Infrared Quantum Dots: Progress, Challenges, and Opportunities

Lu, Haipeng; Carroll, Gerard M.; Neale, Nathan R.; Beard, Matthew C.

doi:10.1021/acsnano.8b09815

Title: Infrared Quantum Dots: Progress, Challenges, and Opportunities

Journal Article · 16 January 2019 · ACS Nano

DOI: https://doi.org/10.1021/acsnano.8b09815 · OSTI ID:1500079

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National Renewable Energy Lab. (NREL), Golden, CO (United States)

Infrared technologies provide tremendous value to our modern-day society. The need for easy-to-fabricate, solution-processable, tunable infrared active optoelectronic materials has driven the development of infrared colloidal quantum dots, whose band gaps can readily be tuned by dimensional constraints due to the quantum confinement effect. In this Perspective, we summarize recent progress in the development of infrared quantum dots both as infrared light emitters (e.g., in light-emitting diodes, biological imaging, etc.) as well as infrared absorbers (e.g., in photovoltaics, solar fuels, photon up-conversion, etc.), focusing on how fundamental breakthroughs in synthesis, surface chemistry, and characterization techniques are facilitating the implementation of these nanostructures into exploratory device architectures as well as in emerging applications. We discuss the ongoing challenges and opportunities associated with infrared colloidal quantum dots.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Advanced Solar Photophysics (CASP); National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1500079

Report Number(s):: NREL/JA--5900-73029

Journal Information:: ACS Nano, Journal Name: ACS Nano Journal Issue: 2 Vol. 13; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (150)

Synthesis and Characterization of InAs/InP and InAs/CdSe Core/Shell Nanocrystals Cao, Yun-Wei; Banin, Uri Angewandte Chemie International Edition, Vol. 38, Issue 24 https://doi.org/10.1002/(SICI)1521-3773(19991216)38:24<3692::AID-ANIE3692>3.0.CO;2-W	journal	December 1999
Silicon Quantum Dots for Biological Applications Chinnathambi, Shanmugavel; Chen, Song; Ganesan, Singaravelu Advanced Healthcare Materials, Vol. 3, Issue 1 https://doi.org/10.1002/adhm.201300157	journal	August 2013
Colloidal PbS Nanocrystals with Size-Tunable Near-Infrared Emission: Observation of Post-Synthesis Self-Narrowing of the Particle Size Distribution Hines, M. A.; Scholes, G. D. Advanced Materials, Vol. 15, Issue 21, p. 1844-1849 https://doi.org/10.1002/adma.200305395	journal	November 2003
1.3μm to 1.55μm Tunable Electroluminescence from PbSe Quantum Dots Embedded within an Organic Device Steckel, J. S.; Coe-Sullivan, S.; Bulović, V. Advanced Materials, Vol. 15, Issue 21 https://doi.org/10.1002/adma.200305449	journal	November 2003
Infrared Quantum Dots H. Sargent, E. Advanced Materials, Vol. 17, Issue 5 https://doi.org/10.1002/adma.200401552	journal	March 2005
High-Performance Shortwave-Infrared Light-Emitting Devices Using Core-Shell (PbS-CdS) Colloidal Quantum Dots Supran, Geoffrey J.; Song, Katherine W.; Hwang, Gyu Weon Advanced Materials, Vol. 27, Issue 8 https://doi.org/10.1002/adma.201404636	journal	January 2015
Quantifying the Thermodynamics of Ligand Binding to CsPbBr ₃ Quantum Dots Smock, Sara R.; Williams, Travis J.; Brutchey, Richard L. Angewandte Chemie, Vol. 130, Issue 36 https://doi.org/10.1002/ange.201806916	journal	August 2018
The Unexpected Influence of Precursor Conversion Rate in the Synthesis of III-V Quantum Dots Franke, Daniel; Harris, Daniel K.; Xie, Lisi Angewandte Chemie International Edition, Vol. 54, Issue 48 https://doi.org/10.1002/anie.201505972	journal	October 2015
Large-Scale Programmable Synthesis of PbS Quantum Dots Preske, Amanda; Liu, Jin; Prezhdo, Oleg V. ChemPhysChem, Vol. 17, Issue 5 https://doi.org/10.1002/cphc.201500909	journal	January 2016
Near infrared quantum dots in biomedical applications: current status and future perspective: Near infrared quantum dots in biomedical applications Zhao, Peng; Xu, Quan; Tao, Jia Wiley Interdisciplinary Reviews: Nanomedicine and Nanobiotechnology, Vol. 10, Issue 3 https://doi.org/10.1002/wnan.1483	journal	July 2017
Synthesis of nanoparticles in the gas phase for electronic, optical and magnetic applications—a review Kruis, F. Einar; Fissan, Heinz; Peled, Aaron Journal of Aerosol Science, Vol. 29, Issue 5-6 https://doi.org/10.1016/S0021-8502(97)10032-5	journal	June 1998
Quantum dots for next-generation photovoltaics Semonin, Octavi E.; Luther, Joseph M.; Beard, Matthew C. Materials Today, Vol. 15, Issue 11, p. 508-515 https://doi.org/10.1016/S1369-7021(12)70220-1	journal	November 2012
