Magnetotransport Anomaly in Room-Temperature Ferrimagnetic NiCo2O4 Thin Films

Chen, Xuegang; Zhang, Xiaozhe; Han, Myung -Geun; Zhang, Le; Zhu, Yimei; Xu, Xiaoshan; Hong, Xia

doi:10.1002/adma.201805260

Title: Magnetotransport Anomaly in Room-Temperature Ferrimagnetic NiCo₂O₄ Thin Films

Journal Article · 28 November 2018 · Advanced Materials

DOI: https://doi.org/10.1002/adma.201805260 · OSTI ID:1495005

Chen, Xuegang ^[1]; Zhang, Xiaozhe ^[1];

^[2]; Zhang, Le ^[1]; Zhu, Yimei ^[2]; Xu, Xiaoshan ^[1];

^[1]

Univ. of Nebraska-Lincoln, Lincoln, NE (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

The inverse spinel ferrimagnetic NiCo₂O₄ presents a unique model system for studying the competing effects of crystalline fields, magnetic exchange, and various types of chemical and lattice disorder on the electronic and magnetic states. Here, magnetotransport anomalies in high–quality epitaxial NiCo₂O₄ thin films resulting from the complex energy landscape are reported. A strong out–of–plane magnetic anisotropy, linear magnetoresistance, and robust anomalous Hall effect above 300 K are observed in 5–30 unit cell NiCo₂O₄ films. The anomalous Hall resistance exhibits a nonmonotonic temperature dependence that peaks around room temperature, and reverses its sign at low temperature in films thinner than 20 unit cells. The scaling relation between the anomalous Hall conductivity and longitudinal conductivity reveals the intricate interplay between the spin–dependent impurity scattering, band intrinsic Berry phase effect, and electron correlation. Here, this study provides important insights into the functional design of NiCo₂O₄ for developing spinel–based spintronic applications.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012704

OSTI ID:: 1495005

Report Number(s):: BNL--211269-2019-JAAM

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 4 Vol. 31; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (63)

