Simultaneously Dual Modification of Ni-Rich Layered Oxide Cathode for High-Energy Lithium-Ion Batteries
Abstract
A critical challenge in the commercialization of layer-structured Ni-rich materials is the fast capacity drop and voltage fading due to the interfacial instability and bulk structural degradation of the cathodes during battery operation. Herein, with the guidance of theoretical calculations of migration energy difference between La and Ti from the surface to the inside of LiNi0.8Co0.1Mn0.1O2, for the first time, Ti-doped and La4NiLiO8-coated LiNi0.8Co0.1Mn0.1O2 cathodes are rationally designed and prepared, via a simple and convenient dual-modification strategy of synchronous synthesis and in situ modification. Impressively, the dual modified materials show remarkably improved electrochemical performance and largely suppressed voltage fading, even under exertive operational conditions at elevated temperature and under extended cutoff voltage. Further studies reveal that the nanoscale structural degradation on material surfaces and the appearance of intergranular cracks associated with the inconsistent evolution of structural degradation at the particle level can be effectively suppressed by the synergetic effect of the conductive La4NiLiO8 coating layer and the strong Ti—O bond. The present work demonstrates that our strategy can simultaneously address the two issues with respect to interfacial instability and bulk structural degradation, and it represents a significant progress in the development of advanced cathode materials for high-performance lithium-ion batteries.
- Authors:
-
- Changsha Univ. of Science and Technology, Changsha (People's Republic of China)
- Univ. of Nebraska‐Lincoln, Lincoln, NE (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- NingDe Ampere Technology Ltd., Fujian (China)
- Xiamen Univ., Fujian (China)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1513538
- Alternate Identifier(s):
- OSTI ID: 1493848; OSTI ID: 1506672
- Report Number(s):
- BNL-211647-2019-JAAM
Journal ID: ISSN 1616-301X
- Grant/Contract Number:
- SC0012704; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Volume: 29; Journal Issue: 13; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; DFT calculation; dual‐modification strategy; lithium‐ion batteries; Ni‐rich materials; synchronous synthesis
Citation Formats
Yang, Huiping, Wu, Hong ‐Hui, Ge, Mingyuan, Li, Lingjun, Yuan, Yifei, Yao, Qi, Chen, Jie, Xia, Lingfeng, Zheng, Jiangming, Chen, Zhaoyong, Duan, Junfei, Kisslinger, Kim, Zeng, Xiao Cheng, Lee, Wah ‐Keat, Zhang, Qiaobao, and Lu, Jun. Simultaneously Dual Modification of Ni-Rich Layered Oxide Cathode for High-Energy Lithium-Ion Batteries. United States: N. p., 2019.
Web. doi:10.1002/adfm.201808825.
Yang, Huiping, Wu, Hong ‐Hui, Ge, Mingyuan, Li, Lingjun, Yuan, Yifei, Yao, Qi, Chen, Jie, Xia, Lingfeng, Zheng, Jiangming, Chen, Zhaoyong, Duan, Junfei, Kisslinger, Kim, Zeng, Xiao Cheng, Lee, Wah ‐Keat, Zhang, Qiaobao, & Lu, Jun. Simultaneously Dual Modification of Ni-Rich Layered Oxide Cathode for High-Energy Lithium-Ion Batteries. United States. https://doi.org/10.1002/adfm.201808825
Yang, Huiping, Wu, Hong ‐Hui, Ge, Mingyuan, Li, Lingjun, Yuan, Yifei, Yao, Qi, Chen, Jie, Xia, Lingfeng, Zheng, Jiangming, Chen, Zhaoyong, Duan, Junfei, Kisslinger, Kim, Zeng, Xiao Cheng, Lee, Wah ‐Keat, Zhang, Qiaobao, and Lu, Jun. Thu .
"Simultaneously Dual Modification of Ni-Rich Layered Oxide Cathode for High-Energy Lithium-Ion Batteries". United States. https://doi.org/10.1002/adfm.201808825. https://www.osti.gov/servlets/purl/1513538.