Design of new quantum dot materials for deep tissue infrared imaging Cassette, Elsa; Helle, Marion; Bezdetnaya, Lina Advanced Drug Delivery Reviews, Vol. 65, Issue 5 https://doi.org/10.1016/j.addr.2012.08.016	journal	May 2013
Diorganyl Dichalcogenides as Useful Synthons for Colloidal Semiconductor Nanocrystals Brutchey, Richard L. Accounts of Chemical Research, Vol. 48, Issue 11 https://doi.org/10.1021/acs.accounts.5b00362	journal	October 2015
One-Pot Microwave Synthesis of Water-Dispersible, High Fluorescence Silicon Nanoparticles and Their Imaging Applications in Vitro and in Vivo Ye, Hong-Li; Cai, Shi-Jiao; Li, Si Analytical Chemistry, Vol. 88, Issue 23 https://doi.org/10.1021/acs.analchem.6b03209	journal	November 2016
Silyl Radical Abstraction in the Functionalization of Plasma-Synthesized Silicon Nanocrystals Wheeler, Lance M.; Anderson, Nicholas C.; Palomaki, Peter K. B. Chemistry of Materials, Vol. 27, Issue 19, p. 6869-6878 https://doi.org/10.1021/acs.chemmater.5b03309	journal	September 2015
Iodide-Passivated Colloidal PbS Nanocrystals Leading to Highly Efficient Polymer:Nanocrystal Hybrid Solar Cells Lu, Haipeng; Joy, Jimmy; Gaspar, Rachel L. Chemistry of Materials, Vol. 28, Issue 6 https://doi.org/10.1021/acs.chemmater.6b00185	journal	February 2016
Quantifying Ligand Exchange Reactions at CdSe Nanocrystal Surfaces Knauf, Robin R.; Lennox, J. Christian; Dempsey, Jillian L. Chemistry of Materials, Vol. 28, Issue 13 https://doi.org/10.1021/acs.chemmater.6b01827	journal	June 2016
Shining Light on Indium Phosphide Quantum Dots: Understanding the Interplay among Precursor Conversion, Nucleation, and Growth Cossairt, Brandi M. Chemistry of Materials, Vol. 28, Issue 20 https://doi.org/10.1021/acs.chemmater.6b03408	journal	October 2016
Tunable Room-Temperature Synthesis of Coinage Metal Chalcogenide Nanocrystals from N -Heterocyclic Carbene Synthons Lu, Haipeng; Brutchey, Richard L. Chemistry of Materials, Vol. 29, Issue 3 https://doi.org/10.1021/acs.chemmater.6b05293	journal	January 2017
Toward Improved Scalability of Cation Exchange Reactions of Metal Chalcogenide Nanocrystals Morris, Alexander L.; Lin, Chen; Benjamin, Savannah E. Chemistry of Materials, Vol. 29, Issue 16 https://doi.org/10.1021/acs.chemmater.7b01065	journal	August 2017
Impact of Size Dispersity, Ligand Coverage, and Ligand Length on the Structure of PbS Nanocrystal Superlattices Weidman, Mark C.; Nguyen, Quan; Smilgies, Detlef-M. Chemistry of Materials, Vol. 30, Issue 3 https://doi.org/10.1021/acs.chemmater.7b04322	journal	January 2018
Monodisperse InAs Quantum Dots from Aminoarsine Precursors: Understanding the Role of Reducing Agent Srivastava, Vishwas; Dunietz, Eleanor; Kamysbayev, Vladislav Chemistry of Materials, Vol. 30, Issue 11 https://doi.org/10.1021/acs.chemmater.8b01137	journal	May 2018
Morphological Control of In _x Ga _{1– x} P Nanocrystals Synthesized in a Nonthermal Plasma Bronstein, Noah D.; Wheeler, Lance M.; Anderson, Nicholas C. Chemistry of Materials, Vol. 30, Issue 9 https://doi.org/10.1021/acs.chemmater.8b01358	journal	April 2018
Utilizing Diselenide Precursors toward Rationally Controlled Synthesis of Metastable CuInSe ₂ Nanocrystals Tappan, Bryce A.; Barim, Gözde; Kwok, Jacky C. Chemistry of Materials, Vol. 30, Issue 16 https://doi.org/10.1021/acs.chemmater.8b02205	journal	July 2018
Colloidal Quantum Dot Solar Cells Carey, Graham H.; Abdelhady, Ahmed L.; Ning, Zhijun Chemical Reviews, Vol. 115, Issue 23 https://doi.org/10.1021/acs.chemrev.5b00063	journal	June 2015
Nonthermal Plasma Synthesis of Nanocrystals: Fundamental Principles, Materials, and Applications Kortshagen, Uwe R.; Sankaran, R. Mohan; Pereira, Rui N. Chemical Reviews, Vol. 116, Issue 18 https://doi.org/10.1021/acs.chemrev.6b00039	journal	August 2016
Localized Surface Plasmon Resonance in Semiconductor Nanocrystals Agrawal, Ankit; Cho, Shin Hum; Zandi, Omid Chemical Reviews, Vol. 118, Issue 6 https://doi.org/10.1021/acs.chemrev.7b00613	journal	February 2018
HgSe/CdE (E = S, Se) Core/Shell Nanocrystals by Colloidal Atomic Layer Deposition Sagar, Laxmi Kishore; Walravens, Willem; Maes, Jorick The Journal of Physical Chemistry C, Vol. 121, Issue 25 https://doi.org/10.1021/acs.jpcc.7b02803	journal	June 2017
Optical Absorbance Enhancement in PbS QD/Cinnamate Ligand Complexes Kroupa, Daniel M.; Vörös, Márton; Brawand, Nicholas P. The Journal of Physical Chemistry Letters, Vol. 9, Issue 12 https://doi.org/10.1021/acs.jpclett.8b01451	journal	June 2018
Semiconductor Nanocrystal Light Absorbers for Photon Upconversion Huang, Zhiyuan; Lee Tang, Ming The Journal of Physical Chemistry Letters, Vol. 9, Issue 21 https://doi.org/10.1021/acs.jpclett.8b02154	journal	October 2018
