skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Surface characterization and chemical speciation of adsorbed iron( iii ) on oxidized carbon nanoparticles


Iron speciation on oxidized carbon nanoparticles changes with surface concentration.

ORCiD logo [1];  [2];  [3]; ORCiD logo [1]
  1. School of Natural Sciences, Sierra Nevada Research Institute, University of California, Merced, USA
  2. School of Engineering, University of California, Merced, USA
  3. Leonard Davis School of Gerontology, University of Southern California, Los Angeles, USA
Publication Date:
Sponsoring Org.:
OSTI Identifier:
Grant/Contract Number:  
AC02-76SF00515; DE-AC02-05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Environmental Science: Processes & Impacts
Additional Journal Information:
Journal Name: Environmental Science: Processes & Impacts Journal Volume: 21 Journal Issue: 3; Journal ID: ISSN 2050-7887
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom

Citation Formats

Pattammattel, Ajith, Leppert, Valerie J., Forman, Henry Jay, and O'Day, Peggy A.. Surface characterization and chemical speciation of adsorbed iron( iii ) on oxidized carbon nanoparticles. United Kingdom: N. p., 2019. Web.
Pattammattel, Ajith, Leppert, Valerie J., Forman, Henry Jay, & O'Day, Peggy A.. Surface characterization and chemical speciation of adsorbed iron( iii ) on oxidized carbon nanoparticles. United Kingdom.
Pattammattel, Ajith, Leppert, Valerie J., Forman, Henry Jay, and O'Day, Peggy A.. Wed . "Surface characterization and chemical speciation of adsorbed iron( iii ) on oxidized carbon nanoparticles". United Kingdom.
title = {Surface characterization and chemical speciation of adsorbed iron( iii ) on oxidized carbon nanoparticles},
author = {Pattammattel, Ajith and Leppert, Valerie J. and Forman, Henry Jay and O'Day, Peggy A.},
abstractNote = {Iron speciation on oxidized carbon nanoparticles changes with surface concentration.},
doi = {10.1039/C8EM00545A},
journal = {Environmental Science: Processes & Impacts},
number = 3,
volume = 21,
place = {United Kingdom},
year = {2019},
month = {3}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Save / Share:

Works referenced in this record:

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

Review of Recent Advances in Detection of Organic Markers in Fine Particulate Matter and Their Use for Source Apportionment
journal, January 2010

  • Lin, Lin; Lee, Milton L.; Eatough, Delbert J.
  • Journal of the Air & Waste Management Association, Vol. 60, Issue 1
  • DOI: 10.3155/1047-3289.60.1.3

Air pollution–aerosol interactions produce more bioavailable iron for ocean ecosystems
journal, March 2017

HRTEM investigation of some commercially available furnace carbon blacks
journal, January 2004

Organic Aerosol Growth Mechanisms and Their Climate-Forcing Implications
journal, December 2004

Heterogeneous oxidation of atmospheric aerosol particles by gas-phase radicals
journal, August 2010

  • George, I. J.; Abbatt, J. P. D.
  • Nature Chemistry, Vol. 2, Issue 9
  • DOI: 10.1038/nchem.806

Effect of Mild Nitric Acid Oxidation on Dispersability, Size, and Structure of Single-Walled Carbon Nanotubes
journal, November 2007

  • Tchoul, Maxim N.; Ford, Warren T.; Lolli, Giulio
  • Chemistry of Materials, Vol. 19, Issue 23
  • DOI: 10.1021/cm071758l

Improved background-fitting algorithms for ionization edges in electron energy-loss spectra
journal, July 2002

Iron Solubility Related to Particle Sulfur Content in Source Emission and Ambient Fine Particles
journal, May 2012

  • Oakes, M.; Ingall, E. D.; Lai, B.
  • Environmental Science & Technology, Vol. 46, Issue 12
  • DOI: 10.1021/es300701c

Delayed Nrf2-regulated antioxidant gene induction in response to silica nanoparticles
journal, July 2017

Quinones and Aromatic Chemical Compounds in Particulate Matter Induce Mitochondrial Dysfunction: Implications for Ultrafine Particle Toxicity
journal, October 2004

  • Xia, Tian; Korge, Paavo; Weiss, James N.
  • Environmental Health Perspectives, Vol. 112, Issue 14
  • DOI: 10.1289/ehp.7167

XPS Analysis of Combustion Aerosols for Chemical Composition, Surface Chemistry, and Carbon Chemical State
journal, March 2011

