skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Sulfate promotion of selective catalytic reduction of nitric oxide by ammonia on ceria

Abstract

Selective catalytic reduction of nitric oxide by ammonia (NH 3 -SCR) is a promising technology for NO x emission control.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Dept. of Chemistry, Indiana University, Bloomington, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1499819
Grant/Contract Number:  
SC0016367
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Catalysis Science and Technology
Additional Journal Information:
Journal Name: Catalysis Science and Technology Journal Volume: 9 Journal Issue: 8; Journal ID: ISSN 2044-4753
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Chen, Linxiao, Agrawal, Vaibhav, and Tait, Steven L. Sulfate promotion of selective catalytic reduction of nitric oxide by ammonia on ceria. United Kingdom: N. p., 2019. Web. doi:10.1039/C8CY02590H.
Chen, Linxiao, Agrawal, Vaibhav, & Tait, Steven L. Sulfate promotion of selective catalytic reduction of nitric oxide by ammonia on ceria. United Kingdom. doi:10.1039/C8CY02590H.
Chen, Linxiao, Agrawal, Vaibhav, and Tait, Steven L. Mon . "Sulfate promotion of selective catalytic reduction of nitric oxide by ammonia on ceria". United Kingdom. doi:10.1039/C8CY02590H.
@article{osti_1499819,
title = {Sulfate promotion of selective catalytic reduction of nitric oxide by ammonia on ceria},
author = {Chen, Linxiao and Agrawal, Vaibhav and Tait, Steven L.},
abstractNote = {Selective catalytic reduction of nitric oxide by ammonia (NH 3 -SCR) is a promising technology for NO x emission control.},
doi = {10.1039/C8CY02590H},
journal = {Catalysis Science and Technology},
number = 8,
volume = 9,
place = {United Kingdom},
year = {2019},
month = {4}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8CY02590H

Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Influence of hexagonal boron nitride on the selective catalytic reduction of NO with NH 3 over CuO X /TiO 2
journal, January 2015

  • Zhou, Dongsheng; Ren, Zhiyuan; Li, Bo
  • RSC Advances, Vol. 5, Issue 40
  • DOI: 10.1039/C5RA01697E

The use of ceria for the selective catalytic reduction of NOx with NH3
journal, August 2014


In situ DRIFTS study of NO reduction by NH3 over Fe–Ce–Mn/ZSM-5 catalysts
journal, October 2011


Identification of adsorbed species on Cu-ZSM-5 under NH3 SCR conditions
journal, May 2007

  • Sjövall, Hanna; Fridell, Erik; Blint, Richard J.
  • Topics in Catalysis, Vol. 42-43, Issue 1-4
  • DOI: 10.1007/s11244-007-0162-6

NH 3 interaction with chromium-doped WO 3 nanocrystalline powders for gas sensing applications
journal, January 2004

  • Jiménez, I.; Centeno, M. A.; Scotti, R.
  • J. Mater. Chem., Vol. 14, Issue 15
  • DOI: 10.1039/B400872C

Acid pretreatment effect on the physicochemical property and catalytic performance of CeO 2 for NH 3 -SCR
journal, July 2017


Mechanistic Study of Selective Catalytic Reduction of NO x with NH 3 over Mn-TiO 2 : A Combination of Experimental and DFT Study
journal, August 2017

  • Zheng, Huiling; Song, Weiyu; Zhou, Yan
  • The Journal of Physical Chemistry C, Vol. 121, Issue 36
  • DOI: 10.1021/acs.jpcc.7b06715

SCR of NO by NH3 over TiO2-supported V2O5–MoO3 catalysts: reactivity and redox behavior
journal, August 1999


Synthesis of Fe-ZSM-5@Ce/mesoporous-silica and its enhanced activity by sequential reaction process for NH3-SCR
journal, April 2017


Kinetics of selective catalytic reduction of NO with NH3 on Fe-ZSM-5 catalyst
journal, August 2002


Enhancement of Catalytic Activity Over the Iron-Modified Ce/TiO 2 Catalyst for Selective Catalytic Reduction of NO x with Ammonia
journal, November 2012

  • Shu, Yun; Sun, Hong; Quan, Xie
  • The Journal of Physical Chemistry C, Vol. 116, Issue 48
  • DOI: 10.1021/jp307038q