Hybrid Molecule–Nanocrystal Photon Upconversion Across the Visible and Near-Infrared Huang, Zhiyuan; Li, Xin; Mahboub, Melika Nano Letters, Vol. 15, Issue 8 https://doi.org/10.1021/acs.nanolett.5b02130	journal	July 2015
Plasmonic Properties of Silicon Nanocrystals Doped with Boron and Phosphorus Kramer, Nicolaas J.; Schramke, Katelyn S.; Kortshagen, Uwe R. Nano Letters, Vol. 15, Issue 8 https://doi.org/10.1021/acs.nanolett.5b02287	journal	July 2015
Lead Telluride Quantum Dot Solar Cells Displaying External Quantum Efficiencies Exceeding 120% Böhm, Marcus L.; Jellicoe, Tom C.; Tabachnyk, Maxim Nano Letters, Vol. 15, Issue 12 https://doi.org/10.1021/acs.nanolett.5b03161	journal	November 2015
Evolution of the Single-Nanocrystal Photoluminescence Linewidth with Size and Shell: Implications for Exciton–Phonon Coupling and the Optimization of Spectral Linewidths Cui, Jian; Beyler, Andrew P.; Coropceanu, Igor Nano Letters, Vol. 16, Issue 1 https://doi.org/10.1021/acs.nanolett.5b03790	journal	December 2015
All-Inorganic Germanium Nanocrystal Films by Cationic Ligand Exchange Wheeler, Lance M.; Nichols, Asa W.; Chernomordik, Boris D. Nano Letters, Vol. 16, Issue 3 https://doi.org/10.1021/acs.nanolett.5b05192	journal	January 2016
Efficient Infrared-to-Visible Upconversion with Subsolar Irradiance Mahboub, Melika; Huang, Zhiyuan; Tang, Ming Lee Nano Letters, Vol. 16, Issue 11 https://doi.org/10.1021/acs.nanolett.6b03503	journal	October 2016
Tuning Confinement in Colloidal Silicon Nanocrystals with Saturated Surface Ligands Carroll, Gerard M.; Limpens, Rens; Neale, Nathan R. Nano Letters, Vol. 18, Issue 5 https://doi.org/10.1021/acs.nanolett.8b00680	journal	April 2018
Donor–Acceptor Pair Recombination in Size-Purified Silicon Quantum Dots Sugimoto, Hiroshi; Yamamura, Masataka; Fujii, Riku Nano Letters, Vol. 18, Issue 11 https://doi.org/10.1021/acs.nanolett.8b03489	journal	September 2018
Nonthermal Plasma Synthesis of Core/Shell Quantum Dots: Strained Ge/Si Nanocrystals Hunter, Katharine I.; Held, Jacob T.; Mkhoyan, K. Andre ACS Applied Materials & Interfaces, Vol. 9, Issue 9 https://doi.org/10.1021/acsami.6b16170	journal	February 2017
Air-Stable and Efficient PbSe Quantum-Dot Solar Cells Based upon ZnSe to PbSe Cation-Exchanged Quantum Dots Kim, Sungwoo; Marshall, Ashley R.; Kroupa, Daniel M. ACS Nano, Vol. 9, Issue 8 https://doi.org/10.1021/acsnano.5b02326	journal	July 2015
Dismantling the “Red Wall” of Colloidal Perovskites: Highly Luminescent Formamidinium and Formamidinium–Cesium Lead Iodide Nanocrystals Protesescu, Loredana; Yakunin, Sergii; Kumar, Sudhir ACS Nano, Vol. 11, Issue 3 https://doi.org/10.1021/acsnano.7b00116	journal	March 2017
Fast and Sensitive Colloidal Quantum Dot Mid-Wave Infrared Photodetectors Ackerman, Matthew M.; Tang, Xin; Guyot-Sionnest, Philippe ACS Nano, Vol. 12, Issue 7 https://doi.org/10.1021/acsnano.8b03425	journal	June 2018
Enhanced Multiple Exciton Generation in PbS\|CdS Janus-like Heterostructured Nanocrystals Kroupa, Daniel M.; Pach, Gregory F.; Vörös, Márton ACS Nano, Vol. 12, Issue 10 https://doi.org/10.1021/acsnano.8b04850	journal	September 2018
Perovskite Quantum Dot Photovoltaic Materials beyond the Reach of Thin Films: Full-Range Tuning of A-Site Cation Composition Hazarika, Abhijit; Zhao, Qian; Gaulding, E. Ashley ACS Nano, Vol. 12, Issue 10 https://doi.org/10.1021/acsnano.8b05555	journal	September 2018
Single Nanocrystal Spectroscopy of Shortwave Infrared Emitters Bertram, Sophie N.; Spokoyny, Boris; Franke, Daniel ACS Nano https://doi.org/10.1021/acsnano.8b07578	journal	November 2018
Ag ₂ Se Quantum Dots with Tunable Emission in the Second Near-Infrared Window Zhu, Chun-Nan; Jiang, Peng; Zhang, Zhi-Ling ACS Applied Materials & Interfaces, Vol. 5, Issue 4 https://doi.org/10.1021/am303110x	journal	February 2013
Third Generation Photovoltaics based on Multiple Exciton Generation in Quantum Confined Semiconductors Beard, Matthew C.; Luther, Joseph M.; Semonin, Octavi E. Accounts of Chemical Research, Vol. 46, Issue 6 https://doi.org/10.1021/ar3001958	journal	October 2012
Synthesis of Metastable Wurtzite CuInSe ₂ Nanocrystals Norako, Michelle E.; Brutchey, Richard L. Chemistry of Materials, Vol. 22, Issue 5 https://doi.org/10.1021/cm100341r	journal	March 2010
Synthesis and Characterization of Near-Infrared Cu−In−Se/ZnS Core/Shell Quantum Dots for In vivo Imaging Cassette, E.; Pons, T.; Bouet, C. Chemistry of Materials, Vol. 22, Issue 22 https://doi.org/10.1021/cm101881b	journal	November 2010
A Solution NMR Toolbox for Characterizing the Surface Chemistry of Colloidal Nanocrystals Hens, Zeger; Martins, José C. Chemistry of Materials, Vol. 25, Issue 8 https://doi.org/10.1021/cm303361s	journal	February 2013
