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Title: Effects of Scavenging, Entrainment, and Aqueous Chemistry on Peroxides and Formaldehyde in Deep Convective Outflow Over the Central and Southeast United States: DEEP CONVECTIVE SCAVENGING, ENTRAINMENT, AND CHEMISTRY

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4];  [5]; ORCiD logo [6]; ORCiD logo [7]; ORCiD logo [8]; ORCiD logo [9]; ORCiD logo [2]; ORCiD logo [10]; ORCiD logo [11]; ORCiD logo [11]; ORCiD logo [9]; ORCiD logo [9]; ORCiD logo [9]
  1. Department of Atmospheric and Oceanic Sciences, University of Colorado Boulder, Boulder CO USA, Laboratory for Atmospheric and Space Physics, University of Colorado Boulder, Boulder CO USA, Cooperative Institute for Research in the Environmental Sciences, University of Colorado Boulder, Boulder CO USA, Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder CO USA
  2. National Center for Atmospheric Research, Boulder CO USA
  3. Department of Atmospheric and Oceanic Sciences, University of Colorado Boulder, Boulder CO USA, Laboratory for Atmospheric and Space Physics, University of Colorado Boulder, Boulder CO USA
  4. Institute of Arctic and Alpine Research, University of Colorado Boulder, Boulder CO USA
  5. National Severe Storms Laboratory, National Oceanic and Atmospheric Administration, Norman OK USA
  6. Department of Atmospheric and Oceanic Science, University of Maryland, College Park MD USA, Kennedy Space Center, National Aeronautics and Space Administration, Merritt Island FL USA
  7. Department of Atmospheric and Oceanic Science, University of Maryland, College Park MD USA
  8. Department of Atmospheric and Oceanic Science, University of Maryland, College Park MD USA, Goddard Space Flight Center, National Aeronautics and Space Administration, Greenbelt MD USA
  9. School of Meteorology, University of Oklahoma, Norman OK USA
  10. Pacific Northwest National Laboratory, Richland WA USA
  11. Department of Atmospheric Science, University of Alabama, Huntsville AL USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1493469
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Geophysical Research: Atmospheres
Additional Journal Information:
Journal Name: Journal of Geophysical Research: Atmospheres Journal Volume: 123 Journal Issue: 14; Journal ID: ISSN 2169-897X
Publisher:
American Geophysical Union (AGU)
Country of Publication:
United States
Language:
English

Citation Formats

Bela, Megan M., Barth, Mary C., Toon, Owen Brian, Fried, Alan, Ziegler, Conrad, Cummings, Kristin A., Li, Yunyao, Pickering, Kenneth E., Homeyer, Cameron R., Morrison, Hugh, Yang, Qing, Mecikalski, Retha M., Carey, Larry, Biggerstaff, Michael I., Betten, Daniel P., and Alford, A. Addison. Effects of Scavenging, Entrainment, and Aqueous Chemistry on Peroxides and Formaldehyde in Deep Convective Outflow Over the Central and Southeast United States: DEEP CONVECTIVE SCAVENGING, ENTRAINMENT, AND CHEMISTRY. United States: N. p., 2018. Web. doi:10.1029/2018JD028271.
Bela, Megan M., Barth, Mary C., Toon, Owen Brian, Fried, Alan, Ziegler, Conrad, Cummings, Kristin A., Li, Yunyao, Pickering, Kenneth E., Homeyer, Cameron R., Morrison, Hugh, Yang, Qing, Mecikalski, Retha M., Carey, Larry, Biggerstaff, Michael I., Betten, Daniel P., & Alford, A. Addison. Effects of Scavenging, Entrainment, and Aqueous Chemistry on Peroxides and Formaldehyde in Deep Convective Outflow Over the Central and Southeast United States: DEEP CONVECTIVE SCAVENGING, ENTRAINMENT, AND CHEMISTRY. United States. doi:https://doi.org/10.1029/2018JD028271
Bela, Megan M., Barth, Mary C., Toon, Owen Brian, Fried, Alan, Ziegler, Conrad, Cummings, Kristin A., Li, Yunyao, Pickering, Kenneth E., Homeyer, Cameron R., Morrison, Hugh, Yang, Qing, Mecikalski, Retha M., Carey, Larry, Biggerstaff, Michael I., Betten, Daniel P., and Alford, A. Addison. Thu . "Effects of Scavenging, Entrainment, and Aqueous Chemistry on Peroxides and Formaldehyde in Deep Convective Outflow Over the Central and Southeast United States: DEEP CONVECTIVE SCAVENGING, ENTRAINMENT, AND CHEMISTRY". United States. doi:https://doi.org/10.1029/2018JD028271.
@article{osti_1493469,
title = {Effects of Scavenging, Entrainment, and Aqueous Chemistry on Peroxides and Formaldehyde in Deep Convective Outflow Over the Central and Southeast United States: DEEP CONVECTIVE SCAVENGING, ENTRAINMENT, AND CHEMISTRY},
author = {Bela, Megan M. and Barth, Mary C. and Toon, Owen Brian and Fried, Alan and Ziegler, Conrad and Cummings, Kristin A. and Li, Yunyao and Pickering, Kenneth E. and Homeyer, Cameron R. and Morrison, Hugh and Yang, Qing and Mecikalski, Retha M. and Carey, Larry and Biggerstaff, Michael I. and Betten, Daniel P. and Alford, A. Addison},
abstractNote = {},
doi = {10.1029/2018JD028271},
journal = {Journal of Geophysical Research: Atmospheres},
number = 14,
volume = 123,
place = {United States},
year = {2018},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: https://doi.org/10.1029/2018JD028271

