A chlorinated polymer promoted analogue co-donors for efficient ternary all-polymer solar cells

Chen, Hui; Guo, Yikun; Chao, Pengjie; Liu, Longzhu; Chen, Wei; Zhao, Dahui; He, Feng

doi:10.1007/s11426-018-9371-0

Title: A chlorinated polymer promoted analogue co-donors for efficient ternary all-polymer solar cells

Journal Article · 09 November 2018 · Science China Chemistry

DOI: https://doi.org/10.1007/s11426-018-9371-0 · OSTI ID:1496595

Chen, Hui ^[1]; Guo, Yikun ^[2]; Chao, Pengjie ^[1]; Liu, Longzhu ^[1]; Chen, Wei ^[3]; Zhao, Dahui ^[2]; He, Feng ^[1]

Southern Univ. of Science and Technology, Shenzhen (China)
Peking Univ., Beijing (China)
Argonne National Lab. (ANL), Lemont, IL (United States); The Univ. of Chicago, Chicago, IL (United States)

The efficient ternary all-polymer solar cells (PSCs) are designed and fabricated, using a polymer acceptor of NDP-V-C₇ and analogue co-donors containing a chlorinated polymer PBClT and classical PTB₇-Th. PBClT and PTB₇-Th possess very similar chemical structure and matched energy levels to form the cascade of the co-donors. Meanwhile, benefiting from those analogous polymer structures, there is little influence of the morphology in blend film compared to their pristine polymer films. The binary PBClT:NDP-V-C₇ devices exhibit a high open-circuit voltage (Voc) due to the deep HOMO level of PBClT. The V_oc of all-PSCs could be finely manipulated by adjusting the content of PBClT in blend film. The ternary all-PSCs have the more balanced charge mobility and prolonged carrier lifetime compared to the binary devices. The PBClT also help improve the miscibility of ternary blend and suppress crystallization in films, bringing about favorable morphology with appropriate orientation and surface roughness in blend film. With the optimal processing, the champion ternary all-PSCs obtain a high PCE of 9.03%, which is about 10% enhancement compared to that of binary device. Finally, the results indicate that the ternary approach using analogue co-donors is a practical method to enhance the performance of all-PSCs.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: South University of Science and Technology of China (SUSTC); National Natural Science Foundation of China (NSFC); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1496595

Journal Information:: Science China Chemistry, Vol. 62, Issue 2; ISSN 1674-7291

Publisher:: Science China Press and SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 29 works

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References (48)

