The Role of Chain-End Association Lifetime in Segmental and Chain Dynamics of Telechelic Polymers

Xing, Kunyue; Tress, Martin; Cao, Peng-Fei; Fan, Fei; Cheng, Shiwang; Saito, Tomonori; Sokolov, Alexei P.

doi:10.1021/acs.macromol.8b01210

Title: The Role of Chain-End Association Lifetime in Segmental and Chain Dynamics of Telechelic Polymers

Journal Article · 18 October 2018 · Macromolecules

DOI: https://doi.org/10.1021/acs.macromol.8b01210 · OSTI ID:1493982

^[1]; Tress, Martin ^[1];

^[2]; Fan, Fei ^[1];

^[3];

^[2]; Sokolov, Alexei P. ^[4]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Michigan State Univ., East Lansing, MI (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

Broadband dielectric spectroscopy, differential scanning calorimetry, and rheology were employed to study the impact of hydrogen (H)-bonding end-groups on segmental and chain dynamics of telechelic polypropylene glycol (PPG) and poly(dimethylsiloxane) (PDMS). Polymer chains with three types of H-bonding end-groups possessing different interaction strengths and a non-H-bonding end-group as reference were compared. The glass transition temperature (Tg) of H-bonding PPG systems with low molecular weight increases compared to the reference, and the Tg difference varies with chain-end interaction strength. In contrast, their shear viscosities (for Tg-scaled temperature, i.e., when the shift in Tg is accounted for) are similar to that one of the reference. This is in strong contrast to the behavior of telechelic PDMS with the same set of end-groups, where the Tg increase of all H-bonding systems is independent of H-bond strengths, while shear viscosity increases significantly only for the strongest H-bonding end-groups. These observations are explained by the difference in lifetime of the end-group associations relative to segmental and chain relaxation times.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1493982

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 21 Vol. 51; ISSN 0024-9297

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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