Facile Synthesis of Highly Photoluminescent Ag ₂ Se Quantum Dots as a New Fluorescent Probe in the Second Near-Infrared Window for in Vivo Imaging Dong, Bohua; Li, Chunyan; Chen, Guangcun Chemistry of Materials, Vol. 25, Issue 12 https://doi.org/10.1021/cm400812v	journal	June 2013
Investigation of Indium Phosphide Quantum Dot Nucleation and Growth Utilizing Triarylsilylphosphine Precursors Gary, Dylan C.; Glassy, Benjamin A.; Cossairt, Brandi M. Chemistry of Materials, Vol. 26, Issue 4 https://doi.org/10.1021/cm500102q	journal	February 2014
Highly Luminescent CuInS ₂ /ZnS Core/Shell Nanocrystals: Cadmium-Free Quantum Dots for In Vivo Imaging Li, Liang; Daou, T. Jean; Texier, Isabelle Chemistry of Materials, Vol. 21, Issue 12 https://doi.org/10.1021/cm900103b	journal	June 2009
Growth Kinetics of Monodisperse Cu−In−S Nanocrystals Using a Dialkyl Disulfide Sulfur Source Norako, Michelle E.; Franzman, Matthew A.; Brutchey, Richard L. Chemistry of Materials, Vol. 21, Issue 18 https://doi.org/10.1021/cm9015673	journal	September 2009
Semiconductor Quantum Dots and Quantum Dot Arrays and Applications of Multiple Exciton Generation to Third-Generation Photovoltaic Solar Cells Nozik, A. J.; Beard, M. C.; Luther, J. M. Chemical Reviews, Vol. 110, Issue 11 https://doi.org/10.1021/cr900289f	journal	November 2010
A luminescent silicon nanocrystal colloid via a high-temperature aerosol reaction Littau, K. A.; Szajowski, P. J.; Muller, A. J. The Journal of Physical Chemistry, Vol. 97, Issue 6 https://doi.org/10.1021/j100108a019	journal	February 1993
Theory, Production and Mechanism of Formation of Monodispersed Hydrosols LaMer, Victor K.; Dinegar, Robert H. Journal of the American Chemical Society, Vol. 72, Issue 11 https://doi.org/10.1021/ja01167a001	journal	November 1950
Pushing the Band Gap Envelope: Mid-Infrared Emitting Colloidal PbSe Quantum Dots Pietryga, Jeffrey M.; Schaller, Richard D.; Werder, Donald Journal of the American Chemical Society, Vol. 126, Issue 38 https://doi.org/10.1021/ja047659f	journal	September 2004
Synthesis of InAs/CdSe/ZnSe Core/Shell1/Shell2 Structures with Bright and Stable Near-Infrared Fluorescence Aharoni, Assaf; Mokari, Taleb; Popov, Inna Journal of the American Chemical Society, Vol. 128, Issue 1 https://doi.org/10.1021/ja056326v	journal	January 2006
PbTe Colloidal Nanocrystals: Synthesis, Characterization, and Multiple Exciton Generation Murphy, James E.; Beard, Matthew C.; Norman, Andrew G. Journal of the American Chemical Society, Vol. 128, Issue 10 https://doi.org/10.1021/ja0574973	journal	March 2006
Colloidal HgTe Nanocrystals with Widely Tunable Narrow Band Gap Energies: From Telecommunications to Molecular Vibrations Kovalenko, Maksym V.; Kaufmann, Erich; Pachinger, Dietmar Journal of the American Chemical Society, Vol. 128, Issue 11 https://doi.org/10.1021/ja058440j	journal	March 2006
Aqueous Synthesis of Zinc Blende CdTe/CdS Magic-Core/Thick-Shell Tetrahedral-Shaped Nanocrystals with Emission Tunable to Near-Infrared Deng, Zhengtao; Schulz, Olaf; Lin, Su Journal of the American Chemical Society, Vol. 132, Issue 16 https://doi.org/10.1021/ja101476b	journal	April 2010
Highly Effective Surface Passivation of PbSe Quantum Dots through Reaction with Molecular Chlorine Bae, Wan Ki; Joo, Jin; Padilha, Lazaro A. Journal of the American Chemical Society, Vol. 134, Issue 49 https://doi.org/10.1021/ja309783v	journal	November 2012
Colloidal InSb Nanocrystals Liu, Wenyong; Chang, Angela Y.; Schaller, Richard D. Journal of the American Chemical Society, Vol. 134, Issue 50 https://doi.org/10.1021/ja309821j	journal	December 2012
Improved Precursor Chemistry for the Synthesis of III–V Quantum Dots Harris, Daniel K.; Bawendi, Moungi G. Journal of the American Chemical Society, Vol. 134, Issue 50 https://doi.org/10.1021/ja309863n	journal	December 2012
Ligand Exchange and the Stoichiometry of Metal Chalcogenide Nanocrystals: Spectroscopic Observation of Facile Metal-Carboxylate Displacement and Binding Anderson, Nicholas C.; Hendricks, Mark P.; Choi, Joshua J. Journal of the American Chemical Society, Vol. 135, Issue 49, p. 18536-18548 https://doi.org/10.1021/ja4086758	journal	November 2013
“Darker-than-Black” PbS Quantum Dots: Enhancing Optical Absorption of Colloidal Semiconductor Nanocrystals via Short Conjugated Ligands Giansante, Carlo; Infante, Ivan; Fabiano, Eduardo Journal of the American Chemical Society, Vol. 137, Issue 5 https://doi.org/10.1021/ja510739q	journal	January 2015
Utilizing the Lability of Lead Selenide to Produce Heterostructured Nanocrystals with Bright, Stable Infrared Emission Pietryga, Jeffrey M.; Werder, Donald J.; Williams, Darrick J. Journal of the American Chemical Society, Vol. 130, Issue 14 https://doi.org/10.1021/ja710437r	journal	April 2008
