skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Heterogeneous viologen catalysts for metal-free and selective oxidations

Abstract

Metal-free oxidation, a green chemistry process, has drawn significant attention from catalysis researchers.

Authors:
 [1];  [2]; ORCiD logo [3]; ORCiD logo [4]
  1. School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
  2. Department of Chemistry, University of Tennessee, Knoxville, USA
  3. School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China, Department of Chemistry
  4. Department of Chemistry, University of Tennessee, Knoxville, USA, Chemical Sciences Division
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1495248
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Green Chemistry
Additional Journal Information:
Journal Name: Green Chemistry Journal Volume: 21 Journal Issue: 6; Journal ID: ISSN 1463-9262
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Hou, Shengtai, Chen, Nanqing, Zhang, Pengfei, and Dai, Sheng. Heterogeneous viologen catalysts for metal-free and selective oxidations. United Kingdom: N. p., 2019. Web. doi:10.1039/C8GC03772H.
Hou, Shengtai, Chen, Nanqing, Zhang, Pengfei, & Dai, Sheng. Heterogeneous viologen catalysts for metal-free and selective oxidations. United Kingdom. doi:10.1039/C8GC03772H.
Hou, Shengtai, Chen, Nanqing, Zhang, Pengfei, and Dai, Sheng. Mon . "Heterogeneous viologen catalysts for metal-free and selective oxidations". United Kingdom. doi:10.1039/C8GC03772H.
@article{osti_1495248,
title = {Heterogeneous viologen catalysts for metal-free and selective oxidations},
author = {Hou, Shengtai and Chen, Nanqing and Zhang, Pengfei and Dai, Sheng},
abstractNote = {Metal-free oxidation, a green chemistry process, has drawn significant attention from catalysis researchers.},
doi = {10.1039/C8GC03772H},
journal = {Green Chemistry},
number = 6,
volume = 21,
place = {United Kingdom},
year = {2019},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8GC03772H

Citation Metrics:
Cited by: 5 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Core–Shell Fe–Pt Nanoparticles in Ionic Liquids: Magnetic and Catalytic Properties
journal, February 2018

  • Adamski, Janice; Qadir, Muhammad I.; Serna, Jilder P.
  • The Journal of Physical Chemistry C, Vol. 122, Issue 8
  • DOI: 10.1021/acs.jpcc.7b12219

Oxidation of sulfides to sulfoxides. Part 2: Oxidation by hydrogen peroxide
journal, August 2005


Nanocarbons for the Development of Advanced Catalysts
journal, May 2013

  • Su, Dang Sheng; Perathoner, Siglinda; Centi, Gabriele
  • Chemical Reviews, Vol. 113, Issue 8
  • DOI: 10.1021/cr300367d

Highly selective Pd@mpg-C3N4 catalyst for phenol hydrogenation in aqueous phase
journal, January 2013


Synthesis and Characterization of a Highly Reducing Neutral “Extended Viologen” and the Isostructural Hydrocarbon 4,4‘ ‘‘ ‘-Di- n -octyl- p -quaterphenyl
journal, November 2005

  • Porter, William W.; Vaid, Thomas P.; Rheingold, Arnold L.
  • Journal of the American Chemical Society, Vol. 127, Issue 47
  • DOI: 10.1021/ja053084q

Selective oxidation of sulfides to sulfoxides with molecular oxygen catalyzed by N-hydroxyphthalimide (NHPI) in the presence of alcohols
journal, December 1998


Electro-Fenton Process and Related Electrochemical Technologies Based on Fenton’s Reaction Chemistry
journal, December 2009

  • Brillas, Enric; Sirés, Ignasi; Oturan, Mehmet A.
  • Chemical Reviews, Vol. 109, Issue 12
  • DOI: 10.1021/cr900136g

Catalysis of methyl viologen radical reactions by polymer-stabilized gold sols
journal, January 1981

  • Meisel, D.; Mulac, W. A.; Matheson, M. S.
  • The Journal of Physical Chemistry, Vol. 85, Issue 2, p. 179-187
  • DOI: 10.1021/j150602a015

A Mild, Chemoselective Oxidation of Sulfides to Sulfoxides Using o- Iodoxybenzoic Acid and Tetraethylammonium Bromide as Catalyst
journal, June 2003

  • Shukla, Vidyanand G.; Salgaonkar, Paresh D.; Akamanchi, Krishnacharya G.
  • The Journal of Organic Chemistry, Vol. 68, Issue 13
  • DOI: 10.1021/jo034483b

Polymer solid electrolytes based on viologen-type poly(oxytetramethylene) ionene
journal, April 2004


Metal-free oxidation of sulfides by carbon nitride with visible light illumination at room temperature
journal, January 2012

  • Zhang, Pengfei; Wang, Yong; Li, Haoran
  • Green Chemistry, Vol. 14, Issue 7
  • DOI: 10.1039/c2gc35148j

Propylene epoxidation with in situ generated H2O2 in supercritical conditions
journal, May 2014


Polymeric Graphitic Carbon Nitride as a Heterogeneous Organocatalyst: From Photochemistry to Multipurpose Catalysis to Sustainable Chemistry
journal, November 2011

