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Title: Tuning self-healing properties of stiff, ion-conductive polymers

Abstract

Stiff polymers with tunable self-healing and mechanical properties show promising potential in electrochemical devices.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1];  [2];  [3]; ORCiD logo [2];  [4]; ORCiD logo [3]; ORCiD logo [5]
  1. Molecular Engineering & Science Institute, University of Washington, Seattle, USA
  2. Department of Chemistry, University of Washington, Seattle, USA
  3. Department of Materials Science and Engineering, University of Washington, Seattle, USA
  4. Department of Chemistry, University of Washington, Seattle, USA, Department of Materials Science and Engineering
  5. Molecular Engineering & Science Institute, University of Washington, Seattle, USA, Department of Chemistry
Publication Date:
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1497747
Grant/Contract Number:  
EE0007791
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 7 Journal Issue: 12; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Qin, Jiaxu, Lin, Francis, Hubble, Dion, Wang, Yujia, Li, Yun, Murphy, Ian A., Jang, Sei-Hum, Yang, Jihui, and Jen, Alex K. -Y. Tuning self-healing properties of stiff, ion-conductive polymers. United Kingdom: N. p., 2019. Web. doi:10.1039/C8TA11353J.
Qin, Jiaxu, Lin, Francis, Hubble, Dion, Wang, Yujia, Li, Yun, Murphy, Ian A., Jang, Sei-Hum, Yang, Jihui, & Jen, Alex K. -Y. Tuning self-healing properties of stiff, ion-conductive polymers. United Kingdom. doi:10.1039/C8TA11353J.
Qin, Jiaxu, Lin, Francis, Hubble, Dion, Wang, Yujia, Li, Yun, Murphy, Ian A., Jang, Sei-Hum, Yang, Jihui, and Jen, Alex K. -Y. Tue . "Tuning self-healing properties of stiff, ion-conductive polymers". United Kingdom. doi:10.1039/C8TA11353J.
@article{osti_1497747,
title = {Tuning self-healing properties of stiff, ion-conductive polymers},
author = {Qin, Jiaxu and Lin, Francis and Hubble, Dion and Wang, Yujia and Li, Yun and Murphy, Ian A. and Jang, Sei-Hum and Yang, Jihui and Jen, Alex K. -Y.},
abstractNote = {Stiff polymers with tunable self-healing and mechanical properties show promising potential in electrochemical devices.},
doi = {10.1039/C8TA11353J},
journal = {Journal of Materials Chemistry. A},
number = 12,
volume = 7,
place = {United Kingdom},
year = {2019},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8TA11353J

Citation Metrics:
Cited by: 1 work
Citation information provided by
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Works referenced in this record:

Material and Structural Design of Novel Binder Systems for High-Energy, High-Power Lithium-Ion Batteries
journal, October 2017


A highly stretchable autonomous self-healing elastomer
journal, April 2016

  • Li, Cheng-Hui; Wang, Chao; Keplinger, Christoph
  • Nature Chemistry, Vol. 8, Issue 6
  • DOI: 10.1038/nchem.2492

A flexible, self-healing and highly stretchable polymer electrolyte via quadruple hydrogen bonding for lithium-ion batteries
journal, January 2018

  • Zhou, Binghua; He, Dan; Hu, Ji
  • Journal of Materials Chemistry A, Vol. 6, Issue 25
  • DOI: 10.1039/C8TA01907J

Mechanically Robust and Self-Healable Superlattice Nanocomposites by Self-Assembly of Single-Component “Sticky” Polymer-Grafted Nanoparticles
journal, May 2015

  • Williams, Gregory A.; Ishige, Ryohei; Cromwell, Olivia R.
  • Advanced Materials, Vol. 27, Issue 26
  • DOI: 10.1002/adma.201500927

Multiphase design of autonomic self-healing thermoplastic elastomers
journal, April 2012

  • Chen, Yulin; Kushner, Aaron M.; Williams, Gregory A.
  • Nature Chemistry, Vol. 4, Issue 6
  • DOI: 10.1038/nchem.1314

