Non‐Tacky Fluorinated and Elastomeric STEM Networks

Cuthbert, Julia; Martinez, Michael R.; Sun, Mingkang; Flum, Jacob; Li, Lingchun; Olszewski, Mateusz; Wang, Zhenhua; Kowalewski, Tomasz; Matyjaszewski, Krzysztof

doi:10.1002/marc.201800876

Title: Non‐Tacky Fluorinated and Elastomeric STEM Networks

Journal Article · 09 February 2019 · Macromolecular Rapid Communications

DOI: https://doi.org/10.1002/marc.201800876 · OSTI ID:1494201

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^[1]; Flum, Jacob ^[1];

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Department of Chemistry Carnegie Mellon University 4400 Fifth Avenue Pittsburgh PA 15213 USA

Abstract Soft, elastomeric, non‐tacky polymer networks are synthesized by reversible deactivation radical polymerization (RDRP). First, the pristine, structurally tailored and engineered macromolecular (STEM) networks are synthesized by reversible addition–fragmentation chain transfer (RAFT) polymerization and incorporated an atom transfer radical polymerization (ATRP) inimer into the network. Subsequently, poly( n ‐butyl acrylate) (PBA) and/or poly(octafluoropentyl acrylate) (POFPA) side chains are grafted from the network by photo‐induced ATRP. These low glass transition temperature side chains produced soft materials ( E = 104–178 kPa). However, only the POFPA‐containing networks are also non‐tacky. The fluorine content and material properties are investigated by dynamic mechanical analysis, elemental analysis, spectroscopy, and contact angle measurements.

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Sponsoring Organization:: USDOE

OSTI ID:: 1494201

Journal Information:: Macromolecular Rapid Communications, Journal Name: Macromolecular Rapid Communications Journal Issue: 10 Vol. 40; ISSN 1022-1336

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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