Size and Shape Control of Colloidally Synthesized IV−VI Nanoparticulate Tin(II) Sulfide Hickey, Stephen G.; Waurisch, Christian; Rellinghaus, Bernd Journal of the American Chemical Society, Vol. 130, Issue 45 https://doi.org/10.1021/ja8048755	journal	October 2008
InAs(ZnCdS) Quantum Dots Optimized for Biological Imaging in the Near-Infrared Allen, Peter M.; Liu, Wenhao; Chauhan, Vikash P. Journal of the American Chemical Society, Vol. 132, Issue 2 https://doi.org/10.1021/ja908250r	journal	January 2010
Synthesis and Characterization of Cadmium Phosphide Quantum Dots Emitting in the Visible Red to Near-Infrared Miao, Shiding; Hickey, Stephen G.; Rellinghaus, Bernd Journal of the American Chemical Society, Vol. 132, Issue 16 https://doi.org/10.1021/ja9105732	journal	April 2010
Photogenerated Excitons in Plain Core CdSe Nanocrystals with Unity Radiative Decay in Single Channel: The Effects of Surface and Ligands Gao, Yuan; Peng, Xiaogang Journal of the American Chemical Society, Vol. 137, Issue 12 https://doi.org/10.1021/jacs.5b01314	journal	March 2015
Air-Stable PbSe Nanocrystals Passivated by Phosphonic Acids Woo, Ju Young; Lee, Sooho; Lee, Seokwon Journal of the American Chemical Society, Vol. 138, Issue 3 https://doi.org/10.1021/jacs.5b10273	journal	January 2016
Synthesis and Optical Properties of Lead-Free Cesium Tin Halide Perovskite Nanocrystals Jellicoe, Tom C.; Richter, Johannes M.; Glass, Hugh F. J. Journal of the American Chemical Society, Vol. 138, Issue 9 https://doi.org/10.1021/jacs.5b13470	journal	February 2016
Exposing the Dynamics and Energetics of the N-Heterocyclic Carbene–Nanocrystal Interface Lu, Haipeng; Zhou, Zhaohui; Prezhdo, Oleg V. Journal of the American Chemical Society, Vol. 138, Issue 45 https://doi.org/10.1021/jacs.6b09065	journal	November 2016
A Library of Selenourea Precursors to PbSe Nanocrystals with Size Distributions near the Homogeneous Limit Campos, Michael P.; Hendricks, Mark P.; Beecher, Alexander N. Journal of the American Chemical Society, Vol. 139, Issue 6 https://doi.org/10.1021/jacs.6b11021	journal	February 2017
Synthesis and Spectroscopy of Silver-Doped PbSe Quantum Dots Kroupa, Daniel M.; Hughes, Barbara K.; Miller, Elisa M. Journal of the American Chemical Society, Vol. 139, Issue 30 https://doi.org/10.1021/jacs.7b04551	journal	July 2017
Colloidal Synthesis of Air-Stable Alloyed CsSn _{1– x} Pb _x I ₃ Perovskite Nanocrystals for Use in Solar Cells Liu, Feng; Ding, Chao; Zhang, Yaohong Journal of the American Chemical Society, Vol. 139, Issue 46 https://doi.org/10.1021/jacs.7b08628	journal	November 2017
Colloidal Chemistry in Molten Salts: Synthesis of Luminescent In 1– x Ga x P and In 1– x Ga x As Quantum Dots Srivastava, Vishwas; Kamysbayev, Vladislav; Hong, Liang Journal of the American Chemical Society, Vol. 140, Issue 38 https://doi.org/10.1021/jacs.8b06971	journal	August 2018
n -Type PbSe Quantum Dots via Post-Synthetic Indium Doping Lu, Haipeng; Carroll, Gerard M.; Chen, Xihan Journal of the American Chemical Society, Vol. 140, Issue 42 https://doi.org/10.1021/jacs.8b07910	journal	September 2018
High-Quality and Water-Soluble Near-Infrared Photoluminescent CdHgTe/CdS Quantum Dots Prepared by Adjusting Size and Composition Qian, Huifeng; Dong, Chaoqing; Peng, Jinliang The Journal of Physical Chemistry C, Vol. 111, Issue 45 https://doi.org/10.1021/jp074961c	journal	November 2007
Codoping n- and p-Type Impurities in Colloidal Silicon Nanocrystals: Controlling Luminescence Energy from below Bulk Band Gap to Visible Range Sugimoto, Hiroshi; Fujii, Minoru; Imakita, Kenji The Journal of Physical Chemistry C, Vol. 117, Issue 22 https://doi.org/10.1021/jp4027767	journal	May 2013
Absolute Photoluminescence Quantum Yields of IR-26 Dye, PbS, and PbSe Quantum Dots Semonin, Octavi E.; Johnson, Justin C.; Luther, Joseph M. The Journal of Physical Chemistry Letters, Vol. 1, Issue 16 https://doi.org/10.1021/jz100830r	journal	July 2010
Tunable Band Gap Emission and Surface Passivation of Germanium Nanocrystals Synthesized in the Gas Phase Wheeler, Lance M.; Levij, Laszlo M.; Kortshagen, Uwe R. The Journal of Physical Chemistry Letters, Vol. 4, Issue 20 https://doi.org/10.1021/jz401576b	journal	September 2013
High-Yield Plasma Synthesis of Luminescent Silicon Nanocrystals Mangolini, L.; Thimsen, E.; Kortshagen, U. Nano Letters, Vol. 5, Issue 4 https://doi.org/10.1021/nl050066y	journal	April 2005
Highly Efficient Multiple Exciton Generation in Colloidal PbSe and PbS Quantum Dots Ellingson, Randy J.; Beard, Matthew C.; Johnson, Justin C. Nano Letters, Vol. 5, Issue 5, p. 865-871 https://doi.org/10.1021/nl0502672	journal	May 2005
Fluorescence Spectroscopy of Single Lead Sulfide Quantum Dots Peterson, Jeffrey J.; Krauss, Todd D. Nano Letters, Vol. 6, Issue 3 https://doi.org/10.1021/nl0525756	journal	March 2006
