Selective binding of (thio)sulfate and phosphate in water by quaternary ammonium functionalized oligo-ureas

Huang, Zhe; Jia, Chuandong; Wu, Biao; Jansone-Popova, Santa; Seipp, Charles A.; Custelcean, Radu

doi:10.1039/c8cc09550g

Title: Selective binding of (thio)sulfate and phosphate in water by quaternary ammonium functionalized oligo-ureas

Journal Article · 14 January 2019 · ChemComm

DOI: https://doi.org/10.1039/c8cc09550g · OSTI ID:1492147

Huang, Zhe ^[1];

^[1];

^[2];

^[2]

Northwest Univ., Xi’an (China). Key Lab. of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

Recognition of (thio)sulfate and phosphate in aqueous solutions has been demonstrated by using oligo-urea-based receptors functionalized with quaternary ammonium groups. The ammonium groups allow for increased aqueous solubility while simultaneously providing positive coulombic interactions and stronger hydrogen bonding through an inductive effect. This simple and generally applicable modification provides an effective way to bolster the anion binding and water solubility of oligo-urea-based receptors. Finally, with a water soluble receptor 2, selective binding of adenosine phosphates was achieved at physiological pH.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1492147

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 12 Vol. 55; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Selective binding of (thio)sulfate and phosphate in water by quaternary ammonium functionalized oligo-ureas

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