@article{osti_1513538,
title = {Simultaneously Dual Modification of Ni-Rich Layered Oxide Cathode for High-Energy Lithium-Ion Batteries},
author = {Yang, Huiping and Wu, Hong ‐Hui and Ge, Mingyuan and Li, Lingjun and Yuan, Yifei and Yao, Qi and Chen, Jie and Xia, Lingfeng and Zheng, Jiangming and Chen, Zhaoyong and Duan, Junfei and Kisslinger, Kim and Zeng, Xiao Cheng and Lee, Wah ‐Keat and Zhang, Qiaobao and Lu, Jun},
abstractNote = {A critical challenge in the commercialization of layer-structured Ni-rich materials is the fast capacity drop and voltage fading due to the interfacial instability and bulk structural degradation of the cathodes during battery operation. Herein, with the guidance of theoretical calculations of migration energy difference between La and Ti from the surface to the inside of LiNi0.8Co0.1Mn0.1O2, for the first time, Ti-doped and La4NiLiO8-coated LiNi0.8Co0.1Mn0.1O2 cathodes are rationally designed and prepared, via a simple and convenient dual-modification strategy of synchronous synthesis and in situ modification. Impressively, the dual modified materials show remarkably improved electrochemical performance and largely suppressed voltage fading, even under exertive operational conditions at elevated temperature and under extended cutoff voltage. Further studies reveal that the nanoscale structural degradation on material surfaces and the appearance of intergranular cracks associated with the inconsistent evolution of structural degradation at the particle level can be effectively suppressed by the synergetic effect of the conductive La4NiLiO8 coating layer and the strong Ti—O bond. The present work demonstrates that our strategy can simultaneously address the two issues with respect to interfacial instability and bulk structural degradation, and it represents a significant progress in the development of advanced cathode materials for high-performance lithium-ion batteries.},
doi = {10.1002/adfm.201808825},
journal = {Advanced Functional Materials},
number = 13,
volume = 29,
place = {United States},
year = {Thu Feb 07 00:00:00 EST 2019},
month = {Thu Feb 07 00:00:00 EST 2019}
}
Web of Science
Works referenced in this record:
Surface/Interfacial Structure and Chemistry of High-Energy Nickel-Rich Layered Oxide Cathodes: Advances and Perspectives
journal, October 2017
- Hou, Peiyu; Yin, Jiangmei; Ding, Meng
- Small, Vol. 13, Issue 45
LiLaPO4-coated Li[Ni0.5Co0.2Mn0.3]O2 and AlF3-coated Li[Ni0.5Co0.2Mn0.3]O2 blend composite for lithium ion batteries
journal, October 2012
- Song, Han Gab; Park, Yong Joon
- Materials Research Bulletin, Vol. 47, Issue 10
Reaction mechanism and kinetics of lithium ion battery cathode material LiNiO2 with CO2
journal, November 2007
- Liu, Hansan; Yang, Yong; Zhang, Jiujun
- Journal of Power Sources, Vol. 173, Issue 1
In situ formed LiNi0.8Co0.15Al0.05O2@Li4SiO4 composite cathode material with high rate capability and long cycling stability for lithium-ion batteries
journal, November 2018
- Zheng, Jun-chao; Yang, Zhuo; He, Zhen-jiang
- Nano Energy, Vol. 53
Controllable Solid Electrolyte Interphase in Nickel-Rich Cathodes by an Electrochemical Rearrangement for Stable Lithium-Ion Batteries
journal, December 2017
- Kim, Junhyeok; Lee, Jieun; Ma, Hyunsoo
- Advanced Materials, Vol. 30, Issue 5
Improved Cycling Stability of Na-Doped Cathode Materials Li 1.2 Ni 0.2 Mn 0.6 O 2 via a Facile Synthesis
journal, August 2018
- Liu, Yunjian; Liu, Dongming; Wu, Hong-Hui
- ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 10
Fluorescent Anion Receptor of Tweezer-type: Using Pyrene Amide Unit with Cationic Pyridinium Skeleton
journal, December 2009
- Ryu, Byung-Ju; Lee, Ah-Leum; Lee, Young-Ju
- Bulletin of the Korean Chemical Society, Vol. 30, Issue 12
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries
journal, March 2014
- Lin, Feng; Markus, Isaac M.; Nordlund, Dennis
- Nature Communications, Vol. 5, Issue 1
Mn(II) deposition on anodes and its effects on capacity fade in spinel lithium manganate–carbon systems
journal, September 2013
- Zhan, Chun; Lu, Jun; Jeremy Kropf, A.
