Polyaniline-based all-polymeric adhesive layer: An effective lightning strike protection technology for high residual mechanical strength of CFRPs
Abstract
Carbon fiber reinforced plastics (CFRPs) are vulnerable to lightning strikes due to their low electrical conductivity and low heat resistance. A lightning strike can damage CFRP structure catastrophically. Most common lightning strike protection (LSP) technology, consists of expanded metal foils/films on top of composite structures. This technology possesses disadvantages such as increased weight, galvanic corrosion, expensive integration and repair costs. In the present study, authors introduce a novel, easy to apply and all-polymeric LSP material. A doped intrinsic conductive polymer i.e. Polyaniline (PANI) dispersed in a thermosetting cross-linking polymer divinylbenzene (DVB) has been used to prepare an adhesive layer of 0.25–0.4 mm thickness. CFRP structure coated with PANI-based LSP layer, when tested against simulated lightning impulse current of 100 kA, demonstrated effective dissipation of the current, rendering almost 100% safety to the CFRP structure. PANI showed the capability to create a 3-D conductive network due to its self-assembling property, which makes it superior compared to its counterpart carbon/metal nano-filler based LSP technologies. Almost 100% residual strength of PANI-LSP protected CFRPs is reported in this work.
- Authors:
-
[1];
[3];
- Univ. of Tokyo (Japan). Dept. of Aeronautics and Astronautics; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Manufacturing Demonstration Facility (MDF)
- Univ. of Tokyo (Japan). Dept. of Aeronautics and Astronautics
- Japan Aerospace Exploration Agency, Tokyo (Japan)
- Yamagata Univ., Yamagata (Japan). Dept. of Organic Device Engineering
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Manufacturing Demonstration Facility (MDF)
- Tokyo Univ. of Agriculture and Technology, Tokyo (Japan). Dept. of Mechanical Systems Engineering
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1494880
- Alternate Identifier(s):
- OSTI ID: 1777570
- Grant/Contract Number:
- AC05-00OR22725; 16H02424; AC05-00OR22725 with UT-Battelle
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Composites Science and Technology
- Additional Journal Information:
- Journal Volume: 172; Journal Issue: C; Journal ID: ISSN 0266-3538
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING; Polyaniline; CFRP; Adhesive; Lightning Strike Protection; Multifunctional Composites
Citation Formats
Kumar, Vipin, Yokozeki, Tomohiro, Okada, Takao, Hirano, Yoshiyasu, Goto, Teruya, Takahashi, Tatsuhiro, Hassen, Ahmed Arabi, and Ogasawara, Toshio. Polyaniline-based all-polymeric adhesive layer: An effective lightning strike protection technology for high residual mechanical strength of CFRPs. United States: N. p., 2019.
Web. doi:10.1016/j.compscitech.2019.01.006.
Kumar, Vipin, Yokozeki, Tomohiro, Okada, Takao, Hirano, Yoshiyasu, Goto, Teruya, Takahashi, Tatsuhiro, Hassen, Ahmed Arabi, & Ogasawara, Toshio. Polyaniline-based all-polymeric adhesive layer: An effective lightning strike protection technology for high residual mechanical strength of CFRPs. United States. https://doi.org/10.1016/j.compscitech.2019.01.006
Kumar, Vipin, Yokozeki, Tomohiro, Okada, Takao, Hirano, Yoshiyasu, Goto, Teruya, Takahashi, Tatsuhiro, Hassen, Ahmed Arabi, and Ogasawara, Toshio. Wed .
"Polyaniline-based all-polymeric adhesive layer: An effective lightning strike protection technology for high residual mechanical strength of CFRPs". United States. https://doi.org/10.1016/j.compscitech.2019.01.006. https://www.osti.gov/servlets/purl/1494880.