Electrical Transport Properties of Large, Individual NiCo2O4 Nanoplates Hu, Linfeng; Wu, Limin; Liao, Meiyong Advanced Functional Materials, Vol. 22, Issue 5 https://doi.org/10.1002/adfm.201102155	journal	January 2012
Control of the Electrical Properties in Spinel Oxides by Manipulating the Cation Disorder Ndione, Paul F.; Shi, Yezhou; Stevanovic, Vladan Advanced Functional Materials, Vol. 24, Issue 5 https://doi.org/10.1002/adfm.201302535	journal	October 2013
NixCo3−xO4 Nanowire Arrays for Electrocatalytic Oxygen Evolution Li, Yanguang; Hasin, Panitat; Wu, Yiying Advanced Materials, Vol. 22, Issue 17 https://doi.org/10.1002/adma.200903896	journal	February 2010
High-Performance NiCo2O4 Nanofilm Photodetectors Fabricated by an Interfacial Self-Assembly Strategy Hu, Linfeng; Wu, Limin; Liao, Meiyong Advanced Materials, Vol. 23, Issue 17 https://doi.org/10.1002/adma.201004109	journal	March 2011
Observation of large low-field magnetoresistance in spinel cobaltite: A new half-metal Li, Peng; Xia, Chuan; Zheng, Dongxing physica status solidi (RRL) - Rapid Research Letters, Vol. 10, Issue 2 https://doi.org/10.1002/pssr.201510402	journal	December 2015
Characterization of the Nickel Cobaltite, NiCo2O4, Prepared by Several Methods: An XRD, XANES, EXAFS, and XPS Study Marco, J. F.; Gancedo, J. R.; Gracia, M. Journal of Solid State Chemistry, Vol. 153, Issue 1 https://doi.org/10.1006/jssc.2000.8749	journal	August 2000
Infrared transparent spinel films with p-type conductivity Windisch, C. F.; Exarhos, G. J.; Ferris, K. F. Thin Solid Films, Vol. 398-399 https://doi.org/10.1016/S0040-6090(01)01302-5	journal	November 2001
Synthesis of NiCo2O4 and its application in the electrocatalytic oxidation of methanol Anu Prathap, M. U.; Srivastava, Rajendra Nano Energy, Vol. 2, Issue 5 https://doi.org/10.1016/j.nanoen.2013.04.003	journal	September 2013
Nickel cobaltite as an emerging material for supercapacitors: An overview Dubal, Deepak P.; Gomez-Romero, Pedro; Sankapal, Babasaheb R. Nano Energy, Vol. 11 https://doi.org/10.1016/j.nanoen.2014.11.013	journal	January 2015
Spin Filtering in Epitaxial Spinel Films with Nanoscale Phase Separation Li, Peng; Xia, Chuan; Li, Jun ACS Nano, Vol. 11, Issue 5 https://doi.org/10.1021/acsnano.7b01743	journal	April 2017
Large anomalous Hall effect in a non-collinear antiferromagnet at room temperature Nakatsuji, Satoru; Kiyohara, Naoki; Higo, Tomoya Nature, Vol. 527, Issue 7577 https://doi.org/10.1038/nature15723	journal	October 2015
Large anomalous Hall effect in a non-collinear antiferromagnet at room temperature Nakatsuji, S.; Kiyohara, N.; Higo, T. Nature, Vol. 534, Issue 7607 https://doi.org/10.1038/nature19416	journal	June 2016
A perpendicular-anisotropy CoFeB–MgO magnetic tunnel junction Ikeda, S.; Miura, K.; Yamamoto, H. Nature Materials, Vol. 9, Issue 9 https://doi.org/10.1038/nmat2804	journal	July 2010
Controlled lateral anisotropy in correlated manganite heterostructures by interface-engineered oxygen octahedral coupling Liao, Z.; Huijben, M.; Zhong, Z. Nature Materials, Vol. 15, Issue 4 https://doi.org/10.1038/nmat4579	journal	March 2016
Evidence for magnetic Weyl fermions in a correlated metal Kuroda, K.; Tomita, T.; Suzuki, M. -T. Nature Materials, Vol. 16, Issue 11 https://doi.org/10.1038/nmat4987	journal	September 2017
Twisting the thermoelectric potential May, Andrew F.; Sales, Brian C. Nature Materials, Vol. 20, Issue 4 https://doi.org/10.1038/s41563-020-00908-x	journal	January 2021
