Supported black phosphorus nanosheets as hydrogen-evolving photocatalyst achieving 5.4% energy conversion efficiency at 353 K

Tian, Bin; Tian, Bining; Smith, Bethany; Scott, M. C.; Hua, Ruinian; Lei, Qin; Tian, Yue

doi:10.1038/s41467-018-03737-4

Title: Supported black phosphorus nanosheets as hydrogen-evolving photocatalyst achieving 5.4% energy conversion efficiency at 353 K

Journal Article · 10 April 2018 · Nature Communications

DOI: https://doi.org/10.1038/s41467-018-03737-4 · OSTI ID:1493270

Tian, Bin ^[1]; Tian, Bining ^[1]; Smith, Bethany ^[2]; Scott, M. C. ^[2]; Hua, Ruinian ^[3]; Lei, Qin ^[1];

^[4]

Taiyuan Univ. of Technology, Taiyuan (China). Key Lab. of Advanced Transducers and Intelligent Control System of Ministry of Education, College of Physics and Optoelectronics
Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry
Dalian Nationalities Univ., Dalian (China). College of Life science
Taiyuan Univ. of Technology, Taiyuan (China). Key Lab. of Advanced Transducers and Intelligent Control System of Ministry of Education, College of Physics and Optoelectronics; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry

Solar-driven water splitting using powdered catalysts is considered as the most economical means for hydrogen generation. However, four-electron-driven oxidation half-reaction showing slow kinetics, accompanying with insufficient light absorption and rapid carrier combination in photocatalysts leads to low solar-to-hydrogen energy conversion efficiency. Here, we report amorphous cobalt phosphide (Co-P)-supported black phosphorus nanosheets employed as photocatalysts can simultaneously address these issues. The nanosheets exhibit robust hydrogen evolution from pure water (pH = 6.8) without bias and hole scavengers, achieving an apparent quantum efficiency of 42.55% at 430 nm and energy conversion efficiency of over 5.4% at 353 K. This photocatalytic activity is attributed to extremely efficient utilization of solar energy (~75% of solar energy) by black phosphorus nanosheets and high-carrier separation efficiency by amorphous Co-P. The hybrid material design realizes efficient solar-to-chemical energy conversion in suspension, demonstrating the potential of black phosphorus-based materials as catalysts for solar hydrogen production.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1493270

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 9; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Self-regenerated solar-driven photocatalytic water-splitting by urea derived graphitic carbon nitride with platinum nanoparticles Liu, Jinghai; Zhang, Yuewei; Lu, Luhua Chemical Communications, Vol. 48, Issue 70 https://doi.org/10.1039/c2cc33644h	journal	January 2012
Structure of chemically derived mono- and few-atomic-layer boron nitride sheets Han, Wei-Qiang; Wu, Lijun; Zhu, Yimei Applied Physics Letters, Vol. 93, Issue 22 https://doi.org/10.1063/1.3041639	journal	December 2008
Efficient Photochemical Water Splitting by a Chemically Modified n-TiO2 Khan, S. U. M. Science, Vol. 297, Issue 5590 https://doi.org/10.1126/science.1075035	journal	September 2002
Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway Liu, Juan; Liu, Yang; Liu, Naiyun Science, Vol. 347, Issue 6225 https://doi.org/10.1126/science.aaa3145	journal	February 2015
Phosphorous Alloying and Annealing Effects on the Corrosion Properties of Nanocrystalline Co-P Alloys in Acidic Solution Jung, H.; Alfantazi, A. CORROSION, Vol. 63, Issue 2 https://doi.org/10.5006/1.3278340	journal	February 2007

