Modulating Blue Phosphorene by Synergetic Codoping: Indirect to Direct Gap Transition and Strong Bandgap Bowing

Tian, Xiaoqing; Duan, Jingyi; Wei, Yadong; Feng, Naixing; Wang, Xiangrong; Gong, Zhirui; Du, Yu; Yakobson, Boris I.

doi:10.1002/adfm.201808721

Title: Modulating Blue Phosphorene by Synergetic Codoping: Indirect to Direct Gap Transition and Strong Bandgap Bowing

Abstract

Abstract The structural and electronic properties of synergistically modified blue phosphorene (BP) is investigated. The inversion and threefold rotational symmetries of BP are broken. The codoping of group IV and VI impurities can turn monolayer BP into direct bandgap semiconductors. The underlying physical mechanism is that group IV and VI impurities tailor the valence band maximum and conduction band minimum, respectively, and move them to Γ. All the bandgaps of monolayer, nanoribbons, and quantum dots of BP can be modulated in a wide range, and the strong bandgap bowing is found. In addition, the Coulomb interactions between the screened impurities are revealed. Lower formation energies indicate the fabricating practicability of synergeticly modified BP. Spin–orbit coupling (SOC) can also be tuned by the introduction of impurities.

Authors:

^[1]; Duan, Jingyi ^[2]; Wei, Yadong ^[2]; Feng, Naixing ^[2]; Wang, Xiangrong ^[3]; Gong, Zhirui ^[2];

^[2]; Yakobson, Boris I. ^[4]

Shenzhen Univ. (China); Hong Kong University of Science and Technology (HKUST) (Hong Kong)
Shenzhen Univ. (China)
Hong Kong University of Science and Technology (HKUST) (Hong Kong)
Rice Univ., Houston, TX (United States)

Publication Date:: Tue Jan 29 00:00:00 EST 2019

Research Org.:: Rice Univ., Houston, TX (United States)

Sponsoring Org.:: USDOE Office of Science (SC); National Natural Sciences Foundation of China (NSFC); National Science Foundation (NSF) of Guangdong; Hong Kong RGC; US Army Research Office (ARO); US Department of the Navy, Office of Naval Research (ONR); R. Welch Foundation

OSTI Identifier:: 1611843

Alternate Identifier(s):: OSTI ID: 1492744

Grant/Contract Number:: SC0012547; 11774296; 1154217; 11734012; 11574218; 11504241; 2018A0303130311; 2016A030313059; 2017A010101018; JCYJ201811915; JCYJ201803053000266; JCYJ20160307142444674; JCYJ20160307111047701; 16300117; 16301816; W911NF-16-1-0255; N00014-15-1-2372; C-1590; DE‐SC0012547

Resource Type:: Accepted Manuscript

Journal Name:: Advanced Functional Materials

Additional Journal Information:: Journal Volume: 29; Journal Issue: 11; Journal ID: ISSN 1616-301X

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; chemistry; science & technology; materials science; physics

Citation Formats


                    Tian, Xiaoqing, Duan, Jingyi, Wei, Yadong, Feng, Naixing, Wang, Xiangrong, Gong, Zhirui, Du, Yu, and Yakobson, Boris I. Modulating Blue Phosphorene by Synergetic Codoping: Indirect to Direct Gap Transition and Strong Bandgap Bowing.  United States: N. p., 2019. 
Web.  doi:10.1002/adfm.201808721.

Copy to clipboard


                    Tian, Xiaoqing, Duan, Jingyi, Wei, Yadong, Feng, Naixing, Wang, Xiangrong, Gong, Zhirui, Du, Yu, & Yakobson, Boris I. Modulating Blue Phosphorene by Synergetic Codoping: Indirect to Direct Gap Transition and Strong Bandgap Bowing.  United States.  https://doi.org/10.1002/adfm.201808721

Copy to clipboard


                    Tian, Xiaoqing, Duan, Jingyi, Wei, Yadong, Feng, Naixing, Wang, Xiangrong, Gong, Zhirui, Du, Yu, and Yakobson, Boris I. Tue .  
"Modulating Blue Phosphorene by Synergetic Codoping: Indirect to Direct Gap Transition and Strong Bandgap Bowing".  United States.  https://doi.org/10.1002/adfm.201808721.  https://www.osti.gov/servlets/purl/1611843.

