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Title: Casting Nanoporous Platinum in Metal–Organic Frameworks

Abstract

Nanocasting based on porous templates is a powerful strategy in accessing materials and structures that are difficult to form by bottom-up syntheses in a controlled fashion. A facile synthetic strategy for casting ordered, nanoporous platinum (NP-Pt) networks with a high degree of control by using metal-organic frameworks (MOFs) as templates is reported here. The Pt precursor is first infiltrated into zirconium-based MOFs and subsequently transformed to 3D metallic networks via a chemical reduction process. It is demonstrated that the dimensions and topologies of the cast NP-Pt networks can be accurately controlled by using different MOFs as templates. The Brunauer-Emmett-Teller surface areas of the NP-Pt networks are estimated to be >100 m2 g-1 and they exhibit excellent catalytic activities in the methanol electrooxidation reaction (MEOR). Finally, this new methodology presents an attractive route to prepare well-defined nanoporous materials for diverse applications ranging from energy to sensing and biotechnology.

Authors:
ORCiD logo [1];  [1];  [1];  [1];  [1];  [1];  [1];  [2];  [2]; ORCiD logo [1]
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  1. Univ. of California, Berkeley CA (United States)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Publication Date:
Research Org.:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1581334
Alternate Identifier(s):
OSTI ID: 1493386
Grant/Contract Number:  
AC02-05CH11231; AC02‐05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Volume: 31; Journal Issue: 12; Journal ID: ISSN 0935-9648
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; metal-organic frameworks; methanol electrooxidation reaction; nanocasting; nanoporous platinum

Citation Formats

Gao, Xiang, Pei, Xiaokun, Gardner, David W., Diercks, Christian S., Lee, Seungkyu, Rungtaweevoranit, Bunyarat, Prevot, Mathieu S., Zhu, Chenhui, Fakra, Sirine, and Maboudian, Roya. Casting Nanoporous Platinum in Metal–Organic Frameworks. United States: N. p., 2019. Web. doi:10.1002/adma.201807553.
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Gao, Xiang, Pei, Xiaokun, Gardner, David W., Diercks, Christian S., Lee, Seungkyu, Rungtaweevoranit, Bunyarat, Prevot, Mathieu S., Zhu, Chenhui, Fakra, Sirine, & Maboudian, Roya. Casting Nanoporous Platinum in Metal–Organic Frameworks. United States. https://doi.org/10.1002/adma.201807553
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Gao, Xiang, Pei, Xiaokun, Gardner, David W., Diercks, Christian S., Lee, Seungkyu, Rungtaweevoranit, Bunyarat, Prevot, Mathieu S., Zhu, Chenhui, Fakra, Sirine, and Maboudian, Roya. Sun . "Casting Nanoporous Platinum in Metal–Organic Frameworks". United States. https://doi.org/10.1002/adma.201807553. https://www.osti.gov/servlets/purl/1581334.
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@article{osti_1581334,
title = {Casting Nanoporous Platinum in Metal–Organic Frameworks},
author = {Gao, Xiang and Pei, Xiaokun and Gardner, David W. and Diercks, Christian S. and Lee, Seungkyu and Rungtaweevoranit, Bunyarat and Prevot, Mathieu S. and Zhu, Chenhui and Fakra, Sirine and Maboudian, Roya},
abstractNote = {Nanocasting based on porous templates is a powerful strategy in accessing materials and structures that are difficult to form by bottom-up syntheses in a controlled fashion. A facile synthetic strategy for casting ordered, nanoporous platinum (NP-Pt) networks with a high degree of control by using metal-organic frameworks (MOFs) as templates is reported here. The Pt precursor is first infiltrated into zirconium-based MOFs and subsequently transformed to 3D metallic networks via a chemical reduction process. It is demonstrated that the dimensions and topologies of the cast NP-Pt networks can be accurately controlled by using different MOFs as templates. The Brunauer-Emmett-Teller surface areas of the NP-Pt networks are estimated to be >100 m2 g-1 and they exhibit excellent catalytic activities in the methanol electrooxidation reaction (MEOR). Finally, this new methodology presents an attractive route to prepare well-defined nanoporous materials for diverse applications ranging from energy to sensing and biotechnology.},
doi = {10.1002/adma.201807553},
journal = {Advanced Materials},
number = 12,
volume = 31,
place = {United States},
year = {Sun Jan 27 00:00:00 EST 2019},
month = {Sun Jan 27 00:00:00 EST 2019}
}
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https://doi.org/10.1002/adma.201807553
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Works referenced in this record:

