Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol

Bianchi, Federico; Kurtén, Theo; Riva, Matthieu; Mohr, Claudia; Rissanen, Matti P.; Roldin, Pontus; Berndt, Torsten; Crounse, John D.; Wennberg, Paul O.; Mentel, Thomas F.; Wildt, Jürgen; Junninen, Heikki; Jokinen, Tuija; Kulmala, Markku; Worsnop, Douglas R.; Thornton, Joel A.; Donahue, Neil; Kjaergaard, Henrik G.; Ehn, Mikael

doi:10.1021/acs.chemrev.8b00395

Title: Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol

Journal Article · 25 February 2019 · Chemical Reviews

DOI: https://doi.org/10.1021/acs.chemrev.8b00395 · OSTI ID:1496495

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^[2]; Riva, Matthieu ^[3]; Mohr, Claudia ^[4];

^[2]; Roldin, Pontus ^[5];

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^[7]; Mentel, Thomas F. ^[8]; Wildt, Jürgen ^[8]; Junninen, Heikki ^[9]; Jokinen, Tuija ^[2]; Kulmala, Markku ^[1]; Worsnop, Douglas R. ^[10];

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^[2]

Institute for Atmospheric and Earth System Research, Faculty of Science, University of Helsinki, Helsinki 00014, Finland, Aerosol and Haze Laboratory, University of Chemical Technology, Beijing 100029, P.R. China
Institute for Atmospheric and Earth System Research, Faculty of Science, University of Helsinki, Helsinki 00014, Finland
IRCELYON, CNRSUniversity of Lyon, Villeurbanne 69626, France
Department of Environmental Science and Analytical Chemistry, Stockholm University, Stockholm 11418, Sweden
Division of Nuclear Physics, Department of Physics, Lund University, Lund 22100, Sweden
Leibniz Institute for Tropospheric Research, Leipzig 04318, Germany
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, United States
Institut für Energie und Klimaforschung, IEK-8, Forschungszentrum Jülich GmbH, Jülich 52425, Germany
Institute for Atmospheric and Earth System Research, Faculty of Science, University of Helsinki, Helsinki 00014, Finland, Institute of Physics, University of Tartu, Tartu 50090, Estonia
Institute for Atmospheric and Earth System Research, Faculty of Science, University of Helsinki, Helsinki 00014, Finland, Aerodyne Research Inc., Billerica, Massachusetts 01821, United States
Department of Atmospheric Sciences, University of Washington, Seattle, Washington 98195, United States
Center for Atmospheric Particle Studies, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, United States
Department of Chemistry, University of Cøpenhagen, Cøpenhagen 2100, Denmark

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Research Organization:: Univ. of Washington, Seattle, WA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: SC0018221

OSTI ID:: 1496495

Journal Information:: Chemical Reviews, Journal Name: Chemical Reviews Journal Issue: 6 Vol. 119; ISSN 0009-2665

