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Title: Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake

Abstract

Alkylamine modified MOF prepared with a less polar solvent (cyclohexane) has a higher alkylamine loading amount and higher CO 2 uptake than when prepared in a more polar solvent (dichloromethane).

Authors:
 [1];  [1]; ORCiD logo [2];  [3];  [4]; ORCiD logo [2]; ORCiD logo [3]
+ Show Author Affiliations
  1. Department of Chemistry, Texas A&M University, College Station, USA
  2. Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore
  3. Department of Chemistry, Texas A&M University, College Station, USA, Department of Materials Science and Engineering
  4. Profusa, Inc., South San Francisco, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Fossil Energy (FE)
OSTI Identifier:
1499827
Grant/Contract Number:  
FE0026472; SC0001015
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 7 Journal Issue: 13; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Li, Hao, Wang, Kecheng, Hu, Zhigang, Chen, Ying-Pin, Verdegaal, Wolfgang, Zhao, Dan, and Zhou, Hong-Cai. Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake. United Kingdom: N. p., 2019. Web. doi:10.1039/C8TA11300A.
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Li, Hao, Wang, Kecheng, Hu, Zhigang, Chen, Ying-Pin, Verdegaal, Wolfgang, Zhao, Dan, & Zhou, Hong-Cai. Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake. United Kingdom. doi:10.1039/C8TA11300A.
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Li, Hao, Wang, Kecheng, Hu, Zhigang, Chen, Ying-Pin, Verdegaal, Wolfgang, Zhao, Dan, and Zhou, Hong-Cai. Tue . "Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake". United Kingdom. doi:10.1039/C8TA11300A.
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@article{osti_1499827,
title = {Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake},
author = {Li, Hao and Wang, Kecheng and Hu, Zhigang and Chen, Ying-Pin and Verdegaal, Wolfgang and Zhao, Dan and Zhou, Hong-Cai},
abstractNote = {Alkylamine modified MOF prepared with a less polar solvent (cyclohexane) has a higher alkylamine loading amount and higher CO 2 uptake than when prepared in a more polar solvent (dichloromethane).},
doi = {10.1039/C8TA11300A},
journal = {Journal of Materials Chemistry. A},
number = 13,
volume = 7,
place = {United Kingdom},
year = {2019},
month = {3}
}
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Journal Article:
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Accepted Manuscript (Publisher)
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DOI: 10.1039/C8TA11300A
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Works referenced in this record:

Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers
journal, May 2018

Porous metal–organic-framework nanoscale carriers as a potential platform for drug delivery and imaging
journal, December 2009

  • Horcajada, Patricia; Chalati, Tamim; Serre, Christian
  • Nature Materials, Vol. 9, Issue 2
  • DOI: 10.1038/nmat2608

Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010

Metal−Organic Frameworks with Functional Pores for Recognition of Small Molecules
journal, August 2010

  • Chen, Banglin; Xiang, Shengchang; Qian, Guodong
  • Accounts of Chemical Research, Vol. 43, Issue 8
  • DOI: 10.1021/ar100023y

Synergistic Catalysis of Au@Ag Core−Shell Nanoparticles Stabilized on Metal−Organic Framework
journal, February 2011

  • Jiang, Hai-Long; Akita, Tomoki; Ishida, Tamao
  • Journal of the American Chemical Society, Vol. 133, Issue 5
  • DOI: 10.1021/ja1099006

Heterogeneity in homogeneous nucleation from billion-atom molecular dynamics simulation of solidification of pure metal
journal, April 2017

Incorporation of Alkylamine into Metal-Organic Frameworks through a Brønsted Acid-Base Reaction for CO 2 Capture
journal, September 2016

Selective Capture of Carbon Dioxide under Humid Conditions by Hydrophobic Chabazite-Type Zeolitic Imidazolate Frameworks
journal, July 2014

  • Nguyen, Nhung T. T.; Furukawa, Hiroyasu; Gándara, Felipe
  • Angewandte Chemie International Edition, Vol. 53, Issue 40
  • DOI: 10.1002/anie.201403980

Controlling guest conformation for efficient purification of butadiene
journal, June 2017

Putting an ultrahigh concentration of amine groups into a metal–organic framework for CO 2 capture at low pressures
journal, January 2016