@article{osti_1494880,
title = {Polyaniline-based all-polymeric adhesive layer: An effective lightning strike protection technology for high residual mechanical strength of CFRPs},
author = {Kumar, Vipin and Yokozeki, Tomohiro and Okada, Takao and Hirano, Yoshiyasu and Goto, Teruya and Takahashi, Tatsuhiro and Hassen, Ahmed Arabi and Ogasawara, Toshio},
abstractNote = {Carbon fiber reinforced plastics (CFRPs) are vulnerable to lightning strikes due to their low electrical conductivity and low heat resistance. A lightning strike can damage CFRP structure catastrophically. Most common lightning strike protection (LSP) technology, consists of expanded metal foils/films on top of composite structures. This technology possesses disadvantages such as increased weight, galvanic corrosion, expensive integration and repair costs. In the present study, authors introduce a novel, easy to apply and all-polymeric LSP material. A doped intrinsic conductive polymer i.e. Polyaniline (PANI) dispersed in a thermosetting cross-linking polymer divinylbenzene (DVB) has been used to prepare an adhesive layer of 0.25–0.4 mm thickness. CFRP structure coated with PANI-based LSP layer, when tested against simulated lightning impulse current of 100 kA, demonstrated effective dissipation of the current, rendering almost 100% safety to the CFRP structure. PANI showed the capability to create a 3-D conductive network due to its self-assembling property, which makes it superior compared to its counterpart carbon/metal nano-filler based LSP technologies. Almost 100% residual strength of PANI-LSP protected CFRPs is reported in this work.},
doi = {10.1016/j.compscitech.2019.01.006},
journal = {Composites Science and Technology},
number = C,
volume = 172,
place = {United States},
year = {Wed Jan 09 00:00:00 EST 2019},
month = {Wed Jan 09 00:00:00 EST 2019}
}
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Works referenced in this record:
Experimental study to assess the effect of carbon nanotube addition on the through-thickness electrical conductivity of CFRP laminates for aircraft applications
journal, July 2015
- Lin, Yueguo; Gigliotti, Marco; Lafarie-Frenot, Marie Christine
- Composites Part B: Engineering, Vol. 76
Electrical and thermal property enhancement of fiber-reinforced polymer laminate composites through controlled implementation of multi-walled carbon nanotubes
journal, November 2012
- Yamamoto, Namiko; Guzman de Villoria, Roberto; Wardle, Brian L.
- Composites Science and Technology, Vol. 72, Issue 16
The enhancement effect of carbon-based nano-fillers/polyaniline hybrids on the through-thickness electric conductivity of carbon fiber reinforced polymer
journal, February 2018
- Cheng, Xiuyan; Yokozeki, Tomohiro; Wu, Lixin
- Composites Part A: Applied Science and Manufacturing, Vol. 105
Damage response of composites coated with conducting materials subjected to emulated lightning strikes
journal, February 2018
- Rajesh, P. S. M.; Sirois, Frederic; Therriault, Daniel
- Materials & Design, Vol. 139
Lightning strike protection of composites
journal, January 2014
- Gagné, Martin; Therriault, Daniel
- Progress in Aerospace Sciences, Vol. 64
The combination of carbon nanotube buckypaper and insulating adhesive for lightning strike protection of the carbon fiber/epoxy laminates
journal, November 2015
- Han, Jin-hua; Zhang, Hui; Chen, Ming-ji
- Carbon, Vol. 94
Residual mechanical properties of carbon fibre reinforced thermoplastics with thin-ply prepreg after simulated lightning strike
journal, October 2017
- Yamashita, Shinichiro; Hirano, Yoshiyasu; Sonehara, Takeo
- Composites Part A: Applied Science and Manufacturing, Vol. 101
Electrochemical investigations of the anticorrosive and electrochromic properties of electroactive polyamide
journal, February 2012
- Huang, Tsao-Cheng; Yeh, Tzu-Chun; Huang, Hsiu-Ying
- Electrochimica Acta, Vol. 63
A new approach to enhancing interlaminar strength and galvanic corrosion resistance of CFRP/Mg laminates
