Pressure-induced amorphization in plagioclase feldspars: A time-resolved powder diffraction study during rapid compression
Abstract
The pressure-induced amorphization of the two endmembers of the plagioclase ((Na1–xCax)Al1+xSi3–xO8) solid-solution, anorthite (CaAl2Si2O8) and albite (NaAlSi3O8), has been studied as a function of compression rate by means of time-resolved powder diffraction. Anorthite and albite were compressed in a diamond anvil cell to 80 GPa at multiple rates from 0.05 GPa/s to 80 GPa/s. The amorphization pressure decreases with increasing compression rate. This negative strain rate sensitivity indicates a change in deformation mechanism in the plagioclase solid-solution endmembers from brittle to ductile with increasing compression rate. The presented data support the previously proposed shear deformation mechanism for the amorphization of plagioclase. Furthermore, amorphization progresses over a wide pressure range suggesting heterogeneous amorphization, similar to observations based on recovered material from shock-compression experiments of plagioclase. As a result, our experiments support the contention that amorphization pressures for plagioclase may occur at lower pressures than usually considered.
- Authors:
-
- Stony Brook Univ., Stony Brook, NY (United States)
- Albert-Ludwig-Univ. Freiburg, Freiburg (Germany)
- Goethe-Univ. Frankfurt, Frankfurt (Germany)
- Friedrich-Schiller-Univ. Jena, Jena (Germany)
- Carnegie Institution of Washington, Argonne, IL (United States)
- European XFEL GmbH, Schenefeld (Germany)
- Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany)
- Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1495010
- Alternate Identifier(s):
- OSTI ID: 1635864
- Report Number(s):
- BNL-211280-2019-JAAM
Journal ID: ISSN 0012-821X
- Grant/Contract Number:
- SC0012704; NA0001974; FG02-99ER45775; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Earth and Planetary Science Letters
- Additional Journal Information:
- Journal Volume: 507; Journal Issue: C; Journal ID: ISSN 0012-821X
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 58 GEOSCIENCES; plagioclase amorphization; maskelynite; rapid compression experiments
Citation Formats
Sims, Melissa, Jaret, Steven J., Carl, Eva -Regine, Rhymer, Brandon, Schrodt, Nadine, Mohrholz, Vivien, Smith, Jesse, Konopkova, Zuzana, Liermann, Hanns -Peter, Glotch, Timothy D., and Ehm, Lars. Pressure-induced amorphization in plagioclase feldspars: A time-resolved powder diffraction study during rapid compression. United States: N. p., 2018.
Web. doi:10.1016/j.epsl.2018.11.038.
Sims, Melissa, Jaret, Steven J., Carl, Eva -Regine, Rhymer, Brandon, Schrodt, Nadine, Mohrholz, Vivien, Smith, Jesse, Konopkova, Zuzana, Liermann, Hanns -Peter, Glotch, Timothy D., & Ehm, Lars. Pressure-induced amorphization in plagioclase feldspars: A time-resolved powder diffraction study during rapid compression. United States. https://doi.org/10.1016/j.epsl.2018.11.038
Sims, Melissa, Jaret, Steven J., Carl, Eva -Regine, Rhymer, Brandon, Schrodt, Nadine, Mohrholz, Vivien, Smith, Jesse, Konopkova, Zuzana, Liermann, Hanns -Peter, Glotch, Timothy D., and Ehm, Lars. Mon .
"Pressure-induced amorphization in plagioclase feldspars: A time-resolved powder diffraction study during rapid compression". United States. https://doi.org/10.1016/j.epsl.2018.11.038. https://www.osti.gov/servlets/purl/1495010.
@article{osti_1495010,
title = {Pressure-induced amorphization in plagioclase feldspars: A time-resolved powder diffraction study during rapid compression},
author = {Sims, Melissa and Jaret, Steven J. and Carl, Eva -Regine and Rhymer, Brandon and Schrodt, Nadine and Mohrholz, Vivien and Smith, Jesse and Konopkova, Zuzana and Liermann, Hanns -Peter and Glotch, Timothy D. and Ehm, Lars},
abstractNote = {The pressure-induced amorphization of the two endmembers of the plagioclase ((Na1–xCax)Al1+xSi3–xO8) solid-solution, anorthite (CaAl2Si2O8) and albite (NaAlSi3O8), has been studied as a function of compression rate by means of time-resolved powder diffraction. Anorthite and albite were compressed in a diamond anvil cell to 80 GPa at multiple rates from 0.05 GPa/s to 80 GPa/s. The amorphization pressure decreases with increasing compression rate. This negative strain rate sensitivity indicates a change in deformation mechanism in the plagioclase solid-solution endmembers from brittle to ductile with increasing compression rate. The presented data support the previously proposed shear deformation mechanism for the amorphization of plagioclase. Furthermore, amorphization progresses over a wide pressure range suggesting heterogeneous amorphization, similar to observations based on recovered material from shock-compression experiments of plagioclase. As a result, our experiments support the contention that amorphization pressures for plagioclase may occur at lower pressures than usually considered.},
doi = {10.1016/j.epsl.2018.11.038},
journal = {Earth and Planetary Science Letters},
number = C,
volume = 507,
place = {United States},
year = {Mon Dec 17 00:00:00 EST 2018},
month = {Mon Dec 17 00:00:00 EST 2018}
}
Web of Science
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