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Title: Elucidating the mobility of H + and Li + ions in (Li 6.25−x H x Al 0.25 )La 3 Zr 2 O 12 via correlative neutron and electron spectroscopy

Neutron and electron spectroscopy reveal diffusion behavior of individual ions in lithium garnets, paving the way towards high-performance aqueous lithium batteries.
Authors:
ORCiD logo [1] ; ORCiD logo [2] ; ORCiD logo [3] ;  [4] ; ORCiD logo [5] ;  [5] ;  [6] ; ORCiD logo [2] ;  [5] ; ORCiD logo [7] ;  [2] ; ORCiD logo [8] ; ORCiD logo [1]
  1. Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, USA
  2. Neutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, USA
  3. Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, USA, Department of Materials Science and Engineering
  4. School of Chemistry and Materials Science, University of Science and Technology of China (USTC), Hefei, China
  5. Mechanical Engineering, University of Michigan, Ann Arbor, USA
  6. Mechanical Engineering, Conn Center for Renewable Energy Research, University of Louisville, Louisville, USA
  7. Mechanical Engineering, University of Michigan, Ann Arbor, USA, Department of Materials Science and Engineering
  8. Neutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, USA, JCNS-1
Publication Date:
Type:
Publisher's Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Name: Energy & Environmental Science; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1493632

Liu, Xiaoming, Chen, Yan, Hood, Zachary D., Ma, Cheng, Yu, Seungho, Sharafi, Asma, Wang, Hui, An, Ke, Sakamoto, Jeff, Siegel, Donald J., Cheng, Yongqiang, Jalarvo, Niina H., and Chi, Miaofang. Elucidating the mobility of H + and Li + ions in (Li 6.25−x H x Al 0.25 )La 3 Zr 2 O 12 via correlative neutron and electron spectroscopy. United Kingdom: N. p., Web. doi:10.1039/C8EE02981D.
Liu, Xiaoming, Chen, Yan, Hood, Zachary D., Ma, Cheng, Yu, Seungho, Sharafi, Asma, Wang, Hui, An, Ke, Sakamoto, Jeff, Siegel, Donald J., Cheng, Yongqiang, Jalarvo, Niina H., & Chi, Miaofang. Elucidating the mobility of H + and Li + ions in (Li 6.25−x H x Al 0.25 )La 3 Zr 2 O 12 via correlative neutron and electron spectroscopy. United Kingdom. doi:10.1039/C8EE02981D.
Liu, Xiaoming, Chen, Yan, Hood, Zachary D., Ma, Cheng, Yu, Seungho, Sharafi, Asma, Wang, Hui, An, Ke, Sakamoto, Jeff, Siegel, Donald J., Cheng, Yongqiang, Jalarvo, Niina H., and Chi, Miaofang. 2019. "Elucidating the mobility of H + and Li + ions in (Li 6.25−x H x Al 0.25 )La 3 Zr 2 O 12 via correlative neutron and electron spectroscopy". United Kingdom. doi:10.1039/C8EE02981D.
@article{osti_1493632,
title = {Elucidating the mobility of H + and Li + ions in (Li 6.25−x H x Al 0.25 )La 3 Zr 2 O 12 via correlative neutron and electron spectroscopy},
author = {Liu, Xiaoming and Chen, Yan and Hood, Zachary D. and Ma, Cheng and Yu, Seungho and Sharafi, Asma and Wang, Hui and An, Ke and Sakamoto, Jeff and Siegel, Donald J. and Cheng, Yongqiang and Jalarvo, Niina H. and Chi, Miaofang},
abstractNote = {Neutron and electron spectroscopy reveal diffusion behavior of individual ions in lithium garnets, paving the way towards high-performance aqueous lithium batteries.},
doi = {10.1039/C8EE02981D},
journal = {Energy & Environmental Science},
number = ,
volume = ,
place = {United Kingdom},
year = {2019},
month = {1}
}

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Effect of substitution (Ta, Al, Ga) on the conductivity of Li7La3Zr2O12
journal, May 2012

Study on lithium/air secondary batteries�Stability of NASICON-type lithium ion conducting glass�ceramics with water
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Li�O2 and Li�S batteries with high energy storage
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The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li7La3Zr2O12
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  • Rangasamy, Ezhiyl; Wolfenstine, Jeff; Sakamoto, Jeffrey
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  • DOI: 10.1016/j.ssi.2011.10.022

Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12
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