Oligomerization of ethanol-derived propene and isobutene mixtures to transportation fuels: catalyst and process considerations

Saavedra Lopez, Johnny; Dagle, Robert A.; Dagle, Vanessa Lebarbier; Smith, Colin; Albrecht, Karl O.

doi:10.1039/C8CY02297F

Title: Oligomerization of ethanol-derived propene and isobutene mixtures to transportation fuels: catalyst and process considerations

Abstract

An important activity/selectivity trade-off occurs at increased olefin oligomerization temperatures. Jet-range product decreases and paraffin formation increases at high oligomerization temperatures.

Authors:

^[1];

^[1]; Smith, Colin ^[1];

^[1]

Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, USA

Publication Date:: Mon Mar 04 00:00:00 EST 2019

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1494372

Grant/Contract Number:: AC05-76RL0183

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Catalysis Science and Technology

Additional Journal Information:: Journal Name: Catalysis Science and Technology Journal Volume: 9 Journal Issue: 5; Journal ID: ISSN 2044-4753

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Saavedra Lopez, Johnny, Dagle, Robert A., Dagle, Vanessa Lebarbier, Smith, Colin, and Albrecht, Karl O. Oligomerization of ethanol-derived propene and isobutene mixtures to transportation fuels: catalyst and process considerations.  United Kingdom: N. p., 2019. 
Web.  doi:10.1039/C8CY02297F.

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                    Saavedra Lopez, Johnny, Dagle, Robert A., Dagle, Vanessa Lebarbier, Smith, Colin, & Albrecht, Karl O. Oligomerization of ethanol-derived propene and isobutene mixtures to transportation fuels: catalyst and process considerations.  United Kingdom.  https://doi.org/10.1039/C8CY02297F

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                    Saavedra Lopez, Johnny, Dagle, Robert A., Dagle, Vanessa Lebarbier, Smith, Colin, and Albrecht, Karl O. Mon .  
"Oligomerization of ethanol-derived propene and isobutene mixtures to transportation fuels: catalyst and process considerations".  United Kingdom.  https://doi.org/10.1039/C8CY02297F.

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@article{osti_1494372,

  title        = {Oligomerization of ethanol-derived propene and isobutene mixtures to transportation fuels: catalyst and process considerations},

  author       = {Saavedra Lopez, Johnny and Dagle, Robert A. and Dagle, Vanessa Lebarbier and Smith, Colin and Albrecht, Karl O.},

  abstractNote = {An important activity/selectivity trade-off occurs at increased olefin oligomerization temperatures. Jet-range product decreases and paraffin formation increases at high oligomerization temperatures.},

  doi          = {10.1039/C8CY02297F},

  journal      = {Catalysis Science and Technology},

  number       = 5,

  volume       = 9,

  place        = {United Kingdom},

  year         = {Mon Mar 04 00:00:00 EST 2019},

  month        = {Mon Mar 04 00:00:00 EST 2019}

}

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https://doi.org/10.1039/C8CY02297F

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Title: Oligomerization of ethanol-derived propene and isobutene mixtures to transportation fuels: catalyst and process considerations

Abstract

Citation Formats

Polystyrene sulphonic acid resins with enhanced acid strength via macromolecular self-assembly within confined nanospace journal, January 2014

Effects of Brønsted-acid site proximity on the oligomerization of propene in H-MFI journal, April 2012

Key Roles of Lewis Acid–Base Pairs on Zn x Zr y O z in Direct Ethanol/Acetone to Isobutene Conversion journal, December 2015

Recent Advances in Catalytic Conversion of Ethanol to Chemicals journal, March 2014

Oligomerization of isobutene over solid acid catalysts journal, February 2005

Trimerization of isobutene over a zeolite beta catalyst journal, January 2007

Catalytic Consequences of Spatial Constraints and Acid Site Location for Monomolecular Alkane Activation on Zeolites journal, February 2009