  • Vander Wal, Randy L.; Bryg, Vicky M.; Hays, Michael D.
  • Analytical Chemistry, Vol. 83, Issue 6
  • DOI: 10.1021/ac102365s

A review on the human health impact of airborne particulate matter
journal, January 2015

Magnetic properties and Mössbauer spectra of urban atmospheric particulate matter: a case study from Munich, Germany
journal, August 2002

Toxic Potential of Materials at the Nanolevel
journal, February 2006

MANTiS : a program for the analysis of X-ray spectromicroscopy data
journal, July 2014

Characterization and acid-mobilization study of iron-containing mineral dust source materials: IRON-CONTAINING DUST SOURCE MATERIALS
journal, March 2008

  • Cwiertny, David M.; Baltrusaitis, Jonas; Hunter, Gordon J.
  • Journal of Geophysical Research: Atmospheres, Vol. 113, Issue D5
  • DOI: 10.1029/2007JD009332

Measuring reactive oxygen and nitrogen species with fluorescent probes: challenges and limitations
journal, January 2012

Extraction of Polycyclic Aromatic Hydrocarbons from Soot and Sediment:  Solvent Evaluation and Implications for Sorption Mechanism
journal, October 2002

  • Jonker, Michiel T. O.; Koelmans, Albert A.
  • Environmental Science & Technology, Vol. 36, Issue 19
  • DOI: 10.1021/es0103290

Formation and alteration of airborne particles in the subway environment
journal, January 2017

  • Moreno, T.; Querol, X.; Martins, V.
  • Environmental Science: Processes & Impacts, Vol. 19, Issue 1
  • DOI: 10.1039/C6EM00576D

Association of Particulate Air Pollution and Acute Mortality: Involvement of Ultrafine Particles?
journal, January 1995

  • Oberdörster, Günter; Celein, Robert M.; Ferin, Juraj
  • Inhalation Toxicology, Vol. 7, Issue 1
  • DOI: 10.3109/08958379509014275

Activated Carbon Surface Modifications by Nitric Acid, Hydrogen Peroxide, and Ammonium Peroxydisulfate Treatments
journal, November 1995

  • Moreno-Castilla, C.; Ferro-Garcia, M. A.; Joly, J. P.
  • Langmuir, Vol. 11, Issue 11
  • DOI: 10.1021/la00011a035

Iron-mediated lipid peroxidation and lipid raft disruption in low-dose silica-induced macrophage cytokine production
journal, September 2011

Metal concentrations and soluble iron speciation in fine particulate matter from light rail activity in the Denver-Metropolitan area
journal, May 2015

  • Cartledge, Benton T.; Majestic, Brian J.
  • Atmospheric Pollution Research, Vol. 6, Issue 3
  • DOI: 10.5094/APR.2015.055

Inflammatory Properties of Iron-Containing Carbon Nanoparticles
journal, August 2007

  • Waldman, W. James; Kristovich, Robert; Knight, Deborah A.
  • Chemical Research in Toxicology, Vol. 20, Issue 8
  • DOI: 10.1021/tx700008n

Sources, transport and deposition of iron in the global atmosphere
journal, January 2015

  • Wang, R.; Balkanski, Y.; Boucher, O.
  • Atmospheric Chemistry and Physics, Vol. 15, Issue 11
  • DOI: 10.5194/acp-15-6247-2015

Goethite, α-FeO(OH), from single-crystal data
journal, November 2006

  • Yang, Hexiong; Lu, Ren; Downs, Robert T.
  • Acta Crystallographica Section E Structure Reports Online, Vol. 62, Issue 12
  • DOI: 10.1107/S1600536806047258

Properties of Fe-Organic Matter Associations via Coprecipitation versus Adsorption
journal, November 2014

  • Chen, Chunmei; Dynes, James J.; Wang, Jian
  • Environmental Science & Technology, Vol. 48, Issue 23
  • DOI: 10.1021/es503669u

Low dose inflammatory potential of silica particles in human-derived THP-1 macrophage cell culture studies – Mechanism and effects of particle size and iron
journal, June 2017

  • Premshekharan, Gayatri; Nguyen, Kennedy; Zhang, Hongqiao
  • Chemico-Biological Interactions, Vol. 272
  • DOI: 10.1016/j.cbi.2017.05.004

X-ray absorption near edge structure spectroscopic study of Hayabusa category 3 carbonaceous particles
journal, December 2014

  • Yabuta, Hikaru; Uesugi, Masayuki; Naraoka, Hiroshi
  • Earth, Planets and Space, Vol. 66, Issue 1
  • DOI: 10.1186/s40623-014-0156-0

