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Title: A unique copper coordination structure with both mono- and bi-dentate ethylenediamine ligands

Abstract

A new crystal structure achieving penta-coordination using exclusively ethylenediamine ligands is discovered and characterized.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Materials Science and Engineering, Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1499059
Grant/Contract Number:  
SC0013897
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
CrystEngComm
Additional Journal Information:
Journal Name: CrystEngComm Journal Volume: 21 Journal Issue: 17; Journal ID: ISSN 1466-8033
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Sharma, Jai, Jiang, Zhelong, Bhutani, Ankita, Behera, Piush, and Shoemaker, Daniel P. A unique copper coordination structure with both mono- and bi-dentate ethylenediamine ligands. United Kingdom: N. p., 2019. Web. doi:10.1039/C8CE02188K.
Sharma, Jai, Jiang, Zhelong, Bhutani, Ankita, Behera, Piush, & Shoemaker, Daniel P. A unique copper coordination structure with both mono- and bi-dentate ethylenediamine ligands. United Kingdom. doi:10.1039/C8CE02188K.
Sharma, Jai, Jiang, Zhelong, Bhutani, Ankita, Behera, Piush, and Shoemaker, Daniel P. Thu . "A unique copper coordination structure with both mono- and bi-dentate ethylenediamine ligands". United Kingdom. doi:10.1039/C8CE02188K.
@article{osti_1499059,
title = {A unique copper coordination structure with both mono- and bi-dentate ethylenediamine ligands},
author = {Sharma, Jai and Jiang, Zhelong and Bhutani, Ankita and Behera, Piush and Shoemaker, Daniel P.},
abstractNote = {A new crystal structure achieving penta-coordination using exclusively ethylenediamine ligands is discovered and characterized.},
doi = {10.1039/C8CE02188K},
journal = {CrystEngComm},
number = 17,
volume = 21,
place = {United Kingdom},
year = {2019},
month = {4}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8CE02188K

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Works referenced in this record:

The crystal structure of bis(ethylenediamine)copper(II) fluoroborate
journal, May 1968

  • Brown, D. S.; Lee, J. D.; Melsom, B. G. A.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 24, Issue 5
  • DOI: 10.1107/S0567740868003092

Structure and Spectral Characterization of Coordination Polymers Constructed by CuCN and Aliphatic Diamines
journal, June 2015

  • Etaiw, Safaa-Eldin H.; Abdou, Safaa N.; Badr El-din, Ahmed S.
  • Journal of Inorganic and Organometallic Polymers and Materials, Vol. 25, Issue 6
  • DOI: 10.1007/s10904-015-0252-z

A redetermination of bis(ethylenediamine- N , N ')bis(perchlorato- O )copper(II)
journal, December 1999

  • Maxcy, K. R.; Turnbull, M. M.
  • Acta Crystallographica Section C Crystal Structure Communications, Vol. 55, Issue 12
  • DOI: 10.1107/S010827019901152X

The crystal structure of bis(ethylenediamine)copper(II) thiocyanate
journal, March 1964


Synthesis and Characterization of Magnetic Iron Sulfide Nanowires
journal, December 2003


Controlled Assembly of [Nb 6– x W x O 19 ] (8– x )– ( x = 0–4) Lindqvist Ions with (Amine)copper Complexes
journal, July 2008

  • Anderson, Travis M.; Rodriguez, Mark A.; Stewart, Thomas A.
  • European Journal of Inorganic Chemistry, Vol. 2008, Issue 21
  • DOI: 10.1002/ejic.200800415

Overcoming the chelate effect: hypodentate coordination of ethylenediamine, diethylenetriamine and tris(2-aminoethyl)amine in Co(III) complexes
journal, September 2000


A Novel Mild Route to Nanocrystalline Selenides at Room Temperature
journal, April 1999

  • Wang, Wenzhong; Geng, Yan; Yan, Ping
  • Journal of the American Chemical Society, Vol. 121, Issue 16
  • DOI: 10.1021/ja9832414

One-Step Processing and Bleaching of Mechanically Separated Kenaf Fibers: Effects on Physical and Chemical Properties
journal, April 2003


Temperature-dependent analysis of thermal motion, disorder and structures of tris(ethylenediamine)zinc(II) sulfate and tris(ethylenediamine)copper(II) sulfate
journal, January 2011