Copy to clipboard


                    
@article{osti_1611843,

  title        = {Modulating Blue Phosphorene by Synergetic Codoping: Indirect to Direct Gap Transition and Strong Bandgap Bowing},

  author       = {Tian, Xiaoqing and Duan, Jingyi and Wei, Yadong and Feng, Naixing and Wang, Xiangrong and Gong, Zhirui and Du, Yu and Yakobson, Boris I.},

  abstractNote = {Abstract The structural and electronic properties of synergistically modified blue phosphorene (BP) is investigated. The inversion and threefold rotational symmetries of BP are broken. The codoping of group IV and VI impurities can turn monolayer BP into direct bandgap semiconductors. The underlying physical mechanism is that group IV and VI impurities tailor the valence band maximum and conduction band minimum, respectively, and move them to Γ. All the bandgaps of monolayer, nanoribbons, and quantum dots of BP can be modulated in a wide range, and the strong bandgap bowing is found. In addition, the Coulomb interactions between the screened impurities are revealed. Lower formation energies indicate the fabricating practicability of synergeticly modified BP. Spin–orbit coupling (SOC) can also be tuned by the introduction of impurities.},

  doi          = {10.1002/adfm.201808721},

  journal      = {Advanced Functional Materials},

  number       = 11,

  volume       = 29,

  place        = {United States},

  year         = {Tue Jan 29 00:00:00 EST 2019},

  month        = {Tue Jan 29 00:00:00 EST 2019}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1002/adfm.201808721

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 8 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
DOI: 10.1103/PhysRevLett.77.3865

Implanting Germanium into Graphene
journal, April 2018

Tripathi, Mukesh; Markevich, Alexander; Böttger, Roman
ACS Nano, Vol. 12, Issue 5
DOI: 10.1021/acsnano.8b01191

Giant Spin-Orbit Bowing in ${GaAs}_{1 - x} {Bi}_{x}$
journal, August 2006

Fluegel, B.; Francoeur, S.; Mascarenhas, A.
Physical Review Letters, Vol. 97, Issue 6
DOI: 10.1103/PhysRevLett.97.067205

Strain-Modulated Bandgap and Piezo-Resistive Effect in Black Phosphorus Field-Effect Transistors
journal, September 2017

Zhang, Zuocheng; Li, Likai; Horng, Jason
Nano Letters, Vol. 17, Issue 10
DOI: 10.1021/acs.nanolett.7b02624

Growth of Quasi-Free-Standing Single-Layer Blue Phosphorus on Tellurium Monolayer Functionalized Au(111)
journal, April 2017

Gu, Chengding; Zhao, Songtao; Zhang, Jia Lin
ACS Nano, Vol. 11, Issue 5
DOI: 10.1021/acsnano.7b01575

Observation of tunable band gap and anisotropic Dirac semimetal state in black phosphorus
journal, August 2015

Kim, J.; Baik, S. S.; Ryu, S. H.
Science, Vol. 349, Issue 6249
DOI: 10.1126/science.aaa6486

Tunable Chemical Sensing Performance of Black Phosphorus by Controlled Functionalization with Noble Metals
journal, August 2017

Cho, Soo-Yeon; Koh, Hyeong-Jun; Yoo, Hae-Wook
Chemistry of Materials, Vol. 29, Issue 17
DOI: 10.1021/acs.chemmater.7b01353

Electron Doping of Ultrathin Black Phosphorus with Cu Adatoms
journal, March 2016

Koenig, Steven P.; Doganov, Rostislav A.; Seixas, Leandro
Nano Letters, Vol. 16, Issue 4
DOI: 10.1021/acs.nanolett.5b03278

QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials
journal, September 2009

Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola
Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502
DOI: 10.1088/0953-8984/21/39/395502

Strong Valence-Band Offset Bowing of ${ZnO}_{1 - x} S_{x}$ Enhances $p$ -Type Nitrogen Doping of ZnO-like Alloys
journal, October 2006

Persson, Clas; Platzer-Björkman, Charlotte; Malmström, Jonas
Physical Review Letters, Vol. 97, Issue 14
DOI: 10.1103/PhysRevLett.97.146403

Giant and Composition-Dependent Optical Bowing Coefficient in GaAsN Alloys
journal, January 1996

Wei, Su-Huai; Zunger, Alex
Physical Review Letters, Vol. 76, Issue 4
DOI: 10.1103/PhysRevLett.76.664

Strain-Engineering the Anisotropic Electrical Conductance of Few-Layer Black Phosphorus
journal, April 2014

Fei, Ruixiang; Yang, Li
Nano Letters, Vol. 14, Issue 5
DOI: 10.1021/nl500935z

GeSe Thin-Film Solar Cells Fabricated by Self-Regulated Rapid Thermal Sublimation
journal, January 2017

Xue, Ding-Jiang; Liu, Shun-Chang; Dai, Chen-Min
Journal of the American Chemical Society, Vol. 139, Issue 2
DOI: 10.1021/jacs.6b11705

Tunable Optical Gap at a Fixed Lattice Constant in Group-IV Semiconductor Alloys
journal, March 2009

D’Costa, V. R.; Fang, Y. -Y.; Tolle, J.
Physical Review Letters, Vol. 102, Issue 10
DOI: 10.1103/PhysRevLett.102.107403

One-dimensional phosphorus chain and two-dimensional blue phosphorene grown on Au(111) by molecular-beam epitaxy
journal, November 2017

Xu, Jin-Peng; Zhang, Jun-Qiu; Tian, Hao
Physical Review Materials, Vol. 1, Issue 6
DOI: 10.1103/PhysRevMaterials.1.061002

Silicene field-effect transistors operating at room temperature
journal, February 2015

Tao, Li; Cinquanta, Eugenio; Chiappe, Daniele
Nature Nanotechnology, Vol. 10, Issue 3
DOI: 10.1038/nnano.2014.325

Alloy Engineering of Defect Properties in Semiconductors: Suppression of Deep Levels in Transition-Metal Dichalcogenides
journal, September 2015

Huang, Bing; Yoon, Mina; Sumpter, Bobby G.
Physical Review Letters, Vol. 115, Issue 12
DOI: 10.1103/PhysRevLett.115.126806

Single-Layer Single-Crystalline SnSe Nanosheets
journal, January 2013

Li, Lun; Chen, Zhong; Hu, Ying
Journal of the American Chemical Society, Vol. 135, Issue 4
DOI: 10.1021/ja3108017

Strain-Induced Gap Modification in Black Phosphorus
journal, May 2014

Rodin, A. S.; Carvalho, A.; Castro Neto, A. H.
Physical Review Letters, Vol. 112, Issue 17
DOI: 10.1103/PhysRevLett.112.176801

Semiconducting Layered Blue Phosphorus: A Computational Study
journal, May 2014

Zhu, Zhen; Tománek, David
Physical Review Letters, Vol. 112, Issue 17
DOI: 10.1103/PhysRevLett.112.176802

Coulomb engineering of the bandgap and excitons in two-dimensional materials
journal, May 2017

Raja, Archana; Chaves, Andrey; Yu, Jaeeun
Nature Communications, Vol. 8, Issue 1
DOI: 10.1038/ncomms15251

Two-Dimensional SnS: A Phosphorene Analogue with Strong In-Plane Electronic Anisotropy
journal, February 2017

Tian, Zhen; Guo, Chenglei; Zhao, Mingxing
ACS Nano, Vol. 11, Issue 2
DOI: 10.1021/acsnano.6b08704