Multiple Exciton Generation in Colloidal Silicon Nanocrystals Beard, Matthew C.; Knutsen, Kelly P.; Yu, Pingrong Nano Letters, Vol. 7, Issue 8 https://doi.org/10.1021/nl071486l	journal	August 2007
Carrier Multiplication in InAs Nanocrystal Quantum Dots with an Onset Defined by the Energy Conservation Limit Schaller, Richard D.; Pietryga, Jeffrey M.; Klimov, Victor I. Nano Letters, Vol. 7, Issue 11 https://doi.org/10.1021/nl072046x	journal	November 2007
Single Photon Counting from Individual Nanocrystals in the Infrared Correa, Raoul E.; Dauler, Eric A.; Nair, Gautham Nano Letters, Vol. 12, Issue 6 https://doi.org/10.1021/nl300642k	journal	May 2012
Phosphorus-Doped Silicon Nanocrystals Exhibiting Mid-Infrared Localized Surface Plasmon Resonance Rowe, David J.; Jeong, Jong Seok; Mkhoyan, K. Andre Nano Letters, Vol. 13, Issue 3 https://doi.org/10.1021/nl4001184	journal	February 2013
PbSe Quantum Dot Solar Cells with More than 6% Efficiency Fabricated in Ambient Atmosphere Zhang, Jianbing; Gao, Jianbo; Church, Carena P. Nano Letters, Vol. 14, Issue 10 https://doi.org/10.1021/nl503085v	journal	September 2014
Schottky Solar Cells Based on Colloidal Nanocrystal Films Luther, Joseph M.; Law, Matt; Beard, Matthew C. Nano Letters, Vol. 8, Issue 10 https://doi.org/10.1021/nl802476m	journal	October 2008
An Upper Bound to Carrier Multiplication Efficiency in Type II Colloidal Quantum Dots Gachet, David; Avidan, Assaf; Pinkas, Iddo Nano Letters, Vol. 10, Issue 1 https://doi.org/10.1021/nl903172f	journal	January 2010
Size and Bandgap Control in the Solution-Phase Synthesis of Near-Infrared-Emitting Germanium Nanocrystals Ruddy, Daniel A.; Johnson, Justin C.; Smith, E. Ryan ACS Nano, Vol. 4, Issue 12, p. 7459-7466 https://doi.org/10.1021/nn102728u	journal	November 2010
Ag ₂ S Quantum Dot: A Bright and Biocompatible Fluorescent Nanoprobe in the Second Near-Infrared Window Zhang, Yan; Hong, Guosong; Zhang, Yejun ACS Nano, Vol. 6, Issue 5 https://doi.org/10.1021/nn301218z	journal	April 2012
Diffusion-Controlled Synthesis of PbS and PbSe Quantum Dots with in Situ Halide Passivation for Quantum Dot Solar Cells Zhang, Jianbing; Gao, Jianbo; Miller, Elisa M. ACS Nano, Vol. 8, Issue 1 https://doi.org/10.1021/nn405236k	journal	December 2013
Air-Stable Near-Infrared AgInSe ₂ Nanocrystals Langevin, Marc-Antoine; Ritcey, Anna M.; Allen, Claudine Nì ACS Nano, Vol. 8, Issue 4 https://doi.org/10.1021/nn406439w	journal	March 2014
Energy Level Modification in Lead Sulfide Quantum Dot Thin Films through Ligand Exchange Brown, Patrick R.; Kim, Donghun; Lunt, Richard R. ACS Nano, Vol. 8, Issue 6 https://doi.org/10.1021/nn500897c	journal	May 2014
Monodisperse, Air-Stable PbS Nanocrystals via Precursor Stoichiometry Control Weidman, Mark C.; Beck, Megan E.; Hoffman, Rachel S. ACS Nano, Vol. 8, Issue 6 https://doi.org/10.1021/nn5018654	journal	May 2014
Colloidal Quantum Dots Intraband Photodetectors Deng, Zhiyou; Jeong, Kwang Seob; Guyot-Sionnest, Philippe ACS Nano, Vol. 8, Issue 11 https://doi.org/10.1021/nn505092a	journal	October 2014
Structural, Optical, and Electrical Properties of Self-Assembled Films of PbSe Nanocrystals Treated with 1,2-Ethanedithiol Luther, Joseph M.; Law, Matt; Song, Qing ACS Nano, Vol. 2, Issue 2 https://doi.org/10.1021/nn7003348	journal	January 2008
Ultrasensitive solution-cast quantum dot photodetectors Konstantatos, Gerasimos; Howard, Ian; Fischer, Armin Nature, Vol. 442, Issue 7099 https://doi.org/10.1038/nature04855	journal	July 2006
Solution-processed, high-performance light-emitting diodes based on quantum dots Dai, Xingliang; Zhang, Zhenxing; Jin, Yizheng Nature, Vol. 515, Issue 7525 https://doi.org/10.1038/nature13829	journal	October 2014
Continuous injection synthesis of indium arsenide quantum dots emissive in the short-wavelength infrared Franke, Daniel; Harris, Daniel K.; Chen, Ou Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12749	journal	November 2016
Tuning colloidal quantum dot band edge positions through solution-phase surface chemistry modification Kroupa, Daniel M.; Vörös, Márton; Brawand, Nicholas P. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15257	journal	May 2017
Enhanced carrier multiplication in engineered quasi-type-II quantum dots Cirloganu, Claudiu M.; Padilha, Lazaro A.; Lin, Qianglu Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5148	journal	June 2014
Multiple-exciton generation in lead selenide nanorod solar cells with external quantum efficiencies exceeding 120% Davis, Nathaniel J. L. K.; Böhm, Marcus L.; Tabachnyk, Maxim Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9259	journal	September 2015
