Synthesis of Nickel-Doped Ceria Catalysts for Selective Acetylene Hydrogenation
Abstract
Abstract Metallic nickel is known to be an active, but not a selective hydrogenation catalyst for conversion of alkynes to alkenes. On the other hand, nickel oxide is not active. Recently, we have demonstrated that nickel doped into ceria provides an inexpensive catalyst for selective hydrogenation of acetylene in the presence of ethylene. Here, we evaluate various synthesis methods to achieve optimal selective hydrogenation performance. We examined incipient wetness impregnation, coprecipitation, solution combustion, and sol‐gel synthesis to study how the method of preparation affects catalytic structure and behavior. Sol‐gel synthesis, coprecipitation, and solution combustion synthesis methods favor nickel incorporation into the ceria lattice, while incipient wetness impregnation creates segregated nickel species on the ceria surface. For hydrogenation of acetylene, these nickel surface species lead to poor ethylene selectivity due to ethane and oligomer formation. However, when nickel is incorporated into the ceria lattice, ethane formation is prevented even while achieving 100 % conversion of acetylene. Coke formation is also significantly reduced on these catalysts compared to conventional nanoparticle counterparts. We conclude that sol‐gel synthesis provides the optimal method for creating a uniform dopant distribution within the high surface area ceria.
- Authors:
-
- Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemical and Biological Engineering, and Center for Microengineered Materials
- Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry and Chemical Biology; Jingdezhen Ceramic Inst. (China). Dept. of Material Science and Engineering
- Fuzhou Univ. (China). State Key Lab. of Photocatalysis on Energy and Environment
- Univ. of KwaZulu-Natal, Durban (South Africa). School of Chemistry and Physics, Catalysis Research Group
- Univ. of New Mexico, Albuquerque, NM (United States). Center for Stable Isotopes
- Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry and Chemical Biology
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1530590
- Alternate Identifier(s):
- OSTI ID: 1494787
- Grant/Contract Number:
- FG02-05ER15712
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemCatChem
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 5; Journal ID: ISSN 1867-3880
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; acetylene hydrogenation; catalyst synthesis; ceria; nickel; selective hydrogenation
Citation Formats
Riley, Christopher, De La Riva, Andrew, Zhou, Shulan, Wan, Qiang, Peterson, Eric, Artyushkova, Kateryna, Farahani, Majid D., Friedrich, Holger B., Burkemper, Laura, Atudorei, Nicu‐Viorel, Lin, Sen, Guo, Hua, and Datye, Abhaya. Synthesis of Nickel-Doped Ceria Catalysts for Selective Acetylene Hydrogenation. United States: N. p., 2019.
Web. doi:10.1002/cctc.201801976.
Riley, Christopher, De La Riva, Andrew, Zhou, Shulan, Wan, Qiang, Peterson, Eric, Artyushkova, Kateryna, Farahani, Majid D., Friedrich, Holger B., Burkemper, Laura, Atudorei, Nicu‐Viorel, Lin, Sen, Guo, Hua, & Datye, Abhaya. Synthesis of Nickel-Doped Ceria Catalysts for Selective Acetylene Hydrogenation. United States. https://doi.org/10.1002/cctc.201801976
Riley, Christopher, De La Riva, Andrew, Zhou, Shulan, Wan, Qiang, Peterson, Eric, Artyushkova, Kateryna, Farahani, Majid D., Friedrich, Holger B., Burkemper, Laura, Atudorei, Nicu‐Viorel, Lin, Sen, Guo, Hua, and Datye, Abhaya. Tue .
"Synthesis of Nickel-Doped Ceria Catalysts for Selective Acetylene Hydrogenation". United States. https://doi.org/10.1002/cctc.201801976. https://www.osti.gov/servlets/purl/1530590.
