Effect of aqueous hydrochloric acid and zwitterionic betaine on the mutual solubility between a protic betainium-based ionic liquid and water

Volia, Merinda F.; Tereshatov, Evgeny E.; Mazan, Valérie; Folden, Charles M.; Boltoeva, Maria

doi:10.1016/j.molliq.2018.11.136

Title: Effect of aqueous hydrochloric acid and zwitterionic betaine on the mutual solubility between a protic betainium-based ionic liquid and water

Journal Article · 28 November 2018 · Journal of Molecular Liquids

DOI: https://doi.org/10.1016/j.molliq.2018.11.136 · OSTI ID:1496879

Volia, Merinda F. ^[1]; Tereshatov, Evgeny E. ^[2]; Mazan, Valérie ^[3]; Folden, Charles M. ^[4]; Boltoeva, Maria ^[3]

Texas A & M Univ., College Station, TX (United States). Cyclotron Inst.; Texas A & M Univ., College Station, TX (United States). Dept. of Nuclear Engineering; NSSC
Texas A & M Univ., College Station, TX (United States). Cyclotron Inst.
Univ. de Strasbourg, Strasbourg (France)
Texas A & M Univ., College Station, TX (United States). Cyclotron Inst., Dept. of Chemistry

The solubility of hydrophobic betainium bis(trifluoromethylsulfonyl)imide ionic liquid in an aqueous phase with controlled acidity has been investigated by a standard liquid–liquid extraction technique. The effect of zwitterionic betaine added into the aqueous phase has also been studied. Quantitative NMR was employed to characterize the distribution behavior of the ionic liquid constituents between the two phases. A mathematical model to describe the ionic liquid solubility in the aqueous phase was developed. Here, this approach was utilized to estimate the conditional solubility product constant of the ionic liquid. The possibility of the transfer of some dissociation products back into the organic phase was investigated.

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Research Organization:: Univ. of California, Berkeley, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE National Nuclear Security Administration (NNSA), Office of Defense Nuclear Nonproliferation (NA-20); USDOE Office of Science (SC), Nuclear Physics (NP)

Contributing Organization:: Nuclear Science and Security Consortium

Grant/Contract Number:: NA0003180

OSTI ID:: 1496879

Journal Information:: Journal of Molecular Liquids, Journal Name: Journal of Molecular Liquids Journal Issue: C Vol. 276; ISSN 0167-7322

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited By (2)

Hydrophobic polymerized ionic liquids for trace metal solid phase extraction: thallium transfer from hydrochloric acid media Tereshatov, Evgeny E.; Boltoeva, Maria; Mazan, Valérie New Journal of Chemistry, Vol. 43, Issue 23 https://doi.org/10.1039/c9nj00689c	journal	January 2019
Indium and thallium extraction into betainium bis(trifluoromethylsulfonyl)imide ionic liquid from aqueous hydrochloric acid media Volia, M. F.; Tereshatov, E. E.; Boltoeva, M. New Journal of Chemistry, Vol. 44, Issue 6 https://doi.org/10.1039/c9nj04879k	journal	January 2020

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Betainium bis(trifluoromethylsulfonyl)imide
Hydrochloric acid
Ionic liquid
Mutual solubility
Zwitterionic betaine

Title: Effect of aqueous hydrochloric acid and zwitterionic betaine on the mutual solubility between a protic betainium-based ionic liquid and water

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