  • Smeets, Stef; Parois, Pascal; Bürgi, Hans-Beat
  • Acta Crystallographica Section B Structural Science, Vol. 67, Issue 1
  • DOI: 10.1107/S0108768110054571

Raman and Infrared Spectra of Complexes of Ethylenediamine with Zinc(II), Cadmium(II), and Mercury(II)
journal, May 1966


Thermal and Photo-Responsibility of Axial Semi-Coordination Bonds in a Copper(II) Complex
journal, April 2004

  • Akitsu, Takashiro; Einaga, Yasuaki
  • Bulletin of the Chemical Society of Japan, Vol. 77, Issue 4
  • DOI: 10.1246/bcsj.77.763

Transition metal pentacoordination
journal, February 1975

  • Rossi, Angelo R.; Hoffmann, Roald.
  • Inorganic Chemistry, Vol. 14, Issue 2
  • DOI: 10.1021/ic50144a032

Spectroscopy and Structures of Copper Complexes with Ethylenediamine and Methyl-Substituted Derivatives
journal, June 2006

  • Wang, Xu; Yang, Dong-Sheng
  • The Journal of Physical Chemistry A, Vol. 110, Issue 24
  • DOI: 10.1021/jp061325q

Recurrent H-bond graph motifs between metal tris-ethylenediamine cations and uncoordinated oxalate anions: Fitting a three pin plug into a two pin socket
journal, January 2012

  • Keene, Tony D.; Hursthouse, Michael B.; Price, Daniel J.
  • CrystEngComm, Vol. 14, Issue 1
  • DOI: 10.1039/C1CE05837A

Synthesis and modes of coordination of energetic nitramine ligands in copper(II), nickel(II), and palladium(II) complexes
journal, August 1988

  • Palopoli, S. F.; Geib, S. J.; Rheingold, A. L.
  • Inorganic Chemistry, Vol. 27, Issue 17
  • DOI: 10.1021/ic00290a015

OLEX2 : a complete structure solution, refinement and analysis program
journal, January 2009

  • Dolomanov, Oleg V.; Bourhis, Luc J.; Gildea, Richard J.
  • Journal of Applied Crystallography, Vol. 42, Issue 2
  • DOI: 10.1107/S0021889808042726

Diaquabis(ethylenediamine-κ 2 N , N ′)copper(II) bis(4-aminonaphthalene-1-sulfonate) dihydrate
journal, July 2005

  • Li, Ming-Tian; Wang, Cheng-Gang; Wu, Yu
  • Acta Crystallographica Section E Structure Reports Online, Vol. 61, Issue 8
  • DOI: 10.1107/S1600536805023627

The first-row transition-metal series of tris(ethylenediamine) diacetate complexes [ M (en) 3 ](OAc) 2 ( M is Mn, Fe, Co, Ni, Cu, and Zn)
journal, May 2017

  • Pham, Duyen N. K.; Roy, Mrittika; Golen, James A.
  • Acta Crystallographica Section C Structural Chemistry, Vol. 73, Issue 6
  • DOI: 10.1107/S2053229617006738

FTIR and Raman spectra and structure of Cu(NO3)+ in aqueous solution and acetone
journal, January 1991

  • Castro, Paul M.; Jagodzinski, Paul W.
  • Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 47, Issue 12
  • DOI: 10.1016/0584-8539(91)80008-7

SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8
  • DOI: 10.1107/S2053273314026370

The crystal structure of the mixed valence copper cyanide ethylenediamine complex: aquobis(en)copper(II) di-[catena-di-μ-cyanocuprate(I)], Cu3(en)2(CN)4.H2O
journal, March 1972

  • Williams, R. J.; Larson, A. C.; Cromer, D. T.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 28, Issue 3
  • DOI: 10.1107/S0567740872003310

The first X-ray crystal structures of cobalt complexes containing monodentate and bridging ethylenediamine ligands
journal, May 1999


The electronic properties and stereochemistry of the copper(II) ion. Part I. Bis(ethylenediamine)copper(II) complexes
journal, January 1968

  • Procter, I. M.; Hathaway, B. J.; Nicholls, P.
  • Journal of the Chemical Society A: Inorganic, Physical, Theoretical
  • DOI: 10.1039/j19680001678