@article{osti_1530590,
title = {Synthesis of Nickel-Doped Ceria Catalysts for Selective Acetylene Hydrogenation},
author = {Riley, Christopher and De La Riva, Andrew and Zhou, Shulan and Wan, Qiang and Peterson, Eric and Artyushkova, Kateryna and Farahani, Majid D. and Friedrich, Holger B. and Burkemper, Laura and Atudorei, Nicu‐Viorel and Lin, Sen and Guo, Hua and Datye, Abhaya},
abstractNote = {Abstract Metallic nickel is known to be an active, but not a selective hydrogenation catalyst for conversion of alkynes to alkenes. On the other hand, nickel oxide is not active. Recently, we have demonstrated that nickel doped into ceria provides an inexpensive catalyst for selective hydrogenation of acetylene in the presence of ethylene. Here, we evaluate various synthesis methods to achieve optimal selective hydrogenation performance. We examined incipient wetness impregnation, coprecipitation, solution combustion, and sol‐gel synthesis to study how the method of preparation affects catalytic structure and behavior. Sol‐gel synthesis, coprecipitation, and solution combustion synthesis methods favor nickel incorporation into the ceria lattice, while incipient wetness impregnation creates segregated nickel species on the ceria surface. For hydrogenation of acetylene, these nickel surface species lead to poor ethylene selectivity due to ethane and oligomer formation. However, when nickel is incorporated into the ceria lattice, ethane formation is prevented even while achieving 100 % conversion of acetylene. Coke formation is also significantly reduced on these catalysts compared to conventional nanoparticle counterparts. We conclude that sol‐gel synthesis provides the optimal method for creating a uniform dopant distribution within the high surface area ceria.},
doi = {10.1002/cctc.201801976},
journal = {ChemCatChem},
number = 5,
volume = 11,
place = {United States},
year = {Tue Jan 15 00:00:00 EST 2019},
month = {Tue Jan 15 00:00:00 EST 2019}
}
Web of Science
Works referenced in this record:
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Studies of the cerium-metal–oxygen–hydrogen system (metal=Cu, Ni)
journal, April 1999
- Lamonier, C.; Ponchel, A.; D'Huysser, A.
- Catalysis Today, Vol. 50, Issue 2
Identification of Non-Precious Metal Alloy Catalysts for Selective Hydrogenation of Acetylene
journal, June 2008
- Studt, F.; Abild-Pedersen, F.; Bligaard, T.
- Science, Vol. 320, Issue 5881
Hydrogen storage in CeNiXOY and CeM0.5NiXOY (M=Zr or Al) mixed oxides
journal, November 2008
- Jalowiecki-Duhamel, L.; Debeusscher, S.; Zarrou, H.
- Catalysis Today, Vol. 138, Issue 3-4
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Functionalization of CeO 2 (1 1 1) by Deposition of Small Ni Clusters: Effects on CO 2 Adsorption and O Vacancy Formation
journal, January 2015
- Hahn, Konstanze R.; Seitsonen, Ari P.; Iannuzzi, Marcella
- ChemCatChem, Vol. 7, Issue 4
Challenges in the use of density functional theory to examine catalysis by M-doped ceria surfaces
journal, October 2013
- Krcha, Matthew D.; Janik, Michael J.
- International Journal of Quantum Chemistry, Vol. 114, Issue 1
Hydrogenation of nitrobenzene over a nickel boride catalyst
journal, June 1982
- Collins, Dermot J.; Smith, Andrew D.; Davis, Burtron H.
- Industrial & Engineering Chemistry Product Research and Development, Vol. 21, Issue 2
Molecular-Level Understanding of CeO 2 as a Catalyst for Partial Alkyne Hydrogenation
journal, January 2014
- Carrasco, Javier; Vilé, Gianvito; Fernández-Torre, Delia
- The Journal of Physical Chemistry C, Vol. 118, Issue 10
Unique Reaction Path in Heterogeneous Catalysis: The Concerted Semi-Hydrogenation of Propyne to Propene on CeO 2
journal, October 2014
- García-Melchor, Max; Bellarosa, Luca; López, Núria
- ACS Catalysis, Vol. 4, Issue 11
Ni/CeO2 catalysts for methane partial oxidation: Synthesis driven structural and catalytic effects
journal, July 2016
- Pantaleo, G.; Parola, V. La; Deganello, F.
- Applied Catalysis B: Environmental, Vol. 189
Ag Alloyed Pd Single-Atom Catalysts for Efficient Selective Hydrogenation of Acetylene to Ethylene in Excess Ethylene
journal, May 2015
- Pei, Guang Xian; Liu, Xiao Yan; Wang, Aiqin
- ACS Catalysis, Vol. 5, Issue 6
Study of ceria-supported nickel catalyst and effect of yttria doping on carbon dioxide reforming of methane
journal, September 2001
- Wang, Jenshi B.; Tai, Yu-Lung; Dow, Wei-Ping
- Applied Catalysis A: General, Vol. 218, Issue 1-2
Palladium–gallium intermetallic compounds for the selective hydrogenation of acetylenePart I: Preparation and structural investigation under reaction conditions
journal, August 2008
- Osswald, J.; Giedigkeit, R.; Jentoft, R.
- Journal of Catalysis, Vol. 258, Issue 1
Transfer hydrogenation of ketones by ceria-supported Ni catalysts
journal, January 2012
- Shimura, Katsuya; Shimizu, Ken-ichi
- Green Chemistry, Vol. 14, Issue 11
Enhanced oxygen vacancy formation in ceria (111) and (110) surfaces doped with divalent cations
journal, January 2011
- Nolan, Michael
- Journal of Materials Chemistry, Vol. 21, Issue 25
Reverse water gas shift reaction over Co-precipitated Ni-CeO2 catalysts
journal, February 2008
- Wang, Luhui; Zhang, Shaoxing; Liu, Yuan
- Journal of Rare Earths, Vol. 26, Issue 1
Zinc inclusion to heterogeneous nickel catalysts reduces oligomerization during the semi-hydrogenation of acetylene
journal, July 2014
- Spanjers, Charles S.; Held, Jacob T.; Jones, Michael J.