Origin of metallic behavior in NiCo2O4 ferrimagnet Bitla, Yugandhar; Chin, Yi-Ying; Lin, Jheng-Cyuan Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep15201	journal	October 2015
A simple theory of the anomalous hall effect in semiconductors Nozières, P.; Lewiner, C. Journal de Physique, Vol. 34, Issue 10 https://doi.org/10.1051/jphys:019730034010090100	journal	January 1973
Anisotropic magnetoresistance in tetragonal La _{1− x} Ca _x MnO _δ thin films Eckstein, J. N.; Bozovic, I.; O’Donnell, J. Applied Physics Letters, Vol. 69, Issue 9 https://doi.org/10.1063/1.117402	journal	August 1996
Examining the screening limit of field effect devices via the metal-insulator transition Hong, X.; Posadas, A.; Ahn, C. H. Applied Physics Letters, Vol. 86, Issue 14 https://doi.org/10.1063/1.1897076	journal	April 2005
Metal insulator transition with ferrimagnetic order in epitaxial thin films of spinel NiCo ₂ O ₄ Silwal, Punam; Miao, Ludi; Stern, Ilan Applied Physics Letters, Vol. 100, Issue 3 https://doi.org/10.1063/1.3676439	journal	January 2012
Spinel oxides: Δ1 spin-filter barrier for a class of magnetic tunnel junctions Zhang, Jia; Zhang, X. -G.; Han, X. F. Applied Physics Letters, Vol. 100, Issue 22 https://doi.org/10.1063/1.4722804	journal	May 2012
Temperature and Co thickness dependent sign change of the anomalous Hall effect in Co/Pd multilayers: An experimental and theoretical study Keskin, V.; Aktaş, B.; Schmalhorst, J. Applied Physics Letters, Vol. 102, Issue 2 https://doi.org/10.1063/1.4776737	journal	January 2013
Raman studies of cation distribution and thermal stability of epitaxial spinel NiCo ₂ O ₄ films Iliev, M. N.; Silwal, P.; Loukya, B. Journal of Applied Physics, Vol. 114, Issue 3 https://doi.org/10.1063/1.4815874	journal	July 2013
Thickness dependent structural, magnetic, and electronic properties of the epitaxial films of transparent conducting oxide NiCo ₂ O ₄ Silwal, Punam; Miao, Ludi; Hu, Jin Journal of Applied Physics, Vol. 114, Issue 10 https://doi.org/10.1063/1.4820930	journal	September 2013
Effect of growth temperature on the terahertz-frequency conductivity of the epitaxial transparent conducting spinel NiCo ₂ O ₄ films Silwal, Punam; La-o-vorakiat, Chan; Chia, Elbert E. M. AIP Advances, Vol. 3, Issue 9 https://doi.org/10.1063/1.4821548	journal	September 2013
Carrier density control of magnetism and Berry phases in doped EuTiO ₃ Ahadi, Kaveh; Gui, Zhigang; Porter, Zach APL Materials, Vol. 6, Issue 5 https://doi.org/10.1063/1.5025317	journal	May 2018
Probing optical band gaps at nanoscale from tetrahedral cation vacancy defects and variation of cation ordering in NiCo ₂ O ₄ epitaxial thin films Dileep, K.; Loukya, B.; Silwal, P. Journal of Physics D: Applied Physics, Vol. 47, Issue 40 https://doi.org/10.1088/0022-3727/47/40/405001	journal	September 2014
Nanostructural origin of semiconductivity and large magnetoresistance in epitaxial NiCo ₂ O ₄ /Al ₂ O ₃ thin films Zhen, Congmian; Zhang, XiaoZhe; Wei, Wengang Journal of Physics D: Applied Physics, Vol. 51, Issue 14 https://doi.org/10.1088/1361-6463/aab2a3	journal	March 2018
Giant Anomalous Hall Effect in the Chiral Antiferromagnet Mn 3 Ge Kiyohara, Naoki; Tomita, Takahiro; Nakatsuji, Satoru Physical Review Applied, Vol. 5, Issue 6 https://doi.org/10.1103/PhysRevApplied.5.064009	journal	June 2016
Extraordinary Hall effect in SrRuO 3 Klein, L.; Reiner, J. R.; Geballe, T. H. Physical Review B, Vol. 61, Issue 12 https://doi.org/10.1103/PhysRevB.61.R7842	journal	March 2000