Catalysis on solid acids: Mechanism and catalyst descriptors in oligomerization reactions of light alkenes journal, December 2016

Effects of Void Environment and Acid Strength on Alkene Oligomerization Selectivity journal, September 2016

Properties of Synthetic Fuels from H-ZSM-5 Oligomerization of Fischer–Tropsch Type Feed Materials journal, November 2007

Effect of the Acidity of HZSM-5 Zeolite and the Binder in the DME Transformation to Olefins journal, February 2016

Direct Conversion of Bio-ethanol to Isobutene on Nanosized Zn x Zr y O z Mixed Oxides with Balanced Acid–Base Sites journal, July 2011

Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering journal, September 2006

Oligomerization of isobutene over dealuminated Y zeolite catalysts journal, March 2008

Chemistry of olefin oligomerization over ZSM-5 catalyst journal, April 1988

Oligomerization of 1-Hexene and 1-Octene over Solid Acid Catalysts journal, May 2005

Conversion of Isobutylene to Octane-Booster Compounds after Methyl tert -Butyl Ether Phaseout: The Role of Heterogeneous Catalysis journal, October 2016

β-Scission of Olefins on Acidic Zeolites: A Periodic PBE-D Study in H-ZSM-5 journal, October 2013

Assessment of mass transfer limitations in oligomerization of butene at high pressure on H-beta journal, September 2015

Zeolite catalysts in upgrading of bioethanol to fuels range hydrocarbons: A review journal, November 2015

An integrated process for production of jet-fuel range olefins from ethylene using Ni-AlSBA-15 and Amberlyst-35 catalysts journal, January 2017

Bio-jet fuel conversion technologies journal, January 2016

Tailored Catalytic Propene Trimerization over Acidic Zeolites with Tubular Pores journal, September 2005

Integrated Catalytic Conversion of γ-Valerolactone to Liquid Alkenes for Transportation Fuels journal, February 2010

A study of ZnxZryOz mixed oxides for direct conversion of ethanol to isobutene journal, October 2013

Comparative techno‐economic analysis and process design for indirect liquefaction pathways to distillate‐range fuels via biomass‐derived oxygenated intermediates upgrading journal, September 2016

Conversion of syngas-derived C2+ mixed oxygenates to C3–C5 olefins over ZnxZryOz mixed oxide catalysts journal, January 2016

1-Butene oligomerization over ZSM-5 zeolite: Part 1 – Effect of reaction conditions journal, September 2013

Reaction of small olefins on zeolite H-ZSM-5. A thermogravimetric study at low and intermediate temperatures journal, March 1983

Oligomerization of Light Olefins to Gasoline: An Advanced NMR Characterization of Liquid Products journal, August 2016

Low-temperature oligomerization of 1-butene with H-ferrierite journal, March 2015

Study of the oligomerization of 1-octene catalyzed by macroreticular ion-exchange resins journal, October 2012

Ethanol transformation into hydrocarbons on ZSM-5 zeolites: Influence of Si/Al ratio on catalytic performances and deactivation rate. Study of the radical species role journal, November 2012

The conversion of ethene and propene to higher hydrocarbons over ZSM-5 journal, May 1987

Integrated process for the catalytic conversion of biomass-derived syngas into transportation fuels journal, January 2016

Oligomerization of Biomass-Derived Light Olefins to Liquid Fuel: Effect of Alkali Treatment on the HZSM-5 Catalyst journal, October 2017

Tailored Alkene Oligomerization with H-ZSM-57 Zeolite journal, December 2000

Polystyrene sulphonic acid resins with enhanced acid strength via macromolecular self-assembly within confined nanospace
journal, January 2014

Effects of Brønsted-acid site proximity on the oligomerization of propene in H-MFI
journal, April 2012

Key Roles of Lewis Acid–Base Pairs on Zn _x Zr _y O _z in Direct Ethanol/Acetone to Isobutene Conversion
journal, December 2015

Recent Advances in Catalytic Conversion of Ethanol to Chemicals
journal, March 2014