- Journal of Catalysis, Vol. 316
NiO/Ce 1−x Ni x O 2−δ as an alternative to noble metal catalysts for CO oxidation
journal, January 2013
- Mahammadunnisa, Sk.; Manoj Kumar Reddy, P.; Lingaiah, N.
- Catal. Sci. Technol., Vol. 3, Issue 3
Effect of incorporation of copper or nickel on hydrogen storage in ceria. Mechanism of reduction
journal, January 1996
- Wrobel, Genèvieve; Lamonier, Carole; Bennani, Abdelrhani
- J. Chem. Soc., Faraday Trans., Vol. 92, Issue 11
The selective hydrogenation of acetylene over a Ni/SiO2 catalyst in the presence and absence of carbon monoxide
journal, February 2010
- Trimm, David L.; Liu, Irene O. Y.; Cant, Noel W.
- Applied Catalysis A: General, Vol. 374, Issue 1-2
New interpretations of XPS spectra of nickel metal and oxides
journal, May 2006
- Grosvenor, Andrew P.; Biesinger, Mark C.; Smart, Roger St. C.
- Surface Science, Vol. 600, Issue 9
Fast and selective homogeneous hydrogenation with nickel(II) phosphane catalysts
journal, January 1998
- Angulo, Ingrid M.; Kluwer, Alexander M.; Bouwman, Elisabeth
- Chemical Communications, Issue 24
Structural incoherency and structure reversal in bimetallic nanoclusters
journal, February 2005
- Liu, H. B.; Pal, U.; Medina, A.
- Physical Review B, Vol. 71, Issue 7
The Effect of Exposed Facets of Ceria to the Nickel Species in Nickel-Ceria Catalysts and Their Performance in a NO + CO Reaction
journal, November 2015
- Tang, Ke; Liu, Wei; Li, Jing
- ACS Applied Materials & Interfaces, Vol. 7, Issue 48
Stereo- and Chemoselective Character of Supported CeO 2 Catalysts for Continuous-Flow Three-Phase Alkyne Hydrogenation
journal, June 2014
- Vilé, Gianvito; Wrabetz, Sabine; Floryan, Leonard
- ChemCatChem, Vol. 6, Issue 7
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Mesoporous NiO–CeO2 catalysts for CO oxidation: Nickel content effect and mechanism aspect
journal, March 2015
- Tang, Changjin; Li, Jianchao; Yao, Xiaojiang
- Applied Catalysis A: General, Vol. 494
The selective hydrogenation of acetylene in the presence of carbon monoxide over Ni and Ni–Zn supported on MgAl2O4
journal, December 2011
- Trimm, David L.; Cant, Noel W.; Liu, Irene O. Y.
- Catalysis Today, Vol. 178, Issue 1
Special points for Brillouin-zone integrations
journal, June 1976
- Monkhorst, Hendrik J.; Pack, James D.
- Physical Review B, Vol. 13, Issue 12, p. 5188-5192
Understanding All-Solid Frustrated-Lewis-Pair Sites on CeO 2 from Theoretical Perspectives
journal, December 2017
- Huang, Zheng-Qing; Liu, Li-Ping; Qi, Suitao
- ACS Catalysis, Vol. 8, Issue 1
Design of Effective Catalysts for Selective Alkyne Hydrogenation by Doping of Ceria with a Single-Atom Promotor
journal, September 2018
- Riley, Christopher; Zhou, Shulan; Kunwar, Deepak
- Journal of the American Chemical Society, Vol. 140, Issue 40
The oligomerization of acetylene in hydrogen over Ni/SiO2 catalysts: Product distribution and pathways
journal, June 2008
- Trimm, David L.; Liu, Irene O. Y.; Cant, Noel W.
- Journal of Molecular Catalysis A: Chemical, Vol. 288, Issue 1-2
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Ceria in Hydrogenation Catalysis: High Selectivity in the Conversion of Alkynes to Olefins
journal, July 2012
- Vilé, Gianvito; Bridier, Blaise; Wichert, Jonas
- Angewandte Chemie International Edition, Vol. 51, Issue 34
Precursor influence and catalytic behaviour of Ni/CeO2 and Ni/SiC catalysts for the tri-reforming process
journal, July 2012
- García-Vargas, Jesús Manuel; Valverde, José Luís; de Lucas-Consuegra, Antonio
- Applied Catalysis A: General, Vol. 431-432
Physics of Nickel Clusters: Energetics and Equilibrium Geometries
journal, February 1997
- Nayak, Saroj K.; Khanna, S. N.; Rao, B. K.
