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Title: Bimetallic nickel-lutetium complexes: tuning the properties and catalytic hydrogenation activity of the Ni site by varying the Lu coordination environment

Abstract

We present three heterobimetallic complexes containing an isostructural nickel center and a lutetium ion in varying coordination environments. The bidentate iPr2PCH2NHPh and nonadentate (iPr2PCH2NHAr)3tacn ligands were used to prepare the Lu metalloligands, Lu(iPr2PCH2NPh)3 (1) and Lu{(iPr2PCH2NAr)3tacn} (2), respectively. Reaction of Ni(COD)2 (where COD is 1,5-cyclooctadiene) and 1 afforded NiLu(iPr2PCH2NPh)3 (3), with a Lu coordination number (CN) of 4 and a Ni–Lu distance, d(Ni–Lu), of 2.4644(2) Å. Complex 3 can further bind THF to form 3-THF, increasing both the Lu CN to 5 and d(Ni–Lu) to 2.5989(4) Å. On the other hand, incorporation of Ni(0) into 2 provides NiLu{(iPr2PCH2NAr)3tacn} (4), in which the Lu coordination environment is more saturated (CN = 6), and the d(Ni–Lu) is substantially elongated at 2.9771(5) Å. Cyclic voltammetry of the three Ni–Lu complexes shows an overall ~410 mV shift in the Ni(0/I) redox couple, suggesting tunability of the Ni electronics across the series. Computational studies reveal polarized bonding interactions between the Ni 3dz2 (major) and the Lu 5dz2 (minor) orbitals, where the percentage of Lu character increases in the order: 4 (6.0% Lu 5dz2) < 3-THF (8.5%) < 3 (9.3%). All three Ni–Lu complexes bind H2 at low temperatures (-30 to -80 °C) and are competentmore » catalysts for styrene hydrogenation. Complex 3 outperforms 4 with a four-fold faster rate. Additionally, adding increasing THF equivalents to 3, which would favor build-up of 3-THF, decreases the rate. We propose that altering the coordination sphere of the Lu support can influence the resulting properties and catalytic activity of the active Ni(0) metal center.« less

Authors:
ORCiD logo [1]; ORCiD logo [2];  [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Chemistry, University of Minnesota, Minneapolis, USA
  2. Department of Chemistry, University of Minnesota, Minneapolis, USA, Minnesota Supercomputing Institute
Publication Date:
Research Org.:
Univ. of Minnesota, Minneapolis, MN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); American Chemical Society Petroleum Research Fund; National Science Foundation (NSF)
OSTI Identifier:
1494776
Alternate Identifier(s):
OSTI ID: 1610663
Grant/Contract Number:  
SC0002183
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 10 Journal Issue: 11; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United Kingdom
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Chemistry