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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The MCM v3.3.1 degradation scheme for isoprene Jenkin, M. E.; Young, J. C.; Rickard, A. R. Atmospheric Chemistry and Physics, Vol. 15, Issue 20 https://doi.org/10.5194/acp-15-11433-2015	journal	January 2015
Formation of highly oxidized multifunctional compounds: autoxidation of peroxy radicals formed in the ozonolysis of alkenes – deduced from structure–product relationships Mentel, T. F.; Springer, M.; Ehn, M. Atmospheric Chemistry and Physics, Vol. 15, Issue 12 https://doi.org/10.5194/acp-15-6745-2015	journal	January 2015
Phase partitioning and volatility of secondary organic aerosol components formed from α-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds Lopez-Hilfiker, F. D.; Mohr, C.; Ehn, M. Atmospheric Chemistry and Physics, Vol. 15, Issue 14 https://doi.org/10.5194/acp-15-7765-2015	journal	January 2015
Formation of hydroxyl radicals from photolysis of secondary organic aerosol material Badali, K. M.; Zhou, S.; Aljawhary, D. Atmospheric Chemistry and Physics, Vol. 15, Issue 14 https://doi.org/10.5194/acp-15-7831-2015	journal	January 2015
Chemical characterization of organosulfates in secondary organic aerosol derived from the photooxidation of alkanes Riva, Matthieu; Da Silva Barbosa, Thais; Lin, Ying-Hsuan Atmospheric Chemistry and Physics, Vol. 16, Issue 17 https://doi.org/10.5194/acp-16-11001-2016	journal	January 2016
Source characterization of highly oxidized multifunctional compounds in a boreal forest environment using positive matrix factorization Yan, Chao; Nie, Wei; Äijälä, Mikko Atmospheric Chemistry and Physics, Vol. 16, Issue 19 https://doi.org/10.5194/acp-16-12715-2016	journal	January 2016
Observation of new particle formation and measurement of sulfuric acid, ammonia, amines and highly oxidized organic molecules at a rural site in central Germany Kürten, Andreas; Bergen, Anton; Heinritzi, Martin Atmospheric Chemistry and Physics, Vol. 16, Issue 19 https://doi.org/10.5194/acp-16-12793-2016	journal	January 2016
The acid-catalyzed hydrolysis of an α -pinene-derived organic nitrate: kinetics, products, reaction mechanisms, and atmospheric impact Rindelaub, Joel D.; Borca, Carlos H.; Hostetler, Matthew A. Atmospheric Chemistry and Physics, Vol. 16, Issue 23 https://doi.org/10.5194/acp-16-15425-2016	journal	January 2016
Hydroxyl radicals from secondary organic aerosol decomposition in water Tong, Haijie; Arangio, Andrea M.; Lakey, Pascale S. J. Atmospheric Chemistry and Physics, Vol. 16, Issue 3 https://doi.org/10.5194/acp-16-1761-2016	journal	January 2016
Comprehensive modelling study on observed new particle formation at the SORPES station in Nanjing, China Huang, Xin; Zhou, Luxi; Ding, Aijun Atmospheric Chemistry and Physics, Vol. 16, Issue 4 https://doi.org/10.5194/acp-16-2477-2016	journal	January 2016
Different pathways of the formation of highly oxidized multifunctional organic compounds (HOMs) from the gas-phase ozonolysis of β-caryophyllene Richters, Stefanie; Herrmann, Hartmut; Berndt, Torsten Atmospheric Chemistry and Physics, Vol. 16, Issue 15 https://doi.org/10.5194/acp-16-9831-2016	journal	January 2016
Dynamic consideration of smog chamber experiments Chuang, Wayne K.; Donahue, Neil M. Atmospheric Chemistry and Physics, Vol. 17, Issue 16 https://doi.org/10.5194/acp-17-10019-2017	journal	January 2017
Modelling organic aerosol concentrations and properties during ChArMEx summer campaigns of 2012 and 2013 in the western Mediterranean region Chrit, Mounir; Sartelet, Karine; Sciare, Jean Atmospheric Chemistry and Physics, Vol. 17, Issue 20 https://doi.org/10.5194/acp-17-12509-2017	journal	January 2017
The role of highly oxygenated molecules (HOMs) in determining the composition of ambient ions in the boreal forest Bianchi, Federico; Garmash, Olga; He, Xucheng Atmospheric Chemistry and Physics, Vol. 17, Issue 22 https://doi.org/10.5194/acp-17-13819-2017	journal	January 2017