De-reducibility mechanism of titanium on maghemite catalysts for the SCR reaction: An in situ DRIFTS and quantitative kinetics study
journal, February 2018


Low temperature selective catalytic reduction of NOx by ammonia over H-ZSM-5: an IR study
journal, June 2005

  • Sanchez-Escribano, Vicente; Montanari, Tania; Busca, Guido
  • Applied Catalysis B: Environmental, Vol. 58, Issue 1-2
  • DOI: 10.1016/j.apcatb.2004.11.015

Isolation of the Copper Redox Steps in the Standard Selective Catalytic Reduction on Cu-SSZ-13
journal, September 2014

  • Paolucci, Christopher; Verma, Anuj A.; Bates, Shane A.
  • Angewandte Chemie International Edition, Vol. 53, Issue 44
  • DOI: 10.1002/anie.201407030

Highly dispersed iron vanadate catalyst supported on TiO2 for the selective catalytic reduction of NOx with NH3
journal, November 2013


Eu-Mn-Ti mixed oxides for the SCR of NOx with NH3: The effects of Eu-modification on catalytic performance and mechanism
journal, December 2017


Active Oxygen on a Au/TiO2 Catalyst: Formation, Stability, and CO Oxidation Activity
journal, July 2011

  • Widmann, Daniel; Behm, R. Jürgen
  • Angewandte Chemie International Edition, Vol. 50, Issue 43
  • DOI: 10.1002/anie.201102062

On the mechanism of the SCR reaction on Fe/HBEA zeolite
journal, November 2009


Effect of promoters including WO3 and BaO on the activity and durability of V2O5/sulfated TiO2 catalyst for NO reduction by NH3
journal, August 2003


Deactivation of alumina supported and unsupported PdO methane oxidation catalyst: the effect of water on sulfate poisoning
journal, November 2001


Effect of promoters including tungsten and barium on the thermal stability of V2O5/sulfated TiO2 catalyst for NO reduction by NH3
journal, February 2006


On the Surface Acidity of Some Sulfate-Doped ZrO2 Catalysts
journal, August 1993


Novel manganese oxide confined interweaved titania nanotubes for the low-temperature Selective Catalytic Reduction (SCR) of NO x by NH 3
journal, February 2016


FT-IR characterization of the surface acidity of different titanium dioxide anatase preparations
journal, January 1985


Modifications of CeO2–ZrO2 solid solutions by nickel and sulfate as catalysts for NO reduction with ammonia in excess O2
journal, July 2010


Selective Catalytic Oxidation (SCO) of Ammonia to Nitrogen over Fe-Exchanged Zeolites
journal, July 2001


Nickel-doped Mn/TiO2 as an efficient catalyst for the low-temperature SCR of NO with NH3: Catalytic evaluation and characterizations
journal, April 2012


Promoting Effect of SO2 on Activated Carbon-Supported Vanadia Catalyst for NO Reduction by NH3 at Low Temperatures
journal, October 1999

  • Zhu, Zhenping; Liu, Zhenyu; Niu, Hongxian
  • Journal of Catalysis, Vol. 187, Issue 1
  • DOI: 10.1006/jcat.1999.2605

Characterization and Reactivity of V2O5–MoO3/TiO2 De-NOx SCR Catalysts
journal, October 1999

  • Lietti, Luca; Nova, Isabella; Ramis, Gianguido
  • Journal of Catalysis, Vol. 187, Issue 2
  • DOI: 10.1006/jcat.1999.2603

Mechanism of selective catalytic oxidation of ammonia to nitrogen over Ag/Al2O3
journal, November 2009


Chemical-Looping Steam Methane Reforming over a CeO 2 –Fe 2 O 3 Oxygen Carrier: Evolution of Its Structure and Reducibility
journal, February 2014

  • Zhu, Xing; Li, Kongzhai; Wei, Yonggang
  • Energy & Fuels, Vol. 28, Issue 2
  • DOI: 10.1021/ef402203a

Ce-Based Catalysts for the Selective Catalytic Reduction of NO x in the Presence of Excess Oxygen and Simulated Diesel Engine Exhaust Conditions
journal, May 2017

  • Boningari, Thirupathi; Somogyvari, Arpad; Smirniotis, Panagiotis G.
  • Industrial & Engineering Chemistry Research, Vol. 56, Issue 19
  • DOI: 10.1021/acs.iecr.7b00045

