Large-scale polymeric carbon nanotube membranes with sub–1.27-nm pores

McGinnis, Robert L.; Reimund, Kevin; Ren, Jian; Xia, Lingling; Chowdhury, Maqsud R.; Sun, Xuanhao; Abril, Maritza; Moon, Joshua D.; Merrick, Melanie M.; Park, Jaesung; Stevens, Kevin A.; McCutcheon, Jeffrey R.; Freeman, Benny D.

doi:10.1126/sciadv.1700938

Title: Large-scale polymeric carbon nanotube membranes with sub–1.27-nm pores

Journal Article · 09 March 2018 · Science Advances

DOI: https://doi.org/10.1126/sciadv.1700938 · OSTI ID:1499950

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Mattershift, New York, NY (United States); OSTI
Mattershift, New York, NY (United States); Univ. of Connecticut, Storrs, CT (United States)
Univ. of Connecticut, Storrs, CT (United States)
Univ. of Texas, Austin, TX (United States)

We report the first characterization study of commercial prototype carbon nanotube (CNT) membranes consisting of sub–1.27-nm-diameter CNTs traversing a large-area nonporous polysulfone film. The membranes show rejection of NaCl and MgSO₄ at higher ionic strengths than have previously been reported in CNT membranes, and specific size selectivity for analytes with diameters below 1.24 nm. The CNTs used in the membranes were arc discharge nanotubes with inner diameters of 0.67 to 1.27 nm. Water flow through the membranes was 1000 times higher than predicted by Hagen-Poiseuille flow, in agreement with previous CNT membrane studies. Ideal gas selectivity was found to deviate significantly from that predicted by both viscous and Knudsen flow, suggesting that surface diffusion effects may begin to dominate gas selectivity at this size scale.

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF) (United States)

Grant/Contract Number:: FG02-02ER15362

OSTI ID:: 1499950

Journal Information:: Science Advances, Journal Name: Science Advances Journal Issue: 3 Vol. 4; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

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Tuning the permselectivity of polymeric desalination membranes via control of polymer crystallite size Lu, Xinglin; Feng, Xunda; Yang, Yi Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10132-0	journal	May 2019
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Effect of Confined Spaces in the Catalytic Activity of 1D and 2D Heterogeneous Carbon-Based Catalysts for Synthesis of 1,3,5-Triarylbenzenes: RGO-SO ₃ H vs. MWCNTs-SO ₃ H Golestanzadeh, Mohsen; Naeimi, Hossein ChemistrySelect, Vol. 4, Issue 6 https://doi.org/10.1002/slct.201803626	journal	February 2019
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