- Nature Communications, Vol. 4, Issue 1
A New Coating Method for Alleviating Surface Degradation of LiNi 0.6 Co 0.2 Mn 0.2 O 2 Cathode Material: Nanoscale Surface Treatment of Primary Particles
journal, February 2015
- Kim, Hyejung; Kim, Min Gyu; Jeong, Hu Young
- Nano Letters, Vol. 15, Issue 3
A grid-based Bader analysis algorithm without lattice bias
journal, January 2009
- Tang, W.; Sanville, E.; Henkelman, G.
- Journal of Physics: Condensed Matter, Vol. 21, Issue 8
Factors Influencing the Irreversible Oxygen Loss and Reversible Capacity in Layered Li[Li 1/3 Mn 2/ 3 ]O 2 −Li[M]O 2 (M = Mn 0.5- y Ni 0.5- y Co 2 y and Ni 1- y Co y ) Solid Solutions
journal, June 2007
- Arunkumar, T. A.; Wu, Y.; Manthiram, A.
- Chemistry of Materials, Vol. 19, Issue 12
Improved high voltage electrochemical performance of Li2ZrO3-coated LiNi0.5Co0.2Mn0.3O2 cathode material
journal, October 2015
- Wang, Ding; Li, Xinhai; Wang, Zhixing
- Journal of Alloys and Compounds, Vol. 647
Unraveling the Origin of Instability in Ni-Rich LiNi 1–2 x Co x Mn x O 2 (NCM) Cathode Materials
journal, March 2016
- Liang, Chaoping; Kong, Fantai; Longo, Roberto C.
- The Journal of Physical Chemistry C, Vol. 120, Issue 12
Effect of Al substitution sites on Li 1−x Al x (Ni 0.5 Co 0.2 Mn 0.3 ) 1−y Al y O 2 cathode materials for lithium ion batteries
journal, November 2016
- Li, Lingjun; Yao, Qi; Zhu, Huali
- Journal of Alloys and Compounds, Vol. 686
Oxygen Release Induced Chemomechanical Breakdown of Layered Cathode Materials
journal, April 2018
- Mu, Linqin; Lin, Ruoqian; Xu, Rong
- Nano Letters, Vol. 18, Issue 5
High dielectric constant gate oxides for metal oxide Si transistors
journal, December 2005
- Robertson, John
- Reports on Progress in Physics, Vol. 69, Issue 2
Multiple Linkage Modification of Lithium-Rich Layered Oxide Li 1.2 Mn 0.54 Ni 0.13 Co 0.13 O 2 for Lithium Ion Battery
journal, August 2018
- Zheng, Jun-chao; Yang, Zhuo; Wang, Peng-bo
- ACS Applied Materials & Interfaces, Vol. 10, Issue 37
Stabilizing the Electrode/Electrolyte Interface of LiNi 0.8 Co 0.15 Al 0.05 O 2 through Tailoring Aluminum Distribution in Microspheres as Long-Life, High-Rate, and Safe Cathode for Lithium-Ion Batteries
journal, August 2017
- Hou, Peiyu; Zhang, Hongzhou; Deng, Xiaolong
- ACS Applied Materials & Interfaces, Vol. 9, Issue 35
Electrochemical and Physical Properties of Ti-Substituted Layered Nickel Manganese Cobalt Oxide (NMC) Cathode Materials
journal, January 2012
- Kam, Kinson C.; Mehta, Apurva; Heron, John T.
