skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Entropy‐Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO 2 Fixation

Authors:
 [1];  [2]; ORCiD logo [3];  [2];  [4]; ORCiD logo [3]
  1. Research Center of Applied Solid State ChemistryChemistry Institute for Synthesis and Green ApplicationNingbo University Ningbo Zhejiang 315211 P. R. China, Department of ChemistryUniversity of Tennessee Knoxville TN 37996 USA
  2. Department of ChemistryUniversity of Tennessee Knoxville TN 37996 USA
  3. Department of ChemistryUniversity of Tennessee Knoxville TN 37996 USA, Chemical Sciences DivisionOak Ridge National Laboratory Oak Ridge, TN 37831 USA
  4. Research Center of Applied Solid State ChemistryChemistry Institute for Synthesis and Green ApplicationNingbo University Ningbo Zhejiang 315211 P. R. China
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1498181
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 131 Journal Issue: 15; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Xu, Wei, Chen, Hao, Jie, Kecheng, Yang, Zhenzhen, Li, Tingting, and Dai, Sheng. Entropy‐Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO 2 Fixation. Germany: N. p., 2019. Web. doi:10.1002/ange.201900787.
Xu, Wei, Chen, Hao, Jie, Kecheng, Yang, Zhenzhen, Li, Tingting, & Dai, Sheng. Entropy‐Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO 2 Fixation. Germany. doi:https://doi.org/10.1002/ange.201900787
Xu, Wei, Chen, Hao, Jie, Kecheng, Yang, Zhenzhen, Li, Tingting, and Dai, Sheng. Wed . "Entropy‐Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO 2 Fixation". Germany. doi:https://doi.org/10.1002/ange.201900787.
@article{osti_1498181,
title = {Entropy‐Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO 2 Fixation},
author = {Xu, Wei and Chen, Hao and Jie, Kecheng and Yang, Zhenzhen and Li, Tingting and Dai, Sheng},
abstractNote = {},
doi = {10.1002/ange.201900787},
journal = {Angewandte Chemie},
number = 15,
volume = 131,
place = {Germany},
year = {2019},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: https://doi.org/10.1002/ange.201900787

Save / Share:

Works referenced in this record:

Cu 2+ -doped zeolitic imidazolate frameworks (ZIF-8): efficient and stable catalysts for cycloadditions and condensation reactions
journal, January 2015

  • Schejn, Aleksandra; Aboulaich, Abdelhay; Balan, Lavinia
  • Catalysis Science & Technology, Vol. 5, Issue 3
  • DOI: 10.1039/C4CY01505C

Entropy-stabilized oxides
journal, September 2015

  • Rost, Christina M.; Sachet, Edward; Borman, Trent
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9485

Facile synthesis of Cd-substituted zeolitic-imidazolate framework Cd-ZIF-8 and mixed-metal CdZn-ZIF-8
journal, July 2018


Ligand-Directed Strategy for Zeolite-Type Metal–Organic Frameworks: Zinc(II) Imidazolates with Unusual Zeolitic Topologies
journal, February 2006

  • Huang, Xiao-Chun; Lin, Yan-Yong; Zhang, Jie-Peng
  • Angewandte Chemie International Edition, Vol. 45, Issue 10, p. 1557-1559
  • DOI: 10.1002/anie.200503778

Mechanochemical-Assisted Synthesis of High-Entropy Metal Nitride via a Soft Urea Strategy
journal, April 2018

  • Jin, Tian; Sang, Xiahan; Unocic, Raymond R.
  • Advanced Materials, Vol. 30, Issue 23
  • DOI: 10.1002/adma.201707512

Kovalente postsynthetische Funktionalisierung einer ZIF-90-MOF-Membran zur Erhöhung ihrer Wasserstoffselektivität
journal, March 2011


Enthalpy vs. friction: heat flow modelling of unexpected temperature profiles in mechanochemistry of metal–organic frameworks
journal, January 2018

  • Užarević, Krunoslav; Ferdelji, Nenad; Mrla, Tomislav
  • Chemical Science, Vol. 9, Issue 9
  • DOI: 10.1039/C7SC05312F

Carbothermal shock synthesis of high-entropy-alloy nanoparticles
journal, March 2018