Impact of the photo-induced degradation of electron acceptors on the photophysics, charge transport and device performance of all-polymer and fullerene–polymer solar cells Kim, Taesu; Younts, Robert; Lee, Wonho J. Mater. Chem. A, Vol. 5, Issue 42 https://doi.org/10.1039/C7TA07535A	journal	January 2017
Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells Liu, Yuhang; Zhao, Jingbo; Li, Zhengke Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6293	journal	November 2014
A Chlorinated π-Conjugated Polymer Donor for Efficient Organic Solar Cells Chen, Hui; Hu, Zhiming; Wang, Huan Joule, Vol. 2, Issue 8 https://doi.org/10.1016/j.joule.2018.05.010	journal	August 2018
Effects of Solvent Additives on Morphology, Charge Generation, Transport, and Recombination in Solution-Processed Small-Molecule Solar Cells Kyaw, Aung Ko Ko; Wang, Dong Hwan; Luo, Chan Advanced Energy Materials, Vol. 4, Issue 7 https://doi.org/10.1002/aenm.201301469	journal	January 2014
Energy-Level Modulation of Small-Molecule Electron Acceptors to Achieve over 12% Efficiency in Polymer Solar Cells Li, Sunsun; Ye, Long; Zhao, Wenchao Advanced Materials, Vol. 28, Issue 42 https://doi.org/10.1002/adma.201602776	journal	September 2016
Design and Synthesis of Chlorinated Benzothiadiazole-Based Polymers for Efficient Solar Energy Conversion Hu, Zhiming; Chen, Hui; Qu, Jianfei ACS Energy Letters, Vol. 2, Issue 4 https://doi.org/10.1021/acsenergylett.7b00092	journal	March 2017
Ternary blend polymer solar cells with enhanced power conversion efficiency Lu, Luyao; Xu, Tao; Chen, Wei Nature Photonics, Vol. 8, Issue 9 https://doi.org/10.1038/nphoton.2014.172	journal	August 2014
Ternary organic solar cells offer 14% power conversion efficiency Xiao, Zuo; Jia, Xue; Ding, Liming Science Bulletin, Vol. 62, Issue 23 https://doi.org/10.1016/j.scib.2017.11.003	journal	December 2017
High Performance All-Polymer Solar Cells by Synergistic Effects of Fine-Tuned Crystallinity and Solvent Annealing Li, Zhaojun; Xu, Xiaofeng; Zhang, Wei Journal of the American Chemical Society, Vol. 138, Issue 34 https://doi.org/10.1021/jacs.6b04822	journal	August 2016
Designing ternary blend all-polymer solar cells with an efficiency of over 10% and a fill factor of 78% Li, Zhenye; Ying, Lei; Xie, Ruihao Nano Energy, Vol. 51 https://doi.org/10.1016/j.nanoen.2018.06.081	journal	September 2018
Over 14% Efficiency in Polymer Solar Cells Enabled by a Chlorinated Polymer Donor Zhang, Shaoqing; Qin, Yunpeng; Zhu, Jie Advanced Materials, Vol. 30, Issue 20 https://doi.org/10.1002/adma.201800868	journal	March 2018
Molecular Design of Photovoltaic Materials for Polymer Solar Cells: Toward Suitable Electronic Energy Levels and Broad Absorption Li, Yongfang Accounts of Chemical Research, Vol. 45, Issue 5 https://doi.org/10.1021/ar2002446	journal	January 2012
Flexible, highly efficient all-polymer solar cells Kim, Taesu; Kim, Jae-Han; Kang, Tae Eui Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9547	journal	October 2015
Experimental determination of the rate law for charge carrier decay in a polythiophene: Fullerene solar cell Shuttle, C. G.; O’Regan, B.; Ballantyne, A. M. Applied Physics Letters, Vol. 92, Issue 9 https://doi.org/10.1063/1.2891871	journal	March 2008
All-Polymer Solar Cells Based on Absorption-Complementary Polymer Donor and Acceptor with High Power Conversion Efficiency of 8.27% Gao, Liang; Zhang, Zhi-Guo; Xue, Lingwei Advanced Materials, Vol. 28, Issue 9 https://doi.org/10.1002/adma.201504629	journal	December 2015
Fast charge separation in a non-fullerene organic solar cell with a small driving force Liu, Jing; Chen, Shangshang; Qian, Deping Nature Energy, Vol. 1, Issue 7 https://doi.org/10.1038/nenergy.2016.89	journal	June 2016
Ternary Organic Solar Cells Based on Two Compatible Nonfullerene Acceptors with Power Conversion Efficiency >10% Liu, Tao; Guo, Yuan; Yi, Yuanping Advanced Materials, Vol. 28, Issue 45 https://doi.org/10.1002/adma.201602570	journal	September 2016