- Journal of The Electrochemical Society, Vol. 159, Issue 8
Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes – a critical review
journal, January 2018
- Zhan, Chun; Wu, Tianpin; Lu, Jun
- Energy & Environmental Science, Vol. 11, Issue 2
High-voltage positive electrode materials for lithium-ion batteries
journal, January 2017
- Li, Wangda; Song, Bohang; Manthiram, Arumugam
- Chemical Society Reviews, Vol. 46, Issue 10
Impact of Microcrack Generation and Surface Degradation on a Nickel-Rich Layered Li[Ni 0.9 Co 0.05 Mn 0.05 ]O 2 Cathode for Lithium-Ion Batteries
journal, September 2017
- Sun, Ho-Hyun; Manthiram, Arumugam
- Chemistry of Materials, Vol. 29, Issue 19
Cation Ordering of Zr-Doped LiNiO 2 Cathode for Lithium-Ion Batteries
journal, February 2018
- Yoon, Chong S.; Choi, Min-Jae; Jun, Do-Wook
- Chemistry of Materials, Vol. 30, Issue 5
Investigation on the effect of Na doping on structure and Li-ion kinetics of layered LiNi0.6Co0.2Mn0.2O2 cathode material
journal, February 2016
- Huang, Zhenjun; Wang, Zhixing; Jing, Qun
- Electrochimica Acta, Vol. 192
Nanostructured high-energy cathode materials for advanced lithium batteries
journal, October 2012
- Sun, Yang-Kook; Chen, Zonghai; Noh, Hyung-Joo
- Nature Materials, Vol. 11, Issue 11
The cathode–electrolyte interface in the Li-ion battery
journal, November 2004
- Edström, K.; Gustafsson, T.; Thomas, J. O.
- Electrochimica Acta, Vol. 50, Issue 2-3
Coupling of electrochemically triggered thermal and mechanical effects to aggravate failure in a layered cathode
journal, June 2018
- Yan, Pengfei; Zheng, Jianming; Chen, Tianwu
- Nature Communications, Vol. 9, Issue 1
Microstructural Degradation of Ni-Rich Li[Ni x Co y Mn 1 −x−y ]O 2 Cathodes During Accelerated Calendar Aging
journal, September 2018
- Ryu, Hoon-Hee; Park, Geon-Tae; Yoon, Chong S.
- Small, Vol. 14, Issue 45
TomoPy: a framework for the analysis of synchrotron tomographic data
journal, August 2014
- Gürsoy, Dogˇa; De Carlo, Francesco; Xiao, Xianghui
- Journal of Synchrotron Radiation, Vol. 21, Issue 5
Characterization and electrochemical performance of lithium-active titanium dioxide inlaid LiNi0.5Co0.2Mn0.3O2 material prepared by lithium residue-assisted method
journal, July 2015
- Li, Lingjun; Chen, Zhaoyong; Song, Liubin
- Journal of Alloys and Compounds, Vol. 638
Development of Microstrain in Aged Lithium Transition Metal Oxides
journal, June 2014
- Lee, Eung-Ju; Chen, Zonghai; Noh, Hyung-Ju
- Nano Letters, Vol. 14, Issue 8
Layered Li x Ni y Mn y Co 1-2 y O 2 Cathodes for Lithium Ion Batteries: Understanding Local Structure via Magnetic Properties
journal, September 2007
- Chernova, Natasha A.; Ma, Miaomiao; Xiao, Jie
- Chemistry of Materials, Vol. 19, Issue 19
30 Years of Lithium-Ion Batteries
journal, June 2018
- Li, Matthew; Lu, Jun; Chen, Zhongwei
- Advanced Materials, Vol. 30, Issue 33
Effect of titanium addition as nickel oxide formation inhibitor in nickel-rich cathode material for lithium-ion batteries
journal, December 2015
- Nurpeissova, Arailym; Choi, Moon Ho; Kim, Jik-Soo
- Journal of Power Sources, Vol. 299
Improved cyclic stability of LiNi0.8Co0.1Mn0.1O2 via Ti substitution with a cut-off potential of 4.5V
journal, June 2015
- Du, Rui; Bi, Yujing; Yang, Wenchao
- Ceramics International, Vol. 41, Issue 5
Role of LaNiO3 in suppressing voltage decay of layered lithium-rich cathode materials