Breathable and Stretchable Temperature Sensors Inspired by Skin
journal, June 2015

  • Chen, Ying; Lu, Bingwei; Chen, Yihao
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep11505

A Critical Review of Thermal Issues in Lithium-Ion Batteries
journal, January 2011

  • Bandhauer, Todd M.; Garimella, Srinivas; Fuller, Thomas F.
  • Journal of The Electrochemical Society, Vol. 158, Issue 3, p. R1-R25
  • DOI: 10.1149/1.3515880

Self-Healing Graphene Oxide Based Functional Architectures Triggered by Moisture
journal, September 2017

  • Cheng, Huhu; Huang, Yaxin; Cheng, Qilong
  • Advanced Functional Materials, Vol. 27, Issue 42
  • DOI: 10.1002/adfm.201703096

Stretching Dielectric Elastomer Performance
journal, December 2010


Pursuing prosthetic electronic skin
journal, July 2016

  • Chortos, Alex; Liu, Jia; Bao, Zhenan
  • Nature Materials, Vol. 15, Issue 9
  • DOI: 10.1038/nmat4671

Theoretical analysis of the intermolecular interactions in naphthalene diimide and pyrene complexes
journal, January 2014

  • Yeh, Mei-Yu; Lin, Hsin-Chieh
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 44
  • DOI: 10.1039/C4CP03879G

Freestanding silicon microparticle and self-healing polymer composite design for effective lithiation stress relaxation
journal, January 2018

  • Kim, Donghyuk; Hyun, Seungmin; Han, Seung Min
  • Journal of Materials Chemistry A, Vol. 6, Issue 24
  • DOI: 10.1039/C7TA11269F

Malleable and Self-Healing Covalent Polymer Networks through Tunable Dynamic Boronic Ester Bonds
journal, May 2015

  • Cromwell, Olivia R.; Chung, Jaeyoon; Guan, Zhibin
  • Journal of the American Chemical Society, Vol. 137, Issue 20
  • DOI: 10.1021/jacs.5b03551

DYNAMERS: dynamic polymers as self-healing materials
journal, January 2015

  • Roy, Nabarun; Bruchmann, Bernd; Lehn, Jean-Marie
  • Chemical Society Reviews, Vol. 44, Issue 11
  • DOI: 10.1039/C5CS00194C

Ultra-thin Solid-State Li-Ion Electrolyte Membrane Facilitated by a Self-Healing Polymer Matrix
journal, September 2015

  • Whiteley, Justin M.; Taynton, Philip; Zhang, Wei
  • Advanced Materials, Vol. 27, Issue 43
  • DOI: 10.1002/adma.201502636

Highly sensitive flexible pressure sensors with microstructured rubber dielectric layers
journal, September 2010

  • Mannsfeld, Stefan C. B.; Tee, Benjamin C-K.; Stoltenberg, Randall M.
  • Nature Materials, Vol. 9, Issue 10, p. 859-864
  • DOI: 10.1038/nmat2834

Effect of Temperature on the Aging rate of Li Ion Battery Operating above Room Temperature
journal, August 2015

  • Leng, Feng; Tan, Cher Ming; Pecht, Michael
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep12967

Rethinking the term “pi-stacking”
journal, January 2012

  • Martinez, Chelsea R.; Iverson, Brent L.
  • Chemical Science, Vol. 3, Issue 7
  • DOI: 10.1039/c2sc20045g

Stable cycling of double-walled silicon nanotube battery anodes through solid–electrolyte interphase control
journal, March 2012

  • Wu, Hui; Chan, Gerentt; Choi, Jang Wook
  • Nature Nanotechnology, Vol. 7, Issue 5
  • DOI: 10.1038/nnano.2012.35

Redox-responsive self-healing materials formed from host–guest polymers
journal, September 2011

  • Nakahata, Masaki; Takashima, Yoshinori; Yamaguchi, Hiroyasu
  • Nature Communications, Vol. 2, Issue 1
  • DOI: 10.1038/ncomms1521