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Activating Basal Planes of NiPS ₃ for Hydrogen Evolution by Nonmetal Heteroatom Doping Wang, Jun; Li, Xinzhe; Wei, Bin Advanced Functional Materials, Vol. 30, Issue 12 https://doi.org/10.1002/adfm.201908708	journal	February 2020
Direct Z‐Scheme Hetero‐phase Junction of Black/Red Phosphorus for Photocatalytic Water Splitting Liu, Fulai; Shi, Rui; Wang, Zhuan Angewandte Chemie, Vol. 131, Issue 34 https://doi.org/10.1002/ange.201906416	journal	July 2019
Direct Z-Scheme Hetero-phase Junction of Black/Red Phosphorus for Photocatalytic Water Splitting Liu, Fulai; Shi, Rui; Wang, Zhuan Angewandte Chemie International Edition, Vol. 58, Issue 34 https://doi.org/10.1002/anie.201906416	journal	July 2019
Elimination of 4‐chlorophenol in aqueous solution by the Novel Pd/MIL‐101(Cr)‐Hydrogen‐Accelerated catalytic fenton system Liu, Xin; Fan, Jin‐Hong; Liu, Zhong‐Xing Applied Organometallic Chemistry, Vol. 33, Issue 11 https://doi.org/10.1002/aoc.5194	journal	August 2019
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Black Phosphorus‐Based Semiconductor Heterojunctions for Photocatalytic Water Splitting Liu, Fulai; Huang, Chen; Liu, Chu‐Xuan Chemistry – A European Journal, Vol. 26, Issue 20 https://doi.org/10.1002/chem.201904594	journal	January 2020
2D Elemental Nanomaterials Beyond Graphene Vishnoi, Pratap; Pramoda, K.; Rao, C. N. R. ChemNanoMat, Vol. 5, Issue 9 https://doi.org/10.1002/cnma.201900176	journal	June 2019
Construction of Defective Zinc–Cadmium–Sulfur Nanorods for Visible‐Light‐Driven Hydrogen Evolution Without the Use of Sacrificial Agents or Cocatalysts Zhang, Guoqiang; Ling, Xiang; Liu, Guoshuai ChemSusChem, Vol. 13, Issue 4 https://doi.org/10.1002/cssc.201902889	journal	January 2020
Facile One-Step Synthesis of Black Phosphorus via Microwave Irradiation with Excellent Photocatalytic Activity He, Dongyang; Zhang, Zhaocheng; Qu, Jiao Particle & Particle Systems Characterization, Vol. 35, Issue 11 https://doi.org/10.1002/ppsc.201800306	journal	September 2018
Black Phosphorus, a Rising Star 2D Nanomaterial in the Post-Graphene Era: Synthesis, Properties, Modifications, and Photocatalysis Applications Li, Bisheng; Lai, Cui; Zeng, Guangming Small, Vol. 15, Issue 8 https://doi.org/10.1002/smll.201804565	journal	January 2019
High‐Yield Electrochemical Production of Large‐Sized and Thinly Layered NiPS ₃ Flakes for Overall Water Splitting Li, Xinzhe; Fang, Yiyun; Wang, Jun Small, Vol. 15, Issue 30 https://doi.org/10.1002/smll.201902427	journal	June 2019
Recent Progress on Black Phosphorus‐Based Materials for Photocatalytic Water Splitting Yan, Junqing; Verma, Priyanka; Kuwahara, Yasutaka Small Methods, Vol. 2, Issue 12 https://doi.org/10.1002/smtd.201800212	journal	September 2018
Photocatalytic Systems for Carbon Dioxide Conversion to Hydrocarbons Boudjemaa, Amel; Cherifi, Nabila Conversion of Carbon Dioxide into Hydrocarbons Vol. 1 Catalysis, p. 63-89 https://doi.org/10.1007/978-3-030-28622-4_4	book	January 2020
Black phosphorus: an efficient co-catalyst for charge separation and enhanced photocatalytic hydrogen evolution Wu, Jiahao; Huang, Shaolong; Jin, Zhengyuan Journal of Materials Science, Vol. 53, Issue 24 https://doi.org/10.1007/s10853-018-2830-2	journal	August 2018
Room-temperature pyro-catalytic hydrogen generation of 2D few-layer black phosphorene under cold-hot alternation You, Huilin; Jia, Yanmin; Wu, Zheng Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05343-w	journal	July 2018
Stabilizing black phosphorus nanosheets via edge-selective bonding of sacrificial C60 molecules Zhu, Xianjun; Zhang, Taiming; Jiang, Daochuan Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06437-1	journal	October 2018
Two-dimensional amorphous NiO as a plasmonic photocatalyst for solar H2 evolution Lin, Zhaoyong; Du, Chun; Yan, Bo Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06456-y	journal	October 2018
Manipulating spin polarization of titanium dioxide for efficient photocatalysis Pan, Lun; Ai, Minhua; Huang, Chenyu Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14333-w	journal	January 2020
Unusual oxidation-induced core-level shifts at the HfO2/InP interface Mäkelä, Jaakko; Lahti, Antti; Tuominen, Marjukka Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-018-37518-2	journal	February 2019
A heterojunction strategy to improve the visible light sensitive water splitting performance of photocatalytic materials Afroz, Khurshida; Moniruddin, Md; Bakranov, Nurlan Journal of Materials Chemistry A, Vol. 6, Issue 44 https://doi.org/10.1039/c8ta04165b	journal	January 2018
Stable functionalized phosphorenes with photocatalytic HER activity Vishnoi, Pratap; Gupta, Uttam; Pandey, Richa Journal of Materials Chemistry A, Vol. 7, Issue 12 https://doi.org/10.1039/c8ta08497a	journal	January 2019
Black/red phosphorus quantum dots for photocatalytic water splitting: from a type I heterostructure to a Z-scheme system Shi, Rui; Liu, Fulai; Wang, Zhuan Chemical Communications, Vol. 55, Issue 83 https://doi.org/10.1039/c9cc06146k	journal	January 2019
A bio-inspired strategy for enhanced hydrogen evolution: carbonate ions as hole vehicles to promote carrier separation Tan, Tiening; Xie, Jingjing; Wang, Wenxuan Nanoscale, Vol. 11, Issue 24 https://doi.org/10.1039/c9nr04057a	journal	January 2019
An overview of the optical properties and applications of black phosphorus Chen, Xing; Ponraj, Joice Sophia; Fan, Dianyuan Nanoscale, Vol. 12, Issue 6 https://doi.org/10.1039/c9nr09122j	journal	January 2020
Ultra fast metal-free reduction catalyst of partial oxidized violet phosphorus synthesized via controlled mechanical energy Jeong, Rak Hyun; Kim, Dong In; Lee, Ji Won 2D Materials, Vol. 6, Issue 4 https://doi.org/10.1088/2053-1583/ab39c6	journal	September 2019
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