journal, January 2018
- Wu, Feng; Li, Qing; Bao, Liying
- Electrochimica Acta, Vol. 260
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Tailoring Anisotropic Li-Ion Transport Tunnels on Orthogonally Arranged Li-Rich Layered Oxide Nanoplates Toward High-Performance Li-Ion Batteries
journal, February 2017
- Xu, Ming; Fei, Linfeng; Zhang, Weibing
- Nano Letters, Vol. 17, Issue 3
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
journal, July 2013
- Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy
- APL Materials, Vol. 1, Issue 1
Modified High-Nickel Cathodes with Stable Surface Chemistry Against Ambient Air for Lithium-Ion Batteries
journal, April 2018
- You, Ya; Celio, Hugo; Li, Jianyu
- Angewandte Chemie International Edition, Vol. 57, Issue 22
Effects of lithium-active manganese trioxide coating on the structural and electrochemical characteristics of LiNi0.5Co0.2Mn0.3O2 as cathode materials for lithium ion battery
journal, November 2015
- Li, Lingjun; Yao, Qi; Chen, Zhaoyong
- Journal of Alloys and Compounds, Vol. 650
A new insight into continuous performance decay mechanism of Ni-rich layered oxide cathode for high energy lithium ion batteries
journal, December 2018
- Lin, Qingyun; Guan, Wenhao; Meng, Jie
- Nano Energy, Vol. 54
Co-modification of LiNi0.5Co0.2Mn0.3O2 cathode materials with zirconium substitution and surface polypyrrole coating: towards superior high voltage electrochemical performances for lithium ion batteries
journal, April 2016
- Wang, Ding; Li, Xinhai; Wang, Zhixing
- Electrochimica Acta, Vol. 196
Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries
journal, January 2017
- Yan, Pengfei; Zheng, Jianming; Gu, Meng
- Nature Communications, Vol. 8, Issue 1
Atomic Layer Deposition of Stable LiAlF 4 Lithium Ion Conductive Interfacial Layer for Stable Cathode Cycling
journal, July 2017
- Xie, Jin; Sendek, Austin D.; Cubuk, Ekin D.
- ACS Nano, Vol. 11, Issue 7
One-minute nano-tomography using hard X-ray full-field transmission microscope
journal, August 2018
- Ge, Mingyuan; Coburn, David Scott; Nazaretski, Evgeny
- Applied Physics Letters, Vol. 113, Issue 8
Atomic Resolution Structural and Chemical Imaging Revealing the Sequential Migration of Ni, Co, and Mn upon the Battery Cycling of Layered Cathode
journal, May 2017
- Yan, Pengfei; Zheng, Jianming; Zhang, Ji-Guang
- Nano Letters, Vol. 17, Issue 6
Role of V2O5 coating on LiNiO2-based materials for lithium ion battery
journal, January 2014
- Xiong, Xunhui; Wang, Zhixing; Yan, Guochun
- Journal of Power Sources, Vol. 245
Sufficient Utilization of Zirconium Ions to Improve the Structure and Surface properties of Nickel-Rich Cathode Materials for Lithium-Ion Batteries
journal, April 2018
- He, Tao; Lu, Yun; Su, Yuefeng
- ChemSusChem, Vol. 11, Issue 10
Nickel-Rich Layered Cathode Materials for Automotive Lithium-Ion Batteries: Achievements and Perspectives
journal, December 2016
- Myung, Seung-Taek; Maglia, Filippo; Park, Kang-Joon
- ACS Energy Letters, Vol. 2, Issue 1
Enhanced electrochemical properties of LiCo0.5Ni0.5O2 by Ti-doping: A first-principle study
journal, March 2015
- Hao, Shuang; Zhao, Naiqin; Shi, Chunsheng
- Ceramics International, Vol. 41, Issue 2
Reaction Heterogeneity in LiNi 0.8 Co 0.15 Al 0.05 O 2 Induced by Surface Layer
journal, August 2017
- Grenier, Antonin; Liu, Hao; Wiaderek, Kamila M.