Light-Induced Exciton Spin Hall Effect in van der Waals Heterostructures
journal, October 2015

Li, Yun-Mei; Li, Jian; Shi, Li-Kun
Physical Review Letters, Vol. 115, Issue 16
DOI: 10.1103/PhysRevLett.115.166804

Sodium-Induced Reordering of Atomic Stacks in Black Phosphorus
journal, January 2017

Cheng, Yingchun; Zhu, Yihan; Han, Yu
Chemistry of Materials, Vol. 29, Issue 3
DOI: 10.1021/acs.chemmater.6b05052

Synthesis and Crystallographic Analysis of Shape-Controlled SnS Nanocrystal Photocatalysts: Evidence for a Pseudotetragonal Structural Modification
journal, July 2013

Biacchi, Adam J.; Vaughn, Dimitri D.; Schaak, Raymond E.
Journal of the American Chemical Society, Vol. 135, Issue 31
DOI: 10.1021/ja405203e

Band Gap Modulated by Electronic Superlattice in Blue Phosphorene
journal, April 2018

Zhuang, Jincheng; Liu, Chen; Gao, Qian
ACS Nano, Vol. 12, Issue 5
DOI: 10.1021/acsnano.8b02953

Epitaxial Growth of Single Layer Blue Phosphorus: A New Phase of Two-Dimensional Phosphorus
journal, July 2016

Zhang, Jia Lin; Zhao, Songtao; Han, Cheng
Nano Letters, Vol. 16, Issue 8
DOI: 10.1021/acs.nanolett.6b01459

Quasiparticle excitations in ${GaAs}_{1 - x}$ $N_{x}$ and ${AlAs}_{1 - x}$ $N_{x}$ ordered alloys
journal, February 1995

Rubio, Angel; Cohen, Marvin L.
Physical Review B, Vol. 51, Issue 7
DOI: 10.1103/PhysRevB.51.4343

Magic Carbon Clusters in the Chemical Vapor Deposition Growth of Graphene
journal, December 2011

Yuan, Qinghong; Gao, Junfeng; Shu, Haibo
Journal of the American Chemical Society, Vol. 134, Issue 6
DOI: 10.1021/ja2050875

Coulomb engineering of the bandgap and excitons in two-dimensional materials
text, January 2017

Raja, Archana; Chaves, Andrey; Yu, Jaeeun
Universität Regensburg
DOI: 10.5283/epub.40514

Semiconducting layered blue phosphorus: A computational study
text, January 2014

Zhu, Zhen; Tomanek, David
arXiv
DOI: 10.48550/arxiv.1403.1300

One-dimensional phosphorus chain and two-dimensional blue phosphorene grown on Au(111) by molecular-beam epitaxy
text, January 2017

Xu, Jin-Peng; Zhang, Jun-Qiu; Tian, Hao
arXiv
DOI: 10.48550/arxiv.1705.07569

Works referencing / citing this record:

Metal-free highly efficient photocatalysts for overall water splitting: C ₃ N ₅ multilayers
journal, January 2020

Qi, Siyun; Fan, Yingcai; Wang, Junru
Nanoscale, Vol. 12, Issue 1
DOI: 10.1039/c9nr08416a

Two-dimensional MoS ₂ /GaN van der Waals heterostructures: tunable direct band alignments and excitonic optical properties for photovoltaic applications
journal, December 2019

Gao, Rui; Liu, Hairui; Liu, Hui
Journal of Physics D: Applied Physics, Vol. 53, Issue 9
DOI: 10.1088/1361-6463/ab5ab9

Similar Records in DOE PAGES and OSTI.GOV collections:

Hexagonal layered group IV–VI semiconductors and derivatives: fresh blood of the 2D family

Journal Article Tian, Xiao-Qing ; Duan, Jing-Yi ; Kiani, Maryam ; ... - Nanoscale