  • Wang, Yong; Wang, Xinchen; Antonietti, Markus
  • Angewandte Chemie International Edition, Vol. 51, Issue 1
  • DOI: 10.1002/anie.201101182

Viologen Catalysts for a Direct Carbohydrate Fuel Cell
journal, January 2009

  • Wheeler, Dean R.; Nichols, Joseph; Hansen, Dane
  • Journal of The Electrochemical Society, Vol. 156, Issue 10
  • DOI: 10.1149/1.3183815

Highly carboxyl-decorated graphene oxide sheets as metal-free catalytic system for chemoselective oxidation of sulfides to sulfones
journal, November 2017


Selective oxidation of aromatic sulfide catalyzed by an artificial metalloenzyme: new activity of hemozymes
journal, January 2009

  • Ricoux, Rémy; Allard, Mathieu; Dubuc, Roger
  • Organic & Biomolecular Chemistry, Vol. 7, Issue 16
  • DOI: 10.1039/b907534h

Metal-free allylic/benzylic oxidation strategies with molecular oxygen: recent advances and future prospects
journal, January 2014

  • Chen, Kexian; Zhang, Pengfei; Wang, Yong
  • Green Chemistry, Vol. 16, Issue 5
  • DOI: 10.1039/c3gc42135j

Stable photoinduced charge separation in layered viologen compounds
journal, August 1992

  • Vermeulen, Lori A.; Thompson, Mark E.
  • Nature, Vol. 358, Issue 6388
  • DOI: 10.1038/358656a0

Photoreduction of methylviologen in the interlayer of K4Nb6O17
journal, January 1989

  • Nakato, Teruyuki; Kuroda, Kazuyuki; Kato, Chuzo
  • Journal of the Chemical Society, Chemical Communications, Issue 16
  • DOI: 10.1039/c39890001144

Photosensitized Hydrogen Evolution from Water Using Conjugated Polymers Wrapped in Dendrimeric Electrolytes
journal, September 2004

  • Jiang, Dong-Lin; Choi, Cheol-Kyu; Honda, Kayoko
  • Journal of the American Chemical Society, Vol. 126, Issue 38
  • DOI: 10.1021/ja048912e

Direct catalytic oxidation of benzene to phenol over metal-free graphene-based catalyst
journal, January 2013

  • Yang, Jing-He; Sun, Geng; Gao, Yongjun
  • Energy & Environmental Science, Vol. 6, Issue 3
  • DOI: 10.1039/c3ee23623d

Green, Catalytic Oxidation of Alcohols in Water
journal, March 2000


Albumin-Conjugated Corrole Metal Complexes:  Extremely Simple Yet Very Efficient Biomimetic Oxidation Systems
journal, March 2005

  • Mahammed, Atif; Gross, Zeev
  • Journal of the American Chemical Society, Vol. 127, Issue 9
  • DOI: 10.1021/ja045372c

Long-lived photoinduced charge separation in a redox system trapped in a sol–gel glass
journal, January 1992

  • Slama-Schwok, Anny; Ottolenghi, Michael; Avnir, David
  • Nature, Vol. 355, Issue 6357
  • DOI: 10.1038/355240a0

Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Au-Pd/TiO 2 Catalysts
journal, January 2006


Selective oxidation of benzene to phenol by FeCl3/mpg-C3N4 hybrids
journal, January 2013

  • Zhang, Pengfei; Gong, Yutong; Li, Haoran
  • RSC Advances, Vol. 3, Issue 15
  • DOI: 10.1039/c3ra23357j

Oxidation of organic sulfides by a vanadium(5+) oxo–monoperoxo–picolinate complex: Kinetics and mechanism
journal, August 2009

  • Ballistreri, Francesco P.; Fortuna, Cosimo G.; Pappalardo, Andrea
  • Journal of Molecular Catalysis A: Chemical, Vol. 308, Issue 1-2
  • DOI: 10.1016/j.molcata.2009.03.034

Nanoporous Ionic Organic Networks: Stabilizing and Supporting Gold Nanoparticles for Catalysis
journal, January 2015

  • Zhang, Pengfei; Qiao, Zhen-An; Jiang, Xueguang
  • Nano Letters, Vol. 15, Issue 2
  • DOI: 10.1021/nl504780j

Polymerized Ionic Networks with High Charge Density: Quasi-Solid Electrolytes in Lithium-Metal Batteries
journal, November 2015


Metal-Free Activation of Dioxygen by Graphene/g-C 3 N 4 Nanocomposites: Functional Dyads for Selective Oxidation of Saturated Hydrocarbons
journal, June 2011

  • Li, Xin-Hao; Chen, Jie-Sheng; Wang, Xinchen
  • Journal of the American Chemical Society, Vol. 133, Issue 21
  • DOI: 10.1021/ja200997a

Electron Transfer−Oxygen Transfer Oxygenation of Sulfides Catalyzed by the H 5 PV 2 Mo 10 O 40 Polyoxometalate
journal, August 2010

  • Khenkin, Alexander M.; Leitus, Gregory; Neumann, Ronny
  • Journal of the American Chemical Society, Vol. 132, Issue 33
  • DOI: 10.1021/ja105183w