Enhanced rate capability and cycle stability of lithium–sulfur batteries with a bifunctional MCNT@PEG-modified separator
journal, January 2015

  • Wang, Guanchao; Lai, Yanqing; Zhang, Zhian
  • Journal of Materials Chemistry A, Vol. 3, Issue 13
  • DOI: 10.1039/C4TA07133F

Model Transient Networks from Strongly Hydrogen-Bonded Polymers
journal, November 2009

  • Feldman, Kathleen E.; Kade, Matthew J.; Meijer, E. W.
  • Macromolecules, Vol. 42, Issue 22
  • DOI: 10.1021/ma901668w

Color-tunable luminescent hydrogels with tough mechanical strength and self-healing ability
journal, January 2018

  • Yang, Daqing; Wang, Yige; Li, Zhiqiang
  • Journal of Materials Chemistry C, Vol. 6, Issue 5
  • DOI: 10.1039/C7TC05593E

Self-healing chemistry enables the stable operation of silicon microparticle anodes for high-energy lithium-ion batteries
journal, November 2013

  • Wang, Chao; Wu, Hui; Chen, Zheng
  • Nature Chemistry, Vol. 5, Issue 12
  • DOI: 10.1038/nchem.1802

Intrinsically stretchable and healable semiconducting polymer for organic transistors
journal, November 2016

  • Oh, Jin Young; Rondeau-Gagné, Simon; Chiu, Yu-Cheng
  • Nature, Vol. 539, Issue 7629
  • DOI: 10.1038/nature20102

Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries
journal, July 2017


Novel Biocompatible Polysaccharide-Based Self-Healing Hydrogel
journal, January 2015

  • Wei, Zhao; Yang, Jian Hai; Liu, Zhen Qi
  • Advanced Functional Materials, Vol. 25, Issue 9
  • DOI: 10.1002/adfm.201401502

Control of hierarchical polymer mechanics with bioinspired metal-coordination dynamics
journal, August 2015

  • Grindy, Scott C.; Learsch, Robert; Mozhdehi, Davoud
  • Nature Materials, Vol. 14, Issue 12
  • DOI: 10.1038/nmat4401

Stretchable Self-Healing Polymeric Dielectrics Cross-Linked Through Metal–Ligand Coordination
journal, April 2016

  • Rao, Ying-Li; Chortos, Alex; Pfattner, Raphael
  • Journal of the American Chemical Society, Vol. 138, Issue 18
  • DOI: 10.1021/jacs.6b02428

Enhancing ionic conductivity in composite polymer electrolytes with well-aligned ceramic nanowires
journal, April 2017


Toward an Ideal Polymer Binder Design for High-Capacity Battery Anodes
journal, July 2013

  • Wu, Mingyan; Xiao, Xingcheng; Vukmirovic, Nenad
  • Journal of the American Chemical Society, Vol. 135, Issue 32
  • DOI: 10.1021/ja4054465

Sulphur–TiO2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries
journal, January 2013

  • Wei Seh, Zhi; Li, Weiyang; Cha, Judy J.
  • Nature Communications, Vol. 4, Article No. 1331
  • DOI: 10.1038/ncomms2327

An electrically and mechanically self-healing composite with pressure- and flexion-sensitive properties for electronic skin applications
journal, November 2012

  • Tee, Benjamin C-K.; Wang, Chao; Allen, Ranulfo
  • Nature Nanotechnology, Vol. 7, Issue 12
  • DOI: 10.1038/nnano.2012.192

Self-Healing Supramolecular Block Copolymers
journal, September 2012

  • Hentschel, Jens; Kushner, Aaron M.; Ziller, Joseph
  • Angewandte Chemie International Edition, Vol. 51, Issue 42
  • DOI: 10.1002/anie.201204840

Enhancing Mechanical Performance of a Covalent Self-Healing Material by Sacrificial Noncovalent Bonds
journal, April 2015