Nanocasting: A Versatile Strategy for Creating Nanostructured Porous Materials
journal, July 2006

Preparation of Noble Metal Nanowires Using Hexagonal Mesoporous Silica SBA-15
journal, August 2000

  • Han, Yong-Jin; Kim, Ji Man; Stucky, Galen D.
  • Chemistry of Materials, Vol. 12, Issue 8
  • DOI: 10.1021/cm0010553

Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks
journal, November 1998

  • Yang, Peidong; Zhao, Dongyuan; Margolese, David I.
  • Nature, Vol. 396, Issue 6707
  • DOI: 10.1038/24132

Synthesis of Highly Ordered Carbon Molecular Sieves via Template-Mediated Structural Transformation
journal, September 1999

  • Ryoo, Ryong; Joo, Sang Hoon; Jun, Shinae
  • The Journal of Physical Chemistry B, Vol. 103, Issue 37
  • DOI: 10.1021/jp991673a

Ordered porous materials for emerging applications
journal, June 2002

Generalized synthesis of periodic surfactant/inorganic composite materials
journal, March 1994

  • Huo, Qisheng; Margolese, David I.; Ciesla, Ulrike
  • Nature, Vol. 368, Issue 6469, p. 317-321
  • DOI: 10.1038/368317a0

Directing Zeolite Structures into Hierarchically Nanoporous Architectures
journal, July 2011

Protocol for the Nanocasting Method: Preparation of Ordered Mesoporous Metal Oxides
journal, September 2016

Synthesis of New, Nanoporous Carbon with Hexagonally Ordered Mesostructure
journal, November 2000

  • Jun, Shinae; Joo, Sang Hoon; Ryoo, Ryong
  • Journal of the American Chemical Society, Vol. 122, Issue 43
  • DOI: 10.1021/ja002261e

A new family of mesoporous molecular sieves prepared with liquid crystal templates
journal, December 1992

  • Beck, J. S.; Vartuli, J. C.; Roth, W. J.
  • Journal of the American Chemical Society, Vol. 114, Issue 27, p. 10834-10843
  • DOI: 10.1021/ja00053a020

Mesoporous Platinum Films from Lyotropic Liquid Crystalline Phases
journal, October 1997

Mesoporous TiO2 single crystals delivering enhanced mobility and optoelectronic device performance
journal, March 2013

  • Crossland, Edward J. W.; Noel, Nakita; Sivaram, Varun
  • Nature, Vol. 495, Issue 7440
  • DOI: 10.1038/nature11936

Lanthanum-catalysed synthesis of microporous 3D graphene-like carbons in a zeolite template
journal, June 2016

  • Kim, Kyoungsoo; Lee, Taekyoung; Kwon, Yonghyun
  • Nature, Vol. 535, Issue 7610
  • DOI: 10.1038/nature18284

Enhanced Hydrogen Storage Capacity of High Surface Area Zeolite-like Carbon Materials
journal, February 2007

  • Yang, Zhuxian; Xia, Yongde; Mokaya, Robert
  • Journal of the American Chemical Society, Vol. 129, Issue 6
  • DOI: 10.1021/ja067149g

Generation of subnanometric platinum with high stability during transformation of a 2D zeolite into 3D
journal, September 2016

  • Liu, Lichen; Díaz, Urbano; Arenal, Raul
  • Nature Materials, Vol. 16, Issue 1
  • DOI: 10.1038/nmat4757