Citation Metrics:
Cited by: 6 works
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Works referenced in this record:

Scavenging of acidic gases (HCOOH, CH 3 COOH, HNO 3 , HCl, and SO 2 ) and ammonia in mixed liquid-solid water clouds at the Puy de Dôme mountain (France)
journal, March 2000

  • Voisin, Didier; Legrand, Michel; Chaumerliac, Nadine
  • Journal of Geophysical Research: Atmospheres, Vol. 105, Issue D5
  • DOI: 10.1029/1999JD900983

Combined Satellite- and Surface-Based Estimation of the Intracloud–Cloud-to-Ground Lightning Ratio over the Continental United States
journal, January 2001


Wind tunnel experiments on the retention of trace gases during riming: nitric acid, hydrochloric acid, and hydrogen peroxide
journal, January 2011


A New Vertical Diffusion Package with an Explicit Treatment of Entrainment Processes
journal, September 2006

  • Hong, Song-You; Noh, Yign; Dudhia, Jimy
  • Monthly Weather Review, Vol. 134, Issue 9
  • DOI: 10.1175/MWR3199.1

A Diabatic Lagrangian Technique for the Analysis of Convective Storms. Part II: Application to a Radar-Observed Storm
journal, October 2013


The retention of ammonia and sulfur dioxide during riming of ice particles and dendritic snow flakes: laboratory experiments in the Mainz vertical wind tunnel
journal, June 2013

  • v. Blohn, Nadine; Diehl, Karoline; Nölscher, Anke
  • Journal of Atmospheric Chemistry, Vol. 70, Issue 2
  • DOI: 10.1007/s10874-013-9261-x

Kinetics of aqueous phase reactions of the SO 4 radical with potential importance in cloud chemistry
journal, January 1989

  • Wine, P. H.; Tang, Y.; Thorn, R. P.
  • Journal of Geophysical Research, Vol. 94, Issue D1
  • DOI: 10.1029/JD094iD01p01085

Aqueous phase oxidation of sulfur(IV) by hydrogen peroxide, methylhydroperoxide, and peroxyacetic acid
journal, January 1987

  • Lind, John A.; Lazrus, Allan L.; Kok, Gregory L.
  • Journal of Geophysical Research, Vol. 92, Issue D4
  • DOI: 10.1029/JD092iD04p04171

A simple lightning parameterization for calculating global lightning distributions
journal, June 1992

  • Price, Colin; Rind, David
  • Journal of Geophysical Research: Atmospheres, Vol. 97, Issue D9
  • DOI: 10.1029/92JD00719

Reactions of hydroxyl radicals with hydrogen peroxide at ambient and elevated temperatures
journal, April 1982

  • Christensen, Hilbert; Sehested, Knud; Corfitzen, Hanne
  • The Journal of Physical Chemistry, Vol. 86, Issue 9
  • DOI: 10.1021/j100206a023