Synthesis of magnesium ZIF-8 from Mg(BH 4 ) 2
journal, January 2015

  • Horike, S.; Kadota, K.; Itakura, T.
  • Dalton Transactions, Vol. 44, Issue 34
  • DOI: 10.1039/C5DT01183C

Mechanochemical Synthesis of Chemically Stable Isoreticular Covalent Organic Frameworks
journal, March 2013

  • Biswal, Bishnu P.; Chandra, Suman; Kandambeth, Sharath
  • Journal of the American Chemical Society, Vol. 135, Issue 14
  • DOI: 10.1021/ja4017842

Zeolitic imidazole framework-67 as an efficient heterogeneous catalyst for the conversion of CO 2 to cyclic carbonates
journal, January 2016

  • Mousavi, Bibimaryam; Chaemchuen, Somboon; Moosavi, Behrooz
  • New Journal of Chemistry, Vol. 40, Issue 6
  • DOI: 10.1039/C6NJ00128A

High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture
journal, February 2008


Synthesis of Manganese ZIF-8 from [Mn(BH 4 ) 2 ·3THF]·NaBH 4
journal, July 2017


Entropy-stabilized metal oxide solid solutions as CO oxidation catalysts with high-temperature stability
journal, January 2018

  • Chen, Hao; Fu, Jie; Zhang, Pengfei
  • Journal of Materials Chemistry A, Vol. 6, Issue 24
  • DOI: 10.1039/C8TA01772G

Structural Descriptors of Zeolitic–Imidazolate Frameworks Are Keys to the Activity of Fe–N–C Catalysts
journal, December 2016

  • Armel, Vanessa; Hindocha, Sheena; Salles, Fabrice
  • Journal of the American Chemical Society, Vol. 139, Issue 1
  • DOI: 10.1021/jacs.6b11248

Advancing polymers of intrinsic microporosity by mechanochemistry
journal, January 2015

  • Zhang, Pengfei; Jiang, Xueguang; Wan, Shun
  • Journal of Materials Chemistry A, Vol. 3, Issue 13
  • DOI: 10.1039/C4TA07196D

Solid-State Synthesis of Conjugated Nanoporous Polycarbazoles
journal, September 2017


Ligand-Directed Strategy for Zeolite-Type Metal–Organic Frameworks: Zinc(II) Imidazolates with Unusual Zeolitic Topologies
journal, February 2006

  • Huang, Xiao-Chun; Lin, Yan-Yong; Zhang, Jie-Peng
  • Angewandte Chemie, Vol. 118, Issue 10, p. 1587-1589
  • DOI: 10.1002/ange.200503778

Local structure of the Mg x Ni x Co x Cu x Zn x O( x =0.2) entropy-stabilized oxide: An EXAFS study
journal, April 2017

  • Rost, Christina M.; Rak, Zsolt; Brenner, Donald W.
  • Journal of the American Ceramic Society, Vol. 100, Issue 6
  • DOI: 10.1111/jace.14756

Towards medicinal mechanochemistry: evolution of milling from pharmaceutical solid form screening to the synthesis of active pharmaceutical ingredients (APIs)
journal, January 2016

  • Tan, Davin; Loots, Leigh; Friščić, Tomislav
  • Chemical Communications, Vol. 52, Issue 50
  • DOI: 10.1039/C6CC02015A

Zeolitic Imidazole Framework-8 Catalysts in the Conversion of CO 2 to Chloropropene Carbonate
journal, December 2011

  • Miralda, Carmen M.; Macias, Eugenia E.; Zhu, Minqi
  • ACS Catalysis, Vol. 2, Issue 1
  • DOI: 10.1021/cs200638h

Ion- and Liquid-Assisted Grinding: Improved Mechanochemical Synthesis of Metal-Organic Frameworks Reveals Salt Inclusion and Anion Templating
journal, December 2009

  • Friščić, Tomislav; Reid, David G.; Halasz, Ivan
  • Angewandte Chemie, Vol. 122, Issue 4
  • DOI: 10.1002/ange.200906583

Rapid Room-Temperature Synthesis of Zeolitic Imidazolate Frameworks by Using Mechanochemistry
journal, November 2010

  • Beldon, Patrick J.; Fábián, László; Stein, Robin S.
  • Angewandte Chemie International Edition, Vol. 49, Issue 50
  • DOI: 10.1002/anie.201005547