Metal clusters in zeolites: an intriguing class of catalysts
journal, July 1993

  • Sachtler, Wolfgang M. H.
  • Accounts of Chemical Research, Vol. 26, Issue 7
  • DOI: 10.1021/ar00031a005

Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999

  • Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
  • Nature, Vol. 402, Issue 6759, p. 276-279
  • DOI: 10.1038/46248

Functional Porous Coordination Polymers
journal, April 2004

  • Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro
  • Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375
  • DOI: 10.1002/anie.200300610

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

Robust Photogeneration of H2 in Water Using Semiconductor Nanocrystals and a Nickel Catalyst
journal, November 2012

Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002

  • Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
  • Science, Vol. 295, Issue 5554, p. 469-472
  • DOI: 10.1126/science.1067208

Metal-Organic Framework as a Template for Porous Carbon Synthesis
journal, April 2008

  • Liu, Bo; Shioyama, Hiroshi; Akita, Tomoki
  • Journal of the American Chemical Society, Vol. 130, Issue 16
  • DOI: 10.1021/ja7106146

Microporous Brookite-Phase Titania Made by Replication of a Metal–Organic Framework
journal, October 2013

  • Hall, Anthony Shoji; Kondo, Atsushi; Maeda, Kazuyuki
  • Journal of the American Chemical Society, Vol. 135, Issue 44
  • DOI: 10.1021/ja4083254

Application and Limitations of Nanocasting in Metal–Organic Frameworks
journal, February 2018

Metal-Organic Framework Templated Synthesis of Ultrathin, Well-Aligned Metallic Nanowires
journal, February 2015

  • Volosskiy, Boris; Niwa, Kenta; Chen, Yu
  • ACS Nano, Vol. 9, Issue 3
  • DOI: 10.1021/nn5072446

Quasi-MOF: Exposing Inorganic Nodes to Guest Metal Nanoparticles for Drastically Enhanced Catalytic Activity
journal, April 2018

The MOF-driven synthesis of supported palladium clusters with catalytic activity for carbene-mediated chemistry
journal, June 2017

  • Fortea-Pérez, Francisco R.; Mon, Marta; Ferrando-Soria, Jesús
  • Nature Materials, Vol. 16, Issue 7
  • DOI: 10.1038/nmat4910

Ultrafine Gold Clusters Incorporated into a Metal-Organic Framework
journal, December 2010

  • Jiang, Hai-Long; Lin, Qi-Pu; Akita, Tomoki
  • Chemistry - A European Journal, Vol. 17, Issue 1
  • DOI: 10.1002/chem.201002088

Immobilizing Highly Catalytically Active Pt Nanoparticles inside the Pores of Metal–Organic Framework: A Double Solvents Approach
journal, August 2012

  • Aijaz, Arshad; Karkamkar, Abhi; Choi, Young Joon
  • Journal of the American Chemical Society, Vol. 134, Issue 34
  • DOI: 10.1021/ja3043905

Single-Atom-Based Vanadium Oxide Catalysts Supported on Metal–Organic Frameworks: Selective Alcohol Oxidation and Structure–Activity Relationship
journal, June 2018

  • Otake, Ken-ichi; Cui, Yuexing; Buru, Cassandra T.
  • Journal of the American Chemical Society, Vol. 140, Issue 28
  • DOI: 10.1021/jacs.8b05107

Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
journal, March 2014

  • Furukawa, Hiroyasu; Gándara, Felipe; Zhang, Yue-Biao
  • Journal of the American Chemical Society, Vol. 136, Issue 11, p. 4369-4381
  • DOI: 10.1021/ja500330a

Superacidity in Sulfated Metal–Organic Framework-808
journal, September 2014

  • Jiang, Juncong; Gándara, Felipe; Zhang, Yue-Biao
  • Journal of the American Chemical Society, Vol. 136, Issue 37
  • DOI: 10.1021/ja507119n

IR spectroscopic study of Pt/Kl zeolites using adsorption of CO as a molecular probe
journal, January 1991