New phases of group IV–VI semiconductors in 2D hexagonal structures are predicted and their unusual physical properties are revealed. The structures of monolayer group IV–VI semiconductors are similar to those of blue phosphorene and each unit has the same ten valence electrons. The band gap of 2D hexagonal group IV–VI semiconductors depends on both the thickness and stacking order. Atomic functionalization can induce ferromagnetism, and the Curie temperature can be tuned. Gapped Dirac fermions with zero mass are developed and this makes it exceed that of graphene. Finally, the Fermi velocity can be compared to or even above that ofmore » graphene.« less
Cited by 14
https://doi.org/10.1039/d0nr02217a

Full Text Available
Bandgap engineering in van der Waals heterostructures of blue phosphorene and MoS{sub 2}: A first principles calculation

Journal Article Zhang, Z. Y. ; Si, M.S., E-mail: sims@lzu.edu.cn ; Peng, S. L. ; ... - Journal of Solid State Chemistry

Blue phosphorene (BP) was theoretically predicted to be thermally stable recently. Considering its similar in-layer hexagonal lattice to MoS{sub 2}, MoS{sub 2} could be an appropriate substrate to grow BP in experiments. In this work, the van der Waals (vdW) heterostructures are constructed by stacking BP on top of MoS{sub 2}. The thermal stability and electronic structures are evaluated based on first principles calculations with vdW-corrected exchange-correlation functional. The formation of the heterostructures is demonstrated to be exothermic and the most stable stacking configuration is confirmed. The heterostructures BP/MoS{sub 2} preserve both the properties of BP and MoS{sub 2} butmore »« less
https://doi.org/10.1016/J.JSSC.2015.07.043
Epitaxial Synthesis of Blue Phosphorene

Journal Article Zhang, Wei ; Enriquez, Hanna ; Tong, Yongfeng ; ... - Small

Abstract Phosphorene is a new 2D material composed of a single or few atomic layers of black phosphorus. Phosphorene has both an intrinsic tunable direct bandgap and high carrier mobility values, which make it suitable for a large variety of optical and electronic devices. However, the synthesis of single‐layer phosphorene is a major challenge. The standard procedure to obtain phosphorene is by exfoliation. More recently, the epitaxial growth of single‐layer phosphorene on Au(111) was investigated by molecular beam epitaxy and the obtained structure described as a blue phosphorene sheet. In the present study, large areas of high‐quality monolayer phosphorene, withmore »« less
Cited by 101
https://doi.org/10.1002/smll.201804066

Full Text Available
Li interaction-induced phase transition from black to blue phosphorene

Journal Article Musa, Md Rajib Khan ; Zhang, Congyan ; Rajapakse, Manthila ; ... - Physical Review Materials

A comprehensive first-principle calculation has been carried out and revealed that at sufficiently high Li concentration and certain well-defined configurations a phase transition from black to blue phosphorene can take place. Blue phosphorene, a newly predicted allotrope of phosphorus, possesses unique crystalline and electronic structure and is a promising candidate, not only for fundamental research but also for electronic and optoelectronic applications. Methods to growth high quality blue phosphorene layers are highly desirable but challenging. Here, a novel kinetic pathway to grow blue phosphorene layers from black phosphorene layers via Li intercalation is proposed based on first principle study. Thismore »« less
https://doi.org/10.1103/physrevmaterials.5.024007

Full Text Available
Ultra‐Narrow Phosphorene Nanoribbons Produced by Facile Electrochemical Process

Journal Article Abu, Usman O. ; Akter, Sharmin ; Nepal, Bimal ; ... - Advanced Science

Abstract Phosphorene nanoribbons (PNRs) have inspired strong research interests to explore their exciting properties that are associated with the unique two‐dimensional (2D) structure of phosphorene as well as the additional quantum confinement of the nanoribbon morphology, providing new materials strategy for electronic and optoelectronic applications. Despite several important properties of PNRs, the production of these structures with narrow widths is still a great challenge. Here, a facile and straightforward approach to synthesize PNRs via an electrochemical process that utilize the anisotropic Na ⁺ diffusion barrier in black phosphorus (BP) along the [001] zigzag direction against the [100] armchair direction, ismore »« less
https://doi.org/10.1002/advs.202203148