Citation Formats

Ramirez, Bianca L., Sharma, Prachi, Eisenhart, Reed J., Gagliardi, Laura, and Lu, Connie C. Bimetallic nickel-lutetium complexes: tuning the properties and catalytic hydrogenation activity of the Ni site by varying the Lu coordination environment. United Kingdom: N. p., 2019. Web. doi:10.1039/C8SC04712J.
Ramirez, Bianca L., Sharma, Prachi, Eisenhart, Reed J., Gagliardi, Laura, & Lu, Connie C. Bimetallic nickel-lutetium complexes: tuning the properties and catalytic hydrogenation activity of the Ni site by varying the Lu coordination environment. United Kingdom. doi:https://doi.org/10.1039/C8SC04712J
Ramirez, Bianca L., Sharma, Prachi, Eisenhart, Reed J., Gagliardi, Laura, and Lu, Connie C. Wed . "Bimetallic nickel-lutetium complexes: tuning the properties and catalytic hydrogenation activity of the Ni site by varying the Lu coordination environment". United Kingdom. doi:https://doi.org/10.1039/C8SC04712J.
@article{osti_1494776,
title = {Bimetallic nickel-lutetium complexes: tuning the properties and catalytic hydrogenation activity of the Ni site by varying the Lu coordination environment},
author = {Ramirez, Bianca L. and Sharma, Prachi and Eisenhart, Reed J. and Gagliardi, Laura and Lu, Connie C.},
abstractNote = {We present three heterobimetallic complexes containing an isostructural nickel center and a lutetium ion in varying coordination environments. The bidentate iPr2PCH2NHPh and nonadentate (iPr2PCH2NHAr)3tacn ligands were used to prepare the Lu metalloligands, Lu(iPr2PCH2NPh)3 (1) and Lu{(iPr2PCH2NAr)3tacn} (2), respectively. Reaction of Ni(COD)2 (where COD is 1,5-cyclooctadiene) and 1 afforded NiLu(iPr2PCH2NPh)3 (3), with a Lu coordination number (CN) of 4 and a Ni–Lu distance, d(Ni–Lu), of 2.4644(2) Å. Complex 3 can further bind THF to form 3-THF, increasing both the Lu CN to 5 and d(Ni–Lu) to 2.5989(4) Å. On the other hand, incorporation of Ni(0) into 2 provides NiLu{(iPr2PCH2NAr)3tacn} (4), in which the Lu coordination environment is more saturated (CN = 6), and the d(Ni–Lu) is substantially elongated at 2.9771(5) Å. Cyclic voltammetry of the three Ni–Lu complexes shows an overall ~410 mV shift in the Ni(0/I) redox couple, suggesting tunability of the Ni electronics across the series. Computational studies reveal polarized bonding interactions between the Ni 3dz2 (major) and the Lu 5dz2 (minor) orbitals, where the percentage of Lu character increases in the order: 4 (6.0% Lu 5dz2) < 3-THF (8.5%) < 3 (9.3%). All three Ni–Lu complexes bind H2 at low temperatures (-30 to -80 °C) and are competent catalysts for styrene hydrogenation. Complex 3 outperforms 4 with a four-fold faster rate. Additionally, adding increasing THF equivalents to 3, which would favor build-up of 3-THF, decreases the rate. We propose that altering the coordination sphere of the Lu support can influence the resulting properties and catalytic activity of the active Ni(0) metal center.},
doi = {10.1039/C8SC04712J},
journal = {Chemical Science},
number = 11,
volume = 10,
place = {United Kingdom},
year = {2019},
month = {3}
}

Journal Article:
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DOI: https://doi.org/10.1039/C8SC04712J

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Works referenced in this record:

Molecular Single-Bond Covalent Radii for Elements 1-118
journal, January 2009

  • Pyykkö, Pekka; Atsumi, Michiko
  • Chemistry - A European Journal, Vol. 15, Issue 1
  • DOI: 10.1002/chem.200800987

Molecular [Yb(TM)2] Intermetalloids (TM=Ru, Re)
journal, August 2010

  • Döring, Christian; Dietel, Anna-Maria; Butovskii, Mikhail V.
  • Chemistry - A European Journal, Vol. 16, Issue 35
  • DOI: 10.1002/chem.201001310

Bimetallic lanthanide complexes with lanthanide-transition metal bonds. Molecular structure of (C4H8O)(C5H5)2LuRu(CO)2(C5H5). The use of 139La NMR spectroscopy
journal, April 1993

  • Beletskaya, I. P.; Voskoboynikov, A. Z.; Chuklanova, E. B.
  • Journal of the American Chemical Society, Vol. 115, Issue 8
  • DOI: 10.1021/ja00061a015

Reversible H 2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis
journal, March 2012

  • Harman, W. Hill; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 134, Issue 11
  • DOI: 10.1021/ja211419t

Synthesis and Structures of Novel Discrete Ni(II)–Ln(III) Heterodinuclear Complexes (Ln = Gd or Lu)
journal, May 2003

  • Kondoh, Nobuyuki; Shimizu, Yuko; Kurihara, Masato
  • Bulletin of the Chemical Society of Japan, Vol. 76, Issue 5
  • DOI: 10.1246/bcsj.76.1007

Metal–Metal Bonding in Uranium–Group 10 Complexes
journal, March 2016

  • Hlina, Johann A.; Pankhurst, James R.; Kaltsoyannis, Nikolas
  • Journal of the American Chemical Society, Vol. 138, Issue 10
  • DOI: 10.1021/jacs.5b10698