Multiple exciton generation for photoelectrochemical hydrogen evolution reactions with quantum yields exceeding 100% Yan, Yong; Crisp, Ryan W.; Gu, Jing Nature Energy, Vol. 2, Issue 5 https://doi.org/10.1038/nenergy.2017.52	journal	April 2017
Improved performance and stability in quantum dot solar cells through band alignment engineering Chuang, Chia-Hao M.; Brown, Patrick R.; Bulović, Vladimir Nature Materials, Vol. 13, Issue 8, p. 796-801 https://doi.org/10.1038/nmat3984	journal	May 2014
Resonant energy transfer of triplet excitons from pentacene to PbSe nanocrystals Tabachnyk, Maxim; Ehrler, Bruno; Gélinas, Simon Nature Materials, Vol. 13, Issue 11 https://doi.org/10.1038/nmat4093	journal	October 2014
Energy harvesting of non-emissive triplet excitons in tetracene by emissive PbS nanocrystals Thompson, Nicholas J.; Wilson, Mark W. B.; Congreve, Daniel N. Nature Materials, Vol. 13, Issue 11 https://doi.org/10.1038/nmat4097	journal	October 2014
Charge transport and localization in atomically coherent quantum dot solids Whitham, Kevin; Yang, Jun; Savitzky, Benjamin H. Nature Materials, Vol. 15, Issue 5 https://doi.org/10.1038/nmat4576	journal	February 2016
In situ study of the formation mechanism of two-dimensional superlattices from PbSe nanocrystals Geuchies, Jaco J.; van Overbeek, Carlo; Evers, Wiel H. Nature Materials, Vol. 15, Issue 12 https://doi.org/10.1038/nmat4746	journal	September 2016
Bright infrared quantum-dot light-emitting diodes through inter-dot spacing control Sun, Liangfeng; Choi, Joshua J.; Stachnik, David Nature Nanotechnology, Vol. 7, Issue 6 https://doi.org/10.1038/nnano.2012.63	journal	May 2012
Bright, multicoloured light-emitting diodes based on quantum dots Sun, Qingjiang; Wang, Y. Andrew; Li, Lin Song Nature Photonics, Vol. 1, Issue 12 https://doi.org/10.1038/nphoton.2007.226	journal	November 2007
Mid-infrared HgTe colloidal quantum dot photodetectors Keuleyan, Sean; Lhuillier, Emmanuel; Brajuskovic, Vuk Nature Photonics, Vol. 5, Issue 8 https://doi.org/10.1038/nphoton.2011.142	journal	July 2011
Solution-processed solar cells based on environmentally friendly AgBiS2 nanocrystals Bernechea, María; Miller, Nichole Cates; Xercavins, Guillem Nature Photonics, Vol. 10, Issue 8 https://doi.org/10.1038/nphoton.2016.108	journal	June 2016
Highly efficient quantum dot near-infrared light-emitting diodes Gong, Xiwen; Yang, Zhenyu; Walters, Grant Nature Photonics, Vol. 10, Issue 4 https://doi.org/10.1038/nphoton.2016.11	journal	February 2016
2D matrix engineering for homogeneous quantum dot coupling in photovoltaic solids Xu, Jixian; Voznyy, Oleksandr; Liu, Mengxia Nature Nanotechnology, Vol. 13, Issue 6 https://doi.org/10.1038/s41565-018-0117-z	journal	April 2018
High-efficiency colloidal quantum dot infrared light-emitting diodes via engineering at the supra-nanocrystalline level Pradhan, Santanu; Di Stasio, Francesco; Bi, Yu Nature Nanotechnology, Vol. 14, Issue 1 https://doi.org/10.1038/s41565-018-0312-y	journal	December 2018
Iodide capped PbS/CdS core-shell quantum dots for efficient long-wavelength near-infrared light-emitting diodes Yang, Xuyong; Ren, Fuqiang; Wang, Yue Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-15244-5	journal	November 2017
Near-infrared light emitting diodes using PbSe quantum dots Yan, Long; Shen, Xinyu; Zhang, Yu RSC Advances, Vol. 5, Issue 67 https://doi.org/10.1039/C5RA08130K	journal	January 2015
In situ spectroscopic characterization of a solution-phase X-type ligand exchange at colloidal lead sulphide quantum dot surfaces Kroupa, D. M.; Anderson, N. C.; Castaneda, C. V. Chemical Communications, Vol. 52, Issue 96 https://doi.org/10.1039/C6CC08114B	journal	January 2016
Near-infrared quantum dots: synthesis, functionalization and analytical applications Ma, Qiang; Su, Xingguang The Analyst, Vol. 135, Issue 8 https://doi.org/10.1039/c0an00233j	journal	January 2010
SnSe2 quantum dot sensitized solar cells prepared employing molecular metal chalcogenide as precursors Yu, Xuechao; Zhu, Jun; Zhang, Yaohong Chemical Communications, Vol. 48, Issue 27 https://doi.org/10.1039/c2cc17081g	journal	January 2012
Narrow bandgap colloidal metal chalcogenide quantum dots: synthetic methods, heterostructures, assemblies, electronic and infrared optical properties Kershaw, Stephen V.; Susha, Andrei S.; Rogach, Andrey L. Chemical Society Reviews, Vol. 42, Issue 7 https://doi.org/10.1039/c2cs35331h	journal	January 2013
Spectroscopy of single nanocrystals Fernée, Mark J.; Tamarat, Philippe; Lounis, Brahim Chemical Society Reviews, Vol. 43, Issue 4 https://doi.org/10.1039/c3cs60209e	journal	January 2014