Current methodologies for a sustainable approach to π-conjugated organic semiconductors Marrocchi, Assunta; Facchetti, Antonio; Lanari, Daniela Energy & Environmental Science, Vol. 9, Issue 3 https://doi.org/10.1039/C5EE03727A	journal	January 2016
Molecular Optimization Enables over 13% Efficiency in Organic Solar Cells Zhao, Wenchao; Li, Sunsun; Yao, Huifeng Journal of the American Chemical Society, Vol. 139, Issue 21 https://doi.org/10.1021/jacs.7b02677	journal	May 2017
Single-junction polymer solar cells with high efficiency and photovoltage He, Zhicai; Xiao, Biao; Liu, Feng Nature Photonics, Vol. 9, Issue 3 https://doi.org/10.1038/nphoton.2015.6	journal	February 2015
A Synergetic Effect of Molecular Weight and Fluorine in All-Polymer Solar Cells with Enhanced Performance Chen, Shanshan; An, Yujin; Dutta, Gitish K. Advanced Functional Materials, Vol. 27, Issue 2 https://doi.org/10.1002/adfm.201603564	journal	October 2016
Improved Performance of All-Polymer Solar Cells Enabled by Naphthodiperylenetetraimide-Based Polymer Acceptor Guo, Yikun; Li, Yunke; Awartani, Omar Advanced Materials, Vol. 29, Issue 26 https://doi.org/10.1002/adma.201700309	journal	May 2017
Ternary blend all-polymer solar cells: enhanced performance and evidence of parallel-like bulk heterojunction mechanism Hwang, Ye-Jin; Courtright, Brett A. E.; Jenekhe, Samson A. MRS Communications, Vol. 5, Issue 2 https://doi.org/10.1557/mrc.2015.36	journal	June 2015
Organic solar cells based on non-fullerene acceptors Hou, Jianhui; Inganäs, Olle; Friend, Richard H. Nature Materials, Vol. 17, Issue 2 https://doi.org/10.1038/nmat5063	journal	January 2018
A molecular nematic liquid crystalline material for high-performance organic photovoltaics Sun, Kuan; Xiao, Zeyun; Lu, Shirong Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7013	journal	January 2015
Oligomer Molecules for Efficient Organic Photovoltaics Lin, Yuze; Zhan, Xiaowei Accounts of Chemical Research, Vol. 49, Issue 2 https://doi.org/10.1021/acs.accounts.5b00363	journal	November 2015
A chlorinated low-bandgap small-molecule acceptor for organic solar cells with 14.1% efficiency and low energy loss Kan, Bin; Feng, Huanran; Yao, Huifeng Science China Chemistry, Vol. 61, Issue 10 https://doi.org/10.1007/s11426-018-9334-9	journal	July 2018
Optimized “Alloy-Parallel” Morphology of Ternary Organic Solar Cells Wang, Zaiyu; Zhang, Yajie; Zhang, Jianqi Advanced Energy Materials, Vol. 6, Issue 9 https://doi.org/10.1002/aenm.201502456	journal	February 2016
Theory of space-charge-limited current enhanced by Frenkel effect Murgatroyd, P. N. Journal of Physics D: Applied Physics, Vol. 3, Issue 2 https://doi.org/10.1088/0022-3727/3/2/308	journal	February 1970
High fabrication yield organic tandem photovoltaics combining vacuum- and solution-processed subcells with 15% efficiency Che, Xiaozhou; Li, Yongxi; Qu, Yue Nature Energy, Vol. 3, Issue 5 https://doi.org/10.1038/s41560-018-0134-z	journal	April 2018
Comparative Study of the Mechanical Properties of All-Polymer and Fullerene–Polymer Solar Cells: The Importance of Polymer Acceptors for High Fracture Resistance Kim, Wansun; Choi, Joonhyeong; Kim, Jae-Han Chemistry of Materials, Vol. 30, Issue 6 https://doi.org/10.1021/acs.chemmater.8b00172	journal	March 2018
7.7% Efficient All-Polymer Solar Cells Hwang, Ye-Jin; Courtright, Brett A. E.; Ferreira, Amy S. Advanced Materials, Vol. 27, Issue 31 https://doi.org/10.1002/adma.201501604	journal	July 2015
n-Type Semiconducting Naphthalene Diimide-Perylene Diimide Copolymers: Controlling Crystallinity, Blend Morphology, and Compatibility Toward High-Performance All-Polymer Solar Cells Hwang, Ye-Jin; Earmme, Taeshik; Courtright, Brett A. E. Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/ja513260w	journal	March 2015
A Wide Band Gap Polymer with a Deep Highest Occupied Molecular Orbital Level Enables 14.2% Efficiency in Polymer Solar Cells Li, Sunsun; Ye, Long; Zhao, Wenchao Journal of the American Chemical Society, Vol. 140, Issue 23 https://doi.org/10.1021/jacs.8b02695	journal	May 2018
