Calorimetric study of alkali and alkaline-earth cation adsorption and exchange at the quartz-solution interface

doi:10.1016/j.jcis.2017.06.005

Title: Calorimetric study of alkali and alkaline-earth cation adsorption and exchange at the quartz-solution interface

Full Record
Other Related Research

Authors:

Allen, Nicholas; Machesky, Michael L.; Wesolowski, David J.;

Publication Date:: 2017-10-01

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI Identifier:: 1495558

Grant/Contract Number:: [211267]

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Colloid and Interface Science

Additional Journal Information:: [Journal Name: Journal of Colloid and Interface Science Journal Volume: 504 Journal Issue: C]; Journal ID: ISSN 0021-9797

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Citation Formats


                    Allen, Nicholas, Machesky, Michael L., Wesolowski, David J., and Kabengi, Nadine. Calorimetric study of alkali and alkaline-earth cation adsorption and exchange at the quartz-solution interface.  United States: N. p., 2017. 
        Web.  doi:10.1016/j.jcis.2017.06.005.

Copy to clipboard


                    Allen, Nicholas, Machesky, Michael L., Wesolowski, David J., & Kabengi, Nadine. Calorimetric study of alkali and alkaline-earth cation adsorption and exchange at the quartz-solution interface.  United States.  doi:10.1016/j.jcis.2017.06.005.

Copy to clipboard


                    Allen, Nicholas, Machesky, Michael L., Wesolowski, David J., and Kabengi, Nadine. Sun .  
        "Calorimetric study of alkali and alkaline-earth cation adsorption and exchange at the quartz-solution interface".  United States.  doi:10.1016/j.jcis.2017.06.005.

Copy to clipboard


                    
@article{osti_1495558,

  title        = {Calorimetric study of alkali and alkaline-earth cation adsorption and exchange at the quartz-solution interface},

  author       = {Allen, Nicholas and Machesky, Michael L. and Wesolowski, David J. and Kabengi, Nadine},

  abstractNote = {},

  doi          = {10.1016/j.jcis.2017.06.005},

  journal      = {Journal of Colloid and Interface Science},

  number       = [C],

  volume       = [504],

  place        = {United States},

  year         = {2017},

  month        = {10}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
DOI: 10.1016/j.jcis.2017.06.005

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 5 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

An ab initio study of the selective of alkali and alkaline earth metal cations for crown ethers

Conference Feller, D F ; Glendening, E D ; Thompson, M A ; ...

Crown ethers are a class of macrocyclic polyether that are known to preferentially bind certain cations in potentially complex mixtures of other cations. They are being considered as candidates for separating radioactive cesium (137Cs) and strontium (90Sr) from the high level waste tanks on the Hanford Nuclear Reservation. We present the results of RHF and Mp2 calculations on a variety of crown ethers, including 12-crown-4, 18-crown-6 and Clark Still`s 18-crown-6 derivative. Gas phase calculations show that 18-crown-6 most strongly blinds lithium, but our results indicate that potassium selectivity is recovered with the inclusion of even a small number of watersmore »« less
An ab initio study of the selective binding of alkali and alkaline earth metal cations for crown ethers

Conference Feller, D F ; Glendening, E D ; Thompson, M A

Crown ethers are a class of macrocyclic polyether that are known to preferentially bind certain cations in potentially complex mixtures of other cations. They are being considered as candidates for separating radioactive cesium ({sup 137}Cs) and strontium ({sup 90}Sr) from the high level waste tanks on the Hanford Nuclear Reservation. We present the results of RHF and MP2 calculations on a variety of crown ethers, including 18-crown-6, which is known to prefer potassium in polar solvents. Gas phase calculations show that 18-crown-6 most strongly binds lithium, but our results indicate that potassium selectivity is recovered with the inclusion of evenmore »« less
CATION EXCHANGE SEPARATION OF ALKALINE EARTH ELEMENTS, Al AND Fe WITH FORMATE BUFFER SOLUTION CONTAINING METHANOL (in Japanese)

Journal Article Tanaka, M - Nippon Kagaku Zasshi (Japan) Formerly Nippon Kagaku Kaishi (1921- 47) Merged with Kogyo Kagaku Zasshi to form Nippon Kagaku Kaishi

The ion-exchange separation of Mg, Ca, Sr, Ba, Al, and Fe with the buffer solution of formic acid and ammonium formate containing methanol was studied. The exchanger used was Dowex 50W-X8. Addition of methanol to an eluant of formate buffer solution slows down the elution rate of alkaline earth elements. The result is similar to that obtained previously in the case of hydrochloric acid. The heavier the atomic weight of alkaline earth elements and the lower the pH of formate buffer solution, the slower the elution rate becomes. Little effect of methanol was observed in the case of Al, whichmore »« less
DOI: 10.1246/nikkashi1948.85.2_119
Cation and anion exchange studies of twenty cations in aqueous solutions of formic, oxalic, tartaric and citric acids and their alkali metal salts

Journal Article Qureshi, M ; Rathore, H S ; Kaushik, R C - Anal. Chem., v. 47, no. 9, pp. 1710-1712
DOI: 10.1021/ac60359a034
Alkali or alkaline earth metal promoted catalyst and a process for methanol synthesis using alkali or alkaline earth metals as promoters

Patent Tierney, J W ; Wender, I ; Palekar, V M

The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a heterogeneous catalyst comprising reduced copper chromite impregnated with an alkali or alkaline earth metal. There is thus no need to add a separate alkali or alkaline earth compound. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100--160 C and the pressure range of 40--65 atm. The process produces methanol with up to 90% syngas conversion per passmore »« less

Similar Records