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Title: The Effect of Silver Ion Occupancy on Hollandite Lattice Structure

Abstract

The effect of tunnel cations on tunnel size in α-MnO2structured (hollandite, cryptomelane) materials has long been of interest, as the tunnel size effects catalytic and transport properties. Previous research on the tunnel size has focused on potassium cryptomelane (KxMn8O16). This paper uses synthetic control of silver content in AgxMn8O16to investigate the effect that tunnel silver occupancy has on the lattice parameters. Materials with silver (x) content between 1.14 and 1.66 were synthesized, synchrotron diffraction and Rietveld Refinement was used to determine lattice parameters. The lattice parameters were found to contract as silver content increases (from 9.774 Å to 9.738 Å), in contrast to previous investigations of other tunnel cations.

Authors:
 [1];  [1];  [1];  [1];  [2];  [3];  [3];  [1]
+ Show Author Affiliations
  1. Stony Brook Univ., NY (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1492772
Report Number(s):
BNL-210916-2019-JAAM
Journal ID: ISSN 2059-8521; applab
Grant/Contract Number:  
SC0012704; SC0012673
Resource Type:
Accepted Manuscript
Journal Name:
MRS Advances
Additional Journal Information:
Journal Volume: 3; Journal Issue: 10; Journal ID: ISSN 2059-8521
Publisher:
Materials Research Society (MRS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Brady, Alexander B., Huang, Jianping, Durham, Jessica L., Smith, Paul F., Bai, Jianming, Takeuchi, Esther S., Marschilok, Amy C., and Takeuchi, Kenneth J. The Effect of Silver Ion Occupancy on Hollandite Lattice Structure. United States: N. p., 2018. Web. doi:10.1557/adv.2018.238.
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Brady, Alexander B., Huang, Jianping, Durham, Jessica L., Smith, Paul F., Bai, Jianming, Takeuchi, Esther S., Marschilok, Amy C., & Takeuchi, Kenneth J. The Effect of Silver Ion Occupancy on Hollandite Lattice Structure. United States. https://doi.org/10.1557/adv.2018.238
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Brady, Alexander B., Huang, Jianping, Durham, Jessica L., Smith, Paul F., Bai, Jianming, Takeuchi, Esther S., Marschilok, Amy C., and Takeuchi, Kenneth J. Mon . "The Effect of Silver Ion Occupancy on Hollandite Lattice Structure". United States. https://doi.org/10.1557/adv.2018.238. https://www.osti.gov/servlets/purl/1492772.
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@article{osti_1492772,
title = {The Effect of Silver Ion Occupancy on Hollandite Lattice Structure},
author = {Brady, Alexander B. and Huang, Jianping and Durham, Jessica L. and Smith, Paul F. and Bai, Jianming and Takeuchi, Esther S. and Marschilok, Amy C. and Takeuchi, Kenneth J.},
abstractNote = {The effect of tunnel cations on tunnel size in α-MnO2structured (hollandite, cryptomelane) materials has long been of interest, as the tunnel size effects catalytic and transport properties. Previous research on the tunnel size has focused on potassium cryptomelane (KxMn8O16). This paper uses synthetic control of silver content in AgxMn8O16to investigate the effect that tunnel silver occupancy has on the lattice parameters. Materials with silver (x) content between 1.14 and 1.66 were synthesized, synchrotron diffraction and Rietveld Refinement was used to determine lattice parameters. The lattice parameters were found to contract as silver content increases (from 9.774 Å to 9.738 Å), in contrast to previous investigations of other tunnel cations.},
doi = {10.1557/adv.2018.238},
journal = {MRS Advances},
number = 10,
volume = 3,
place = {United States},
year = {2018},
month = {2}
}
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Publisher's Version of Record
https://doi.org/10.1557/adv.2018.238
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Figure 1 Figure 1: Selected diffraction data examined in this paper.
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Works referenced in this record:

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    Works referencing / citing this record:

    Silver-Containing α-MnO 2  Nanorods: Electrochemistry in Rechargeable Aqueous Zn-MnO 2 Batteries
    journal, January 2019

    • Wang, Lei; Wu, Qiyuan; Abraham, Alyson
    • Journal of The Electrochemical Society, Vol. 166, Issue 15
    • DOI: 10.1149/2.0101915jes

    Capacity Retention for (De)lithiation of Silver Containing α-MnO 2 : Impact of Structural Distortion and Transition Metal Dissolution
    journal, January 2018

    • Huang, Jianping; Housel, Lisa M.; Quilty, Calvin D.
    • Journal of The Electrochemical Society, Vol. 165, Issue 11
    • DOI: 10.1149/2.0371811jes
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