The crystal structure of bisethylenediaminecopper(II) nitrate
journal, September 1964


Effect of Theophylline on Exercise-Induced Myocardial Ischaemia
journal, April 1989


Accessing magnetic chalcogenides with solvothermal synthesis: KFeS2 and KFe2S3
journal, April 2018


Binuclear chloropentaaminecobalt(III) complexes
journal, May 1973


Rate of aquation of trans-difluorobis(ethylenediamine)chromium(III) through an isolable monodentate ethylenediamine complex
journal, November 1971

  • Pyke, Stephen C.; Linck, R. G.
  • Inorganic Chemistry, Vol. 10, Issue 11
  • DOI: 10.1021/ic50105a017

Cobalt(III) Complexes Containing Large Chelate Rings. I. Syntheses and Properties of Bis(ethylenediamine)-1,ω-diaminoalkanecobalt(III) Complexes
journal, June 1975

  • Ogino, Hiroshi; Fujita, Junnosuke
  • Bulletin of the Chemical Society of Japan, Vol. 48, Issue 6
  • DOI: 10.1246/bcsj.48.1836

Monodentate ethylenediamine complex of cobalt(III)
journal, October 1970

  • Alexander, Martin Dale; Spillert, Charles A.
  • Inorganic Chemistry, Vol. 9, Issue 10
  • DOI: 10.1021/ic50092a028

Crystal structure refinement with SHELXL
journal, January 2015

  • Sheldrick, George M.
  • Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8
  • DOI: 10.1107/S2053229614024218

COPPER (II) COORDINATION COMPOUNDS: CLASSIFICATION AND ANALYSIS OF CRYSTALLOGRAPHIC AND STRUCTURAL DATA: I. Mononuclear Tetra — and Pentacoordinate Compounds
journal, February 1997

  • Melník, Milan; Kabešová, Mária; Dunaj-Jurčo, Michal
  • Journal of Coordination Chemistry, Vol. 41, Issue 1-2
  • DOI: 10.1080/00958979708027956

Spectroscopic characterization and thermal stability of copper(II) ethylenediamine complexes on solid surfaces. 2. Montmorillonite
journal, June 1977

  • Velghe, Firmin; Schoonheydt, Robert A.; Uytterhoeven, Jan B.
  • The Journal of Physical Chemistry, Vol. 81, Issue 12
  • DOI: 10.1021/j100527a013

The electronic properties and stereochemistry of the copper(II) ion. Part III. Some penta-ammine complexes
journal, January 1968

  • Tomlinson, A. A. G.; Hathaway, B. J.
  • Journal of the Chemical Society A: Inorganic, Physical, Theoretical
  • DOI: 10.1039/j19680001905

Electron Paramagnetic Resonance Study of Copper–Ethylenediamine Complex Ion Intercalated in Bentonite
journal, October 2013

  • Donoso, José Pedro; Magon, Claudio J.; Lima, José F.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 45
  • DOI: 10.1021/jp408658d

Nanocrystalline Ag from Supramolecular Stabilization of Metals in 4-tert-Butylcalix[4]arene Lattices
journal, October 2006

  • Brown, Philip O.; Enright, Gary D.; Ripmeester, John A.
  • Chemistry – An Asian Journal, Vol. 1, Issue 4
  • DOI: 10.1002/asia.200600101

Chelates in agriculture
journal, January 1990

  • Clemens, D. F.; Whitehurst, B. M.; Whitehurst, G. B.
  • Fertilizer Research, Vol. 25, Issue 2
  • DOI: 10.1007/BF01095092

Chronic Toxicity and Carcinogenicity Studies of Ethylenediamine Dihydrochloride by Dietary Incorporation in Fischer 344 Rats
journal, July 1999


Studies on Absorption Spectra. I. Results of Calculations on the Spectra and Configuration of Copper(II) Ions.
journal, January 1954


Crystal structure and electronic properties of ammine[tris(2-aminoethyl)amine]copper(II) diperchlorate and potassium penta-amminecopper(II) tris(hexafluorophosphate)
journal, January 1980

  • Duggan, Mary; Ray, Noel; Hathaway, Brian
  • Journal of the Chemical Society, Dalton Transactions, Issue 8
  • DOI: 10.1039/dt9800001342