Corrosion Behavior of Zinc-Nickel and Graphene Layered Structures on Steel Substrates
Abstract
Large‐area single layers of graphene are synthesized using chemical vapor deposition techniques and are assembled onto steel substrates that are finished with a thin layer of electrodeposited zinc–nickel (ZnNi). Atomic force microscopy combined with Raman spectroscopy is used to determine the number of the assembled graphene layers and to characterize the defects in their crystal structure. The graphene‐ZnNi‐steel layered specimens are exposed to a salt‐fog environment. The defects in the structure of the graphene single layers are found to accelerate corrosion and the formation of a resistive oxide layer. The chemical composition and element map of the reacted surfaces are studied by x‐ray photoelectron spectroscopy. The electrical properties of the samples before and after the salt‐fog testing are evaluated using sheet resistance measurements.
- Authors:
-
[1];
[1];
[1];
[1]
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1496004
- Alternate Identifier(s):
- OSTI ID: 1489298
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Engineering Materials
- Additional Journal Information:
- Journal Volume: 21; Journal Issue: 3; Journal ID: ISSN 1438-1656
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; corrosion; graphene; salt fog; zinc–nickel
Citation Formats
Polizos, Georgios, Stehle, Yijing Y., Sharma, Jaswinder, Voylov, Dmitry N., Vlassiouk, Ivan V., Shin, Seungha, and Meyer, III, Harry M. Corrosion Behavior of Zinc-Nickel and Graphene Layered Structures on Steel Substrates. United States: N. p., 2019.
Web. doi:10.1002/adem.201800949.
Polizos, Georgios, Stehle, Yijing Y., Sharma, Jaswinder, Voylov, Dmitry N., Vlassiouk, Ivan V., Shin, Seungha, & Meyer, III, Harry M. Corrosion Behavior of Zinc-Nickel and Graphene Layered Structures on Steel Substrates. United States. https://doi.org/10.1002/adem.201800949
Polizos, Georgios, Stehle, Yijing Y., Sharma, Jaswinder, Voylov, Dmitry N., Vlassiouk, Ivan V., Shin, Seungha, and Meyer, III, Harry M. Wed .
"Corrosion Behavior of Zinc-Nickel and Graphene Layered Structures on Steel Substrates". United States. https://doi.org/10.1002/adem.201800949. https://www.osti.gov/servlets/purl/1496004.
@article{osti_1496004,
title = {Corrosion Behavior of Zinc-Nickel and Graphene Layered Structures on Steel Substrates},
author = {Polizos, Georgios and Stehle, Yijing Y. and Sharma, Jaswinder and Voylov, Dmitry N. and Vlassiouk, Ivan V. and Shin, Seungha and Meyer, III, Harry M.},
abstractNote = {Large‐area single layers of graphene are synthesized using chemical vapor deposition techniques and are assembled onto steel substrates that are finished with a thin layer of electrodeposited zinc–nickel (ZnNi). Atomic force microscopy combined with Raman spectroscopy is used to determine the number of the assembled graphene layers and to characterize the defects in their crystal structure. The graphene‐ZnNi‐steel layered specimens are exposed to a salt‐fog environment. The defects in the structure of the graphene single layers are found to accelerate corrosion and the formation of a resistive oxide layer. The chemical composition and element map of the reacted surfaces are studied by x‐ray photoelectron spectroscopy. The electrical properties of the samples before and after the salt‐fog testing are evaluated using sheet resistance measurements.},
doi = {10.1002/adem.201800949},
journal = {Advanced Engineering Materials},
number = 3,
volume = 21,
place = {United States},
year = {Wed Jan 02 00:00:00 EST 2019},
month = {Wed Jan 02 00:00:00 EST 2019}
}
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