scales. United States. https://doi.org/10.1038/s41598-018-26340-5
Guo, Peng, La Plante, Erika Callagon, Wang, Bu, Chen, Xin, Balonis, Magdalena, Bauchy, Mathieu, and Sant, Gaurav. Tue .
"Direct observation of pitting corrosion evolutions on carbon steel surfaces at the nano-to-micro- scales". United States. https://doi.org/10.1038/s41598-018-26340-5. https://www.osti.gov/servlets/purl/1500090.
@article{osti_1500090,
title = {Direct observation of pitting corrosion evolutions on carbon steel surfaces at the nano-to-micro- scales},
author = {Guo, Peng and La Plante, Erika Callagon and Wang, Bu and Chen, Xin and Balonis, Magdalena and Bauchy, Mathieu and Sant, Gaurav},
abstractNote = {The Cl¯-induced corrosion of metals and alloys is of relevance to a wide range of engineered materials, structures, and systems. Because of the challenges in studying pitting corrosion in a quantitative and statistically significant manner, its kinetics remain poorly understood. Herein, by direct, nano- to micro-scale observations using vertical scanning interferometry (VSI), we examine the temporal evolution of pitting corrosion on AISI 1045 carbon steel over large surface areas in Cl¯-free, and Cl¯-enriched solutions. Special focus is paid to examine the nucleation and growth of pits, and the associated formation of roughened regions on steel surfaces. By statistical analysis of hundreds of individual pits, three stages of pitting corrosion, namely, induction, propagation, and saturation, are quantitatively distinguished. By quantifying the kinetics of these processes, we contextualize our current understanding of electrochemical corrosion within a framework that considers spatial dynamics and morphology evolutions. In the presence of Cl¯ ions, corrosion is highly accelerated due to multiple autocatalytic factors including destabilization of protective surface oxide films and preservation of aggressive microenvironments within the pits, both of which promote continued pit nucleation and growth. Furthermore these findings offer new insights into predicting and modeling steel corrosion processes in mid-pH aqueous environments},
doi = {10.1038/s41598-018-26340-5},
journal = {Scientific Reports},
number = 1,
volume = 8,
place = {United States},
year = {Tue May 22 00:00:00 EDT 2018},
month = {Tue May 22 00:00:00 EDT 2018}
}
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Figure 1: Representative frequency diagrams showing the distribution of height differences across different pixel locations for AISI 1045 steel reacting with: (a) DI water, and (b) 100 mM NaCl solution. The height difference is calculated by subtracting the heights at a given (x, y) location at the respective times indicatedmore »
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Perforated Covers for Propagating Pits
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Use of SIMS to Investigate the Induction Stage in the Pitting of Iron
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Stochastic Models of Pitting Corrosion of Stainless Steels
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Occurrence of Salt Films during Initiation and Growth of Corrosion Pits
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The Behavior of Resistive Layers in the Localized Corrosion of Stainless Steel
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Surface Preparation and Pit Propagation in Stainless Steels
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Pitting Corrosion Resistance of Martensite of AISI 1045 Steel and the Beneficial Role of Interstitial Carbon
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- Kadowaki, Mariko; Muto, Izumi; Sugawara, Yu
- Journal of The Electrochemical Society, Vol. 164, Issue 14
A Micro-Raman Spectroscopic Study of Marine Atmospheric Corrosion of Carbon Steel: The Effect of Akaganeite
journal, January 2015
- Li, Shengxi; Hihara, L. H.
- Journal of The Electrochemical Society, Vol. 162, Issue 9
Initiation and Growth of Pits on High-Purity Iron and its Alloys with Chromium and Copper in Neutral Chloride Solutions
journal, July 1972
- Butler, G.; Stretton, P.; Beynon, J. G.
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Fatigue-crack initiation at corrosion pits
journal, January 1982
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Pitting Corrosion of Metals [金属の孔食]
journal, January 1967
- Kolotyrkin, Ja. M.
- CORROSION ENGINEERING DIGEST, Vol. 16, Issue 1
Does a dissolution-precipitation mechanism explain concrete creep in moist environments?
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