Microwave-Assisted, Ni-Induced Fabrication of Hollow ZIF-8 Nanoframes for the Knoevenagel Reaction
journal, April 2018


Covalent Post-Functionalization of Zeolitic Imidazolate Framework ZIF-90 Membrane for Enhanced Hydrogen Selectivity
journal, March 2011

  • Huang, Aisheng; Caro, Jürgen
  • Angewandte Chemie International Edition, Vol. 50, Issue 21
  • DOI: 10.1002/anie.201007861

Ion- and Liquid-Assisted Grinding: Improved Mechanochemical Synthesis of Metal-Organic Frameworks Reveals Salt Inclusion and Anion Templating
journal, December 2009

  • Friščić, Tomislav; Reid, David G.; Halasz, Ivan
  • Angewandte Chemie International Edition, Vol. 49, Issue 4
  • DOI: 10.1002/anie.200906583

Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006

  • Park, K. S.; Ni, Z.; Cote, A. P.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191
  • DOI: 10.1073/pnas.0602439103

Doping copper into ZIF-67 for enhancing gas uptake capacity and visible-light-driven photocatalytic degradation of organic dye
journal, January 2012

  • Yang, Hui; He, Xin-Wei; Wang, Fei
  • Journal of Materials Chemistry, Vol. 22, Issue 41
  • DOI: 10.1039/c2jm35602c

Nanoscale origins of the damage tolerance of the high-entropy alloy CrMnFeCoNi
journal, December 2015

  • Zhang, ZiJiao; Mao, M. M.; Wang, Jiangwei
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms10143

Metal–Organic Framework-Based Catalysts: Chemical Fixation of CO2 with Epoxides Leading to Cyclic Organic Carbonates
journal, January 2015

  • Beyzavi, M. Hassan; Stephenson, Casey J.; Liu, Yangyang
  • Frontiers in Energy Research, Vol. 2
  • DOI: 10.3389/fenrg.2014.00063

Mechanochemistry:  The Mechanical Activation of Covalent Bonds
journal, August 2005

  • Beyer, Martin K.; Clausen-Schaumann, Hauke
  • Chemical Reviews, Vol. 105, Issue 8
  • DOI: 10.1021/cr030697h

A Triazole-Containing Metal–Organic Framework as a Highly Effective and Substrate Size-Dependent Catalyst for CO 2 Conversion
journal, February 2016

  • Li, Pei-Zhou; Wang, Xiao-Jun; Liu, Jia
  • Journal of the American Chemical Society, Vol. 138, Issue 7
  • DOI: 10.1021/jacs.5b13335

High-Entropy Metal Diborides: A New Class of High-Entropy Materials and a New Type of Ultrahigh Temperature Ceramics
journal, November 2016

  • Gild, Joshua; Zhang, Yuanyao; Harrington, Tyler
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep37946

Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks
journal, January 2010

  • Phan, Anh; Doonan, Christian J.; Uribe-Romo, Fernando J.
  • Accounts of Chemical Research, Vol. 43, Issue 1, p. 58-67
  • DOI: 10.1021/ar900116g

Mechanochemical Synthesis of Metal−Organic Frameworks: A Fast and Facile Approach toward Quantitative Yields and High Specific Surface Areas
journal, September 2010

  • Klimakow, Maria; Klobes, Peter; Thünemann, Andreas F.
  • Chemistry of Materials, Vol. 22, Issue 18
  • DOI: 10.1021/cm1012119

In situ X-ray diffraction monitoring of a mechanochemical reaction reveals a unique topology metal-organic framework
journal, March 2015

  • Katsenis, Athanassios D.; Puškarić, Andreas; Štrukil, Vjekoslav
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7662

Rapid Room-Temperature Synthesis of Zeolitic Imidazolate Frameworks by Using Mechanochemistry
journal, November 2010

  • Beldon, Patrick J.; Fábián, László; Stein, Robin S.
  • Angewandte Chemie, Vol. 122, Issue 50
  • DOI: 10.1002/ange.201005547

Real-time and in situ monitoring of mechanochemical milling reactions
journal, December 2012

  • Friščić, Tomislav; Halasz, Ivan; Beldon, Patrick J.
  • Nature Chemistry, Vol. 5, Issue 1
  • DOI: 10.1038/nchem.1505