skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: The Effect of Silver Ion Occupancy on Hollandite Lattice Structure

Abstract

The effect of tunnel cations on tunnel size in α-MnO 2structured (hollandite, cryptomelane) materials has long been of interest, as the tunnel size effects catalytic and transport properties. Previous research on the tunnel size has focused on potassium cryptomelane (K xMn 8O 16). This paper uses synthetic control of silver content in Ag xMn 8O 16to investigate the effect that tunnel silver occupancy has on the lattice parameters. Materials with silver (x) content between 1.14 and 1.66 were synthesized, synchrotron diffraction and Rietveld Refinement was used to determine lattice parameters. The lattice parameters were found to contract as silver content increases (from 9.774 Å to 9.738 Å), in contrast to previous investigations of other tunnel cations.

Authors:
 [1];  [1];  [1];  [1];  [2];  [3];  [3];  [1]
  1. Stony Brook Univ., NY (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1492772
Report Number(s):
BNL-210916-2019-JAAM
Journal ID: ISSN 2059-8521; applab
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
MRS Advances
Additional Journal Information:
Journal Volume: 3; Journal Issue: 10; Journal ID: ISSN 2059-8521
Publisher:
Materials Research Society (MRS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Brady, Alexander B., Huang, Jianping, Durham, Jessica L., Smith, Paul F., Bai, Jianming, Takeuchi, Esther S., Marschilok, Amy C., and Takeuchi, Kenneth J. The Effect of Silver Ion Occupancy on Hollandite Lattice Structure. United States: N. p., 2018. Web. doi:10.1557/adv.2018.238.
Brady, Alexander B., Huang, Jianping, Durham, Jessica L., Smith, Paul F., Bai, Jianming, Takeuchi, Esther S., Marschilok, Amy C., & Takeuchi, Kenneth J. The Effect of Silver Ion Occupancy on Hollandite Lattice Structure. United States. doi:10.1557/adv.2018.238.
Brady, Alexander B., Huang, Jianping, Durham, Jessica L., Smith, Paul F., Bai, Jianming, Takeuchi, Esther S., Marschilok, Amy C., and Takeuchi, Kenneth J. Mon . "The Effect of Silver Ion Occupancy on Hollandite Lattice Structure". United States. doi:10.1557/adv.2018.238. https://www.osti.gov/servlets/purl/1492772.
@article{osti_1492772,
title = {The Effect of Silver Ion Occupancy on Hollandite Lattice Structure},
author = {Brady, Alexander B. and Huang, Jianping and Durham, Jessica L. and Smith, Paul F. and Bai, Jianming and Takeuchi, Esther S. and Marschilok, Amy C. and Takeuchi, Kenneth J.},
abstractNote = {The effect of tunnel cations on tunnel size in α-MnO2structured (hollandite, cryptomelane) materials has long been of interest, as the tunnel size effects catalytic and transport properties. Previous research on the tunnel size has focused on potassium cryptomelane (KxMn8O16). This paper uses synthetic control of silver content in AgxMn8O16to investigate the effect that tunnel silver occupancy has on the lattice parameters. Materials with silver (x) content between 1.14 and 1.66 were synthesized, synchrotron diffraction and Rietveld Refinement was used to determine lattice parameters. The lattice parameters were found to contract as silver content increases (from 9.774 Å to 9.738 Å), in contrast to previous investigations of other tunnel cations.},
doi = {10.1557/adv.2018.238},
journal = {MRS Advances},
number = 10,
volume = 3,
place = {United States},
year = {2018},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Figures / Tables:

Figure 1 Figure 1: Selected diffraction data examined in this paper.

Save / Share:

Works referenced in this record:

Synthesis of cryptomelane type α-MnO 2 (K x Mn 8 O 16 ) cathode materials with tunable K + content: the role of tunnel cation concentration on electrochemistry
journal, January 2017

  • Poyraz, Altug S.; Huang, Jianping; Pelliccione, Christopher J.
  • Journal of Materials Chemistry A, Vol. 5, Issue 32
  • DOI: 10.1039/C7TA03476H

Effects of Cu 2+ Ions on the Structure and Reactivity of Todorokite- and Cryptomelane-Type Manganese Oxide Octahedral Molecular Sieves
journal, July 1999

  • Nicolas-Tolentino, Elaine; Tian, Zheng-Rong; Zhou, Hua
  • Chemistry of Materials, Vol. 11, Issue 7
  • DOI: 10.1021/cm9811040

Microwave-Assisted Hydrothermal Synthesis of Cryptomelane-Type Octahedral Molecular Sieves (OMS-2) and Their Catalytic Studies
journal, June 2010

  • Huang, Hui; Sithambaram, Shanthakumar; Chen, Chun-Hu
  • Chemistry of Materials, Vol. 22, Issue 12
  • DOI: 10.1021/cm100220g

