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Title: Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake

Abstract

Alkylamine modified MOF prepared with a less polar solvent (cyclohexane) has a higher alkylamine loading amount and higher CO 2 uptake than when prepared in a more polar solvent (dichloromethane).

Authors:
 [1];  [1]; ORCiD logo [2];  [3];  [4]; ORCiD logo [2]; ORCiD logo [3]
  1. Department of Chemistry, Texas A&M University, College Station, USA
  2. Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore
  3. Department of Chemistry, Texas A&M University, College Station, USA, Department of Materials Science and Engineering
  4. Profusa, Inc., South San Francisco, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Fossil Energy (FE)
OSTI Identifier:
1499827
Grant/Contract Number:  
FE0026472; SC0001015
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry A Journal Volume: 7 Journal Issue: 13; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Li, Hao, Wang, Kecheng, Hu, Zhigang, Chen, Ying-Pin, Verdegaal, Wolfgang, Zhao, Dan, and Zhou, Hong-Cai. Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake. United Kingdom: N. p., 2019. Web. doi:10.1039/C8TA11300A.
Li, Hao, Wang, Kecheng, Hu, Zhigang, Chen, Ying-Pin, Verdegaal, Wolfgang, Zhao, Dan, & Zhou, Hong-Cai. Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake. United Kingdom. doi:10.1039/C8TA11300A.
Li, Hao, Wang, Kecheng, Hu, Zhigang, Chen, Ying-Pin, Verdegaal, Wolfgang, Zhao, Dan, and Zhou, Hong-Cai. Tue . "Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake". United Kingdom. doi:10.1039/C8TA11300A.
@article{osti_1499827,
title = {Harnessing solvent effects to integrate alkylamine into metal–organic frameworks for exceptionally high CO 2 uptake},
author = {Li, Hao and Wang, Kecheng and Hu, Zhigang and Chen, Ying-Pin and Verdegaal, Wolfgang and Zhao, Dan and Zhou, Hong-Cai},
abstractNote = {Alkylamine modified MOF prepared with a less polar solvent (cyclohexane) has a higher alkylamine loading amount and higher CO 2 uptake than when prepared in a more polar solvent (dichloromethane).},
doi = {10.1039/C8TA11300A},
journal = {Journal of Materials Chemistry A},
number = 13,
volume = 7,
place = {United Kingdom},
year = {2019},
month = {3}
}

Journal Article:
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This content will become publicly available on February 23, 2020
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