Designing ternary blend bulk heterojunction solar cells with reduced carrier recombination and a fill factor of 77% Gasparini, Nicola; Jiao, Xuechen; Heumueller, Thomas Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.118	journal	August 2016
Small-molecule solar cells with efficiency over 9% Zhang, Qian; Kan, Bin; Liu, Feng Nature Photonics, Vol. 9, Issue 1 https://doi.org/10.1038/nphoton.2014.269	journal	November 2014
All-Polymer Solar Cells Based on a Conjugated Polymer Containing Siloxane-Functionalized Side Chains with Efficiency over 10% Fan, Baobing; Ying, Lei; Zhu, Peng Advanced Materials, Vol. 29, Issue 47 https://doi.org/10.1002/adma.201703906	journal	November 2017
Improved air stability of perovskite solar cells via solution-processed metal oxide transport layers You, Jingbi; Meng, Lei; Song, Tze-Bin Nature Nanotechnology, Vol. 11, Issue 1 https://doi.org/10.1038/nnano.2015.230	journal	October 2015
Efficient organic solar cells processed from hydrocarbon solvents Zhao, Jingbo; Li, Yunke; Yang, Guofang Nature Energy, Vol. 1, Issue 2 https://doi.org/10.1038/nenergy.2015.27	journal	January 2016
Chlorination of Side Chains: A Strategy for Achieving a High Open Circuit Voltage Over 1.0 V in Benzo[1,2-b:4,5-b′]dithiophene-Based Non-Fullerene Solar Cells Chao, Pengjie; Mu, Zhao; Wang, Huan ACS Applied Energy Materials, Vol. 1, Issue 5 https://doi.org/10.1021/acsaem.8b00506	journal	April 2018
A Series of Simple Oligomer-like Small Molecules Based on Oligothiophenes for Solution-Processed Solar Cells with High Efficiency Kan, Bin; Li, Miaomiao; Zhang, Qian Journal of the American Chemical Society, Vol. 137, Issue 11 https://doi.org/10.1021/jacs.5b00305	journal	March 2015
Synergistic effect of fluorination on both donor and acceptor materials for high performance non-fullerene polymer solar cells with 13.5% efficiency Fan, Qunping; Su, Wenyan; Wang, Yan Science China Chemistry, Vol. 61, Issue 5 https://doi.org/10.1007/s11426-017-9199-1	journal	January 2018
All-Polymer Solar Cells with 9.4% Efficiency from Naphthalene Diimide-Biselenophene Copolymer Acceptor Kolhe, Nagesh B.; Lee, Hyunjong; Kuzuhara, Daiki Chemistry of Materials, Vol. 30, Issue 18 https://doi.org/10.1021/acs.chemmater.8b03229	journal	August 2018
Polymer solar cells with enhanced fill factors Guo, Xugang; Zhou, Nanjia; Lou, Sylvia J. Nature Photonics, Vol. 7, Issue 10 https://doi.org/10.1038/nphoton.2013.207	journal	August 2013
Transient photoconductivity in polymer bulk heterojunction solar cells: Competition between sweep-out and recombination Cowan, Sarah R.; Street, R. A.; Cho, Shinuk Physical Review B, Vol. 83, Issue 3 https://doi.org/10.1103/PhysRevB.83.035205	journal	January 2011
Over 14% Efficiency in Organic Solar Cells Enabled by Chlorinated Nonfullerene Small-Molecule Acceptors Zhang, Hao; Yao, Huifeng; Hou, Junxian Advanced Materials, Vol. 30, Issue 28 https://doi.org/10.1002/adma.201800613	journal	May 2018
9.0% power conversion efficiency from ternary all-polymer solar cells Li, Zhaojun; Xu, Xiaofeng; Zhang, Wei Energy & Environmental Science, Vol. 10, Issue 10 https://doi.org/10.1039/C7EE01858D	journal	January 2017
Comparative Study of Thermal Stability, Morphology, and Performance of All-Polymer, Fullerene–Polymer, and Ternary Blend Solar Cells Based on the Same Polymer Donor Kim, Taesu; Choi, Joonhyeong; Kim, Hyeong Jun Macromolecules, Vol. 50, Issue 17 https://doi.org/10.1021/acs.macromol.7b00834	journal	August 2017

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Achieving Efficient Thick Film All-polymer Solar Cells Using a Green Solvent Additive Li, Zhen-Ye; Zhong, Wen-Kai; Ying, Lei Chinese Journal of Polymer Science, Vol. 38, Issue 4 https://doi.org/10.1007/s10118-020-2356-3	journal	November 2019

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
all-polymer solar cells
analogue co-donors
carriers transport
chlorination
ternary blend

Title: A chlorinated polymer promoted analogue co-donors for efficient ternary all-polymer solar cells

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