Low temperature NH 3 -SCR activity enhancement of antimony promoted vanadia-ceria catalyst
journal, September 2017


Multiple Roles of SO 2 in Selective Catalytic Reduction of NO by NH 3 over V 2 O 5 /AC Catalyst
journal, April 2014

  • Li, Pan; Liu, Zhenyu; Li, Qichao
  • Industrial & Engineering Chemistry Research, Vol. 53, Issue 19
  • DOI: 10.1021/ie4031488

Formation and Effect of NH 4 + Intermediates in NH 3 –SCR over Fe-ZSM-5 Zeolite Catalysts
journal, October 2016


Lewis and Brønsted acidity at the surface of sulfate-doped ZrO2 catalysts
journal, October 1993


Enhanced soot oxidation by lattice oxygen via La3+-doped CeO2
journal, February 2005


In Situ Characterization of Highly Dispersed, Ceria-Supported Fe Sites for NO Reduction by CO
journal, February 2015

  • Roberts, Charles A.; Prieto-Centurion, Dario; Nagai, Yasutaka
  • The Journal of Physical Chemistry C, Vol. 119, Issue 8
  • DOI: 10.1021/jp5126975

Activity enhancement of WO 3 modified Fe 2 O 3 catalyst for the selective catalytic reduction of NO x by NH 3
journal, September 2016


The effect of Ce–Zr on NH 3 -SCR activity over MnO x (0.6)/Ce 0.5 Zr 0.5 O 2 at low temperature
journal, January 2014


Adsorption and oxidation of NH3 over V2O5/AC surface
journal, November 2009


MnOx-CeO2 mixed oxides prepared by co-precipitation for selective catalytic reduction of NO with NH3 at low temperatures
journal, July 2004


Catalyst Design Based on DFT Calculations: Metal Oxide Catalysts for Gas Phase NO Reduction
journal, June 2014

  • Du, Xuesen; Gao, Xiang; Hu, Wenshuo
  • The Journal of Physical Chemistry C, Vol. 118, Issue 25
  • DOI: 10.1021/jp502040y

Shape dependence and sulfate promotion of CeO2 for selective catalytic reduction of NO with NH3
journal, September 2018


Deactivation of methanol synthesis catalysts - a review
journal, January 1992


Direct Decomposition of NO x over TiO 2 Supported Transition Metal Oxides at Low Temperatures
journal, November 2018

  • Damma, Devaiah; Boningari, Thirupathi; Ettireddy, Padmanabha R.
  • Industrial & Engineering Chemistry Research, Vol. 57, Issue 49
  • DOI: 10.1021/acs.iecr.8b03532

Acidity-activity correlation over bimetallic iron-based ZSM-5 catalysts during selective catalytic reduction of NO by NH3
journal, November 2016


Catalytic reduction of NO with H2 over redox-cycling Fe on CeO2
journal, June 2015

  • Prieto-Centurion, Dario; Eaton, Todd R.; Roberts, Charles A.
  • Applied Catalysis B: Environmental, Vol. 168-169
  • DOI: 10.1016/j.apcatb.2014.11.055

Metal oxide-confined interweaved titania nanotubes M/TNT (M = Mn, Cu, Ce, Fe, V, Cr, and Co) for the selective catalytic reduction of NOx in the presence of excess oxygen
journal, September 2018

  • Boningari, Thirupathi; Pappas, Dimitrios K.; Smirniotis, Panagiotis G.
  • Journal of Catalysis, Vol. 365
  • DOI: 10.1016/j.jcat.2018.07.010

The effect of metal oxide additives on the activity of V2O5/TiO2 catalysts for the selective catalytic reduction of nitric oxide by ammonia
journal, February 1999

  • Amiridis, Michael D.; Duevel, Robert V.; Wachs, Israel E.
  • Applied Catalysis B: Environmental, Vol. 20, Issue 2
  • DOI: 10.1016/S0926-3373(98)00101-5

Formation of carbonyl and nitrosyl complexes on titania- and zirconia-supported nickel: FTIR spectroscopy study
journal, December 2004

  • Mihaylov, Mihail; Chakarova, Kristina; Hadjiivanov, Konstantin
  • Journal of Catalysis, Vol. 228, Issue 2
  • DOI: 10.1016/j.jcat.2004.08.039