Atomic Radii and Interatomic Distances in Metals
journal, March 1947

  • Pauling, Linus
  • Journal of the American Chemical Society, Vol. 69, Issue 3
  • DOI: 10.1021/ja01195a024

Alkene Hydrogenation Catalyzed by Nickel Hydride Complexes of an Aliphatic PNP Pincer Ligand
journal, August 2012

  • Vasudevan, Kalyan V.; Scott, Brian L.; Hanson, Susan K.
  • European Journal of Inorganic Chemistry, Vol. 2012, Issue 30
  • DOI: 10.1002/ejic.201200758

Tailoring the Catalytic Properties of Metal Nanoparticles via Support Interactions
journal, August 2016

  • Ahmadi, M.; Mistry, H.; Roldan Cuenya, B.
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 17
  • DOI: 10.1021/acs.jpclett.6b01198

dlf Complexes with Uniform Coordination Geometry:  Structural and Magnetic Properties of an LnNi2 Core Supported by a Heptadentate Amine Phenol Ligand
journal, March 2003

  • Bayly, Simon R.; Xu, Zhiquiang; Patrick, Brian O.
  • Inorganic Chemistry, Vol. 42, Issue 5
  • DOI: 10.1021/ic0205278

Metal–dioxygen and metal–dinitrogen complexes: where are the electrons?
journal, January 2010

  • Holland, Patrick L.
  • Dalton Transactions, Vol. 39, Issue 23
  • DOI: 10.1039/c001397h

Towards understanding of lanthanide–transition metal bonding: investigations of the first Ce–Fe bonded complex
journal, January 2018

  • Burns, Corey P.; Yang, Xin; Sung, Siyoung
  • Chemical Communications, Vol. 54, Issue 77
  • DOI: 10.1039/C8CC05243C

Bimetallic rare-earth/platinum complexes ligated by phosphinoamides
journal, January 2016

  • Völcker, Franziska; Roesky, Peter W.
  • Dalton Transactions, Vol. 45, Issue 23
  • DOI: 10.1039/C6DT00417B

Stoichiometric and Catalytic Reactions of Thermally Stable Nickel(0) NHC Complexes
journal, January 2012

  • Wu, Jianguo; Faller, John W.; Hazari, Nilay
  • Organometallics, Vol. 31, Issue 3
  • DOI: 10.1021/om300045t

Axial Bonding Capabilities of Square Planar d 8 -ML 4 Complexes. Theoretical Study and Structural Correlations
journal, January 1996

  • Aullón, Gabriel; Alvarez, Santiago
  • Inorganic Chemistry, Vol. 35, Issue 11
  • DOI: 10.1021/ic951643w

An unsupported transition metal–lanthanide bond; synthesis and crystal structure of an Nd–Fe amido N-heterocyclic carbene complex
journal, January 2009

  • Arnold, Polly L.; McMaster, Jonathan; Liddle, Stephen T.
  • Chem. Commun., Issue 7
  • DOI: 10.1039/B819072K

Metal-only Lewis pairs between group 10 metals and Tl( i ) or Ag( i ): insights into the electronic consequences of Z-type ligand binding
journal, January 2015

  • Barnett, Brandon R.; Moore, Curtis E.; Chandrasekaran, Perumalreddy
  • Chemical Science, Vol. 6, Issue 12
  • DOI: 10.1039/C5SC03104D

Determination of Association Constants (Ka) from Solution NMR Data
journal, August 2000


Rare earth–metal bonding in molecular compounds: recent advances, challenges, and perspectives
journal, January 2015

  • Butovskii, Mikhail V.; Kempe, Rhett
  • New Journal of Chemistry, Vol. 39, Issue 10
  • DOI: 10.1039/C5NJ00802F

Selectivity Effects in Bimetallic Catalysis
journal, February 2016


Hydrocarbon-Soluble Nanocatalysts with No Bulk Phase: Coplanar, Two-Coordinate Arrays of the Base Metals
journal, April 2013

  • Camacho-Bunquin, Jeffrey; Ferguson, Michael J.; Stryker, Jeffrey M.
  • Journal of the American Chemical Society, Vol. 135, Issue 15
  • DOI: 10.1021/ja401579x