  • Kustov, Leonid M.; Ostgard, Daniel; Sachtler, Wolfgang M. H.
  • Catalysis Letters, Vol. 9, Issue 1-2
  • DOI: 10.1007/BF00769090

Electrochemical reduction of noble metal compounds in ethylene glycol
journal, April 1999

Shape- and Size-Controlled Synthesis in Hard Templates: Sophisticated Chemical Reduction for Mesoporous Monocrystalline Platinum Nanoparticles
journal, September 2011

  • Wang, Hongjing; Jeong, Hu Young; Imura, Masataka
  • Journal of the American Chemical Society, Vol. 133, Issue 37
  • DOI: 10.1021/ja2058617

Facile Production of Ordered 3D Platinum Nanowire Networks with “Single Diamond” Bicontinuous Cubic Morphology
journal, December 2012

  • Akbar, Samina; Elliott, Joanne M.; Rittman, Martyn
  • Advanced Materials, Vol. 25, Issue 8
  • DOI: 10.1002/adma.201203395

A Highly Stable Zeotype Mesoporous Zirconium Metal-Organic Framework with Ultralarge Pores
journal, November 2014

  • Feng, Dawei; Wang, Kecheng; Su, Jie
  • Angewandte Chemie International Edition, Vol. 54, Issue 1
  • DOI: 10.1002/anie.201409334

Highly Stable Zr(IV)-Based Metal–Organic Frameworks for the Detection and Removal of Antibiotics and Organic Explosives in Water
journal, May 2016

  • Wang, Bin; Lv, Xiu-Liang; Feng, Dawei
  • Journal of the American Chemical Society, Vol. 138, Issue 19
  • DOI: 10.1021/jacs.6b01663

Cooperative Cluster Metalation and Ligand Migration in Zirconium Metal-Organic Frameworks
journal, October 2015

  • Yuan, Shuai; Chen, Ying-Pin; Qin, Junsheng
  • Angewandte Chemie International Edition, Vol. 54, Issue 49
  • DOI: 10.1002/anie.201505625

Shape-Control of Pt–Ru Nanocrystals: Tuning Surface Structure for Enhanced Electrocatalytic Methanol Oxidation
journal, January 2018

  • Huang, Liang; Zhang, Xueping; Wang, Qingqing
  • Journal of the American Chemical Society, Vol. 140, Issue 3
  • DOI: 10.1021/jacs.7b12353

Methanol Electro-Oxidation on the Pt Surface: Revisiting the Cyclic Voltammetry Interpretation
journal, April 2016

  • Chung, Dong Young; Lee, Kyung-Jae; Sung, Yung-Eun
  • The Journal of Physical Chemistry C, Vol. 120, Issue 17
  • DOI: 10.1021/acs.jpcc.5b12303

Atomic origins of the high catalytic activity of nanoporous gold
journal, August 2012

  • Fujita, Takeshi; Guan, Pengfei; McKenna, Keith
  • Nature Materials, Vol. 11, Issue 9
  • DOI: 10.1038/nmat3391

Ultrafine jagged platinum nanowires enable ultrahigh mass activity for the oxygen reduction reaction
journal, November 2016

The atomistic origin of the extraordinary oxygen reduction activity of Pt 3 Ni 7 fuel cell catalysts
journal, January 2015

  • Fortunelli, Alessandro; Goddard III, William A.; Sementa, Luca
  • Chemical Science, Vol. 6, Issue 7
  • DOI: 10.1039/C5SC00840A

Cooperative Cluster Metalation and Ligand Migration in Zirconium Metal-Organic Frameworks
journal, October 2015

  • Yuan, Shuai; Chen, Ying-Pin; Qin, Junsheng
  • Angewandte Chemie, Vol. 127, Issue 49
  • DOI: 10.1002/ange.201505625

A Highly Stable Zeotype Mesoporous Zirconium Metal-Organic Framework with Ultralarge Pores
journal, November 2014

Functional Porous Coordination Polymers
journal, July 2004

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