Plasma synthesis of stoichiometric Cu2S nanocrystals stabilized by oleylamine Thimsen, Elijah; Kortshagen, Uwe R.; Aydil, Eray S. Chemical Communications, Vol. 50, Issue 61 https://doi.org/10.1039/c4cc00998c	journal	January 2014
Size-tunable infrared (1000–1600 nm) electroluminescence from PbS quantum-dot nanocrystals in a semiconducting polymer Bakueva, L.; Musikhin, S.; Hines, M. A. Applied Physics Letters, Vol. 82, Issue 17 https://doi.org/10.1063/1.1570940	journal	April 2003
Near-infrared electroluminescent devices based on colloidal HgTe quantum dot arrays O’Connor, É.; O’Riordan, A.; Doyle, H. Applied Physics Letters, Vol. 86, Issue 20 https://doi.org/10.1063/1.1928321	journal	May 2005
Silicon nanocrystals with ensemble quantum yields exceeding 60% Jurbergs, David; Rogojina, Elena; Mangolini, Lorenzo Applied Physics Letters, Vol. 88, Issue 23 https://doi.org/10.1063/1.2210788	journal	June 2006
Nonthermal plasma synthesis of size-controlled, monodisperse, freestanding germanium nanocrystals Gresback, Ryan; Holman, Zachary; Kortshagen, Uwe Applied Physics Letters, Vol. 91, Issue 9 https://doi.org/10.1063/1.2778356	journal	August 2007
Hot carrier injection at semiconductor-electrolyte junctions Boudreaux, D. S.; Williams, F.; Nozik, A. J. Journal of Applied Physics, Vol. 51, Issue 4 https://doi.org/10.1063/1.327889	journal	January 1980
Boron- and phosphorus-doped silicon germanium alloy nanocrystals—Nonthermal plasma synthesis and gas-phase thin film deposition Rowe, David J.; Kortshagen, Uwe R. APL Materials, Vol. 2, Issue 2 https://doi.org/10.1063/1.4865158	journal	February 2014
Controlled synthesis of germanium nanoparticles by nonthermal plasmas Ahadi, Amir Mohammad; Hunter, Katharine I.; Kramer, Nicolaas J. Applied Physics Letters, Vol. 108, Issue 9 https://doi.org/10.1063/1.4942970	journal	February 2016
Nonthermal plasma synthesized freestanding silicon–germanium alloy nanocrystals Pi, X. D.; Kortshagen, U. Nanotechnology, Vol. 20, Issue 29 https://doi.org/10.1088/0957-4484/20/29/295602	journal	July 2009
High Efficiency Carrier Multiplication in PbSe Nanocrystals: Implications for Solar Energy Conversion Schaller, R. D.; Klimov, V. I. Physical Review Letters, Vol. 92, Issue 18 https://doi.org/10.1103/PhysRevLett.92.186601	journal	May 2004
Silicon and germanium nanoparticle formation in an inductively coupled plasma reactor Gorla, C. R.; Liang, S.; Tompa, G. S. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 15, Issue 3 https://doi.org/10.1116/1.580721	journal	May 1997
Efficient Near-Infrared Polymer Nanocrystal Light-Emitting Diodes Tessler, N. Science, Vol. 295, Issue 5559 https://doi.org/10.1126/science.1068153	journal	February 2002
Colloidal Nanocrystals with Molecular Metal Chalcogenide Surface Ligands Kovalenko, M. V.; Scheele, M.; Talapin, D. V. Science, Vol. 324, Issue 5933 https://doi.org/10.1126/science.1170524	journal	June 2009
Peak External Photocurrent Quantum Efficiency Exceeding 100% via MEG in a Quantum Dot Solar Cell Semonin, O. E.; Luther, J. M.; Choi, S. Science, Vol. 334, Issue 6062 https://doi.org/10.1126/science.1209845	journal	December 2011
A tunable library of substituted thiourea precursors to metal sulfide nanocrystals Hendricks, M. P.; Campos, M. P.; Cleveland, G. T. Science, Vol. 348, Issue 6240 https://doi.org/10.1126/science.aaa2951	journal	June 2015
Direct observation of triplet energy transfer from semiconductor nanocrystals Mongin, C.; Garakyaraghi, S.; Razgoniaeva, N. Science, Vol. 351, Issue 6271 https://doi.org/10.1126/science.aad6378	journal	January 2016
Colloidal synthesis of nanocrystals and nanocrystal superlattices Murray, C. B.; Sun, Shouheng; Gaschler, W. IBM Journal of Research and Development, Vol. 45, Issue 1 https://doi.org/10.1147/rd.451.0047	journal	January 2001
Combined plasma gas-phase synthesis and colloidal processing of InP/ZnS core/shell nanocrystals Gresback, Ryan; Hue, Ryan; Gladfelter, Wayne L. Nanoscale Research Letters, Vol. 6, Issue 1 https://doi.org/10.1186/1556-276X-6-68	journal	January 2011
Facile synthesis of uniform large-sized InP nanocrystal quantum dots using tris(tert-butyldimethylsilyl)phosphine Joung, SoMyoung; Yoon, Sungwoo; Han, Chang-Soo Nanoscale Research Letters, Vol. 7, Issue 1 https://doi.org/10.1186/1556-276X-7-93	journal	January 2012
Carrier Multiplication in CdTe Quantum Dots by Single-photon Timing Spectroscopy Kobayashi, Yoichi; Udagawa, Takeshi; Tamai, Naoto Chemistry Letters, Vol. 38, Issue 8 https://doi.org/10.1246/cl.2009.830	journal	August 2009
Plasma synthesis of group IV quantum dots for luminescence and photovoltaic applications Kortshagen, Uwe; Anthony, Rebeccah; Gresback, Ryan Pure and Applied Chemistry, Vol. 80, Issue 9 https://doi.org/10.1351/pac200880091901	journal	January 2008

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