Structure and Magnetization Dynamics of Dy−Fe and Dy−Ru Bonded Complexes
journal, May 2018

  • Burns, Corey P.; Yang, Xin; Wofford, Joshua D.
  • Angewandte Chemie International Edition, Vol. 57, Issue 27
  • DOI: 10.1002/anie.201803761

Leveraging molecular metal–support interactions for H2 and N2 activation
journal, March 2017

  • Cammarota, Ryan C.; Clouston, Laura J.; Lu, Connie C.
  • Coordination Chemistry Reviews, Vol. 334
  • DOI: 10.1016/j.ccr.2016.06.014

Catalytic Applications of Early/Late Heterobimetallic Complexes
journal, January 2012


A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
journal, April 2010

  • Grimme, Stefan; Antony, Jens; Ehrlich, Stephan
  • The Journal of Chemical Physics, Vol. 132, Issue 15
  • DOI: 10.1063/1.3382344

Divalent first-row transition metal complexes of the rigid pendant-arm ligand 1,4,7-tris(2-aminophenyl)-1,4,7-triazacyclononane †
journal, January 2000

  • Fallis, Ian A.; Farley, Richard D.; Malik, K. M. Abdul
  • Journal of the Chemical Society, Dalton Transactions, Issue 20
  • DOI: 10.1039/b005402j

Fast and selective homogeneous hydrogenation with nickel(II) phosphane catalysts
journal, January 1998

  • Angulo, Ingrid M.; Kluwer, Alexander M.; Bouwman, Elisabeth
  • Chemical Communications, Issue 24
  • DOI: 10.1039/a807497f

Covalent radii revisited
journal, January 2008

  • Cordero, Beatriz; Gómez, Verónica; Platero-Prats, Ana E.
  • Dalton Transactions, Issue 21
  • DOI: 10.1039/b801115j

Tuning Nickel with Lewis Acidic Group 13 Metalloligands for Catalytic Olefin Hydrogenation
journal, September 2015

  • Cammarota, Ryan C.; Lu, Connie C.
  • Journal of the American Chemical Society, Vol. 137, Issue 39
  • DOI: 10.1021/jacs.5b08313

Nickel(II)-Lanthanide(III) Magnetic Exchange Coupling Influencing Single-Molecule Magnetic Features in {Ni 2 Ln 2 } Complexes
journal, September 2014

  • Ahmed, Naushad; Das, Chinmoy; Vaidya, Shefali
  • Chemistry - A European Journal, Vol. 20, Issue 44
  • DOI: 10.1002/chem.201404393

Systematic Variation of Metal–Metal Bond Order in Metal–Chromium Complexes
journal, August 2013

  • Clouston, Laura J.; Siedschlag, Randall B.; Rudd, P. Alex
  • Journal of the American Chemical Society, Vol. 135, Issue 35
  • DOI: 10.1021/ja406506m

Multimetallic Catalysis Based on Heterometallic Complexes and Clusters
journal, November 2014

  • Buchwalter, Paulin; Rosé, Jacky; Braunstein, Pierre
  • Chemical Reviews, Vol. 115, Issue 1
  • DOI: 10.1021/cr500208k

A complete active space SCF method (CASSCF) using a density matrix formulated super-CI approach
journal, May 1980


Twist angle calculations. Fact or fantasy
journal, May 1975

  • Dymock, K. R.; Palenik, Gus J.
  • Inorganic Chemistry, Vol. 14, Issue 5
  • DOI: 10.1021/ic50147a056

Variety of Crystal Structures of Chiral Schiff Base Lu(III)-Ni(II)/ Cu(II)/Zn(II) and the Related Complexes
journal, October 2014


Bimetallic catalysis for C–C and C–X coupling reactions
journal, January 2017

  • Pye, Dominic R.; Mankad, Neal P.
  • Chemical Science, Vol. 8, Issue 3
  • DOI: 10.1039/C6SC05556G

Metal–metal bonds in f-element chemistry
journal, January 2009

  • Liddle, Stephen T.; Mills, David P.
  • Dalton Transactions, Issue 29
  • DOI: 10.1039/b904318g

Additive Covalent Radii for Single-, Double-, and Triple-Bonded Molecules and Tetrahedrally Bonded Crystals: A Summary
journal, September 2014