- Chemistry of Materials, Vol. 29, Issue 17
Nickel-Rich and Lithium-Rich Layered Oxide Cathodes: Progress and Perspectives
journal, October 2015
- Manthiram, Arumugam; Knight, James C.; Myung, Seung-Taek
- Advanced Energy Materials, Vol. 6, Issue 1
MnPO 4 -Coated Li(Ni 0.4 Co 0.2 Mn 0.4 )O 2 for Lithium(-Ion) Batteries with Outstanding Cycling Stability and Enhanced Lithiation Kinetics
journal, August 2018
- Chen, Zhen; Kim, Guk-Tae; Bresser, Dominic
- Advanced Energy Materials, Vol. 8, Issue 27
Electronic structures and thermoelectric properties of layered BiCuOCh oxychalcogenides (Ch = S, Se and Te): first-principles calculations
journal, January 2013
- Zou, Daifeng; Xie, Shuhong; Liu, Yunya
- Journal of Materials Chemistry A, Vol. 1, Issue 31
Capacity Fading of Ni-Rich Li[Ni x Co y Mn 1– x – y ]O 2 (0.6 ≤ x ≤ 0.95) Cathodes for High-Energy-Density Lithium-Ion Batteries: Bulk or Surface Degradation?
journal, January 2018
- Ryu, Hoon-Hee; Park, Kang-Joon; Yoon, Chong S.
- Chemistry of Materials, Vol. 30, Issue 3
Mg doping and zirconium oxyfluoride coating co-modification to enhance the high-voltage performance of LiCoO2 for lithium ion battery
journal, February 2015
- Wang, Zhiguo; Wang, Zhixing; Guo, Huajun
- Journal of Alloys and Compounds, Vol. 621
Significantly improving cycling performance of cathodes in lithium ion batteries: The effect of Al2O3 and LiAlO2 coatings on LiNi0.6Co0.2Mn0.2O2
journal, February 2018
- Liu, Wen; Li, Xifei; Xiong, Dongbin
- Nano Energy, Vol. 44
Enabling the high capacity of lithium-rich anti-fluorite lithium iron oxide by simultaneous anionic and cationic redox
journal, December 2017
- Zhan, Chun; Yao, Zhenpeng; Lu, Jun
- Nature Energy, Vol. 2, Issue 12
Enhancing Interfacial Bonding between Anisotropically Oriented Grains Using a Glue-Nanofiller for Advanced Li-Ion Battery Cathode
journal, April 2016
- Kim, Hyejung; Lee, Sanghan; Cho, Hyeon
- Advanced Materials, Vol. 28, Issue 23
From Surface ZrO 2 Coating to Bulk Zr Doping by High Temperature Annealing of Nickel-Rich Lithiated Oxides and Their Enhanced Electrochemical Performance in Lithium Ion Batteries
journal, September 2017
- Schipper, Florian; Bouzaglo, Hana; Dixit, Mudit
- Advanced Energy Materials, Vol. 8, Issue 4
Structural Changes and Thermal Stability of Charged LiNi x Mn y Co z O 2 Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy
journal, December 2014
- Bak, Seong-Min; Hu, Enyuan; Zhou, Yongning
- ACS Applied Materials & Interfaces, Vol. 6, Issue 24
TomoPy: A framework for the analysis of synchrotron tomographic data
conference, September 2014
- Gürsoy, Doğa; De Carlo, Francesco; Xiao, Xianghui
- SPIE Optical Engineering + Applications, SPIE Proceedings
Works referencing / citing this record:
Defect Engineering on Electrode Materials for Rechargeable Batteries
journal, November 2019
- Zhang, Yiqiong; Tao, Li; Xie, Chao