A cloud chemistry module for the 3-D cloud-resolving mesoscale model Meso-NH with application to idealized cases
journal, January 2013

  • Leriche, M.; Pinty, J. -P.; Mari, C.
  • Geoscientific Model Development, Vol. 6, Issue 4
  • DOI: 10.5194/gmd-6-1275-2013

Fully coupled “online” chemistry within the WRF model
journal, December 2005


Photodissociation in the atmosphere: 1. Actinic flux and the effects of ground reflections and clouds
journal, January 1987


A New Double-Moment Microphysics Parameterization for Application in Cloud and Climate Models. Part I: Description
journal, June 2005

  • Morrison, H.; Curry, J. A.; Khvorostyanov, V. I.
  • Journal of the Atmospheric Sciences, Vol. 62, Issue 6
  • DOI: 10.1175/JAS3446.1

Deep convective clouds with sustained supercooled liquid water down to -37.5 °C
journal, May 2000

  • Rosenfeld, Daniel; Woodley, William L.
  • Nature, Vol. 405, Issue 6785
  • DOI: 10.1038/35013030

The fate of volatile chemicals during wet growth of a hailstone
journal, January 2009


Numerical simulations of the July 10, 1996, Stratospheric-Tropospheric Experiment: Radiation, Aerosols, and Ozone (STERAO)-Deep Convection experiment storm: Redistribution of soluble tracers
journal, June 2001

  • Barth, M. C.; Stuart, A. L.; Skamarock, W. C.
  • Journal of Geophysical Research: Atmospheres, Vol. 106, Issue D12
  • DOI: 10.1029/2001JD900139

Tropospheric Aerosol Optical Thickness from the GOCART Model and Comparisons with Satellite and Sun Photometer Measurements
journal, February 2002


The Shared Mobile Atmospheric Research and Teaching Radar: A Collaboration to Enhance Research and Teaching
journal, September 2005

  • Biggerstaff, Michael I.; Wicker, Louis J.; Guynes, Jerry
  • Bulletin of the American Meteorological Society, Vol. 86, Issue 9
  • DOI: 10.1175/BAMS-86-9-1263

Model sensitivity studies regarding the role of the retention coefficient for the scavenging and redistribution of highly soluble trace gases by deep convective cloud systems
journal, January 2007

  • Salzmann, M.; Lawrence, M. G.; Phillips, V. T. J.
  • Atmospheric Chemistry and Physics, Vol. 7, Issue 8
  • DOI: 10.5194/acp-7-2027-2007

Kinetics and mechanism of the formation of hydroxymethanesulfonic acid at low pH
journal, September 1984

  • Boyce, Scott D.; Hoffmann, Michael R.
  • The Journal of Physical Chemistry, Vol. 88, Issue 20
  • DOI: 10.1021/j150664a059

Decomposition of ozone in water: rate of initiation by hydroxide ions and hydrogen peroxide
journal, October 1982

  • Staehelin, Johannes.; Hoigne, Juerg.
  • Environmental Science & Technology, Vol. 16, Issue 10
  • DOI: 10.1021/es00104a009

Laboratory and modelling studies of tropospheric multiphase conversions involving some C1 and C2 peroxyl radicals
journal, January 1999

  • Herrmann, H.; Reese, A.; Ervens, B.
  • Physics and Chemistry of the Earth, Part B: Hydrology, Oceans and Atmosphere, Vol. 24, Issue 3
  • DOI: 10.1016/S1464-1909(98)00052-5

Transport and scavenging of soluble gases in a deep convective cloud
journal, September 2000

  • Mari, Céline; Jacob, Daniel J.; Bechtold, Peter
  • Journal of Geophysical Research: Atmospheres, Vol. 105, Issue D17
  • DOI: 10.1029/2000JD900211

‘Application of a New Spectral Theory of Stably Stratified Turbulence to the Atmospheric Boundary Layer over Sea Ice’
journal, November 2005

  • Sukoriansky, Semion; Galperin, Boris; Perov, Veniamin
  • Boundary-Layer Meteorology, Vol. 117, Issue 2
  • DOI: 10.1007/s10546-004-6848-4

Kinetics and mechanism of the oxidation of aquated sulfur dioxide by hydrogen peroxide at low pH
journal, December 1983

  • McArdle, James V.; Hoffmann, Michael R.
  • The Journal of Physical Chemistry, Vol. 87, Issue 26
  • DOI: 10.1021/j150644a024