Synthesis, crystal structure and characterization of chiral, three-dimensional anhydrous potassium tris(oxalato)ferrate(III)
journal, November 2012

Red-ox speciation and mixing state of iron in individual African dust particles: Fe IN AFRICAN DUST PARTICLES
journal, June 2012

  • Deboudt, Karine; Gloter, Alexandre; Mussi, Alexandre
  • Journal of Geophysical Research: Atmospheres, Vol. 117, Issue D12
  • DOI: 10.1029/2011JD017298

Photochemical Coupling of Iron Redox Reactions and Transformation of Low-Molecular-Weight Organic Matter
journal, July 2012

  • Wang, Zhaohui; Chen, Chuncheng; Ma, Wanhong
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 15
  • DOI: 10.1021/jz3005333

The role of the iron catalyst in the toxicity of multi-walled carbon nanotubes (MWCNTs)
journal, September 2017

  • Visalli, Giuseppa; Facciolà, Alessio; Iannazzo, Daniela
  • Journal of Trace Elements in Medicine and Biology, Vol. 43
  • DOI: 10.1016/j.jtemb.2017.01.005

A refinement of the crystal structure of ferric acetylacetonate
journal, August 1967

Ultrafine particles in cities
journal, May 2014

Mutation spectrum in FE1-MUTATMMouse lung epithelial cells exposed to nanoparticulate carbon black
journal, October 2010

  • Jacobsen, Nicklas Raun; White, Paul A.; Gingerich, John
  • Environmental and Molecular Mutagenesis, Vol. 52, Issue 4
  • DOI: 10.1002/em.20629

Particulate matter, air quality and climate: lessons learned and future needs
journal, January 2015

  • Fuzzi, S.; Baltensperger, U.; Carslaw, K.
  • Atmospheric Chemistry and Physics, Vol. 15, Issue 14
  • DOI: 10.5194/acp-15-8217-2015

Viscoelastic behavior of carbon black and its relationship with the aggregate size
journal, August 2013

Mechanisms of carbon black formation. Correlation with the morphology of aggregates
journal, January 1994

Particulate air pollution and acute health effects
journal, January 1995

Chemical composition of aerosols collected over the tropical North Atlantic Ocean
journal, June 2000

  • Johansen, Anne M.; Siefert, Ronald L.; Hoffmann, Michael R.
  • Journal of Geophysical Research: Atmospheres, Vol. 105, Issue D12
  • DOI: 10.1029/2000JD900024

Microscopic Observation of Metal-Containing Particles from Chinese Continental Outflow Observed from a Non-Industrial Site
journal, August 2013

  • Li, Weijun; Wang, Tao; Zhou, Shengzhen
  • Environmental Science & Technology, Vol. 47, Issue 16
  • DOI: 10.1021/es400109q

The use of nitrogen adsorption for the characterisation of porous materials
journal, August 2001

Interactions between Ultrafine Particles and Transition Metals in Vivo and in Vitro
journal, November 2002

Arsenic sequestration by sorption processes in high-iron sediments
journal, December 2007

  • Root, Robert A.; Dixit, Suvasis; Campbell, Kate M.
  • Geochimica et Cosmochimica Acta, Vol. 71, Issue 23
  • DOI: 10.1016/j.gca.2007.04.038

Characterisation of iron-rich atmospheric submicrometre particles in the roadside environment
journal, September 2016

Engines and nanoparticles
journal, June 1998

X-ray absorption spectroscopic study of Fe reference compounds for the analysis of natural sediments
journal, April 2004

  • O’Day, Peggy A.; Rivera, Nelson; Root, Robert
  • American Mineralogist, Vol. 89, Issue 4
  • DOI: 10.2138/am-2004-0412

Health Effects of Fine Particulate Air Pollution: Lines that Connect
journal, June 2006

A critical review of assays for hazardous components of air pollution
journal, March 2018

Toxicity of nanomaterials
journal, January 2012

  • Sharifi, Shahriar; Behzadi, Shahed; Laurent, Sophie
  • Chem. Soc. Rev., Vol. 41, Issue 6
  • DOI: 10.1039/C1CS15188F

Iron speciation and mixing in single aerosol particles from the Asian continental outflow: AEROSOL IRON SPECIATION IN ASIAN OUTFLOW
journal, April 2012

  • Moffet, Ryan C.; Furutani, Hiroshi; Rödel, Tobias C.
  • Journal of Geophysical Research: Atmospheres, Vol. 117, Issue D7
  • DOI: 10.1029/2011JD016746