- Advanced Materials, Vol. 32, Issue 7
Surface/Interface Structure Degradation of Ni‐Rich Layered Oxide Cathodes toward Lithium‐Ion Batteries: Fundamental Mechanisms and Remedying Strategies
journal, December 2019
- Liang, Longwei; Zhang, Wenheng; Zhao, Fei
- Advanced Materials Interfaces, Vol. 7, Issue 3
Cooling Induced Surface Reconstruction during Synthesis of High‐Ni Layered Oxides
journal, October 2019
- Zhang, Ming‐Jian; Hu, Xiaobing; Li, Maofan
- Advanced Energy Materials, Vol. 9, Issue 43
A Comprehensive Analysis of the Interphasial and Structural Evolution over Long‐Term Cycling of Ultrahigh‐Nickel Cathodes in Lithium‐Ion Batteries
journal, October 2019
- Li, Jianyu; Manthiram, Arumugam
- Advanced Energy Materials, Vol. 9, Issue 45
Manipulating the Composition and Structure of Solid Electrolyte Interphase at Graphite Anode by Adjusting the Formation Condition
journal, June 2019
- Zhu, Taohe; Hu, Qiyang; Yan, Guochun
- Energy Technology, Vol. 7, Issue 9
Surface Modification of Li 1.144 Ni 0.136 Co 0.136 Mn 0.544 O 2 by Hybrid Protection Layer with Enhanced Rate Capability
journal, January 2020
- Liao, Yingling; Li, Jianbin; Deng, Bangwei
- Energy Technology, Vol. 8, Issue 5
Novel Sepiolite‐Based Materials for Lithium‐ and Sodium‐Ion Storage
journal, December 2019
- Jiang, Wenwu; Jiang, Yunhong; Zhao, Shijun
- Energy Technology, Vol. 8, Issue 3
A new lithium‐rich layer‐structured cathode material with improved electrochemical performance and voltage maintenance
journal, July 2019
- Tian, Xiaoqing; Liu, Shengzhou; Jiang, Xueqin
- International Journal of Energy Research
SiOx‐Modified Biocarbon Materials Derived from Shaddock Peel for Li–Ion Batteries
journal, August 2019
- Li, Feng; Deng, Chaohua; Liu, Xing
- ChemistrySelect, Vol. 4, Issue 29
Critical Advances in Ambient Air Operation of Nonaqueous Rechargeable Li–Air Batteries
journal, September 2019
- Liu, Lili; Guo, Haipeng; Fu, Lijun
- Small
Boosting Cell Performance of LiNi 0.8 Co 0.15 Al 0.05 O 2 via Surface Structure Design
journal, October 2019
- Zheng, Junchao; Yang, Zhuo; Dai, Alvin
- Small, Vol. 15, Issue 50
Enhanced electrochemical performance of LiNi0.8Co0.1Mn0.1O2 cathode via wet-chemical coating of MgO
journal, June 2019
- Ma, Fei; Wu, Yinghong; Wei, Guangye
- Journal of Solid State Electrochemistry, Vol. 23, Issue 7
Electrospun PI@GO separators for Li-ion batteries: a possible solution for high-temperature operation
journal, June 2019
- Song, Kedong; Huang, Yuting; Liu, Xing
- Journal of Sol-Gel Science and Technology, Vol. 94, Issue 1
Enhanced electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material with bamboo essential oil
journal, September 2019
- Song, Changkun; Feng, Wangjun; Wang, Xuan
- Ionics, Vol. 26, Issue 2
Nickel sulfide nanocrystals on nitrogen-doped porous carbon nanotubes with high-efficiency electrocatalysis for room-temperature sodium-sulfur batteries