  • Liao, Pei-Qin; Chen, Xun-Wei; Liu, Si-Yang
  • Chemical Science, Vol. 7, Issue 10
  • DOI: 10.1039/C6SC00836D

Highly controlled acetylene accommodation in a metal–organic microporous material
journal, July 2005

  • Matsuda, Ryotaro; Kitaura, Ryo; Kitagawa, Susumu
  • Nature, Vol. 436, Issue 7048
  • DOI: 10.1038/nature03852

A series of isoreticular chiral metal–organic frameworks as a tunable platform for asymmetric catalysis
journal, July 2010

  • Ma, Liqing; Falkowski, Joseph M.; Abney, Carter
  • Nature Chemistry, Vol. 2, Issue 10
  • DOI: 10.1038/nchem.738

Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels
journal, May 2013

Remarkable CO2/CH4 selectivity and CO2 adsorption capacity exhibited by polyamine-decorated metal–organic framework adsorbents
journal, January 2013

  • Yan, Qiuju; Lin, Yichao; Kong, Chunlong
  • Chemical Communications, Vol. 49, Issue 61
  • DOI: 10.1039/c3cc43352h

Nanoscale Metal–Organic Frameworks for Biomedical Imaging and Drug Delivery
journal, October 2011

  • Della Rocca, Joseph; Liu, Demin; Lin, Wenbin
  • Accounts of Chemical Research, Vol. 44, Issue 10, p. 957-968
  • DOI: 10.1021/ar200028a

Selective gas adsorption and separation in metal–organic frameworks
journal, January 2009

  • Li, Jian-Rong; Kuppler, Ryan J.; Zhou, Hong-Cai
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1477-1504
  • DOI: 10.1039/b802426j

Improving CO 2 Adsorption Capacity and CO 2 /CH 4 Selectivity with Amine Functionalization of MIL-100 and MIL-101
journal, March 2018

  • Babaei, Majideh; Salehi, Samira; Anbia, Mansoor
  • Journal of Chemical & Engineering Data, Vol. 63, Issue 5
  • DOI: 10.1021/acs.jced.8b00014

Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks
journal, August 2011

  • Li, Jian-Rong; Ma, Yuguang; McCarthy, M. Colin
  • Coordination Chemistry Reviews, Vol. 255, Issue 15-16
  • DOI: 10.1016/j.ccr.2011.02.012

Post-synthesis functionalization of MIL-101 using diethylenetriamine: a study on adsorption and catalysis
journal, January 2012

  • Kim, Se-Na; Yang, Seung-Tae; Kim, Jun
  • CrystEngComm, Vol. 14, Issue 12
  • DOI: 10.1039/c2ce06608d

The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion
journal, July 2017

  • Trickett, Christopher A.; Helal, Aasif; Al-Maythalony, Bassem A.
  • Nature Reviews Materials, Vol. 2, Issue 8
  • DOI: 10.1038/natrevmats.2017.45

Alkylamine-Tethered Stable Metal-Organic Framework for CO 2 Capture from Flue Gas
journal, January 2014

Direct Air Capture of CO 2 Using Amine Functionalized MIL-101(Cr)
journal, August 2016

  • Darunte, Lalit A.; Oetomo, Aloysius D.; Walton, Krista S.
  • ACS Sustainable Chemistry & Engineering, Vol. 4, Issue 10
  • DOI: 10.1021/acssuschemeng.6b01692

Conductive MOF electrodes for stable supercapacitors with high areal capacitance
journal, October 2016

  • Sheberla, Dennis; Bachman, John C.; Elias, Joseph S.
  • Nature Materials, Vol. 16, Issue 2
  • DOI: 10.1038/nmat4766

Microporous metal-organic framework with potential for carbon dioxide capture at ambient conditions
journal, January 2012

  • Xiang, Shengchang; He, Yabing; Zhang, Zhangjing
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms1956

Enhancement of CO2 adsorption on nanoporous chromium terephthalate (MIL-101) by amine modification
journal, May 2012

