Selective binding of (thio)sulfate and phosphate in water by quaternary ammonium functionalized oligo-ureas
Abstract
Recognition of (thio)sulfate and phosphate in aqueous solutions has been demonstrated by using oligo-urea-based receptors functionalized with quaternary ammonium groups. The ammonium groups allow for increased aqueous solubility while simultaneously providing positive coulombic interactions and stronger hydrogen bonding through an inductive effect. This simple and generally applicable modification provides an effective way to bolster the anion binding and water solubility of oligo-urea-based receptors. Finally, with a water soluble receptor 2, selective binding of adenosine phosphates was achieved at physiological pH.
- Authors:
-
[1];
[1];
[2];
[2];
[2]
- Northwest Univ., Xi’an (China). Key Lab. of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1492147
- Alternate Identifier(s):
- OSTI ID: 1491430
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 55; Journal Issue: 12; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Huang, Zhe, Jia, Chuandong, Wu, Biao, Jansone-Popova, Santa, Seipp, Charles A., and Custelcean, Radu. Selective binding of (thio)sulfate and phosphate in water by quaternary ammonium functionalized oligo-ureas. United States: N. p., 2019.
Web. doi:10.1039/c8cc09550g.
Huang, Zhe, Jia, Chuandong, Wu, Biao, Jansone-Popova, Santa, Seipp, Charles A., & Custelcean, Radu. Selective binding of (thio)sulfate and phosphate in water by quaternary ammonium functionalized oligo-ureas. United States. https://doi.org/10.1039/c8cc09550g
Huang, Zhe, Jia, Chuandong, Wu, Biao, Jansone-Popova, Santa, Seipp, Charles A., and Custelcean, Radu. Mon .
"Selective binding of (thio)sulfate and phosphate in water by quaternary ammonium functionalized oligo-ureas". United States. https://doi.org/10.1039/c8cc09550g. https://www.osti.gov/servlets/purl/1492147.
@article{osti_1492147,
title = {Selective binding of (thio)sulfate and phosphate in water by quaternary ammonium functionalized oligo-ureas},
author = {Huang, Zhe and Jia, Chuandong and Wu, Biao and Jansone-Popova, Santa and Seipp, Charles A. and Custelcean, Radu},
abstractNote = {Recognition of (thio)sulfate and phosphate in aqueous solutions has been demonstrated by using oligo-urea-based receptors functionalized with quaternary ammonium groups. The ammonium groups allow for increased aqueous solubility while simultaneously providing positive coulombic interactions and stronger hydrogen bonding through an inductive effect. This simple and generally applicable modification provides an effective way to bolster the anion binding and water solubility of oligo-urea-based receptors. Finally, with a water soluble receptor 2, selective binding of adenosine phosphates was achieved at physiological pH.},
doi = {10.1039/c8cc09550g},
journal = {ChemComm},
number = 12,
volume = 55,
place = {United States},
year = {Mon Jan 14 00:00:00 EST 2019},
month = {Mon Jan 14 00:00:00 EST 2019}
}
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