Oligomerization of isobutene over solid acid catalysts
journal, February 2005

Trimerization of isobutene over a zeolite beta catalyst
journal, January 2007

Catalytic Consequences of Spatial Constraints and Acid Site Location for Monomolecular Alkane Activation on Zeolites
journal, February 2009

Catalysis on solid acids: Mechanism and catalyst descriptors in oligomerization reactions of light alkenes
journal, December 2016

Effects of Void Environment and Acid Strength on Alkene Oligomerization Selectivity
journal, September 2016

Properties of Synthetic Fuels from H-ZSM-5 Oligomerization of Fischer–Tropsch Type Feed Materials
journal, November 2007

Effect of the Acidity of HZSM-5 Zeolite and the Binder in the DME Transformation to Olefins
journal, February 2016

Direct Conversion of Bio-ethanol to Isobutene on Nanosized Zn _x Zr _y O _z Mixed Oxides with Balanced Acid–Base Sites
journal, July 2011

Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
journal, September 2006

Oligomerization of isobutene over dealuminated Y zeolite catalysts
journal, March 2008

Chemistry of olefin oligomerization over ZSM-5 catalyst
journal, April 1988

Oligomerization of 1-Hexene and 1-Octene over Solid Acid Catalysts
journal, May 2005

Conversion of Isobutylene to Octane-Booster Compounds after Methyl tert -Butyl Ether Phaseout: The Role of Heterogeneous Catalysis
journal, October 2016

β-Scission of Olefins on Acidic Zeolites: A Periodic PBE-D Study in H-ZSM-5
journal, October 2013

Assessment of mass transfer limitations in oligomerization of butene at high pressure on H-beta
journal, September 2015

Zeolite catalysts in upgrading of bioethanol to fuels range hydrocarbons: A review
journal, November 2015

An integrated process for production of jet-fuel range olefins from ethylene using Ni-AlSBA-15 and Amberlyst-35 catalysts
journal, January 2017

Bio-jet fuel conversion technologies
journal, January 2016

Tailored Catalytic Propene Trimerization over Acidic Zeolites with Tubular Pores
journal, September 2005

Integrated Catalytic Conversion of γ-Valerolactone to Liquid Alkenes for Transportation Fuels
journal, February 2010

A study of ZnxZryOz mixed oxides for direct conversion of ethanol to isobutene
journal, October 2013

Comparative techno‐economic analysis and process design for indirect liquefaction pathways to distillate‐range fuels via biomass‐derived oxygenated intermediates upgrading
journal, September 2016

Conversion of syngas-derived C₂+ mixed oxygenates to C₃–C₅ olefins over Zn_xZr_yO_z mixed oxide catalysts
journal, January 2016

1-Butene oligomerization over ZSM-5 zeolite: Part 1 – Effect of reaction conditions
journal, September 2013

Reaction of small olefins on zeolite H-ZSM-5. A thermogravimetric study at low and intermediate temperatures
journal, March 1983

Oligomerization of Light Olefins to Gasoline: An Advanced NMR Characterization of Liquid Products
journal, August 2016

Low-temperature oligomerization of 1-butene with H-ferrierite
journal, March 2015

Study of the oligomerization of 1-octene catalyzed by macroreticular ion-exchange resins
journal, October 2012

Ethanol transformation into hydrocarbons on ZSM-5 zeolites: Influence of Si/Al ratio on catalytic performances and deactivation rate. Study of the radical species role
journal, November 2012

The conversion of ethene and propene to higher hydrocarbons over ZSM-5
journal, May 1987

Integrated process for the catalytic conversion of biomass-derived syngas into transportation fuels
journal, January 2016

Oligomerization of Biomass-Derived Light Olefins to Liquid Fuel: Effect of Alkali Treatment on the HZSM-5 Catalyst
journal, October 2017

Tailored Alkene Oligomerization with H-ZSM-57 Zeolite
journal, December 2000