  • Pyykkö, Pekka
  • The Journal of Physical Chemistry A, Vol. 119, Issue 11
  • DOI: 10.1021/jp5065819

Electronic perturbations
journal, July 2012


Modulating the σ-Accepting Properties of an Antimony Z-type Ligand via Anion Abstraction: Remote-Controlled Reactivity of the Coordinated Platinum Atom
journal, July 2018

  • You, Di; Yang, Haifeng; Sen, Srobona
  • Journal of the American Chemical Society, Vol. 140, Issue 30
  • DOI: 10.1021/jacs.8b05520

Boryl–Metal Bonds Facilitate Cobalt/Nickel-Catalyzed Olefin Hydrogenation
journal, September 2014

  • Lin, Tzu-Pin; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 136, Issue 39
  • DOI: 10.1021/ja504667f

Metal–Metal Bonds in Catalysis
journal, December 2016


Divalent Silicon-Assisted Activation of Dihydrogen in a Bis(N-heterocyclic silylene)xanthene Nickel(0) Complex for Efficient Catalytic Hydrogenation of Olefins
journal, September 2017

  • Wang, Yuwen; Kostenko, Arseni; Yao, Shenglai
  • Journal of the American Chemical Society, Vol. 139, Issue 38
  • DOI: 10.1021/jacs.7b07167

A New Type of Strong Metal–Support Interaction and the Production of H 2 through the Transformation of Water on Pt/CeO 2 (111) and Pt/CeO x /TiO 2 (110) Catalysts
journal, May 2012

  • Bruix, Albert; Rodriguez, José A.; Ramírez, Pedro J.
  • Journal of the American Chemical Society, Vol. 134, Issue 21
  • DOI: 10.1021/ja302070k

Bi- and trimetallic rare-earth–palladium complexes ligated by phosphinoamides
journal, January 2015

  • Völcker, Franziska; Mück, Felix M.; Vogiatzis, Konstantinos D.
  • Chemical Communications, Vol. 51, Issue 59
  • DOI: 10.1039/C5CC03944D

Homogeneous Hydrogenation and Isomerization of 1-Octene Catalyzed by Nickel(II) Complexes with Bidentate Diarylphosphane Ligands
journal, June 2013

  • Mooibroek, Tiddo J.; Wenker, Erica C. M.; Smit, Wietse
  • Inorganic Chemistry, Vol. 52, Issue 14
  • DOI: 10.1021/ic400973t

Metal—-Metal “Communication” of Rh or Pd with Nd in Novel Heterobinuclear Complexes
journal, August 1998


1,2-Difluorobenzene: a relatively inert and noncoordinating solvent for electrochemical studies on transition-metal complexes
journal, October 1989

  • O'Toole, Terrence R.; Younathan, Janet N.; Sullivan, B. Patrick
  • Inorganic Chemistry, Vol. 28, Issue 20
  • DOI: 10.1021/ic00319a032

Formal Nickelate(−I) Complexes Supported by Group 13 Ions
journal, May 2018

  • Vollmer, Matthew V.; Xie, Jing; Cammarota, Ryan C.
  • Angewandte Chemie International Edition, Vol. 57, Issue 26
  • DOI: 10.1002/anie.201803356

Idealized polytopal forms. Description of real molecules referenced to idealized polygons or polyhedra in geometric reaction path form
journal, March 1974

  • Muetterties, E. L.; Guggenberger, L. J.
  • Journal of the American Chemical Society, Vol. 96, Issue 6
  • DOI: 10.1021/ja00813a017

Air-Stable α-Diimine Nickel Precatalysts for the Hydrogenation of Hindered, Unactivated Alkenes
journal, December 2017


An introduction to NMR-based approaches for measuring protein dynamics
journal, August 2011

  • Kleckner, Ian R.; Foster, Mark P.
  • Biochimica et Biophysica Acta (BBA) - Proteins and Proteomics, Vol. 1814, Issue 8
  • DOI: 10.1016/j.bbapap.2010.10.012

Molecules containing rare-earth atoms solely bonded by transition metals
journal, June 2010