journal, February 2018
- Pan, Yingcai; Wu, Xuan; Huang, Zheng
- Composites Part A: Applied Science and Manufacturing, Vol. 105
Effects of heavy lightning strikes on pristine and repaired carbon composite structures
journal, February 2017
- Wolfrum, Johannes; Schuster, Thomas J.; Körwien, Thomas
- Journal of Composite Materials, Vol. 51, Issue 25
Fabrication of an enriched graphene surface protection of carbon fiber/epoxy composites for lightning strike via a percolating-assisted resin film infusion method
journal, April 2018
- Wang, Ben; Duan, Yugang; Xin, Zhibo
- Composites Science and Technology, Vol. 158
Carbon nanofiber paper for lightning strike protection of composite materials
journal, March 2010
- Gou, Jihua; Tang, Yong; Liang, Fei
- Composites Part B: Engineering, Vol. 41, Issue 2
Thermal Analysis of Montmorillonite/Graphene Double-Layer Coating as a Potential Lightning Strike Protective Layer for Cross-Linked Epoxy by Molecular Dynamics Simulation
journal, May 2018
- Rahmani, Farzin; Nouranian, Sasan
- ACS Applied Nano Materials, Vol. 1, Issue 6
Electrical conductivity and interlaminar shear strength enhancement of carbon fiber reinforced polymers through synergetic effect between graphene oxide and polyaniline
journal, November 2016
- Cheng, Xiuyan; Yokozeki, Tomohiro; Wu, Lixin
- Composites Part A: Applied Science and Manufacturing, Vol. 90
Fabrication and assessment of a thin flexible surface coating made of pristine graphene for lightning strike protection
journal, February 2017
- Zhang, B.; Soltani, S. A.; Le, L. N.
- Materials Science and Engineering: B, Vol. 216
Aircraft Structure Paint Thickness and Lightning Swept Stroke Damages
journal, July 2013
- Moupfouma, Fidele
- SAE International Journal of Aerospace, Vol. 6, Issue 2
Multi-Functional Carbon Fibre Composites using Carbon Nanotubes as an Alternative to Polymer Sizing
journal, November 2016
- Pozegic, T. R.; Anguita, J. V.; Hamerton, I.
- Scientific Reports, Vol. 6, Issue 1
A review of recent research on mechanics of multifunctional composite materials and structures
journal, November 2010
- Gibson, Ronald F.
- Composite Structures, Vol. 92, Issue 12
Epoxy resin/polyetherimide/carbon black conductive polymer composites with a double percolation structure by reaction-induced phase separation
journal, June 2012
- Ma, C. Guo; Xi, D. Yong; Liu, M.
- Journal of Composite Materials, Vol. 47, Issue 9
Improved electrical conductivity of NCF-reinforced CFRP for higher damage resistance to lightning strike
journal, September 2017
- Rehbein, Johannes; Wierach, Peter; Gries, Thomas
- Composites Part A: Applied Science and Manufacturing, Vol. 100
Lightning damage suppression in a carbon fiber-reinforced polymer with a polyaniline-based conductive thermoset matrix
journal, April 2016
- Hirano, Yoshiyasu; Yokozeki, Tomohiro; Ishida, Yuichi
- Composites Science and Technology, Vol. 127
Development and characterization of CFRP using a polyaniline-based conductive thermoset matrix
journal, September 2015
- Yokozeki, Tomohiro; Goto, Teruya; Takahashi, Tatsuhiro
- Composites Science and Technology, Vol. 117
Synthesis and characterization of the electrically conductive polymeric composite for lightning strike protection of aircraft structures
journal, January 2017
- Katunin, Andrzej; Krukiewicz, Katarzyna; Turczyn, Roman
- Composite Structures, Vol. 159
Lightning strike resistance of an electrically conductive CFRP with a CSA-doped PANI/epoxy matrix
journal, December 2017
- Katunin, Andrzej; Krukiewicz, Katarzyna; Turczyn, Roman
- Composite Structures, Vol. 181
Irreversible tunability of through-thickness electrical conductivity of polyaniline-based CFRP by de-doping
journal, November 2017
- Kumar, Vipin; Yokozeki, Tomohiro; Goto, Teruya
- Composites Science and Technology, Vol. 152
Mechanical and electrical properties of PANI-based conductive thermosetting composites
journal, May 2015
- Kumar, V.; Yokozeki, T.; Goto, T.