Composition dependence of the anomalous Hall effect in Ca x Sr 1 − x Ru O 3 films Khalifah, P.; Ohkubo, I.; Sales, B. C. Physical Review B, Vol. 76, Issue 5 https://doi.org/10.1103/PhysRevB.76.054404	journal	August 2007
Quantum transport theory of anomalous electric, thermoelectric, and thermal Hall effects in ferromagnets Onoda, Shigeki; Sugimoto, Naoyuki; Nagaosa, Naoto Physical Review B, Vol. 77, Issue 16 https://doi.org/10.1103/PhysRevB.77.165103	journal	April 2008
Scaling of the anomalous Hall effect in the insulating regime Liu, Xiong-Jun; Liu, Xin; Sinova, Jairo Physical Review B, Vol. 84, Issue 16 https://doi.org/10.1103/PhysRevB.84.165304	journal	October 2011
Effects of surface and interface scattering on anomalous Hall effect in Co/Pd multilayers Guo, Z. B.; Mi, W. B.; Aboljadayel, R. O. Physical Review B, Vol. 86, Issue 10 https://doi.org/10.1103/PhysRevB.86.104433	journal	September 2012
Enhanced tunnel magnetoresistance in a spinel oxide barrier with cation-site disorder Sukegawa, Hiroaki; Miura, Yoshio; Muramoto, Shingo Physical Review B, Vol. 86, Issue 18 https://doi.org/10.1103/PhysRevB.86.184401	journal	November 2012
Electric-field-induced modulation of the anomalous Hall effect in a heterostructured itinerant ferromagnet SrRuO 3 Mizuno, Hayato; Yamada, Kihiro T.; Kan, Daisuke Physical Review B, Vol. 96, Issue 21 https://doi.org/10.1103/PhysRevB.96.214422	journal	December 2017
Sensitivity of the anomalous Hall effect to disorder correlations Ado, I. A.; Dmitriev, I. A.; Ostrovsky, P. M. Physical Review B, Vol. 96, Issue 23 https://doi.org/10.1103/PhysRevB.96.235148	journal	December 2017
Anomalous Hall Effect in Field-Effect Structures of (Ga,Mn)As Chiba, D.; Werpachowska, A.; Endo, M. Physical Review Letters, Vol. 104, Issue 10 https://doi.org/10.1103/PhysRevLett.104.106601	journal	March 2010
Anomalous Hall Effect in Disordered Multiband Metals Kovalev, Alexey A.; Sinova, Jairo; Tserkovnyak, Yaroslav Physical Review Letters, Vol. 105, Issue 3 https://doi.org/10.1103/PhysRevLett.105.036601	journal	July 2010
Metal-Insulator Transition in Ultrathin LaNiO 3 Films Scherwitzl, R.; Gariglio, S.; Gabay, M. Physical Review Letters, Vol. 106, Issue 24 https://doi.org/10.1103/PhysRevLett.106.246403	journal	June 2011
Anomalous Hall Effect Arising from Noncollinear Antiferromagnetism Chen, Hua; Niu, Qian; MacDonald, A. H. Physical Review Letters, Vol. 112, Issue 1 https://doi.org/10.1103/PhysRevLett.112.017205	journal	January 2014
Giant Enhancement of Magnetic Anisotropy in Ultrathin Manganite Films via Nanoscale 1D Periodic Depth Modulation Rajapitamahuni, A.; Zhang, L.; Koten, M. A. Physical Review Letters, Vol. 116, Issue 18 https://doi.org/10.1103/PhysRevLett.116.187201	journal	May 2016
Spin-Orbit Semimetal SrIrO 3 in the Two-Dimensional Limit Groenendijk, D. J.; Autieri, C.; Girovsky, J. Physical Review Letters, Vol. 119, Issue 25 https://doi.org/10.1103/PhysRevLett.119.256403	journal	December 2017
Anomalous Hall Effect in Ferromagnetic Semiconductors Jungwirth, T.; Niu, Qian; MacDonald, A. H. Physical Review Letters, Vol. 88, Issue 20 https://doi.org/10.1103/PhysRevLett.88.207208	journal	May 2002
Scaling of the Anomalous Hall Effect in S r 1 − x C a x R u O 3 Mathieu, R.; Asamitsu, A.; Yamada, H. Physical Review Letters, Vol. 93, Issue 1 https://doi.org/10.1103/PhysRevLett.93.016602	journal	June 2004
