Solubilities and ionic conductivities of ionic liquids containing lithium salts

doi:10.1016/j.electacta.2017.07.053

Title: Solubilities and ionic conductivities of ionic liquids containing lithium salts

Full Record
Other Related Research

Authors:: Asenbauer, Jakob; Ben Hassen, Nour; McCloskey, Bryan D.; Prausnitz, John M.

Publication Date:: 2017-09-01

Sponsoring Org.:: USDOE

OSTI Identifier:: 1495545

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Electrochimica Acta

Additional Journal Information:: Journal Name: Electrochimica Acta Journal Volume: 247 Journal Issue: C; Journal ID: ISSN 0013-4686

Publisher:: Elsevier

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Asenbauer, Jakob, Ben Hassen, Nour, McCloskey, Bryan D., and Prausnitz, John M. Solubilities and ionic conductivities of ionic liquids containing lithium salts.  United Kingdom: N. p., 2017. 
        Web.  doi:10.1016/j.electacta.2017.07.053.

Copy to clipboard


                    Asenbauer, Jakob, Ben Hassen, Nour, McCloskey, Bryan D., & Prausnitz, John M. Solubilities and ionic conductivities of ionic liquids containing lithium salts.  United Kingdom.  doi:https://doi.org/10.1016/j.electacta.2017.07.053

Copy to clipboard


                    Asenbauer, Jakob, Ben Hassen, Nour, McCloskey, Bryan D., and Prausnitz, John M. Fri .  
        "Solubilities and ionic conductivities of ionic liquids containing lithium salts".  United Kingdom.  doi:https://doi.org/10.1016/j.electacta.2017.07.053.

Copy to clipboard


                    
@article{osti_1495545,

  title        = {Solubilities and ionic conductivities of ionic liquids containing lithium salts},

  author       = {Asenbauer, Jakob and Ben Hassen, Nour and McCloskey, Bryan D. and Prausnitz, John M.},

  abstractNote = {},

  doi          = {10.1016/j.electacta.2017.07.053},

  journal      = {Electrochimica Acta},

  number       = C,

  volume       = 247,

  place        = {United Kingdom},

  year         = {2017},

  month        = {9}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
DOI: https://doi.org/10.1016/j.electacta.2017.07.053

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 4 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Mixed-salt Effects on the Ionic Conductivity of Lithium-doped PEO-containing Block Copolymers

Journal Article Young, W ; Albert, J ; Schantz, A ; ... - Macromolecules

We demonstrate a simple, yet effective, mixed-salt method to increase the room temperature ionic conductivity of lithium-doped block copolymer electrolyte membranes by suppressing the crystalline phases in the conducting block. We examined a mixed-salt system of LiClO{sub 4} and LiN(SO{sub 2}CF{sub 3}){sub 2} (LiTFSI) doped into a lamellae-forming poly(styrene-b-ethylene oxide) (PS-PEO) diblock copolymer. The domain spacings, morphologies, thermal behavior, and crystalline phases of salt-doped PS-PEO samples were characterized, and the ionic conductivities of block copolymer electrolytes were obtained through ac impedance measurements. Comparing the ionic conductivity profiles of salt-doped PS-PEO samples at different mixed-salt ratios and total salt concentrations, wemore »« less
DOI: https://doi.org/10.1021/ma2013157
Mixed-Salt Effects on the Ionic Conductivity of Lithium-Doped PEO-Containing Block Copolymers

Journal Article Young, Wen-Shiue ; Albert, Julie N.L. ; Schantz, A Benjamin ; ... - Macromolecules

We demonstrate a simple, yet effective, mixed-salt method to increase the room temperature ionic conductivity of lithium-doped block copolymer electrolyte membranes by suppressing the crystalline phases in the conducting block. We examined a mixed-salt system of LiClO{sub 4} and LiN(SO{sub 2}CF{sub 3}){sub 2} (LiTFSI) doped into a lamellae-forming poly(styrene-b-ethylene oxide) (PS-PEO) diblock copolymer. The domain spacings, morphologies, thermal behavior, and crystalline phases of salt-doped PS-PEO samples were characterized, and the ionic conductivities of block copolymer electrolytes were obtained through ac impedance measurements. Comparing the ionic conductivity profiles of salt-doped PS-PEO samples at different mixed-salt ratios and total salt concentrations, wemore »« less
DOI: https://doi.org/10.1021/ma2013157
Liquid perfluoropolyether electrolytes with enhanced ionic conductivity for lithium battery applications

Journal Article Olson, Kevin R. ; Wong, Dominica H. C. ; Chintapalli, Mahati ; ... - Polymer
Cited by 4
DOI: https://doi.org/10.1016/j.polymer.2016.08.020
Ionic conduction properties of PVDF-HFP type gel polymer electrolytes with lithium imide salts

Journal Article Saito, Yuria ; Kataoka, Hiroshi ; Capiglia, C ; ... - Journal of Physical Chemistry B: Materials, Surfaces, Interfaces, amp Biophysical

Conduction properties of gel polymer electrolytes composed of lithium imide salts, LiN(CF{sub 3}SO{sub 2}){sub 2}, LiN(C{sub 2}F{sub 5}SO{sub 2}){sub 2}, and PVDF-HFP copolymer were investigated using the pulsed-field gradient NMR and complex impedance techniques. The diffusion coefficients of the gel decreased with an increase in the polymer fraction in the gel. Carrier concentration exhibited 3 orders of magnitude variation in the fraction change in polymer from 80% to 20%. These results suggest that the polymer interacts with the electrolyte to affect the carrier concentration and mobility of the gel electrolytes. The interactive effect of polymer would be detected in themore »« less
DOI: https://doi.org/10.1021/jp993723h
Ionic conductivity of dual-phase polymer electrolytes comprised of NBR/SBR latex films swollen with lithium salt solutions

Journal Article Matsumoto, Morihiko ; Ichino, Toshihiro ; Rutt, J S ; ... - Journal of the Electrochemical Society; (United States)

Dual-phase polymer electrolytes (DPE) with high ionic conductivity and good mechanical strength were prepared by swelling poly(acrylonitrile-co-butadiene) rubber (NBR) and poly(styrene-co-butadiene) rubber (SBR) mixed latex films with lithium salt solutions (e.g., 1M LiClO[sub 4]/[gamma]-butyrolactone). The latex films retain particle morphology in the solid state. The NBR phase (formed from fused NBR latex particles) is polar and is impregnated selectively with polar lithium salt solutions, yielding ion-conductive channels, whereas the SBR phase (formed from fused SBR latex particles) is nonpolar and is not impregnated, providing a mechanically supportive matrix. The ionic conductivity of the DPE increased dramatically with increasing content ofmore »« less
DOI: https://doi.org/10.1149/1.2055047

Similar Records