Sensitivity of simulated convection‐driven stratosphere‐troposphere exchange in WRF‐Chem to the choice of physical and chemical parameterization
journal, August 2017

  • Phoenix, Daniel B.; Homeyer, Cameron R.; Barth, Mary C.
  • Earth and Space Science, Vol. 4, Issue 8
  • DOI: 10.1002/2017EA000287

Evaluating Mesoscale NWP Models Using Kinetic Energy Spectra
journal, December 2004

  • Skamarock, William C.
  • Monthly Weather Review, Vol. 132, Issue 12
  • DOI: 10.1175/MWR2830.1

Rate Constants for Reactions of Inorganic Radicals in Aqueous Solution
journal, July 1988

  • Neta, P.; Huie, Robert E.; Ross, Alberta B.
  • Journal of Physical and Chemical Reference Data, Vol. 17, Issue 3
  • DOI: 10.1063/1.555808

The effect of freezing on the composition of supercooled droplets—I. Retention of HCl, HNO3, NH3 and H2O2
journal, January 1990


Hydrogen peroxide, methyl hydroperoxide, and formaldehyde over North America and the North Atlantic
journal, January 2007

  • Snow, Julie A.; Heikes, Brian G.; Shen, Haiwei
  • Journal of Geophysical Research, Vol. 112, Issue D12
  • DOI: 10.1029/2006JD007746

Aircraft Observations of Cumulus Microphysics Ranging from the Tropics to Midlatitudes: Implications for a “New” Secondary Ice Process
journal, September 2017

  • Lawson, Paul; Gurganus, Colin; Woods, Sarah
  • Journal of the Atmospheric Sciences, Vol. 74, Issue 9
  • DOI: 10.1175/JAS-D-17-0033.1

Chemistry of OH in remote clouds and its role in the production of formic acid and peroxymonosulfate
journal, January 1986


The Deep Convective Clouds and Chemistry (DC3) Field Campaign
journal, August 2015

  • Barth, Mary C.; Cantrell, Christopher A.; Brune, William H.
  • Bulletin of the American Meteorological Society, Vol. 96, Issue 8
  • DOI: 10.1175/BAMS-D-13-00290.1

The Fire INventory from NCAR (FINN): a high resolution global model to estimate the emissions from open burning
journal, January 2011

  • Wiedinmyer, C.; Akagi, S. K.; Yokelson, R. J.
  • Geoscientific Model Development, Vol. 4, Issue 3
  • DOI: 10.5194/gmd-4-625-2011

Effect of clouds on photolysis and oxidants in the troposphere
journal, January 2003


Assessing Errors in Variational Dual-Doppler Wind Syntheses of Supercell Thunderstorms Observed by Storm-Scale Mobile Radars
journal, August 2012

  • Potvin, Corey K.; Wicker, Louis J.; Shapiro, Alan
  • Journal of Atmospheric and Oceanic Technology, Vol. 29, Issue 8
  • DOI: 10.1175/JTECH-D-11-00177.1

Factors influencing the retention of hydrogen peroxide and molecular oxygen in rime ice
journal, January 1998

  • Snider, Jefferson R.; Huang, Jun
  • Journal of Geophysical Research: Atmospheres, Vol. 103, Issue D1
  • DOI: 10.1029/97JD02847

Radiative forcing by long-lived greenhouse gases: Calculations with the AER radiative transfer models
journal, January 2008

  • Iacono, Michael J.; Delamere, Jennifer S.; Mlawer, Eli J.
  • Journal of Geophysical Research, Vol. 113, Issue D13
  • DOI: 10.1029/2008JD009944

Transport of ozone to the surface by convective downdrafts at night
journal, January 2002


Radar and Lightning Observations of Deep Moist Convection across Northern Alabama during DC3: 21 May 2012
journal, July 2015

  • Mecikalski, Retha Matthee; Bain, Anthony L.; Carey, Lawrence D.
  • Monthly Weather Review, Vol. 143, Issue 7
  • DOI: 10.1175/MWR-D-14-00250.1

Bulk Parameterization of the Snow Field in a Cloud Model
journal, June 1983


Sensitivity of a Simulated Squall Line to Horizontal Resolution and Parameterization of Microphysics
journal, January 2012


