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Title: Hybrid Li-Ion and Li-O 2 Battery Enabled by Oxyhalogen-Sulfur Electrochemistry

Abstract

We report that the large voltage hysteresis between charge and discharge results in significant energy loss, which hinders practical application of the high-energy Li-O 2 battery. Oxyhalogen-sulfur electrochemistry offers a new hybrid Li-ion/Li-O 2 battery, where both Li ions and O anions are reversibly stored in the MoS 2 structure. A Li 2MoO 2S 2 compound is formed as the main discharge product that has never been previously observed in the literature. The reaction mechanism and the structure of the Li 2MoO 2S 2 are probed by Raman spectroscopy, X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, differential electrochemical mass spectrometry, and UV-visible spectroscopy. The results show that the MoS 2 is oxidized during discharge and is recovered during charge. The iodine intermediates play an important role in triggering the sequence of electrochemical and chemical reactions in the cell. Finally, the Li 2MoO 2S 2 is isostructural to the Li 2MoO 4 rather than adopting structures of other known molybdenum oxysulfides.

Authors:
 [1];  [1];  [2];  [3];  [3];  [1];  [1];  [1];  [1];  [1];  [1];  [2];  [2]; ORCiD logo [1]
  1. University of California San Diego, La Jolla, CA (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Argonne National Lab. (ANL), Lemont, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Science Foundation (NSF)
OSTI Identifier:
1493717
Grant/Contract Number:  
AC02-06CH11357; AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Joule
Additional Journal Information:
Journal Volume: 2; Journal Issue: 11; Journal ID: ISSN 2542-4351
Publisher:
Elsevier - Cell Press
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; hybrid Li-ion/Li-O2 battery; oxyhalogen-sulfur electrochemistry; Li-O2 battery; MoS2; molybdenum oxysulfides; Li2MoO2S2; oxyhalogen-sulfur chemistry; thiomolybdates; iodine intermediates

Citation Formats

Wang, Xuefeng, Li, Yejing, Bi, Xuanxuan, Ma, Lu, Wu, Tianpin, Sina, Mahsa, Wang, Shen, Zhang, Minghao, Alvarado, Judith, Lu, Bingyu, Banerjee, Abhik, Amine, Khalil, Lu, Jun, and Meng, Ying Shirley. Hybrid Li-Ion and Li-O2 Battery Enabled by Oxyhalogen-Sulfur Electrochemistry. United States: N. p., 2018. Web. doi:10.1016/j.joule.2018.07.019.
Wang, Xuefeng, Li, Yejing, Bi, Xuanxuan, Ma, Lu, Wu, Tianpin, Sina, Mahsa, Wang, Shen, Zhang, Minghao, Alvarado, Judith, Lu, Bingyu, Banerjee, Abhik, Amine, Khalil, Lu, Jun, & Meng, Ying Shirley. Hybrid Li-Ion and Li-O2 Battery Enabled by Oxyhalogen-Sulfur Electrochemistry. United States. doi:10.1016/j.joule.2018.07.019.
Wang, Xuefeng, Li, Yejing, Bi, Xuanxuan, Ma, Lu, Wu, Tianpin, Sina, Mahsa, Wang, Shen, Zhang, Minghao, Alvarado, Judith, Lu, Bingyu, Banerjee, Abhik, Amine, Khalil, Lu, Jun, and Meng, Ying Shirley. Thu . "Hybrid Li-Ion and Li-O2 Battery Enabled by Oxyhalogen-Sulfur Electrochemistry". United States. doi:10.1016/j.joule.2018.07.019.
@article{osti_1493717,
title = {Hybrid Li-Ion and Li-O2 Battery Enabled by Oxyhalogen-Sulfur Electrochemistry},
author = {Wang, Xuefeng and Li, Yejing and Bi, Xuanxuan and Ma, Lu and Wu, Tianpin and Sina, Mahsa and Wang, Shen and Zhang, Minghao and Alvarado, Judith and Lu, Bingyu and Banerjee, Abhik and Amine, Khalil and Lu, Jun and Meng, Ying Shirley},
abstractNote = {We report that the large voltage hysteresis between charge and discharge results in significant energy loss, which hinders practical application of the high-energy Li-O2 battery. Oxyhalogen-sulfur electrochemistry offers a new hybrid Li-ion/Li-O2 battery, where both Li ions and O anions are reversibly stored in the MoS2 structure. A Li2MoO2S2 compound is formed as the main discharge product that has never been previously observed in the literature. The reaction mechanism and the structure of the Li2MoO2S2 are probed by Raman spectroscopy, X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, differential electrochemical mass spectrometry, and UV-visible spectroscopy. The results show that the MoS2 is oxidized during discharge and is recovered during charge. The iodine intermediates play an important role in triggering the sequence of electrochemical and chemical reactions in the cell. Finally, the Li2MoO2S2 is isostructural to the Li2MoO4 rather than adopting structures of other known molybdenum oxysulfides.},
doi = {10.1016/j.joule.2018.07.019},
journal = {Joule},
number = 11,
volume = 2,
place = {United States},
year = {2018},
month = {8}
}

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This content will become publicly available on August 9, 2019
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