The Effect of Silver Ion Occupancy on Hollandite Lattice Structure

Brady, Alexander B.; Huang, Jianping; Durham, Jessica L.; Smith, Paul F.; Bai, Jianming; Takeuchi, Esther S.; Marschilok, Amy C.; Takeuchi, Kenneth J.

doi:10.1557/adv.2018.238

Title: The Effect of Silver Ion Occupancy on Hollandite Lattice Structure

Journal Article · 26 February 2018 · MRS Advances

DOI: https://doi.org/10.1557/adv.2018.238 · OSTI ID:1492772

Brady, Alexander B. ^[1]; Huang, Jianping ^[1]; Durham, Jessica L. ^[1]; Smith, Paul F. ^[1]; Bai, Jianming ^[2]; Takeuchi, Esther S. ^[3]; Marschilok, Amy C. ^[3]; Takeuchi, Kenneth J. ^[1]

Stony Brook Univ., NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States)

The effect of tunnel cations on tunnel size in α-MnO₂structured (hollandite, cryptomelane) materials has long been of interest, as the tunnel size effects catalytic and transport properties. Previous research on the tunnel size has focused on potassium cryptomelane (K_xMn₈O₁₆). This paper uses synthetic control of silver content in Ag_xMn₈O₁₆to investigate the effect that tunnel silver occupancy has on the lattice parameters. Materials with silver (x) content between 1.14 and 1.66 were synthesized, synchrotron diffraction and Rietveld Refinement was used to determine lattice parameters. The lattice parameters were found to contract as silver content increases (from 9.774 Å to 9.738 Å), in contrast to previous investigations of other tunnel cations.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; SC0012673

OSTI ID:: 1492772

Report Number(s):: BNL-210916-2019-JAAM; applab

Journal Information:: MRS Advances, Vol. 3, Issue 10; ISSN 2059-8521

Publisher:: Materials Research Society (MRS)Copyright Statement

Country of Publication:: United States

Language:: English

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