Intrinsic Versus Extrinsic Anomalous Hall Effect in Ferromagnets Onoda, Shigeki; Sugimoto, Naoyuki; Nagaosa, Naoto Physical Review Letters, Vol. 97, Issue 12 https://doi.org/10.1103/PhysRevLett.97.126602	journal	September 2006
Creep and Flow Regimes of Magnetic Domain-Wall Motion in Ultrathin Pt / Co / Pt Films with Perpendicular Anisotropy Metaxas, P. J.; Jamet, J. P.; Mougin, A. Physical Review Letters, Vol. 99, Issue 21 https://doi.org/10.1103/PhysRevLett.99.217208	journal	November 2007
Anomalous Hall effect Nagaosa, Naoto; Sinova, Jairo; Onoda, Shigeki Reviews of Modern Physics, Vol. 82, Issue 2 https://doi.org/10.1103/RevModPhys.82.1539	journal	May 2010
Large anomalous Hall effect driven by a nonvanishing Berry curvature in the noncolinear antiferromagnet Mn ₃ Ge Nayak, Ajaya K.; Fischer, Julia Erika; Sun, Yan Science Advances, Vol. 2, Issue 4 https://doi.org/10.1126/sciadv.1501870	journal	April 2016
Interface-driven topological Hall effect in SrRuO ₃ -SrIrO ₃ bilayer Matsuno, Jobu; Ogawa, Naoki; Yasuda, Kenji Science Advances, Vol. 2, Issue 7 https://doi.org/10.1126/sciadv.1600304	journal	July 2016
The Anomalous Hall Effect and Magnetic Monopoles in Momentum Space Fang, Z. Science, Vol. 302, Issue 5642 https://doi.org/10.1126/science.1089408	journal	October 2003
Chalkogenides of the transition elements. VI. X-Ray, neutron, and magnetic investigation of the spinels Co ₃ O ₄ , NiCo ₂ O ₄ , Co ₃ S ₄ , and NiCo ₂ S ₄ Knop, Osvald; Reid, K. I. G. Canadian Journal of Chemistry, Vol. 46, Issue 22 https://doi.org/10.1139/v68-576	journal	November 1968
A Scaling Relation of Anomalous Hall Effect in Ferromagnetic Semiconductors and Metals Fukumura, Tomoteru; Toyosaki, Hidemi; Ueno, Kazunori Japanese Journal of Applied Physics, Vol. 46, Issue No. 26 https://doi.org/10.1143/JJAP.46.L642	journal	June 2007
A scaling relation of anomalous Hall effect in ferromagnetic semiconductors and metals Fukumura, Tomoteru; Toyosaki, Hidemi; Ueno, Kazunori arXiv https://doi.org/10.48550/arxiv.0706.2924	text	January 2007
Quantum transport theory of anomalous electric, thermoelectric, and thermal Hall effects in ferromagnets Onoda, Shigeki; Sugimoto, Naoyuki; Nagaosa, Naoto arXiv https://doi.org/10.48550/arxiv.0712.0210	text	January 2007
Anomalous Hall Effect in Disordered Multiband Metals Kovalev, Alexey A.; Sinova, Jairo; Tserkovnyak, Yaroslav arXiv https://doi.org/10.48550/arxiv.1003.2626	text	January 2010
Anomalous Hall effect in field-effect structures of (Ga,Mn)As Chiba, D.; Werpachowska, A.; Endo, M. arXiv https://doi.org/10.48550/arxiv.1101.0652	text	January 2011
Anomalous Hall effect arising from noncollinear antiferromagnetism Chen, Hua; Niu, Qian; MacDonald, A. H. arXiv https://doi.org/10.48550/arxiv.1309.4041	text	January 2013
Interface-driven topological Hall effect in SrRuO$_3$-SrIrO$_3$ bilayer Matsuno, J.; Ogawa, N.; Yasuda, K. arXiv https://doi.org/10.48550/arxiv.1607.07536	text	January 2016
Anomalous Hall effect in ferromagnetic semiconductors Jungwirth, T.; Niu, Qian; MacDonald, A. H. arXiv https://doi.org/10.48550/arxiv.cond-mat/0110484	text	January 2001
Anomalous Hall Effect and Magnetic Monopoles in Momentum-Space Fang, Z.; Nagaosa, N.; Takahashi, K. S. arXiv https://doi.org/10.48550/arxiv.cond-mat/0310232	text	January 2003
Creep and flow regimes of magnetic domain wall motion in ultrathin Pt/Co/Pt films with perpendicular anisotropy Metaxas, P. J.; Jamet, J. P.; Mougin, A. arXiv https://doi.org/10.48550/arxiv.cond-mat/0702654	text	January 2007

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