Similar Records

Title: Modulating Blue Phosphorene by Synergetic Codoping: Indirect to Direct Gap Transition and Strong Bandgap Bowing

Abstract

Citation Formats

Generalized Gradient Approximation Made Simple journal, October 1996

Implanting Germanium into Graphene journal, April 2018

Giant Spin-Orbit Bowing in GaAs 1 − x Bi x journal, August 2006

Strain-Modulated Bandgap and Piezo-Resistive Effect in Black Phosphorus Field-Effect Transistors journal, September 2017

Growth of Quasi-Free-Standing Single-Layer Blue Phosphorus on Tellurium Monolayer Functionalized Au(111) journal, April 2017

Observation of tunable band gap and anisotropic Dirac semimetal state in black phosphorus journal, August 2015

Tunable Chemical Sensing Performance of Black Phosphorus by Controlled Functionalization with Noble Metals journal, August 2017

Electron Doping of Ultrathin Black Phosphorus with Cu Adatoms journal, March 2016

QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials journal, September 2009

Strong Valence-Band Offset Bowing of ZnO 1 − x S x Enhances p -Type Nitrogen Doping of ZnO-like Alloys journal, October 2006

Giant and Composition-Dependent Optical Bowing Coefficient in GaAsN Alloys journal, January 1996

Strain-Engineering the Anisotropic Electrical Conductance of Few-Layer Black Phosphorus journal, April 2014

GeSe Thin-Film Solar Cells Fabricated by Self-Regulated Rapid Thermal Sublimation journal, January 2017

Tunable Optical Gap at a Fixed Lattice Constant in Group-IV Semiconductor Alloys journal, March 2009

One-dimensional phosphorus chain and two-dimensional blue phosphorene grown on Au(111) by molecular-beam epitaxy journal, November 2017

Silicene field-effect transistors operating at room temperature journal, February 2015

Alloy Engineering of Defect Properties in Semiconductors: Suppression of Deep Levels in Transition-Metal Dichalcogenides journal, September 2015

Single-Layer Single-Crystalline SnSe Nanosheets journal, January 2013

Strain-Induced Gap Modification in Black Phosphorus journal, May 2014

Semiconducting Layered Blue Phosphorus: A Computational Study journal, May 2014

Coulomb engineering of the bandgap and excitons in two-dimensional materials journal, May 2017

Two-Dimensional SnS: A Phosphorene Analogue with Strong In-Plane Electronic Anisotropy journal, February 2017

Light-Induced Exciton Spin Hall Effect in van der Waals Heterostructures journal, October 2015

Sodium-Induced Reordering of Atomic Stacks in Black Phosphorus journal, January 2017

Synthesis and Crystallographic Analysis of Shape-Controlled SnS Nanocrystal Photocatalysts: Evidence for a Pseudotetragonal Structural Modification journal, July 2013

Band Gap Modulated by Electronic Superlattice in Blue Phosphorene journal, April 2018

Epitaxial Growth of Single Layer Blue Phosphorus: A New Phase of Two-Dimensional Phosphorus journal, July 2016

Quasiparticle excitations in GaAs 1 − x N x and AlAs 1 − x N x ordered alloys journal, February 1995

Magic Carbon Clusters in the Chemical Vapor Deposition Growth of Graphene journal, December 2011

Coulomb engineering of the bandgap and excitons in two-dimensional materials text, January 2017

Semiconducting layered blue phosphorus: A computational study text, January 2014

One-dimensional phosphorus chain and two-dimensional blue phosphorene grown on Au(111) by molecular-beam epitaxy text, January 2017

Metal-free highly efficient photocatalysts for overall water splitting: C 3 N 5 multilayers journal, January 2020

Two-dimensional MoS 2 /GaN van der Waals heterostructures: tunable direct band alignments and excitonic optical properties for photovoltaic applications journal, December 2019