journal, October 2019
- Yan, Zichao; Xiao, Jin; Lai, Weihong
- Nature Communications, Vol. 10, Issue 1
Advances in nanostructures fabricated via spray pyrolysis and their applications in energy storage and conversion
journal, January 2019
- Leng, Jin; Wang, Zhixing; Wang, Jiexi
- Chemical Society Reviews, Vol. 48, Issue 11
Exploring the origin of electrochemical performance of Cr-doped LiNi 0.5 Mn 1.5 O 4
journal, January 2020
- Li, Fei; Ma, Jiani; Lin, Jianyan
- Physical Chemistry Chemical Physics, Vol. 22, Issue 7
Monolayer triphosphates MP 3 (M = Sn, Ge) with excellent basal catalytic activity for hydrogen evolution reaction
journal, January 2019
- Wu, Hong-Hui; Huang, He; Zhong, Jie
- Nanoscale, Vol. 11, Issue 25
Out-of-plane ion transport makes nitrogenated holey graphite a promising high-rate anode for both Li and Na ion batteries
journal, January 2019
- Huang, He; Wu, Hong-Hui; Chi, Cheng
- Nanoscale, Vol. 11, Issue 40
Rate-independent and ultra-stable low-temperature sodium storage in pseudocapacitive TiO 2 nanowires
journal, January 2019
- Lin, Dongmei; Li, Kaikai; Wang, Qian
- Journal of Materials Chemistry A, Vol. 7, Issue 33
Mesoporous aluminium manganese cobalt oxide with pentahedron structures for energy storage devices
journal, January 2019
- Wu, Chun; Zhu, Ying; Guan, Cao
- Journal of Materials Chemistry A, Vol. 7, Issue 31
Origins of capacity and voltage fading of LiCoO 2 upon high voltage cycling
journal, January 2019
- Jiang, Yuyuan; Qin, Changdong; Yan, Pengfei
- Journal of Materials Chemistry A, Vol. 7, Issue 36
Rational design of 3D N-doped carbon nanosheet framework encapsulated ultrafine ZnO nanocrystals as superior performance anode materials in lithium ion batteries
journal, January 2019
- Li, Jianding; Zhao, Huajun; Wang, Meimei
- Journal of Materials Chemistry A, Vol. 7, Issue 43
Decoration by dual-phase Li 2 ZrO 3 islands with core–shell structures enhances the electrochemical performance of high-voltage LiNi 0.5 Mn 1.5 O 4
journal, January 2020
- Zhao, R.; Li, L.; Li, Y. P.
- Applied Physics Letters, Vol. 116, Issue 2
Safety Issues in Lithium Ion Batteries: Materials and Cell Design
journal, July 2019
- Wu, Xiangkun; Song, Kaifang; Zhang, Xiaoyan
- Frontiers in Energy Research, Vol. 7
Effect of Different Composition on Voltage Attenuation of Li-Rich Cathode Material for Lithium-Ion Batteries
journal, December 2019
- Liu, Jun; Liu, Qiming; Zhu, Huali
- Materials, Vol. 13, Issue 1
The Effects of Reversibility of H2-H3 Phase Transition on Ni-Rich Layered Oxide Cathode for High-Energy Lithium-Ion Batteries
journal, July 2019
- Chen, Jie; Yang, Huiping; Li, Tianhao
- Frontiers in Chemistry, Vol. 7
Effect of Different Composition on Voltage Attenuation of Li-Rich Cathode Material for Lithium-Ion Batteries
journal, December 2019
- Liu, Jun; Liu, Qiming; Zhu, Huali
- Materials, Vol. 13, Issue 1