Transformation of Active Sites in Fe/SSZ-13 SCR Catalysts during Hydrothermal Aging: A Spectroscopic, Microscopic, and Kinetics Study
journal, March 2017


N 2 Selectivity of NO Reduction by NH 3 over MnO x –CeO 2 : Mechanism and Key Factors
journal, September 2014

  • Yang, Shijian; Liao, Yong; Xiong, Shangchao
  • The Journal of Physical Chemistry C, Vol. 118, Issue 37
  • DOI: 10.1021/jp5062489

Adsorption, Activation, and Oxidation of Ammonia over SCR Catalysts
journal, December 1995


Characterization and FTIR Studies of MnO x −CeO 2 Catalyst for Low-Temperature Selective Catalytic Reduction of NO with NH 3
journal, October 2004

  • Qi, Gongshin; Yang, Ralph T.
  • The Journal of Physical Chemistry B, Vol. 108, Issue 40
  • DOI: 10.1021/jp048431h

Development of stable and efficient CeVO4 systems for the selective reduction of NOx by ammonia: Structure-activity relationship
journal, December 2017


Selective catalytic reduction of NO with NH3 on iron zeolite monolithic catalysts: Steady-state and transient kinetics
journal, April 2011

  • Metkar, Pranit S.; Salazar, Nelson; Muncrief, Rachel
  • Applied Catalysis B: Environmental, Vol. 104, Issue 1-2
  • DOI: 10.1016/j.apcatb.2011.02.022

Mechanistic study of selective catalytic reduction of NO with NH 3 over highly dispersed Fe 2 O 3 loaded on Fe-ZSM-5
journal, January 2016

  • Li, Bo; Huang, Zhennan; Huang, Xiaodong
  • RSC Advances, Vol. 6, Issue 8
  • DOI: 10.1039/C5RA25736K

Novel promoting effect of SO2 on the selective catalytic reduction of NOx by ammonia over Co3O4 catalyst
journal, December 2007


The role of Brønsted acidity in the SCR of NO over Fe-MFI catalysts
journal, April 2008


Immobilization of catalytic virus-like particles in a flow reactor
journal, January 2017

  • Liu, A.; Yang, L.; Traulsen, C. H. -H.
  • Chemical Communications, Vol. 53, Issue 54
  • DOI: 10.1039/C7CC03024J

A superior Ce-W-Ti mixed oxide catalyst for the selective catalytic reduction of NOx with NH3
journal, April 2012


Superior Fe-ZSM-5 Catalyst for Selective Catalytic Reduction of Nitric Oxide by Ammonia
journal, June 1999

  • Long, Richard Q.; Yang, Ralph T.
  • Journal of the American Chemical Society, Vol. 121, Issue 23
  • DOI: 10.1021/ja9842262

The activity and characterization of CeO2-TiO2 catalysts prepared by the sol–gel method for selective catalytic reduction of NO with NH3
journal, February 2010


Effect of Nickel as Dopant in Mn/TiO2 Catalysts for the Low-Temperature Selective Reduction of NO with NH3
journal, August 2011


Wet oxidation of ammonia catalyzed by cerium-based composite oxides
journal, March 1985

  • Imamura, Seiichiro; Doi, Akira; Ishida, Shingo
  • Industrial & Engineering Chemistry Product Research and Development, Vol. 24, Issue 1
  • DOI: 10.1021/i300017a014

Investigation of the Facet-Dependent Catalytic Performance of Fe 2 O 3 /CeO 2 for the Selective Catalytic Reduction of NO with NH 3
journal, January 2016

  • Han, Jin; Meeprasert, Jittima; Maitarad, Phornphimon
  • The Journal of Physical Chemistry C, Vol. 120, Issue 3
  • DOI: 10.1021/acs.jpcc.5b09834

An XPS study of nitrogen-sulfur compounds
journal, February 1995

  • Littlejohn, David; Chang, Shih-Ger
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 71, Issue 1
  • DOI: 10.1016/0368-2048(94)02244-5

A re-examination of the catalyst activation and temperature hysteresis in methane combustion on Pt/Al2O3
journal, January 2018


The role of various iron species in Fe-β catalysts with low iron loadings for NH 3 -SCR
journal, January 2014