Generalized Gradient Approximation Made Simple
journal, October 1996

Implanting Germanium into Graphene
journal, April 2018

Giant Spin-Orbit Bowing in ${GaAs}_{1 - x} {Bi}_{x}$
journal, August 2006

Strain-Modulated Bandgap and Piezo-Resistive Effect in Black Phosphorus Field-Effect Transistors
journal, September 2017

Growth of Quasi-Free-Standing Single-Layer Blue Phosphorus on Tellurium Monolayer Functionalized Au(111)
journal, April 2017

Observation of tunable band gap and anisotropic Dirac semimetal state in black phosphorus
journal, August 2015

Tunable Chemical Sensing Performance of Black Phosphorus by Controlled Functionalization with Noble Metals
journal, August 2017

Electron Doping of Ultrathin Black Phosphorus with Cu Adatoms
journal, March 2016

QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials
journal, September 2009

Strong Valence-Band Offset Bowing of ${ZnO}_{1 - x} S_{x}$ Enhances $p$ -Type Nitrogen Doping of ZnO-like Alloys
journal, October 2006

Giant and Composition-Dependent Optical Bowing Coefficient in GaAsN Alloys
journal, January 1996

Strain-Engineering the Anisotropic Electrical Conductance of Few-Layer Black Phosphorus
journal, April 2014

GeSe Thin-Film Solar Cells Fabricated by Self-Regulated Rapid Thermal Sublimation
journal, January 2017

Tunable Optical Gap at a Fixed Lattice Constant in Group-IV Semiconductor Alloys
journal, March 2009

One-dimensional phosphorus chain and two-dimensional blue phosphorene grown on Au(111) by molecular-beam epitaxy
journal, November 2017

Silicene field-effect transistors operating at room temperature
journal, February 2015

Alloy Engineering of Defect Properties in Semiconductors: Suppression of Deep Levels in Transition-Metal Dichalcogenides
journal, September 2015

Single-Layer Single-Crystalline SnSe Nanosheets
journal, January 2013

Strain-Induced Gap Modification in Black Phosphorus
journal, May 2014

Semiconducting Layered Blue Phosphorus: A Computational Study
journal, May 2014

Coulomb engineering of the bandgap and excitons in two-dimensional materials
journal, May 2017

Two-Dimensional SnS: A Phosphorene Analogue with Strong In-Plane Electronic Anisotropy
journal, February 2017

Light-Induced Exciton Spin Hall Effect in van der Waals Heterostructures
journal, October 2015

Sodium-Induced Reordering of Atomic Stacks in Black Phosphorus
journal, January 2017

Synthesis and Crystallographic Analysis of Shape-Controlled SnS Nanocrystal Photocatalysts: Evidence for a Pseudotetragonal Structural Modification
journal, July 2013

Band Gap Modulated by Electronic Superlattice in Blue Phosphorene
journal, April 2018

Epitaxial Growth of Single Layer Blue Phosphorus: A New Phase of Two-Dimensional Phosphorus
journal, July 2016

Quasiparticle excitations in ${GaAs}_{1 - x}$ $N_{x}$ and ${AlAs}_{1 - x}$ $N_{x}$ ordered alloys
journal, February 1995

Magic Carbon Clusters in the Chemical Vapor Deposition Growth of Graphene
journal, December 2011

Coulomb engineering of the bandgap and excitons in two-dimensional materials
text, January 2017

Semiconducting layered blue phosphorus: A computational study
text, January 2014

One-dimensional phosphorus chain and two-dimensional blue phosphorene grown on Au(111) by molecular-beam epitaxy
text, January 2017

Metal-free highly efficient photocatalysts for overall water splitting: C ₃ N ₅ multilayers
journal, January 2020

Two-dimensional MoS ₂ /GaN van der Waals heterostructures: tunable direct band alignments and excitonic optical properties for photovoltaic applications
journal, December 2019