Synthesis and Characterization of Ag−Hollandite Nanofibers and Its Catalytic Application in Ethanol Oxidation
journal, August 2007

  • Chen, Junli; Tang, Xingfu; Liu, Junlong
  • Chemistry of Materials, Vol. 19, Issue 17
  • DOI: 10.1021/cm070904k

Selective exchange of divalent transition metal ions in cryptomelane-type manganic acid with tunnel structure
journal, March 1993

  • Tsuji, Masamichi; Komarneni, Sridhar
  • Journal of Materials Research, Vol. 8, Issue 3
  • DOI: 10.1557/JMR.1993.0611

Development of Microstrain in Aged Lithium Transition Metal Oxides
journal, June 2014

  • Lee, Eung-Ju; Chen, Zonghai; Noh, Hyung-Ju
  • Nano Letters, Vol. 14, Issue 8
  • DOI: 10.1021/nl5022859

Ag1.8Mn8O16: Square Planar Coordinated Ag⊕ Ions in the Channels of a Novel Hollandite Variant
journal, November 1984

  • Chang, Fung Ming; Jansen, Martin
  • Angewandte Chemie International Edition in English, Vol. 23, Issue 11
  • DOI: 10.1002/anie.198409061

Synthesis and Characterization of Silver Hollandite and Its Application in Emission Control
journal, August 2005

  • Li, Liyu; King, David L.
  • Chemistry of Materials, Vol. 17, Issue 17
  • DOI: 10.1021/cm0506508

Direct Sonochemical Synthesis of Manganese Octahedral Molecular Sieve (OMS-2) Nanomaterials Using Cosolvent Systems, Their Characterization, and Catalytic Applications
journal, February 2012

  • Dharmarathna, Saminda; King’ondu, Cecil K.; Pedrick, Wyatt
  • Chemistry of Materials, Vol. 24, Issue 4
  • DOI: 10.1021/cm203366m

Sorption Behavior of Radionuclides on Crystalline Synthetic Tunnel Manganese Oxides
journal, December 2000

  • Dyer, Alan; Pillinger, Martyn; Newton, Jon
  • Chemistry of Materials, Vol. 12, Issue 12
  • DOI: 10.1021/cm001142v

The crystal structure of hollandite, the related manganese oxide minerals, and α-MnO2
journal, March 1950


Synthetic Control of Composition and Crystallite Size of Silver Hollandite, Ag x Mn 8 O 16 : Impact on Electrochemistry
journal, September 2012

  • Takeuchi, Kenneth J.; Yau, Shali Z.; Menard, Melissa C.
  • ACS Applied Materials & Interfaces, Vol. 4, Issue 10
  • DOI: 10.1021/am301443g

Structural Defects of Silver Hollandite, Ag x Mn 8 O y , Nanorods: Dramatic Impact on Electrochemistry
journal, July 2015


The structure of K 1.33 Mn 8 O 16 and cation ordering in hollandite-type structures
journal, April 1986

  • Vicat, J.; Fanchon, E.; Strobel, P.
  • Acta Crystallographica Section B Structural Science, Vol. 42, Issue 2
  • DOI: 10.1107/S0108768186098415

Crystal structure of an open-tunnel oxide α-MnO2 analyzed by Rietveld refinements and MEM-based pattern fitting
journal, April 2004

  • Kijima, Norihito; Ikeda, Takuji; Oikawa, Kenichi
  • Journal of Solid State Chemistry, Vol. 177, Issue 4-5
  • DOI: 10.1016/j.jssc.2003.10.038

Symmetry and cation displacements in hollandites: structure refinements of hollandite, cryptomelane and priderite
journal, April 1982

  • Post, J. E.; Von Dreele, R. B.; Buseck, P. R.
  • Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 38, Issue 4
  • DOI: 10.1107/S0567740882004968

GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013


Structural and magnetic properties of hydrothermally synthesized β-MnO2 and α-KxMnO2 nanorods
journal, April 2016


Two-dimensional detector software: From real detector to idealised image or two-theta scan
journal, January 1996

  • Hammersley, A. P.; Svensson, S. O.; Hanfland, M.
  • High Pressure Research, Vol. 14, Issue 4-6, p. 235-248
  • DOI: 10.1080/08957959608201408

The Electrochemistry of Silver Hollandite Nanorods, Ag x Mn 8 O 16 : Enhancement of Electrochemical Battery Performance via Dimensional and Compositional Control
journal, January 2013

  • Takeuchi, Kenneth J.; Yau, Shali Z.; Subramanian, Aditya
  • Journal of The Electrochemical Society, Vol. 160, Issue 5
  • DOI: 10.1149/2.014305jes

Synthesis and Electrochemistry of Silver Hollandite
journal, January 2010

  • Zhu, Shali; Marschilok, Amy C.; Lee, Chia-Ying
  • Electrochemical and Solid-State Letters, Vol. 13, Issue 8
  • DOI: 10.1149/1.3428747

    Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.