Metal–Organic Frameworks in Biomedicine
journal, September 2011

  • Horcajada, Patricia; Gref, Ruxandra; Baati, Tarek
  • Chemical Reviews, Vol. 112, Issue 2, p. 1232-1268
  • DOI: 10.1021/cr200256v

Postsynthetic Methods for the Functionalization of Metal–Organic Frameworks
journal, September 2011

  • Cohen, Seth M.
  • Chemical Reviews, Vol. 112, Issue 2, p. 970-1000
  • DOI: 10.1021/cr200179u

Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources
journal, September 2009

  • Choi, Sunho; Drese, Jeffrey H.; Jones, Christopher W.
  • ChemSusChem, Vol. 2, Issue 9, p. 796-854
  • DOI: 10.1002/cssc.200900036

Selectivity and direct visualization of carbon dioxide and sulfur dioxide in a decorated porous host
journal, September 2012

  • Yang, Sihai; Sun, Junliang; Ramirez-Cuesta, Anibal J.
  • Nature Chemistry, Vol. 4, Issue 11
  • DOI: 10.1038/nchem.1457

Ionized Zr-MOFs for highly efficient post-combustion CO 2 capture
journal, March 2015

Bottom-up construction of a superstructure in a porous uranium-organic crystal
journal, April 2017

  • Li, Peng; Vermeulen, Nicolaas A.; Malliakas, Christos D.
  • Science, Vol. 356, Issue 6338
  • DOI: 10.1126/science.aam7851

Carbon Dioxide Capture in Metal–Organic Frameworks
journal, September 2011

  • Sumida, Kenji; Rogow, David L.; Mason, Jarad A.
  • Chemical Reviews, Vol. 112, Issue 2, p. 724-781
  • DOI: 10.1021/cr2003272

Direct Observation and Quantification of CO 2 Binding Within an Amine-Functionalized Nanoporous Solid
journal, October 2010

  • Vaidhyanathan, Ramanathan; Iremonger, Simon S.; Shimizu, George K. H.
  • Science, Vol. 330, Issue 6004
  • DOI: 10.1126/science.1194237

A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
journal, September 2005

  • Ferey, G.; Mellot-Draznieks, C.; Serre, C.
  • Science, Vol. 309, Issue 5743, p. 2040-2042
  • DOI: 10.1126/science.1116275

De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities
journal, September 2010

  • Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim
  • Nature Chemistry, Vol. 2, Issue 11, p. 944-948
  • DOI: 10.1038/nchem.834

Metal-Organic Frameworks for Separation
journal, March 2018

  • Zhao, Xiang; Wang, Yanxiang; Li, Dong-Sheng
  • Advanced Materials, Vol. 30, Issue 37
  • DOI: 10.1002/adma.201705189

MOFs as proton conductors – challenges and opportunities
journal, January 2014

  • Ramaswamy, Padmini; Wong, Norman E.; Shimizu, George K. H.
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00093E

A Fine-Tuned Fluorinated MOF Addresses the Needs for Trace CO 2 Removal and Air Capture Using Physisorption
journal, July 2016

  • Bhatt, Prashant M.; Belmabkhout, Youssef; Cadiau, Amandine
  • Journal of the American Chemical Society, Vol. 138, Issue 29
  • DOI: 10.1021/jacs.6b05345

Controlling Cooperative CO 2 Adsorption in Diamine-Appended Mg 2 (dobpdc) Metal–Organic Frameworks
journal, July 2017

  • Siegelman, Rebecca L.; McDonald, Thomas M.; Gonzalez, Miguel I.
  • Journal of the American Chemical Society, Vol. 139, Issue 30
  • DOI: 10.1021/jacs.7b05858

Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water
journal, June 2014

  • Fracaroli, Alejandro M.; Furukawa, Hiroyasu; Suzuki, Mitsuharu
  • Journal of the American Chemical Society, Vol. 136, Issue 25, p. 8863-8866
  • DOI: 10.1021/ja503296c

Carbon dioxide capture and conversion by an acid-base resistant metal-organic framework
journal, November 2017

A highly stable metal-organic framework with optimum aperture size for CO 2 capture
journal, June 2017

  • Hu, Zhigang; Wang, Yuxiang; Farooq, Shamsuzzaman
  • AIChE Journal, Vol. 63, Issue 9
  • DOI: 10.1002/aic.15837

Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene
journal, May 2016

Controlled Gas Uptake in Metal–Organic Frameworks with Record Ammonia Sorption
journal, February 2018

  • Rieth, Adam J.; Dincă, Mircea
  • Journal of the American Chemical Society, Vol. 140, Issue 9
  • DOI: 10.1021/jacs.8b00313

Pore Space Partition by Symmetry-Matching Regulated Ligand Insertion and Dramatic Tuning on Carbon Dioxide Uptake
journal, January 2015

  • Zhao, Xiang; Bu, Xianhui; Zhai, Quan-Guo
  • Journal of the American Chemical Society, Vol. 137, Issue 4
  • DOI: 10.1021/ja512137t

Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
journal, March 2015

  • McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian
  • Nature, Vol. 519, Issue 7543
  • DOI: 10.1038/nature14327

Metal–metalloporphyrin frameworks: a resurging class of functional materials
journal, January 2014

  • Gao, Wen-Yang; Chrzanowski, Matthew; Ma, Shengqian
  • Chem. Soc. Rev., Vol. 43, Issue 16
  • DOI: 10.1039/C4CS00001C

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc)
journal, April 2012

  • McDonald, Thomas M.; Lee, Woo Ram; Mason, Jarad A.
  • Journal of the American Chemical Society, Vol. 134, Issue 16, p. 7056-7065
  • DOI: 10.1021/ja300034j

Amine-Functionalized Metal Organic Framework as a Highly Selective Adsorbent for CO 2 over CO
journal, September 2012

  • Wang, Xingrui; Li, Huiquan; Hou, Xin-Juan
  • The Journal of Physical Chemistry C, Vol. 116, Issue 37
  • DOI: 10.1021/jp3052938

Methane storage in flexible metal–organic frameworks with intrinsic thermal management
journal, October 2015

  • Mason, Jarad A.; Oktawiec, Julia; Taylor, Mercedes K.
  • Nature, Vol. 527, Issue 7578
  • DOI: 10.1038/nature15732

Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
journal, February 2013

  • Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.
  • Nature, Vol. 495, Issue 7439, p. 80-84
  • DOI: 10.1038/nature11893

Supramolecular binding and separation of hydrocarbons within a functionalized porous metal–organic framework
journal, December 2014

  • Yang, Sihai; Ramirez-Cuesta, Anibal J.; Newby, Ruth
  • Nature Chemistry, Vol. 7, Issue 2
  • DOI: 10.1038/nchem.2114

Functional Porous Coordination Polymers
journal, April 2004

  • Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro
  • Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375
  • DOI: 10.1002/anie.200300610

Systematic study of the chemical and hydrothermal stability of selected “stable” Metal Organic Frameworks
journal, May 2016

Porous materials with pre-designed single-molecule traps for CO2 selective adsorption
journal, February 2013

  • Li, Jian-Rong; Yu, Jiamei; Lu, Weigang
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms2552

Enhanced selective CO 2 adsorption on polyamine/MIL-101(Cr) composites
journal, January 2014

  • Lin, Yichao; Lin, Hao; Wang, Haimin
  • J. Mater. Chem. A, Vol. 2, Issue 35
  • DOI: 10.1039/C4TA01174K

Hypersensitive dual-function luminescence switching of a silver-chalcogenolate cluster-based metal–organic framework
journal, February 2017

  • Huang, Ren-Wu; Wei, Yong-Sheng; Dong, Xi-Yan
  • Nature Chemistry, Vol. 9, Issue 7
  • DOI: 10.1038/nchem.2718

Diamine-Functionalization of a Metal-Organic Framework Adsorbent for Superb Carbon Dioxide Adsorption and Desorption Properties
journal, April 2018

Catalytic chemoselective functionalization of methane in a metal−organic framework
journal, May 2018

Monodentate hydroxide as a super strong yet reversible active site for CO 2 capture from high-humidity flue gas
journal, January 2015

  • Liao, Pei-Qin; Chen, Huayao; Zhou, Dong-Dong
  • Energy & Environmental Science, Vol. 8, Issue 3
  • DOI: 10.1039/C4EE02717E

Metal–organic framework composites
journal, January 2014

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