Real-time detection of highly oxidized organosulfates and BSOA marker compounds during the F-BEACh 2014 field study Brüggemann, Martin; Poulain, Laurent; Held, Andreas Atmospheric Chemistry and Physics, Vol. 17, Issue 2 https://doi.org/10.5194/acp-17-1453-2017	journal	January 2017
Chemical characterization of atmospheric ions at the high altitude research station Jungfraujoch (Switzerland) Frege, Carla; Bianchi, Federico; Molteni, Ugo Atmospheric Chemistry and Physics, Vol. 17, Issue 4 https://doi.org/10.5194/acp-17-2613-2017	journal	January 2017
Modeling the role of highly oxidized multifunctional organic molecules for the growth of new particles over the boreal forest region Öström, Emilie; Putian, Zhou; Schurgers, Guy Atmospheric Chemistry and Physics, Vol. 17, Issue 14 https://doi.org/10.5194/acp-17-8887-2017	journal	January 2017
Wintertime photochemistry in Beijing: observations of RO_x radical concentrations in the North China Plain during the BEST-ONE campaign Tan, Zhaofeng; Rohrer, Franz; Lu, Keding Atmospheric Chemistry and Physics, Vol. 18, Issue 16 https://doi.org/10.5194/acp-18-12391-2018	journal	January 2018
Vertical characterization of highly oxygenated molecules (HOMs) below and above a boreal forest canopy Zha, Qiaozhi; Yan, Chao; Junninen, Heikki Atmospheric Chemistry and Physics, Vol. 18, Issue 23 https://doi.org/10.5194/acp-18-17437-2018	journal	January 2018
Formation of highly oxygenated organic molecules from aromatic compounds Molteni, Ugo; Bianchi, Federico; Klein, Felix Atmospheric Chemistry and Physics, Vol. 18, Issue 3 https://doi.org/10.5194/acp-18-1909-2018	journal	January 2018
Measurement–model comparison of stabilized Criegee intermediate and highly oxygenated molecule production in the CLOUD chamber Sarnela, Nina; Jokinen, Tuija; Duplissy, Jonathan Atmospheric Chemistry and Physics, Vol. 18, Issue 4 https://doi.org/10.5194/acp-18-2363-2018	journal	January 2018
Characterization of organic nitrate constituents of secondary organic aerosol (SOA) from nitrate-radical-initiated oxidation of limonene using high-resolution chemical ionization mass spectrometry Faxon, Cameron; Hammes, Julia; Le Breton, Michael Atmospheric Chemistry and Physics, Vol. 18, Issue 8 https://doi.org/10.5194/acp-18-5467-2018	journal	January 2018
Influence of temperature on the molecular composition of ions and charged clusters during pure biogenic nucleation Frege, Carla; Ortega, Ismael K.; Rissanen, Matti P. Atmospheric Chemistry and Physics, Vol. 18, Issue 1 https://doi.org/10.5194/acp-18-65-2018	journal	January 2018
High-molecular-weight esters in α-pinene ozonolysis secondary organic aerosol: structural characterization and mechanistic proposal for their formation from highly oxygenated molecules Kahnt, Ariane; Vermeylen, Reinhilde; Iinuma, Yoshiteru Atmospheric Chemistry and Physics, Vol. 18, Issue 11 https://doi.org/10.5194/acp-18-8453-2018	journal	January 2018
Protocol for the development of the Master Chemical Mechanism, MCM v3 (Part A): tropospheric degradation of non-aromatic volatile organic compounds Saunders, S. M.; Jenkin, M. E.; Derwent, R. G. Atmospheric Chemistry and Physics, Vol. 3, Issue 1 https://doi.org/10.5194/acp-3-161-2003	journal	January 2003
The role of VOC oxidation products in continental new particle formation Laaksonen, A.; Kulmala, M.; O'Dowd, C. D. Atmospheric Chemistry and Physics, Vol. 8, Issue 10 https://doi.org/10.5194/acp-8-2657-2008	journal	January 2008
SIMPOL.1: a simple group contribution method for predicting vapor pressures and enthalpies of vaporization of multifunctional organic compounds Pankow, J. F.; Asher, W. E. Atmospheric Chemistry and Physics, Vol. 8, Issue 10 https://doi.org/10.5194/acp-8-2773-2008	journal	January 2008
Fast airborne aerosol size and chemistry measurements above Mexico City and Central Mexico during the MILAGRO campaign DeCarlo, P. F.; Dunlea, E. J.; Kimmel, J. R. Atmospheric Chemistry and Physics, Vol. 8, Issue 14 https://doi.org/10.5194/acp-8-4027-2008	journal	January 2008