  • Neal, James A.; Mozhdehi, Davoud; Guan, Zhibin
  • Journal of the American Chemical Society, Vol. 137, Issue 14
  • DOI: 10.1021/jacs.5b01601

The rise of plastic bioelectronics
journal, December 2016

  • Someya, Takao; Bao, Zhenan; Malliaras, George G.
  • Nature, Vol. 540, Issue 7633
  • DOI: 10.1038/nature21004

Functional Naphthalene Diimides: Synthesis, Properties, and Applications
journal, August 2016


Self-Healing Shape Memory PUPCL Copolymer with High Cycle Life
journal, December 2017

  • Ur Rehman, Hafeez; Chen, Yujie; Hedenqvist, Mikael S.
  • Advanced Functional Materials, Vol. 28, Issue 7
  • DOI: 10.1002/adfm.201704109

Self-healing and thermoreversible rubber from supramolecular assembly
journal, February 2008

  • Cordier, Philippe; Tournilhac, François; Soulié-Ziakovic, Corinne
  • Nature, Vol. 451, Issue 7181, p. 977-980
  • DOI: 10.1038/nature06669

Self-Healing Hydrogels
journal, August 2016

  • Taylor, Danielle Lynne; in het Panhuis, Marc
  • Advanced Materials, Vol. 28, Issue 41
  • DOI: 10.1002/adma.201601613

A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries
journal, September 2011


Surface-initiated self-healing of polymers in aqueous media
journal, July 2014

  • Ahn, B. Kollbe; Lee, Dong Woog; Israelachvili, Jacob N.
  • Nature Materials, Vol. 13, Issue 9
  • DOI: 10.1038/nmat4037

Binding Studies between Tetrathiafulvalene Derivatives and Cyclobis(paraquat- p -phenylene)
journal, May 2001

  • Nielsen, Mogens Brøndsted; Jeppesen, Jan Oskar; Lau, Jesper
  • The Journal of Organic Chemistry, Vol. 66, Issue 10
  • DOI: 10.1021/jo010173m

Tattoo-Based Noninvasive Glucose Monitoring: A Proof-of-Concept Study
journal, December 2014

  • Bandodkar, Amay J.; Jia, Wenzhao; Yardımcı, Ceren
  • Analytical Chemistry, Vol. 87, Issue 1
  • DOI: 10.1021/ac504300n

Design, synthesis and computational modelling of aromatic tweezer-molecules as models for chain-folding polymer blends
journal, September 2008


A Transparent, Self-Healing, Highly Stretchable Ionic Conductor
journal, December 2016

  • Cao, Yue; Morrissey, Timothy G.; Acome, Eric
  • Advanced Materials, Vol. 29, Issue 10
  • DOI: 10.1002/adma.201605099

High-Strength, Healable, Supramolecular Polymer Nanocomposites
journal, March 2012

  • Fox, Justin; Wie, Jeong J.; Greenland, Barnaby W.
  • Journal of the American Chemical Society, Vol. 134, Issue 11
  • DOI: 10.1021/ja300050x

Adhesion and Surface Interactions of a Self-Healing Polymer with Multiple Hydrogen-Bonding Groups
journal, January 2014

  • Faghihnejad, Ali; Feldman, Kathleen E.; Yu, Jing
  • Advanced Functional Materials, Vol. 24, Issue 16
  • DOI: 10.1002/adfm.201303013

Self-Healing Multiphase Polymers via Dynamic Metal–Ligand Interactions
journal, November 2014

  • Mozhdehi, Davoud; Ayala, Sergio; Cromwell, Olivia R.
  • Journal of the American Chemical Society, Vol. 136, Issue 46
  • DOI: 10.1021/ja5097094

Hierarchically Structured Self-Healing Sensors with Tunable Positive/Negative Piezoresistivity
journal, February 2018

  • Liu, Xuehui; Su, Gehong; Guo, Quanquan
  • Advanced Functional Materials, Vol. 28, Issue 15
  • DOI: 10.1002/adfm.201706658