Evolution of ozone, particulates, and aerosol direct radiative forcing in the vicinity of Houston using a fully coupled meteorology-chemistry-aerosol model
journal, January 2006

  • Fast, Jerome D.; Gustafson, William I.; Easter, Richard C.
  • Journal of Geophysical Research, Vol. 111, Issue D21
  • DOI: 10.1029/2005JD006721

Chemistry of riming: the retention of organic and inorganic atmospheric trace constituents
journal, January 2017

  • Jost, Alexander; Szakáll, Miklós; Diehl, Karoline
  • Atmospheric Chemistry and Physics, Vol. 17, Issue 16
  • DOI: 10.5194/acp-17-9717-2017

REEVALUATION OF THE SPECTRAL AND KINETIC PROPERTIES OF HO 2 AND O 2 - FREE RADICALS
journal, October 1978


Rate constants for some oxidations of S(IV) by radicals in aqueous solutions
journal, January 1987


Reaction of Dihydroxymethyl Radical with Molecular Oxygen in Aqueous Solution
journal, August 1980

  • Bothe, Eberhard; Schulte-Frohlinde, Dietrich
  • Zeitschrift für Naturforschung B, Vol. 35, Issue 8
  • DOI: 10.1515/znb-1980-0821

Convective injection and photochemical decay of peroxides in the tropical upper troposphere: Methyl iodide as a tracer of marine convection
journal, March 1999

  • Cohan, Daniel S.; Schultz, Martin G.; Jacob, Daniel J.
  • Journal of Geophysical Research: Atmospheres, Vol. 104, Issue D5
  • DOI: 10.1029/98JD01963

Resolution Requirements for the Simulation of Deep Moist Convection
journal, October 2003


The role of clouds in tropospheric photochemistry
journal, April 1991

  • Lelieveld, J.; Crutzen, P. J.
  • Journal of Atmospheric Chemistry, Vol. 12, Issue 3
  • DOI: 10.1007/BF00048075

Summary of the cloud chemistry modeling intercomparison: Photochemical box model simulation
journal, January 2003


Downward transport of ozone rich air and implications for atmospheric chemistry in the Amazon rainforest
journal, January 2016


Flash propagation and inferred charge structure relative to radar‐observed ice alignment signatures in a small Florida mesoscale convective system
journal, August 2017

  • Biggerstaff, Michael I.; Zounes, Zackery; Addison Alford, A.
  • Geophysical Research Letters, Vol. 44, Issue 15
  • DOI: 10.1002/2017GL074610

Description and evaluation of the Model for Ozone and Related chemical Tracers, version 4 (MOZART-4)
journal, January 2010

  • Emmons, L. K.; Walters, S.; Hess, P. G.
  • Geoscientific Model Development, Vol. 3, Issue 1
  • DOI: 10.5194/gmd-3-43-2010

Hydrogen peroxide retention in rime ice
journal, January 1992

  • Snider, Jefferson R.; Montague, Derek C.; Vali, Gabor
  • Journal of Geophysical Research, Vol. 97, Issue D7
  • DOI: 10.1029/92JD00237

Relationships between Lightning Location and Polarimetric Radar Signatures in a Small Mesoscale Convective System
journal, December 2009

  • Lund, Nicole R.; MacGorman, Donald R.; Schuur, Terry J.
  • Monthly Weather Review, Vol. 137, Issue 12
  • DOI: 10.1175/2009MWR2860.1

TELEX The Thunderstorm Electrification and Lightning Experiment
journal, July 2008

  • MacGorman, Donald R.; Rust, W. David; Schuur, Terry J.
  • Bulletin of the American Meteorological Society, Vol. 89, Issue 7
  • DOI: 10.1175/2007BAMS2352.1

The impact of North American anthropogenic emissions and lightning on long-range transport of trace gases and their export from the continent during summers 2002 and 2004
journal, January 2011

  • Martini, Matus; Allen, Dale J.; Pickering, Kenneth E.
  • Journal of Geophysical Research, Vol. 116, Issue D7
  • DOI: 10.1029/2010JD014305

Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature)
journal, January 2006

  • Guenther, A.; Karl, T.; Harley, P.
  • Atmospheric Chemistry and Physics, Vol. 6, Issue 11
  • DOI: 10.5194/acp-6-3181-2006