- The Journal of Physical Chemistry A, Vol. 101, Issue 6
Spectroscopic Studies of Nickel(II) and Nickel(III) Species Generated upon Thermal Treatments of Nickel/Ceria-Supported Materials
journal, January 1996
- Davidson, A.; Tempere, J. F.; Che, M.
- The Journal of Physical Chemistry, Vol. 100, Issue 12
Effect of Zn Content on Catalytic Activity and Physicochemical Properties of Ni-Based Catalysts for Selective Hydrogenation of Acetylene
journal, October 1997
- Rodrı́guez, J. C.; Marchi, A. J.; Borgna, A.
- Journal of Catalysis, Vol. 171, Issue 1
Characterization and catalytic properties of Ni–Sn intermetallic compounds in acetylene hydrogenation
journal, January 2000
- Onda, Ayumu; Komatsu, Takayuki; Yashima, Tatsuaki
- Physical Chemistry Chemical Physics, Vol. 2, Issue 13
CeNixOy and CeAlzNixOy solids studied by electron microscopy, XRD, XPS and depth sputtering techniques
journal, January 2000
- Ponchel, Anne; D'Huysser, Alain; Lamonier, Carole
- Physical Chemistry Chemical Physics, Vol. 2, Issue 2
Opposite Face Sensitivity of CeO 2 in Hydrogenation and Oxidation Catalysis
journal, August 2014
- Vilé, Gianvito; Colussi, Sara; Krumeich, Frank
- Angewandte Chemie International Edition, Vol. 53, Issue 45
Advances in the Design of Nanostructured Catalysts for Selective Hydrogenation
journal, December 2015
- Vilé, Gianvito; Albani, Davide; Almora-Barrios, Neyvis
- ChemCatChem, Vol. 8, Issue 1
Atomic carbon adsorption on Ni nanoclusters: a DFT study
journal, March 2010
- Wang, Qiang; Lim, Kok Hwa; Yang, Shuo-Wang
- Theoretical Chemistry Accounts, Vol. 128, Issue 1
Influence of the support on the catalytic properties of nickel/ceria in carbon monoxide and benzene hydrogenation
journal, January 1989
- Barrault, J.; Alouche, A.; Paul-Boncour, V.
- Applied Catalysis, Vol. 46, Issue 2
Acetylene and Ethylene Hydrogenation on Alumina Supported Pd-Ag Model Catalysts
journal, May 2006
- Khan, N. A.; Shaikhutdinov, S.; Freund, H. -J.
- Catalysis Letters, Vol. 108, Issue 3-4
Electronic and Atomistic Structures of Clean and Reduced Ceria Surfaces
journal, December 2005
- Fabris, Stefano; Vicario, Gianpaolo; Balducci, Gabriele
- The Journal of Physical Chemistry B, Vol. 109, Issue 48
Biogas reforming for syngas production over nickel supported on ceria–alumina catalysts
journal, November 2012
- Bereketidou, O. A.; Goula, M. A.
- Catalysis Today, Vol. 195, Issue 1
Opposite Face Sensitivity of CeO 2 in Hydrogenation and Oxidation Catalysis
journal, August 2014
- Vilé, Gianvito; Colussi, Sara; Krumeich, Frank
- Angewandte Chemie, Vol. 126, Issue 45
Ceria in Hydrogenation Catalysis: High Selectivity in the Conversion of Alkynes to Olefins
journal, July 2012
- Vilé, Gianvito; Bridier, Blaise; Wichert, Jonas
- Angewandte Chemie, Vol. 124, Issue 34
High-resolution X-ray luminescence extension imaging
journal, February 2021
- Ou, Xiangyu; Qin, Xian; Huang, Bolong
- Nature, Vol. 590, Issue 7846
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect
journal, February 2020
- Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna
- Scientific Reports, Vol. 10, Issue 1
Spectroscopic Studies of Nickel(II) and Nickel(III) Species Generated upon Thermal Treatments of Nickel/Ceria-Supported Materials
journal, January 1996
- Davidson, A.; Tempere, J. F.; Che, M.
- The Journal of Physical Chemistry, Vol. 100, Issue 41
Works referencing / citing this record:
Ni–Cu/Al 2 O 3 catalysts for the selective hydrogenation of acetylene: a study on catalytic performance and reaction mechanism
journal, January 2019
- Hu, Ningmeng; Yang, Chenghuan; He, Liang
- New Journal of Chemistry, Vol. 43, Issue 46