  • Liu, Haiyan; Wang, Jun; Yu, Tie
  • Catal. Sci. Technol., Vol. 4, Issue 5
  • DOI: 10.1039/C3CY01026K

Enhancement of SCR activity and SO 2 resistance on VO x /TiO 2 catalyst by addition of molybdenum
journal, January 2016


Vibrational study of ammonia adsorption on Pt/SiO2
journal, August 2004


In situ DRIFTS and temperature-programmed technology study on NH3-SCR of NO over Cu-SSZ-13 and Cu-SAPO-34 catalysts
journal, September 2014


DRIFT study on promotion effects of tungsten-modified Mn/Ce/Ti catalysts for the SCR reaction at low-temperature
journal, July 2017


Simultaneous NO x and Particulate Matter Removal from Diesel Exhaust by Hierarchical Fe-Doped Ce–Zr Oxide
journal, May 2017


In situ FTIR spectroscopy of highly dispersed FeOx catalysts for NO reduction: Role of Na promoter
journal, June 2016


Ultra-low loading of copper modified TiO2/CeO2 catalysts for low-temperature selective catalytic reduction of NO by NH3
journal, June 2017


Influence of elevated surface texture hydrated titania on Ce-doped Mn/TiO2 catalysts for the low-temperature SCR of NO under oxygen-rich conditions
journal, May 2015

  • Boningari, Thirupathi; Ettireddy, Padmanabha R.; Somogyvari, Arpad
  • Journal of Catalysis, Vol. 325
  • DOI: 10.1016/j.jcat.2015.03.002

Fe–Ce–ZSM-5 a new catalyst of outstanding properties in the selective catalytic reduction of NO with NH 3
journal, January 2004

  • Carja, G.; Delahay, G.; Signorile, C.
  • Chem. Commun., Issue 12
  • DOI: 10.1039/B402660H

The effect of zirconia additive on the activity and structure stability of V2O5/WO3-TiO2 ammonia SCR catalysts
journal, August 2011


Novel effect of SO2 on the SCR reaction over CeO2: Mechanism and significance
journal, June 2013


In situ DRIFTS-MS studies on the oxidation of adsorbed NH3 by NOx over a Cu-SSZ-13 zeolite
journal, April 2013


The Origin of an Unexpected Increase in NH 3 –SCR Activity of Aged Cu-LTA Catalysts
journal, September 2017


Titania Supported Bimetallic Transition Metal Oxides for Low-Temperature SCR of NO with NH 3
journal, September 2006

  • Sreekanth, Pavani M.; Peña, Donovan A.; Smirniotis, Panagiotis G.
  • Industrial & Engineering Chemistry Research, Vol. 45, Issue 19
  • DOI: 10.1021/ie060485l

FTIR in situ mechanistic study of the NH3NO/NO2 “Fast SCR” reaction over a commercial Fe-ZSM-5 catalyst
journal, April 2012


Superior ion-exchanged ZSM-5 catalysts for selective catalytic oxidation of ammonia to nitrogen
journal, January 2000

  • Long, Richard Q.; Yang, Ralph T.
  • Chemical Communications, Issue 17
  • DOI: 10.1039/b004957n

SO2 poisoning impact on the NH3-SCR reaction over a commercial Cu-SAPO-34 SCR catalyst
journal, September 2014


Deactivation of PdO–Al2O3 oxidation catalyst in lean-burn natural gas engine exhaust: aged catalyst characterization and studies of poisoning by H2O and SO2
journal, July 1999


MnO x −CeO 2 Binary Oxides for Catalytic NO x Sorption at Low Temperatures. Sorptive Removal of NO x
journal, October 2000

  • Machida, Masato; Uto, Masatoshi; Kurogi, Daisuke
  • Chemistry of Materials, Vol. 12, Issue 10
  • DOI: 10.1021/cm000207r

Impact of nitrogen oxides on the environment and human health: Mn-based materials for the NO x abatement
journal, August 2016


Transmission FT-IR and Knudsen Cell Study of the Heterogeneous Reactivity of Gaseous Nitrogen Dioxide on Mineral Oxide Particles
journal, August 1999

  • Underwood, G. M.; Miller, T. M.; Grassian, V. H.
  • The Journal of Physical Chemistry A, Vol. 103, Issue 31
  • DOI: 10.1021/jp991586i