  • Butovskii, Mikhail V.; Döring, Christian; Bezugly, Viktor
  • Nature Chemistry, Vol. 2, Issue 9
  • DOI: 10.1038/nchem.718

Kinetics of the hydrogenation of 1-octene catalyzed by [Ni(o-MeO-dppp)(OAc)2]
journal, October 2001


A d 10 Ni-(H 2 ) Adduct as an Intermediate in HH Oxidative Addition across a NiB Bond
journal, December 2013

  • Harman, W. Hill; Lin, Tzu-Pin; Peters, Jonas C.
  • Angewandte Chemie International Edition, Vol. 53, Issue 4
  • DOI: 10.1002/anie.201308175

Trivalent Lewis Acidic Cations Govern the Electronic Properties and Stability of Heterobimetallic Complexes of Nickel
journal, November 2017

  • Kumar, Amit; Lionetti, Davide; Day, Victor W.
  • Chemistry - A European Journal, Vol. 24, Issue 1
  • DOI: 10.1002/chem.201704006

Semiempirical GGA-type density functional constructed with a long-range dispersion correction
journal, January 2006

  • Grimme, Stefan
  • Journal of Computational Chemistry, Vol. 27, Issue 15, p. 1787-1799
  • DOI: 10.1002/jcc.20495

Molecular Lanthanoid-Transition-Metal Cluster through CH Bond Activation by Polar Metal-Metal Bonds
journal, June 2011

  • Butovskii, Mikhail V.; Tok, Oleg L.; Bezugly, Viktor
  • Angewandte Chemie International Edition, Vol. 50, Issue 33
  • DOI: 10.1002/anie.201102363

A Bimetallic Nickel–Gallium Complex Catalyzes CO 2 Hydrogenation via the Intermediacy of an Anionic d 10 Nickel Hydride
journal, September 2017

  • Cammarota, Ryan C.; Vollmer, Matthew V.; Xie, Jing
  • Journal of the American Chemical Society, Vol. 139, Issue 40
  • DOI: 10.1021/jacs.7b07911

Solution and solid state structures and magnetism of a series of linear trinuclear compounds with a hexacoordinate Ln III and two terminal Ni II centers
journal, January 2017

  • Comba, Peter; Enders, Markus; Großhauser, Michael
  • Dalton Transactions, Vol. 46, Issue 1
  • DOI: 10.1039/C6DT03488H

Determining association constants from titration experiments in supramolecular chemistry
journal, January 2011


Rationale for mixing exact exchange with density functional approximations
journal, December 1996

  • Perdew, John P.; Ernzerhof, Matthias; Burke, Kieron
  • The Journal of Chemical Physics, Vol. 105, Issue 22, p. 9982-9985
  • DOI: 10.1063/1.472933

Metal–Alane Adducts with Zero-Valent Nickel, Cobalt, and Iron
journal, December 2011

  • Rudd, P. Alex; Liu, Shengsi; Gagliardi, Laura
  • Journal of the American Chemical Society, Vol. 133, Issue 51
  • DOI: 10.1021/ja2099744

Bismetallocenes: Lanthanoid-Transition-Metal Bonds through Alkane Elimination
journal, August 2008

  • Butovskii, M. V.; Tok, O. L.; Wagner, F. R.
  • Angewandte Chemie International Edition, Vol. 47, Issue 34
  • DOI: 10.1002/anie.200800407

Phosphine- and thiophosphorane-amine ligands: Lithiation and coordination to Rh(I)
journal, May 2010


Series of Trinuclear Ni II Ln III Ni II Complexes Derived from 2,6-Di(acetoacetyl)pyridine:  Synthesis, Structure, and Magnetism
journal, April 2007

  • Shiga, Takuya; Ito, Nobuhiro; Hidaka, Akiko
  • Inorganic Chemistry, Vol. 46, Issue 9
  • DOI: 10.1021/ic0619153

3d–4f {Co II 3 Ln(OR) 4 } Cubanes as Bio-Inspired Water Oxidation Catalysts
journal, August 2015

  • Evangelisti, Fabio; Moré, René; Hodel, Florian
  • Journal of the American Chemical Society, Vol. 137, Issue 34
  • DOI: 10.1021/jacs.5b05831

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