Secondary organic aerosol (SOA) formation from reaction of isoprene with nitrate radicals (NO ₃ ) Ng, N. L.; Kwan, A. J.; Surratt, J. D. Atmospheric Chemistry and Physics, Vol. 8, Issue 14 https://doi.org/10.5194/acp-8-4117-2008	journal	January 2008
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV – gas phase reactions of organic halogen species Atkinson, R.; Baulch, D. L.; Cox, R. A. Atmospheric Chemistry and Physics, Vol. 8, Issue 15 https://doi.org/10.5194/acp-8-4141-2008	journal	January 2008
Laboratory investigation of photochemical oxidation of organic aerosol from wood fires 1: measurement and simulation of organic aerosol evolution Grieshop, A. P.; Logue, J. M.; Donahue, N. M. Atmospheric Chemistry and Physics, Vol. 9, Issue 4 https://doi.org/10.5194/acp-9-1263-2009	journal	January 2009
Photodegradation of secondary organic aerosol generated from limonene oxidation by ozone studied with chemical ionization mass spectrometry Pan, X.; Underwood, J. S.; Xing, J. -H. Atmospheric Chemistry and Physics, Vol. 9, Issue 12 https://doi.org/10.5194/acp-9-3851-2009	journal	January 2009
The formation, properties and impact of secondary organic aerosol: current and emerging issues Hallquist, M.; Wenger, J. C.; Baltensperger, U. Atmospheric Chemistry and Physics, Vol. 9, Issue 14 https://doi.org/10.5194/acp-9-5155-2009	journal	January 2009
Sulfuric acid and OH concentrations in a boreal forest site Petäjä, T.; Mauldin, III, R. L.; Kosciuch, E. Atmospheric Chemistry and Physics, Vol. 9, Issue 19 https://doi.org/10.5194/acp-9-7435-2009	journal	January 2009
Production of highly oxygenated organic molecules (HOMs) from trace contaminants during isoprene oxidation Bernhammer, Anne-Kathrin; Fischer, Lukas; Mentler, Bernhard Atmospheric Measurement Techniques, Vol. 11, Issue 8 https://doi.org/10.5194/amt-11-4763-2018	journal	January 2018
A high-resolution mass spectrometer to measure atmospheric ion composition Junninen, H.; Ehn, M.; Petäjä, T. Atmospheric Measurement Techniques, Vol. 3, Issue 4 https://doi.org/10.5194/amt-3-1039-2010	journal	January 2010
A field-deployable, chemical ionization time-of-flight mass spectrometer Bertram, T. H.; Kimmel, J. R.; Crisp, T. A. Atmospheric Measurement Techniques, Vol. 4, Issue 7 https://doi.org/10.5194/amt-4-1471-2011	journal	January 2011
Performance of a corona ion source for measurement of sulfuric acid by chemical ionization mass spectrometry Kürten, A.; Rondo, L.; Ehrhart, S. Atmospheric Measurement Techniques, Vol. 4, Issue 3 https://doi.org/10.5194/amt-4-437-2011	journal	January 2011
Application of high-resolution time-of-flight chemical ionization mass spectrometry measurements to estimate volatility distributions of α-pinene and naphthalene oxidation products Chhabra, P. S.; Lambe, A. T.; Canagaratna, M. R. Atmospheric Measurement Techniques, Vol. 8, Issue 1 https://doi.org/10.5194/amt-8-1-2015	journal	January 2015
A switchable reagent ion high resolution time-of-flight chemical ionization mass spectrometer for real-time measurement of gas phase oxidized species: characterization from the 2013 southern oxidant and aerosol study Brophy, P.; Farmer, D. K. Atmospheric Measurement Techniques, Vol. 8, Issue 7 https://doi.org/10.5194/amt-8-2945-2015	journal	January 2015
Characterization of the mass-dependent transmission efficiency of a CIMS Heinritzi, Martin; Simon, Mario; Steiner, Gerhard Atmospheric Measurement Techniques, Vol. 9, Issue 4 https://doi.org/10.5194/amt-9-1449-2016	journal	January 2016
Constraining the sensitivity of iodide adduct chemical ionization mass spectrometry to multifunctional organic molecules using the collision limit and thermodynamic stability of iodide ion adducts Lopez-Hilfiker, Felipe D.; Iyer, Siddarth; Mohr, Claudia Atmospheric Measurement Techniques, Vol. 9, Issue 4 https://doi.org/10.5194/amt-9-1505-2016	journal	January 2016

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