- Journal of Reinforced Plastics and Composites, Vol. 34, Issue 16
Self-assembly of the electroactive complexes of polyaniline and surfactant
journal, August 1995
- Zheng, Wen-Yue; Wang, Rong-Hai; Levon, Kalle
- Macromolecular Chemistry and Physics, Vol. 196, Issue 8
Studies on properties of polyaniline-dodecylbenzene sulfonic acid composite films synthesized using different oxidants
journal, August 2009
- Basavaraja, C.; Pierson, R.; Huh, Do Sung
- Macromolecular Research, Vol. 17, Issue 8
Corrosion prevention with an organic metal (polyaniline): corrosion test results
journal, January 1999
- Wessling, Bernhard; Posdorfer, Joerg
- Electrochimica Acta, Vol. 44, Issue 12
A comparative study of epoxy and polyurethane based coatings containing polyaniline-DBSA pigments for corrosion protection on mild steel
journal, May 2013
- Diniz, F. B.; De Andrade, G. F.; Martins, C. R.
- Progress in Organic Coatings, Vol. 76, Issue 5
Corrosion protection of mild steel by coatings containing polyaniline
journal, April 1995
- Lu, Wei-Kang; Elsenbaumer, Ronald L.; Wessling, Bernhard
- Synthetic Metals, Vol. 71, Issue 1-3
Effect of processing temperature on thermal doping of polyaniline without shear
journal, May 2011
- Goto, Teruya; Awano, Hiroshi; Takahashi, Tatsuhiro
- Polymers for Advanced Technologies, Vol. 22, Issue 8
Significantly improved electrical and interlaminar mechanical properties of carbon fiber laminated composites by using special carbon nanotube pre-dispersion mixture
journal, April 2017
- Guo, Jian; Zhang, Qingjie; Gao, Liang
- Composites Part A: Applied Science and Manufacturing, Vol. 95
Effect of through-thickness electrical conductivity of CFRPs on lightning strike damages
journal, November 2018
- Kumar, Vipin; Yokozeki, Tomohiro; Okada, Takao
- Composites Part A: Applied Science and Manufacturing, Vol. 114
Mechanical and Electrical Properties of Solution-Processed Polyaniline/Multiwalled Carbon Nanotube Composite Films
journal, January 2004
- Ramamurthy, Praveen C.; Harrell, William R.; Gregory, Richard V.
- Journal of The Electrochemical Society, Vol. 151, Issue 8
Artificial lightning testing on graphite/epoxy composite laminate
journal, October 2010
- Hirano, Yoshiyasu; Katsumata, Shingo; Iwahori, Yutaka
- Composites Part A: Applied Science and Manufacturing, Vol. 41, Issue 10
Lightning strike damage behavior of carbon fiber reinforced epoxy, bismaleimide, and polyetheretherketone composites
journal, June 2018
- Kamiyama, Shintaro; Hirano, Yoshiyasu; Okada, Takao
- Composites Science and Technology, Vol. 161
Thermal degradation of polyaniline films prepared in solutions of strong and weak acids and in water – FTIR and Raman spectroscopic studies
journal, December 2008
- Šeděnková, Ivana; Trchová, Miroslava; Stejskal, Jaroslav
- Polymer Degradation and Stability, Vol. 93, Issue 12
Works referencing / citing this record:
Novel Unsaturated Polyester Nanocomposites via Hybrid 3D POSS-Modified Graphene Oxide Reinforcement: Electro-Technical Application Perspective
journal, February 2020
- Divakaran, Nidhin; Kale, Manoj B.; Senthil, T.
- Nanomaterials, Vol. 10, Issue 2
Research on the Blow-Off Impulse Effect of a Composite Reinforced Panel Subjected to Lightning Strike
journal, March 2019
- Jia, Senqing; Wang, Fusheng; Huang, Weichao
- Applied Sciences, Vol. 9, Issue 6